Injection Molding
2.810
T. Gutowski
D. Roylance
Short history of plastics
1862
1866
1891
1907
1913
1926
1933
1938
1939
1957
1967
first synthetic plastic
Celluloid
Rayon
Bakelite
Cellophane
PVC
Polyethylene
Teflon
Nylon stockings
velcro
The Graduate
Ref Kalpakjian and Schmid
McCrum, Buckley, Buckknall
Outline
Basic operation
Cycle time and heat transfer
Flow and solidification
Part design
Tooling
New developments
Environment
30 ton, 1.5 oz (45 cm3) Engel
Injection Molding Machine
for wheel fabrication
Process & machine schematics
*
Schematic of thermoplastic Injection molding machine
* Source: http://www.idsa-mp.org/proc/plastic/injection/injection_process.htm
Process Operation
Temperature: barrel zones, tool, die zone
Pressures: injection max, hold
Times: injection, hold, tool opening
Shot size: screw travel
Processing window
Temp.
Thermal
degradation
Flash
Shortshot
Melt
Pressure
Typical pressure/temperature cycle
*
Time(sec)
Time(sec)
Cooling time generally dominates cycle time
tcool
* Source: http://islnotes.cps.msu.edu/trp/inj/inj_time.html
half thickness
10 3 cm 2 sec for polymers
Calculate clamp force, & shot size
F=P X A = 420 tons
3.8 lbs = 2245 cm3
=75 oz
Actual ; 2 cavity 800 ton
Clamp force and machine cost
Heat transfer
Note; Tool > polymer
1-dimensional heat conduction equation :
qx
qx + qx
Fouriers law
Boundary Conditions:
q
( c T )xy x xy
t
x
T
q x k
x
T
2T
T
2T
c
k 2
or
2
t
x
t
x
1st kind
2nd kind
3rd kind
T ( x x' ) constant
T
k
( x x' ) constant
x
T
k
( x x' ) h (T T )
x
The boundary condition of 1st kind applies to injection molding since the
tool is often maintained at a constant temperature
Heat transfer
Tii
t
TW
-L
+L
Let Lch = H/2 (half thickness) = L ; tch = L2/ ;
Tch = Ti TW (initial temp. wall temp.)
T TW
x
t
; 1; FO 2
Non-dimensionalize:
Ti TW
L
L
Dimensionless equation:
Initial condition
Boundary condition
Separation of variables ;
matching B.C.; matching I.C.
2
2
FO
FO 0
0
2
0
0
( , FO ) f ( FO ) g ( )
Temperature in a slab
Centerline, = 0.1, Fo = t/L2 = 1
See Heat Transfer Text
By Lienhard on line
Bi-1 =k/hL
Reynolds Number
Reynolds Number:
V2
inertia
VL
L
Re
2 viscous
L
For typical injection molding
1g cm 3 10 3 N m 4 s 2 ; LZ 10 3 m thickness
1
Part length 10
V
;
Fill time
1s
For Die casting
10 3 N s m 2
3 103 101 103
Re
300
3
10
* Source: http://www.idsa-mp.org/proc/plastic/injection/injection_process.htm
Re 104
Viscous Shearing of Fluids
F
F/A
v
h
F v
A h
v/h
Newtonian Viscosity
Generalization:
( )
: shear rate
Injection molding
Shear Thinning
~ 1 sec-1 for PE
Typical shear rate for
Polymer processes (sec)-1
Extrusion
Calendering
Injection molding
Comp. Molding
102~103
10~102
103~104
1~10
Viscous Heating
P
F v F v
v
:
h
Vol Vol A h
Rate of Heating
= Rate of Viscous Work
Rate of Temperature rise
Rate of Conduction out
cp
dT
v
dt
h
or
dT
v
dt c p h
dT
k d 2T
k T
~
dt c p dx 2 c p h 2
Viscous heating v 2
Conduction
kT
Brinkman number
For injection molding, order of magnitude ~ 0.1 to 10
Non-Isothermal Flow
Flow rate: 1/t ~V/Lx
Pclet N o.
