ATOMS, IONS AND
MOLECULES
• Laws of Matter
Dalton’s Atomic Theory
OBJECTIVES:
• Explain how the basic laws of matter led to
the formulation of Dalton’s Atomic Theory
• Describe Dalton’s Atomic Theory
Table 4. Activity Data Sheet on Law of Conservation of Mass
Mass of Flask (g)
Open Closed
After adding vinegar
Baking soda packet
Flask (with cork) and
packet
After inserting the packet
Mass difference after
reaction
NaHCO3(s) + HC2H3O2(aq) CO2(g) + Na+(aq) + C2H3O2-(aq)
1. Law of Conservation of Mass : Antoine Lavoisier
Mass is neither created nor destroyed in
chemical reactions.
• The mass of the substances before a
chemical change/reaction is the same as the
mass of the substances produced by the
chemical change.
• The mass of the substances before and the
mass of the substances after the reaction are
equal.
Sample Exercises:
• If 46.5 grams of reactants are used in the following
reaction, what will be the mass of the products?
Zn (s) + 2 HCl (aq) --- > ZnCl2 (aq) + H2 (g)
• Consider the following reaction,
Ca (s) + ZnCO3(aq) --- > CaCO3 (aq) + Zn (g)
50 g 150 g 125 g ?
what mass of zinc in grams is produced?
Seatwork
Sodium chloride can be formed by the
reaction of sodium metal with chlorine gas. If
45.98 g of sodium combine with an excess of
chlorine to form 116.89 g of sodium chloride,
how much chlorine gas is used in the reaction?
2. Law of Definite Composition : Joseph Proust
Any sample of a compound will invariably
have the same proportion by mass of its
constituent elements.
• water
• carbon dioxide
• methane
Sample Exercises:
• A pure sample of sodium fluoride (NaF) contains 35 g of
sodium. How many grams of fluorine are present in this
sample?
• If 40% of a 300 g NaCl solution is sodium, what is the mass
of the sodium present in the sample?
• If there are 42 g of hydrogen in a sample of pure methane
(CH4), how many grams of carbon are present?
Seatwork:
• If there are 19 g oxygen in a sample of aluminum
oxide, (Al2O3), how many grams of aluminum are
present?
3. Law of Multiple Proportion : John Dalton
Elements can combine in different ways to form
different substances, whose mass ratios are small
whole numbers.
When two elements A and B form two different
compounds, the masses of element B that
combine with a fixed mass of element A can be
expressed as a ratio of small whole numbers.
Take nitrogen monoxide (NO) and nitrogen dioxide (NO2) as example
NO NO2
Two elements A and B form two
different compound. In the first
compound one gram of A is
combines with 1.44g of B. In the
second compound 0.15g of A is
combined with 0.65g of B. Show
how these data illustrate the law of
multiple proportions.