SAFETY DATA SHEET

Issue date 23-Jan-2017

23-Mar-2015 23-Jan-2017
Revision Date 25-Jan-2016
25-Apr-2016 1
Version 3

Section 1: PRODUCT AND COMPANY IDENTIFICATION

Product identifier
Product name ThreeBond 1211

Recommended use of the chemical and restrictions on use

Recommended use Adhesive, Sealant

Details of the supplier of the safety data sheet

Manufacturer Department in charge & Address
Threebond
ThreeBond Singapore Pte.Ltd
Fine Chemical Co., Ltd. Australia
ProductionBranch
Engineering Division
1-1 Oyama-cho,
Factory Midori-ku
: 2/38 Jellico dve Scoresby
Sagamihara-shi,
3179 Kanagawa,
Melbourne Victoria Japan
Australia
Tel : 61-3-9753-2522
Emergency telephone number Fax : 61-3-9753-2566
+81-42-774-1333
Tel : 0417-350-027 (Mr.Wesley Mallett)

Section 2: HAZARDS IDENTIFICATION

Classification of the substance or mixture
Acute toxicity - Dermal Category 4
Skin sensitization Category 1
Carcinogenicity Category 2
Specific target organ toxicity (repeated exposure) Category 2
Category 2 blood forming system.

Label elements

Signal word Warning

Hazard statements
H312 - Harmful in contact with skin
H317 - May cause an allergic skin reaction
H351 - Suspected of causing cancer
H373 - May cause damage to organs through prolonged or repeated exposure
May cause damage to the following organs through prolonged or repeated exposure: blood forming system.

Precautionary Statements - Prevention

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Precautionary Statements - Response

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Precautionary Statements - Storage
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Precautionary Statements - Disposal
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Other hazards
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Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

Effective June 1, 2016, regarding Japan’s Industrial Safety and Health Law’s
Single substance or mixture
Single substance or mixture Mixture “Notifiable Dangerous and Harmful”, target substances will be subjected to risk
Mixture
2-Butanone, assessment
oxime; Generated in accordance with Japan’s Industrial
during polymerization reaction.Safety and Health Law’s “Harmful
2-Butanone, oxime; Generated during polymerization reaction.
Substances Whose Names Are to be Indicated on the Label.”
Chemical name Weight-% ENCS ISHL No. CAS No.
Silicone resin 80-90 - - -
Titanium dioxide (IV) <2 (5)-5225,(1)-558 - 13463-67-7
Organic tin compound <1 - - -
Toluene <1 (3)-2 - 108-88-3
Silica 10-20 - - -
Methyl ethyl ketone - - - -
oxime

Industrial Safety and Health Law

Law Name Chemical Name in Regulation Ordinance Number
Notifiable Substances (Law Art.57-2, Titanium(IV) oxide 191
Enforcement Oder Art.18-2 Attached Table No.9)
Notifiable Substances (Law Art.57-2, Silica 312
Enforcement Oder Art.18-2 Attached Table No.9)
Notifiable Substances (Law Art.57-2, Tin and its compounds 322
Enforcement Oder Art.18-2 Attached Table No.9)
Notifiable Substances (Law Art.57-2, Toluene 407
Enforcement Oder Art.18-2 Attached Table No.9)

Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc
Law Name Chemical Name in Regulation Ordinance Number
Priority Assessment Chemical Substances (Law Toluene 46
Article 2, Para.5)

Section 4: FIRST AID MEASURES

INHALATION Remove to fresh air. Seek immediate medical attention/advice.

Skin contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. In the case of skin irritation or allergic reactions see a physician.

Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing Seek immediate medical attention/advice.

INGESTION Rinse mouth. Get medical attention.

Section 5: FIRE FIGHTING MEASURES

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Suitable extinguishing media Water spray (fog) Carbon dioxide (CO2) Extinguishing powder Alcohol resistant foam Sand

Specific hazards arising from the May generate irritate, harmful gas.
chemical

Special extinguishing media Wear protection gear and extinguish from windward.

Section 6: ACCIDENTAL RELEASE MEASURES

Personal precautions Wear appropriate protection gear (Refer to Section 8) and avoid eye and skin contact.

Environmental precautions Keep out of waterways. Avoid release to the environment.

Methods for containment In case of small spill, absorb the spill in dry sand, soil or cloth and keep in closed container.
In case of large spill, surround the spill by bank to prevent from leakage, and collect the spill
after it is moved to safety place.

Prevention of secondary hazards Keep ignition source away from spill.

Section 7: HANDLING AND STORAGE

Handling
Precautions for safe handling
Advice on safe handling Take equipment measures listed in Section 8. Wear protection gear.

Local and general ventilation Take equipment measures listed in Section 8. Wear protection gear.

Storage
Storage conditions Close lid. Avoid direct sun light and ignition source. Keep appropriate temperature.

Material of vessels and Keep this product in original container. Do not put it back in the container.
packaging

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure guidelines

Chemical name Japan ISHL Working Environmental ACGIH TLV

Evaluation Standards -
Administrative Control Levels
Titanium dioxide (IV) TWA: 0.3 mg/m3 - TWA: 10 mg/m3
Toluene TWA: 50 ppm ISHL/ACL: 20 ppm TWA: 20 ppm
TWA: 188 mg/m3
Skin
ISHL/ACL: 20 ppm

Engineering controls Install local ventilation or seal source of substances. Install safety shower, hand wash, and
eye wash station. Clearly indicate the location.