Heat transfer rate: 1/t ~a/(Lz/2)2
Flow rate
V L2z
1 VLz Lz
~
Heat xfer rate 4 Lx 4 Lx
Small value
=> Short shot
For injection molding
Flow rate
1 10cm / s 0.1cm 0.1cm
~
2.5
3
2
Heat xfer rate 4 10 cm / s
10cm
For Die casting of aluminum
Flow rate
1 10cm / s 0.1cm 0.1cm
2
~
10
Heat xfer rate 4 0.3cm 2 / s
10cm
* Very small, therefore it requires thick runners
Non-Isothermal Flow
Flow rate: 1/t ~V/Lx
Pclet N o.
Heat transfer rate: 1/t ~a/(Lz/2)2
Flow rate
V L2z
1 VLz Lz
~
Heat xfer rate 4 Lx 4 Lx
Small value
=> Short shot
For injection molding
Flow rate
1 10cm / s 0.1cm 0.1cm
~
2.5
3
2
Heat xfer rate 4 10 cm / s
10cm
For Die casting of aluminum
Flow rate
1 10cm / s 0.1cm 0.1cm
2
~
10
Heat xfer rate 4 0.3cm 2 / s
10cm
Very small value for aluminum requires thicker runners
Injection mold
die cast mold
Fountain Flow
*
**
* Source: http://islnotes.cps.msu.edu/trp/inj/flw_froz.html ; ** Z. Tadmore and C. Gogos, Principles of Polymer Processing
Shrinkage distributions
sample
Transverse direction
V=3.5cm/s
V=8cm/s
* Source: G. Menges and W. Wubken, Influence of processing conditions on Molecular Orientation in Injection Molds
Gate Location and Warping
Sprue
2.0
60
2.0
Before shrinkage
1.96
Shrinkage
Direction of flow 0.020 in/in
Perpendicular to flow 0.012
60.32
1.976
After shrinkage
Air entrapment
Gate
Center gate: radial flow severe distortion
Diagonal gate: radial flow twisting
Edge gate: warp free, air entrapment
End gates: linear flow minimum warping
Effects of mold temperature and
pressure on shrinkage
LDPE
LDPE
0.030
PP
0.025
Acetal
0.025
0.020
Nylon 6/6
0.020
Shrinkage
Shrinkage
0.030
0.015
0.010
0.015
Acetal
PP with
flow
PP across
flow
0.010
0.005
0.005
Nylon
6/6
PMMA
PMMA
0.000
0.000
100
120
140
160
180
200
Mold Temperature (F)
220
240
6000
10000
8000
14000
12000
18000
16000
Pressure on injection plunger (psi)
Where would you gate this part?
Weld line, Sink mark
Gate
Weld line
Mold Filling
Solidified part
Sink mark
* Source: http://www.idsa-mp.org/proc/plastic/injection/injection_design_7.htm
Basic rules in designing ribs
to minimize sink marks
Injection Molding
*
* Source: http://www.idsa-mp.org/proc/plastic/injection/injection_design_2.htm
Where is injection
molding?
Controlled by shrinkage
and warping. Hence,
polymer, fillers, mold
geometry and processing
conditions can all
influence the final
tolerance.
Shrinkage is of order
10-100/1000 for unfilled
and
1-10/1000 for filled across
the thickness
Effects of mold pressure on
shrinkage
LDPE
0.030
Acetal
PP with
flow
0.025
Shrinkage
0.020
0.015
PP across
flow
Nylon
6/6
0.010
0.005
PMMA
0.000
6000
10000
8000
14000
12000
18000
16000
Pressure on injection plunger (psi)
Tooling Basics
Sprue
Nozzle
Core Plate
Cavity Plate
Moulding
Core
Cavity
Cavity
Gate
Runner
Melt Delivery
Basic mould consisting of cavity and core plate
Tooling for a plastic cup
Nozzle
Knob
Runner
Cavity
Part
Stripper plate
Core
Tooling for a plastic cup
Nozzle
Nozzle
Knob
Runner
Cavity
Runner
Part
Cavity
Cavity
Part
Part
Stripper
plate
Tooling
*
*
*
*
**
* Source: http://www.idsa-mp.org/proc/plastic/injection/; ** http://www.hzs.co.jp/english/products/e_trainer/mold/basic/basic.htm (E-trainer by HZS Co.,Ltd.)
Tooling Alternatives
Kalpakjian & Schmid
Part design rules
Simple shapes to reduce tooling cost
No undercuts, etc.
