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Solvent Properties and Thresholds Data

This document provides a table summarizing various solvents including their chemical formulas, boiling points, melting points, densities, solubility in water, relative polarities, eluant strengths, and threshold limits. Over 50 common solvents are listed with their key chemical and physical properties.

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0% found this document useful (0 votes)
315 views2 pages

Solvent Properties and Thresholds Data

This document provides a table summarizing various solvents including their chemical formulas, boiling points, melting points, densities, solubility in water, relative polarities, eluant strengths, and threshold limits. Over 50 common solvents are listed with their key chemical and physical properties.

Uploaded by

ozpozp
Copyright
© Attribution Non-Commercial (BY-NC)
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Solvent formula boiling melting density 

solubility in relative eluant threshold


point (oC) point (oC)  (g/mL) H2O1  (g/100g) polarity2 strength3 limits4 (ppm

acetic acid C2H4O2 118 16.6 1.049 M 0.648 >1 10


acetone C3H6O 56.2 -94.3 0.786 M 0.355 0.56 500
acetonitrile C2H3N 81.6 -46 0.786 M 0.460 0.65 20
acetyl acetone C5H8O2 140.4 -23 0.975 16 0.571    
2-aminoethanol C2H7NO 170.9 10.5 1.018 M 0.651   3
aniline C6H7N 184.4 -6.0 1.022 3.4 0.420   2
anisole C7H8O 153.7 -37.5 0.996 0.10 0.198    
benzene C6H6 80.1 5.5 0.879 0.18 0.111 0.32 0.5
benzonitrile C7H5N 205 -13 0.996 0.2 0.333   10
benzyl alcohol C7H8O 205.4 -15.3 1.042 3.5 0.608    
1-butanol C4H10O 117.6 -89.5 0.81 7.7 0.586   20

2-butanol C4H10O 99.5 -114.7 0.808 18.1 0.506   100


i-butanol C4H10O 107.9 -108.2 0.803 8.5 0.552    
2-butanone C4H8O 79.6 -86.3 0.805 25.6 0.327 0.51 200
t-butyl alcohol  C4H10O 82.2 25.5 0.786 M 0.389   100
carbon disulfide CS2 46.3 -111.6 1.263 0.2 0.065 0.15  10
carbon tetrachloride CCl4 76.7 -22.4 1.594 0.08  0.052 0.18 5
chlorobenzene C6H5Cl 132 -45.6 1.106 0.05 0.188 0.30 10
chloroform  CHCl3 61.2 -63.5 1.498 0.8 0.259   10
cyclohexane C6H12 80.7 6.6 0.779 0.005 0.006 0.04 100
cyclohexanol C6H12O 161.1 25.2 0.962 4.2 0.509   50
cyclohexanone C6H10O 155.6 -16.4 0.948 2.3 0.281   25
di-n-butylphthalate C16H22O4 340 -35 1.049 0.0011 0.272    
1,1-dichloroethane C2H4Cl2 57.3 -97.0 1.176 0.5 0.269   100
diethylene glycol C4H10O3 245 -10 1.118 M 0.713    
diglyme C6H14O3 162 -64 0.945 M 0.244    
dimethoxyethane (glyme) C4H10O2 85 -58 0.868 M 0.231    
N,N-dimethylaniline C8H11N 194.2 2.4 0.956 0.14 0.179    
dimethylformamide (DMF) C3H7NO 153 -61 0.944 M 0.386   10
dimethylphthalate C10H10O4 283.8 1 1.190 0.43 0.309    
dimethylsulfoxide (DMSO) C2H6OS 189 18.4 1.092 M 0.444 0.75  
dioxane  C4H8O2 101.1 11.8 1.033 M 0.164 0.56 20
ethanol  C2H6O 78.5 -114.1 0.789 M 0.654 0.88 100
ether C4H10O 34.6 -116.3 0.713 7.5 0.117 0.38 400
ethyl acetate C4H8O2 77 -83.6 0.894 8.7 0.228 0.58 400
ethyl acetoacetate C6H10O3 180.4 -80 1.028 2.9 0.577    
ethyl benzoate C9H10O2 213 -34.6 1.047 0.07 0.228    
ethylene glycol  C2H6O2 197 -13 1.115 M 0.790 1.11  
glycerin C3H8O3 290 17.8 1.261 M 0.812    
heptane C7H16 98 -90.6 0.684 0.0003 0.012   400
1-heptanol C7H16O 176.4 -35 0.819 0.17 0.549    
hexane C6H14 69 -95 0.655 0.0014 0.009 0.01 50
1-hexanol C6H14O 158 -46.7 0.814 0.59 0.559    
methanol CH4O 64.6 -98 0.791 M 0.762 0.95 200
methyl acetate C3H6O2 56.9 -98.1  0.933 24.4 0.253    200
methyl t-butyl ether (MTBE) C5H12O 55.2 -109 0.741 4.8 0.124 0.20  
methylene chloride CH2Cl2 39.8 -96.7 1.326 1.32 0.309 0.42 50
1-octanol C8H18O 194.4 -15 0.827 0.096 0.537    
pentane C5H12 36.1 -129.7 0.626 0.004  0.009 0.00 600
1-pentanol C5H12O 138.0 -78.2 0.814 2.2 0.568    
2-pentanol C5H12O 119.0 -50 0.810 4.5 0.488    
3-pentanol C5H12O 115.3 -8 0.821 5.1 0.463    
2-pentanone C5H10O 102.3 -76.9 0.809 4.3 0.321    
3-pentanone C5H12O 101.7 -39.8 0.814 3.4 0.265   200
1-propanol C3H8O 97 -126 0.803 M 0.617 0.82  
2-propanol C3H8O 82.4 -88.5 0.785 M 0.546 0.82 400
pyridine C5H5N 115.5 -42 0.982 M 0.302 0.71 5
tetrahydrofuran(THF) C4H8O 66 -108.4 0.886 30 0.207 0.57 200
toluene C7H8 110.6 -93 0.867 0.05 0.099 0.29 50
water H2O 100.00 0.00 0.998 M 1.000 >>1  
water, heavy  D2O 101.3 4 1.107 M 0.991    
p-xylene C8H10 138.3 13.3 0.861 0.02 0.074 0.26 100

1    M = miscible.
2    The values for relative polarity are normalized from measurements of solvent shifts of absorption spectra and were
      extracted from Christian Reichardt, Solvents and Solvent Effects in Organic Chemistry, Wiley-VCH Publishers, 3rd ed., 2003.
3     Snyder's empirical eluant strength parameter for alumina.  Extracted from Reichardt, page 495.
4   Threshold limits for exposure.  Extracted from Reichardt, pages 501-502.

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