Personal protective equipment

O Respiratory protection In case of inadequate ventilation wear respiratory protection

O Hand protection Wear appropriate protection glove (Made from non-permeable material such as
polyethylene, rubber)
O Eye/face protection Wear safety glasses with side shields (or goggles)
O Skin and body protection Wear protection apron, protection boots. Wear long sleeve cloth.

Other information Wash hands thoroughly after handling. When using do not eat, drink or smoke.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES

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Physical state Liquid

Odor Distinct odor
Color White

Property Values Remarks

pH No data available
Melting point/freezing point No data available
Boiling point / boiling range No data available
Flash point 140 °C
Evaporation rate No data available
Flammability (solid,
gas)
Flammability limit in air
Upper flammability limit: No data available
Lower flammability limit: No data available
Specific gravity 1.01
Water solubility Slightly soluble
Autoignition temperature No data available
Decomposition temperature No data available
Dynamic viscosity 70 Pa嘻s

Section 10: STABILITY AND REACTIVITY

Stability Stable under normal conditions.

Possibility of hazardous reactions React with moisture in air. Gradually release hazardous gas.

Conditions to avoid Extreme heat

Incompatible materials Strong oxidizing agents.

Hazardous decomposition products May generate harmful gas by incineration

Section 11: TOXICOLOGICAL INFORMATION

Acute toxicity

The following values are calculated based on chapter 3.1 of the GHS document
Inhalation LC50 No data available as this product.

Numerical measures of toxicity - Component Information

Chemical name Oral LD50 Dermal LD50 Inhalation LC50

Titanium dioxide (IV) > 10000 mg/kg ( Rat ) - -
Toluene = 2600 mg/kg ( Rat ) = 12000 mg/kg ( Rabbit ) = 12.5 mg/L ( Rat ) 4 h

Delayed and immediate effects as well as chronic effects from short and long-term exposure

Skin corrosion/irritation No data available as this product.

Serious eye damage/eye irritation No data available as this product.

Sensitization No data available as this product.

Germ cell mutagenicity No data available as this product.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen

Chemical name Japan IARC

Titanium dioxide (IV) 2 Group 2B

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Toluene Group 3

Reproductive toxicity No data available as this product.

STOT - single exposure No data available as this product.

STOT - repeated exposure No data available as this product.

Aspiration hazard No data available as this product.

Section 12: ECOLOGICAL INFORMATION

Ecotoxicity
Acute aquatic hazard No data available as this product.

Chronic aquatic hazard No data available as this product.

Chemical name Algae/aquatic plants Fish Crustacea

Toluene 433: 96 h Pseudokirchneriella 15.22 - 19.05: 96 h Pimephales 11.5: 48 h Daphnia magna mg/L
subcapitata mg/L EC50 12.5: 72 promelas mg/L LC50 EC50
h Pseudokirchneriella flow-through 12.6: 96 h 5.46 - 9.83: 48 h Daphnia
subcapitata mg/L EC50 static Pimephales promelas mg/L magna mg/L EC50 Static
LC50 static 5.89 - 7.81: 96 h
Oncorhynchus mykiss mg/L
LC50 flow-through 5.8: 96 h
Oncorhynchus mykiss mg/L
LC50 semi-static 11.0 - 15.0: 96
h Lepomis macrochirus mg/L
LC50 static 54: 96 h Oryzias
latipes mg/L LC50 static 14.1 -
17.16: 96 h Oncorhynchus
mykiss mg/L LC50 static 28.2:
96 h Poecilia reticulata mg/L
LC50 semi-static 50.87 - 70.34:
96 h Poecilia reticulata mg/L
LC50 static

Persistence and degradability No data available as this product.

Bioaccumulation No data available as this product.

Mobility in soil No data available as this product.

Endocrine disruptor information No data available as this product.

Section 13: DISPOSAL CONSIDERATIONS

Waste from residues / unused Dispose of in accordance with national, state and local regulations. Consult industrial waste
products managent companies for waste. Do not release this product to natural environment nor
reclaim.

Contaminated packaging Dispose containers as same as residual of this product.

Section 14: TRANSPORT INFORMATION

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IMDG Not regulated

ICAO/IATA (air) Not regulated

ADR Not regulated

Japanese regulations
Marine Transportation Safety Not applicable
Act
Civil Aeronautics Act Not applicable

Section 15: REGULATORY INFORMATION

Effective June 1, 2016, regarding Japan’s Industrial Safety and Health Law’s “Notifiable Dangerous and Harmful”, target substances will be
subjected to risk assessment in accordance with Japan’s Industrial Safety and Health Law’s “Harmful Substances Whose Names Are to be
Indicated on the Label.”
Fire protection law criteria Group 4 - Petroleums - 3rd Class(not Water solubility)

Act on the Evaluation of Chemical Priority Assessment Chemical Substances (Law Article 2, Para.5)
Substances and Regulation of Their
Manufacture, etc

Industrial Safety and Health Law Notifiable Substances (Law Art.57-2, Enforcement Oder Art.18-2 Attached Table No.9)

Section 16: OTHER INFORMATION

Issue date 23-Mar-2015
23-Jan-2017

Other information Please contact to local sales offices for further information.

Disclaimer
Handle with care. The data in this document is not guaranteed. This information may be revised based on new findings or test
results. This data sheet is authored in accordance with Japanese regulations.

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