Week 002
Stoichiometry
Week 002: Stoichiometry
Stoichiometry in Space Travel
Carbon Dioxide Poisoning
•Humans produce carbon dioxide as a product of
cellular respiration.
•Plants remove carbon dioxide via photosyntheis
•In spacecrafts, chemical means are needed to eliminate
carbon dioxide
•Carbon dioxide is a toxic gas which can cause death      Launch of a space shuttle;
when its percentage in air exceeds 8%                     https://upload.wikimedia.org/wikipedia/commons/2/2a/Space_Shuttle_Atlanti
                                                          s_launches_from_KSC_on_STS-132_side_view.jpg; 24-Apr-17
Week 002: Stoichiometry
Lithium Hydroxide Canisters
•Photosynthesis
    6CO2 + 6H2O →C6H12O6 + 6O2
•Lithium Hydroxide Canisters
     2LiOH(S) + CO2(g) →Li2CO3(s) + H2O(l)
                                                                      https://ruknews.files.wordpress.com/2015/04/plant
                                                                      s.jpg; 24-Apr-17
• Excess Reactant: CO2
• Limiting Reactant: LiOH
•There should be enough LiOH canisters in the spacecraft to prevent
carbon dioxide poisoning.
                                                                      LiOH canister;
                                                                      http://www.space1.com/Artifacts/Apollo_Artifacts/L
                                                                      iOH_Canister/lioh_canister1a_600.jpg; 24-Apr-17
Week 002: Stoichiometry
Apollo 13 Mission
 •Apollo 13 spacecraft launched in the year 1970 with three astronauts.
 •An explosion happened in the command module so they were forced to
 stay in the lunar module
                                                                              Apollo 13 astronauts;
 •Designed for two people only , the lunar module’s LiOH canisters were       https://upload.wikimedia.org/wikipedia/commons/thu
                                                                              mb/1/17/Apollo_13_Prime_Crew.jpg/800px-
 depleting fast                                                               Apollo_13_Prime_Crew.jpg; 24-Apr-17
 •LiOH canisters left were not the same shape as the round canisters in
 the round module
 •They were able to rig a system to use the square canisters from the
 command module
                                                                          LiOH canister adapted for the lunar module;
                                                                          https://www.hq.nasa.gov/alsj/a13/AS13-62-
                                                                          8929HR.jpg; 24-Apr-17
Week 002: Stoichiometry
New Technologies
 •International Space Station also uses molecular sieve to
 remove carbon dioxide
 •Molecular sieves are zeolites with pores that can trap carbon
 dioxide
 •Future plans involved growing plants to remove carbon
 dioxide naturally.
                                                                  http://www.divermag.com/wp-
                                                                  content/uploads/2012/01/s118e06298.jpg; 24-Apr-
                                                                  17
Week 002: Stoichiometry
References
 http://science.howstuffworks.com/carbon-dioxide-eliminated-aboard-spacecraft.htm
 http://www.space.com/17250-apollo-13-facts.html
 https://www.nasa.gov/mission_pages/apollo/missions/apollo13.html