Lipids are esters of
long chain fatty acids and alcohols. They are waxy or oily substance present
in all living organism. They are non-polar (hydrophobic) compounds, soluble in
organic solvents (chloroform, benzene, ether etc.). Fatty acids have a long
hydrocarbon chain with a terminal carboxylic acid group.
General
formula: CH3 (CH2) n
COOH where n is an even number
Even though lipids exhibit a variety of structures, they
have certain common characters:
- All lipids are formed of Carbon (C), Hydrogen (H) and sometime Oxygen (O).
- Small amount of phosphorus, nitrogen and sulfur are also present in some lipids.
- They are insoluble in water but soluble in non polar solvents like benzene and chloroform.
Classification of Lipids |
Lipids are commonly subdivided into 4 main groups
1. Fatty acids (saturated & unsaturated)
2. Glycerids(Glycerol containing lipids)
3. Nonglyceride (Sphingolipids, steroids, waxes)
4. Complex lipids (Lipo proteins)
-
Functions:
1. Major source of energy: Fats form the
highly concentrated source of energy for man. Energy is released by the
oxidative break down of fat if necessary. They are producing more than twice as
much energy per gram as do the carbohydrates.
2. Food reserves: The neutral fats form
the important food reserves in both plants and animals.
In plants, they
are stored in the seeds to provide nourishment for the embryo during
germination.
Eg: Oil seeds
like ground nut, mustard, coconut and castor. The oil i extracted from the
seeds is used for cooking and other purposes.
3. Protection and Insulation: In animals
they are stored in adipose cells. Deposited beneath the skin and around the
internal organs prevent the loss of body heat. They are act as shock absorbing
cushions around the eye ball, kidney and gonads. About four percentage of the
total body fat is reserved for this critical function.
4. Cell membrane structural components: Phospholipids,
Glycolipids and sterols form the important components of biomembranes. Some
glycolipids are found in myelin sheath. Waxes form a protective coat on plant
parts and animal furs.
5. Hormones: Cholesterol IS used in the
synthesis of steroid hormones, vitamin D and bile salts. Prostaglandins are
hormone like compounds derived from fatty acids like arachidonic acid (20:4).
6. Vitamins: The lipid soluble
vitamins (A,D E and K) play a major role in the regulation of several critical
biological processes, including blood clotting and vision.
7. Vitamin absorption: Dietary fat serves as a carrier of the lipid soluble
vitamins. All are transported into cells of the small intestine in association
with fat molecules. Therefore a diet that is too low in fat can result in a
deficiency of these four vitamins.