Draft angle to remove part
In some cases, small angles (1/4) will do
Problem for gears
Even wall thickness
Minimum wall thickness ~ 0.025 in
Avoid sharp corners
Hide weld lines
Holes may be molded 2/3 of the way through the
wall only, with final drilling to eliminate weld lines
New developments- Gas
assisted injection molding
New developments ; injection
molding with cores
Injection Molded Housing
Cores used in Injection Molding
Cores and
Part Molded in Clear Plastic
Micro injection molding
Micro embossing
Replacing serial processes with parallel processes
at small scales
B. Kim UMass
Environmental issues
System boundaries
Polymer production
Compounding
Machine types
Out gassing & energy during processing
CRADLE
Additives
Naphtha, Oil.
Natural Gas
Ancilliary Raw
Materials
Compounder
Thermoplastic Production
(Boustead)
Polymer
Delivery
Internal Transport
Drying
Extrusion
Pelletizing
Emissions
to air,
water &
land
Building (lights,heating, ect..)
Emissions to
air, water, &
land
Polymer
Delivery
Injection Molder
Energy Production Industry
Internal Transport
Drying
Injection Molding
Emissions to air, water, & land
Scrap
Anciliary Raw
Materials
Emissions
to air,
water &
land
Building (lights,heating, ect..)
Packaging
Note to Reader:
= Focus of this Analysis
FACTORY GATE
1 kg of Injection Molded Polymer
= Also included in the Paper
Service Period
Waste Management
Polymer Production
Largest Player in the Injection Molding LCI
What is a polymer:
How much energy does it take to make 1 kg of polymer = a lot !!!
Sources
Boustead
Ashby
Patel
Kindler/Nickles
[Patel 1999]
Worrell et al.
[Patel 1999]
E3 Handbook
[OIT 1997]
Energieweb
HDPE
76.56
111.50
-------
LLDPE
77.79
-------------
LDPE
73.55
92.00
64.60
PP
72.49
111.50
-------
PVC
58.41
79.50
53.20
PS
86.46
118.00
70.80
PC
115.45
------80.30
PET
77.14
------59.40
-------
-------
71.00
-------
53.00
81.00
107.00
96.00
-------
-------
67.80
-------
52.40
82.70
78.20
131.65
121.18
136.07
126.07
33.24
-------
-------
-------
80.00
-------
68.00
64.00
57.00
84.00
-------
81.00
Values are in MJ per kg of polymer produced. Thiriez 06
Compounding - extrusion
An extruder is used to mix additives with a polymer base, to
bestow the polymer with the required characteristics.
Similar to an injection molding machine, but without a mold
and continuous production.
Thus it has a similar energy consumption profile.
Environmentally Unfriendly Additives:
Fluorinated blowing agents (GHGs)
Phalates (some toxic to human
liver, kidney and testicles)
Organotin stabilizers (toxic and
damage marine wildlife)
Injection Molding Process
Source:
http://cache.husky.ca/pdf/br
ochures/br-hylectric03a.pdf
Machine types: Hydraulic, electric, hydro-electric
All-electrics have very low fixed energy costs (small
idling power). SEC is constant as throughput
increases.
SEC pv
9
8
7
SEC (MJ/kg)
All-Electric - 85 tons
6
Hydraulic - 85 tons
5
Material: PP
4
3
2
1
0
0
10
Throughput (kg/hr)
15
20
Source: [Thiriez]
For Hydraulics and Hybrids as throughput
increases, SEC k.
Variable Pump Hydraulic Injection Molding Machines.
HP 52
HP 05
HP 06
HP 57
HP 001
Low Enthalpy - Raise Resin to Inj. Temp - PVC
High Enthalpy - Raise Resin to Inj. Temp - HDPE
8
7
SEC (MJ/kg)
6
5
4
3
2
1
0
0
50
100
Throughput (kg/hr)
150
Does not account for the electric grid.
200
Source: [Thiriez]
Enthalpy value to melt plastics is just 0.1 to 0.7 MJ/kg !!!
All-electric vs. hybrid
Ton
Buildup
120
Power Required (kW)
Cool
100
Clamp open-close
Plasticize
Inject high
80
ton
60
Inject low
40
20
0
0
6
7
8
9
10
11
Time (seconds)
MM 550 Hybrid
NT 440 All-Electric
12
13
14
Source: [Thiriez]
The hydraulic plot would be even higher than the hybrid curve
Driers
Used to dry internal moisture in hygroscopic polymers and external
moisture in non-hygroscopic ones.
