Material Product Data Sheet
Chromium Carbide – 25 % Nickel Chromium Powders
Thermal Spray Powder Products:                                    Quick Facts
Woka 7201, Woka 7202, Woka 7203, Woka 7204,
                                                                  Classification              Carbide, chromium-based
Woka 7205, Woka 7207, Woka 7210, Woka 7215,
                                                                  Chemistry                   Cr3C2 25(Ni 20Cr)
Woka 7218, Woka 7219
                                                                  Manufacture                 Agglomerated and sintered
1	Introduction                                                    Morphology                  Spheroidal
When compared to coating materials containing tungsten            Apparent Density            2.3 – 3.1 g/cm3
carbide, coating materials that contain chromium carbide are      Service Temperature         < 870 °C (1600 °F)
often used because they can withstand higher service tem-         Purpose                     Corrosion and wear resistance
peratures up to 870 °C (1600 °F).                                 Process                     HVOF or combustion powder
                                                                                              Thermospray™
Woka™ 7200 series of products are spheroidal, agglomerat-
ed and sintered powders for thermal spray that contain 75 %
chromium carbide as a hard, wear-resistant phase that has a
minimal tendency for decomposition during the thermal
spray process. A nickel-chromium (80 % / 20 %) matrix func-
tions as a binder for the carbides, and is also responsible for
the excellent corrosion and oxidation resistance of these
coatings.
Coatings of Woka 7200 series materials protect against
abrasion, various forms of erosion and tribo-corrosion at ele-
vated temperatures. They are well-known as an alternative to
hard chromium plating with better corrosion resistance in so-
dium chloride, acidic and alkaline environments. Environ-
ments with HCl as a corrosive medium should be avoided.
HVOF coatings of these materials are dense, show good
bond strength and are more homogeneous than coatings
applied using atmospheric plasma spray or combustion
powder flame sprayed coatings.
1.1	 Typical Uses and Applications:
nn Hydraulic cylinders and piston rods
nn Valve stems
nn Boiler coatings
nn Chemical processing tooling
nn Turbine components
nn Sieves and cones
nn Ship engine valve spindles
nn Furnace rolls in metal production
nn Pump housings
                                                                  SEM photomicrographs showing the morphology (top) and the microstructure
                                                                  (bottom) of a Woka 7200 series materials.
DSMTS-0031.4 – Woka 7200 CrC-NiCr Series
© 2017 Oerlikon Metco                                                                                                                       1
2	      Material Information
2.1	 Chemical Composition (all products)
Product                                                      Weight Percent (nominal)
                                                             Cr                             C (total)             Ni                    Fe
Woka 7200 Series                                             Balance                        9.0 – 10.2            17.5 – 22.5           < 0.5
2.2	 Particle Size Distribution
Product                             Nominal Range                    D95                    D5                    Primary Carbide       Apparent Density
                                    µm                               µm                     µm                    Size                  g/cm3
Woka 7201                           –53 +20                          53                     20                    Coarse                2.4 – 3.0
Woka 7202                           –45 +15                          45                     15                    Coarse                2.4 – 3.0
Woka 7203                           –45 +11                          45                     11                    Coarse                2.4 – 3.0
Woka 7204                           –30 +10                          30                     10                    Coarse                2.3 – 2.9
Woka 7205                           –38 +10                          38                     10                    Coarse                2.3 – 2.9
Woka 7207                           –45 +20                          45                     20                    Coarse                2.4 – 3.0
Woka 7210                           –25 +5                           25                     5                     Coarse                2.3 – 2.9
Woka 7215                           –106 +45                         106                    45                    Coarse                2.5 – 3.1
Woka 7218                           –75 +45                          75                     45                    Coarse                2.5 – 3.1
Woka 7219                           –63 +20                          63                     20                    Coarse                2.5 – 3.1
Size analysis using laser diffraction (Microtrac). Other particle size distributions are available on request.
2.3	 Key Selection Criteria                                                                        products (see datasheet DSMTS-0027) or plas-
Main selection criteria for choosing a Woka 7200 series ma-                                        ma-densified chromium carbides such as Woka 73xx
terial are:                                                                                        series materials (see datasheet DSMTS-0058).
nn Particle size distributions are optimized for a variety of                               nn For better corrosion resistance in sulfuric acid (H2SO4) or
    HVOF guns on the market today. See Section 2.5 for                                         sodium chloride (NaCl) solutions choose materials that
    recommendations.                                                                           contain both chromium carbide and tungsten carbide,
nn Woka 7215 is suitable for application using combustion                                      such as Woka 75xx or Woka 37xx series products (see
    powder Thermospray™.                                                                       datasheets DSMTS-0056, DSMTS-0059, respectively).
nn Desired as-sprayed surface roughness. For the smooth-                                    nn For better resistance to acidic salt environments choose:
    est possible surface, choose a product with the lowest                                     nn A tungsten carbide materials with a cobalt-chromium
    particle size distribution appropriate for the spray gun to                                    matrix such as Woka 365x series products (see data-
    be used.                                                                                       sheet DSMTS-0025) or Woka 360x series products
                                                                                                   (see datasheet DSMTS-0051).