It is done before extruding and injection molding.
Specific Power Consumption
(MJ/kg)
1.8
Power Trendline
W300
1.6
R = 0.8225
W400
1.4
W200
1.2
1
0.8
W150
0.6
W3200
W1600
W600
0.4
W5000
W800
0.2
W1000
W2400
0
0
500
1000
1500
2000
2500
3000
3500
Throughput (kg/hr)
Source: [Thiriez]
Same as
P0
P E
SEC
k
m m
m
LCI Summarized Results
ENERGY CONSUMPTION BY STAGE in MJ/kg of shot
Thermoplastic Production
avg
low
high
HDPE LLDPE LDPE
89.8
79.7
73.1
77.9
79.7
64.6
111.5 79.7
92.0
PP
83.0
64.0
111.5
PVC
59.2
52.4
79.5
PS
87.2
70.8
118.0
Polymer Delivery
Extras
Generic by Amount
PET
Consumed Inj. Molded PC
81.2
74.6
95.7
78.8
69.7
62.8
78.2
59.4
102.7
97.6
117.4
96.0
avg
low
high
0.19
0.12
0.24
Compounder
avg
low
high
Subtotal
Internal
Transport
0.09
--------avg
low
high
Drying
0.70
0.30
1.62
Extrusion
3.57
1.82
5.00
Building (lights,
heating, ect..)
0.99
---------
Pelletizing
0.16
0.06
0.31
5.51
3.25
8.01
Polymer Delivery
avg
low
high
0.19
0.12
0.24
Injection Molder
avg
low
high
Internal
Transport
0.04
---------
avg
low
high
Subtotal
TOTAL w/
Generic Inj.
Molded
Polymer
TOTAL w/o
Polymer Prod
Notes
Drying
Injection Molding
(look below)
Scrap (Granulating)
0.70
0.30
1.62
0.05
0.03
0.12
Building (lights,
heating, ect..)
0.99
---------
Injection Molding - Choose One
Hydraulic
Hybrid
All-Electric
11.29
5.56
4.89
3.99
3.11
1.80
69.79
8.45
15.29
avg
low
high
13.08
5.35
72.57
7.35
4.47
11.22
6.68
3.17
18.06
avg
low
high
Hydraulic
93.60
71.65
178.68
Hybrid
87.87
70.77
117.34
All-Electric
87.20
69.46
124.18
avg
low
high
18.97
8.84
81.04
13.24
7.96
19.70
12.57
6.66
26.54
Drying - the values presented assume no knowledge of the materials' hygroscopia. In order words, they are
averages between hygroscopic and non-hygroscopic values. For hygroscopic materials such as PC and PET
additional drying energy is needed (0.65 MJ/kg in the case of PC and 0.52 MJ/kg in the case of PET)
Pelletizing - in the case of pelletizing an extra 0.3 MJ/kg is needed for PP
Granulating - a scarp rate of 10 % is assumed
Source: [Thiriez]
Energy Production Industry
United States Electricity Composition by Source
Hydro
7.1%
Nuclear
19.6%
Other
0.0%
Coal
50.7%
Oil
3.1%
Gas
16.7%
The Grid is about 30% efficient
For every MJ of electricity we also get:
171.94 g of CO2
0.76 g of SO2
0.31 g of NOx
6.24 g of CH4
0.0032 mg of Hg
Waste/
Renewable
2.2%
Scale
HDPE,
LDPE,
LLDPE,
PP, PS,
PVC
Compounder and Injection
Molder
6 Main Thermoplastics
All Plastics
U.S.
GJ/year
9.34E+07
2.06E+08
Global
GJ/year
4.01E+08
6.68E+08
The Injection Molding Industry in the U.S. consumes 6.19 x
107 GJ of electricity (or 2.06 x 108 GJ in total energy).
This is larger than the entire electric production of some
small countries.
In such a scale imagine what a 0.1 % energy savings mean !!!
Do Polymers get recycled?
Ref Ashby 2009
The printer goes in the hopper
And comes out.
Readings
Tadmore and Gogos
Molding and Casting pp 584 -610
Boothroyd Dewhurst
Design for Injection Molding pp 319 - 359
Kalpakjian Ch 7 & 19
Thiriez et al, "An Environmental Analysis of Injection
Molding
"Injection Molding Case Study (Gas Assist)