2.4	 Related Products                                                                          nn A material that contains both chromium carbide and
nn For better wear resistance or higher coating hardness                                           tungsten carbide, such as Woka 75xx or Woka 37xx
   choose:                                                                                         series products (see datasheets DSMTS-0056,
   nn A tungsten carbide material when service temperatures                                        DSMTS-0059, respectively).
      are below 500 °C (930 °F). Metco offers an extensive                                  nn Diamalloy 3007 is a clad material [Cr3C2 20(Ni 20Cr)].
      portfolio of tungsten carbide materials. A few examples                                  Coatings of Diamalloy 3007 show outstanding properties
      are WC 12Co (see datasheet DSMTS-0044 and                                                in applications with erosion, cavitation, heavy abrasion or
      WC 17Co (see datasheet DSMTS-0030). Other prod-                                          substantial friction wear at service temperatures between
      ucts are available with corrosion resistance matrixes.                                   540 °C – 870 °C (1000 °F – 1600 °F) (see datasheet
   nn Woka 75xx series products, which can be used at ser-                                     DSMTS-0022).
      vice temperatures up to 700 °C (1290 °F).                                             nn Within Metco’s portfolio are various chromium carbide
   nn At higher temperatures, chromium carbide materials                                       blends such as Diamalloy 3004 and Metco 5255, as well
      with higher carbide content such as Woka 71xx series                                     as specialty products such as Amdry 5241.
DSMTS-0031.4 – Woka 7200 CrC-NiCr Series
© 2017 Oerlikon Metco                                                                                                                                   2
2.5	 Recommended Spray Guns
Product               HVOF                                                                                                                        Combustion
                      DiamondJet           WokaJet /           K2                   Jet Kote            Top Gun /           CJS                   Powder
                                           WokaStar /                                                   HV2000                                    Thermospray
                                           JP5000
Woka 7201
Woka 7202
Woka 7203
Woka 7204
Woka 7205
Woka 7207
Woka 7210
Woka 7215
3	        Coating Information
3.1	 Key Thermal Spray Coating Information
Characteristic                                                                        Typical Data  a
Recommended Process                                                                   HVOF
Microhardness 	                                           HV0.3                       850 – 1200
Macrohardness 	                                           HR15N                       > 90
Wear Rate 	                                               ASTM G65 B                  < 9 mm3	                                                < 0.00055 in3
Porosity                                                                              < 1 %
Corrosion Resistance                                                                  Excellent in 1 M NaOH, very good in 1M NaCl, good in 0.5 M H2SO4
Maximum Service Temperature                                                           870 °C	                                                 1600 °F
Deposition Efficiency                                                                 30 – 55 %
a    epending on the HVOF spray gun used, parameter used and coating thickness applied. Please note that typical data is given for application using HVOF processes.
    D
    Woka 7215 is designed to be applied using Combustion Powder Thermospray™ and coating results can be expected to be significantly different.
3.2	 Coating Parameters                                                               Recommended Spray Guns
Please contact your Oerlikon Metco Account Representative
                                                                                      HVOF                                   Combustion Powder
for parameter availability. For specific coating application
                                                                                      DiamondJet series                      Metco 6P-II series
requirements, the services of Oerlikon Metco’s Coating
 Solution Centers are available.                                                     WokaJet series
                                                                                      WokaStar series
DSMTS-0031.4 – Woka 7200 CrC-NiCr Series
© 2017 Oerlikon Metco                                                                                                                                              3
4	      Commercial Information
4.1	 Ordering Information and Availability
Product                           Order No.                      Package Size                                Availability                        Distribution
Woka 7201                         1041120                        5	kg (approx. 11	lb)                        Special Order                       Europe
                                  1041074                        10	lb (approx. 4.5	kg)
Woka 7202                         1041121                        5	kg (approx. 11	lb)                        Stock                               Europe
                                  1041075                        10	lb (approx. 4.5	kg)                                                          Americas
Woka 7203                         1059066                        5	kg (approx. 11	lb)                        Special Order                       Europe
                                  1049664                        10	lb (approx. 4.5	kg)                                                          Americas
Woka 7204                         1041180                        5	kg (approx. 11	lb)                        Special Order                       Europe
                                  1041192                        10	lb (approx. 4.5	kg)                                                          Americas
Woka 7205                         1041122                        5	kg (approx. 11	lb)                        Stock                               Europe
                                  1041076                        10	lb (approx. 4.5	kg)                                                          Americas
Woka 7207                         1041123                        5	kg (approx. 11	lb)                        Stock                               Europe
                                  1041077                        10	lb (approx. 4.5	kg)                                                          Americas
Woka 7210                         1050159                        5	kg (approx. 11	lb)                        Special Order                       Europe
                                  1049657                        10	lb (approx. 4.5	kg)                                                          Americas
Woka 7215                         1075481                        10	lb (approx. 4.5	kg)                      Special Order                       Americas
Woka 7218                         1065672                        5	kg (approx. 11	lb)                        Special Order                       Europe
                                  1042908                        10	lb (approx. 4.5	kg)                                                          Americas
Woka 7219                         1065678                        5	kg (approx. 11	lb)                        Special Order                       Europe
Note: For products available in both kg and lb weights, the kg package will be supplied to unspecified regions (Africa, Asia/Pacific, Japan and Middle East) unless the lb
package is specifically requested by the customer.
4.2	 Handling Recommendations                                                          4.3	 Safety Recommendations
nn Store in the original container in a dry location.                                  See SDS 50-880 (Safety Data Sheet) in the version localized
nn Tumble contents prior to use to prevent segregation.                                for the country where the material will be used. SDS are
nn Remove desiccant bag prior to use, where applicable.                                available from the Oerlikon web site at
nn Open containers should be stored in a drying oven to                                www.oerlikon.com/metco (Resources – Safety Data Sheets).
   prevent moisture pickup.
Information is subject to change without prior notice.
DSMTS-0031.4 – Woka 7200 CrC-NiCr Series                                                                                                   www.oerlikon.com/metco
© 2017 Oerlikon Metco                                                                                                                     info.metco@oerlikon.com4