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Alkali - Chlorine - Sulfur - Balance: Preheater / PC Kiln

This document contains data from a kiln operation including fuel inputs, emissions outputs, and mass balances of chemicals. Key metrics monitored include heat consumption, clinker production rate, sulfur and chlorine inputs and outputs, and balances of alkalis, sulfur, chlorine and loss on ignition. The data is analyzed to determine compliance with emissions limits and efficiency of the kiln system.

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100% found this document useful (1 vote)
1K views4 pages

Alkali - Chlorine - Sulfur - Balance: Preheater / PC Kiln

This document contains data from a kiln operation including fuel inputs, emissions outputs, and mass balances of chemicals. Key metrics monitored include heat consumption, clinker production rate, sulfur and chlorine inputs and outputs, and balances of alkalis, sulfur, chlorine and loss on ignition. The data is analyzed to determine compliance with emissions limits and efficiency of the kiln system.

Uploaded by

Bùi Hắc Hải
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as XLS, PDF, TXT or read online on Scribd
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ALKALI - CHLORINE - SULFUR - BALANCE

Plant Date Time


Kiln Type, make Preheater / PC kiln Heat consumption kJ/kg cli
Length m Thermal load (BZ) 0.0 MW/m2 Clinker production t/d
Diameter (BZ) m Length of fix coating m 0.0 t/h
Cooler Type, make L coating / kiln diam.: 0.0 -
Cleaning method Obser- O2 kiln inlet %
frequency vations O2 PH outlet %

Fuels (sulfur input) Emission at main stack (including bypass stack)


Fuel type CV S Fineness Rate Heat SO2-Emission (sulfur output) HCl-Emission (chlorine output)
[kJ/kg] [%] [% 90mm] [t/h] [%] O2, at SO2 measurement %O2 O2, at HCl measurement %O2
0.0 Dry exh.gas at 0.0%O2 0.280 Nm3/kg cli Dry exh.gas at 0.0%O2 0.280 Nm3/kg cli
Main firing

0.0 SO2 dry ppm HCl dry ppm


0.0 SO2 0 mg /Nm3 HCl 0 mg /Nm3
0.0 0 mg/kg cli 0 mg/kg cli
0.0 0.0 kg SO2/h 0.0 kg HCl/h
Sec. Firing

0.0 SO3 0 mg/kg cli Cl 0 mg/kg cli


or PC

0.0 SO3 cli basis 0.000 % Cl cli basis 0.000 %


0.0
Calculated specific fuel cons. (from above data) 0 kJ/kg

Balance Massflow SO3 K2O Na2O Na2Oequiv Cl A/S Mass Balance


rate cli basis conc. cli basis conc. cli basis conc. cli basis cli basis conc. cli basis LOI cli basis
[t/h] [t/t cli] [%] [%] [%] [%] [%] [%] [%] [%] [%] [-] [%] [t/h]
1 Kiln Feed (dry) as fed 0.00 0.000 0.000 0.000 0.000 0.0000 0.0
2 0.00 0.000 0.000 0.000 0.000 0.0000 0.0
0.00 0.00 0.0
0.00 0.00 0.0
INPUT

0.00 0.00 0.0


0.00 0.00 0.0
3
0.00 0.00 0.0
0.00 0.00 0.0
0.00 0.00 0.0
0.00 0.00 0.0
TOTAL INPUT 0.000 0.000 0.000 0.000 0.0000 0.000 0.0
4 Clinker 0.00 0.00 0.000 0.000 0.000 0.000 0.0000 0.000 0.0
OUTPUT

5 Bypass dust removed from kiln 0.00 0.000 0.000 0.000 0.000 0.0000 0.0
6a Dust (main filter) returned via kiln feed 0.00 0.000 0.000 0.000 0.000 0.0000 0.0
7 Dust (main filter) removed from kiln 0.00 0.000 0.000 0.000 0.000 0.0000 0.0
8 Emission - - 0.000 - - - - - - 0.0000 - - -
TOTAL OUTPUT 0.000 0.000 0.000 0.000 0.0000 0.000 0.0
Input - output 0.000 0.000 0.000 0.000 0.000 0.00
Diff.

in % of input 0.0 0.0 0.0 0.0 0.0 0.0


(red values: estimated figures)
Hot meal Massflow SO3 K2O Na2O Na2Oequiv Cl A/S Mass Balance
conc. Limits conc. conc. conc. Limits conc. Limits LOI Calcination
[%] [%] [%] [%] [%] [%] [%] [%] [%] [%]
Mix right + left - 0.000 - - -

437656658.xls HGRS/CTS/TPT 09/16/2019


- - - -
Average 0.000 0.000 0.000 0.000 0.000 0.000 0.0

437656658.xls HGRS/CTS/TPT 09/16/2019


Applicable Balance Boundary for all Kiln Types:

437656658.xls HGRS/CTS/TPT 09/16/2019


EVALUATION of ALKALI - CHLORINE - SULFUR - BALANCE
- The following section is only applicable if the balance boundary as shown on the balance sheet is used
(balance boundary excluding outer dust cycle).
- For additional information and explanations see 'Manual Alk/SO3/Cl - Balance"

Main Results: HGRS criteria for Preheater / PC kiln :

1. "Calculated" Cl in clinker*/**: n/a g/t cli < 200-300 for all kilns

2. Actual Sulfur in clinker: n/a %SO3cli < 1.5


3. Alk/SO3 ratio in clinker: n/a - 0.8 - 1.2
4. "Relevant" Cl input***: n/a g/t cli < 300 (no Cl valve)

5. Sulfur Volatility #DIV/0! - <0.7

6. Hot Meal: see graph below

* "Calculated" value in clinker = Total inputs minus dust output and emission, referred to clinker.
** "calculated" CL value shows more reliable values than the real value in clinker (which is heavily depending
on the current circulation situation)
*** "Relevant Input= All Cl inputs minus Cl in dust reused (via kiln feed or returned directly) in the kiln process minus emission
Limiting criteria HGRS: Maximum possible Cl input when maximising Cl valves
Note: The Chlorine limit of 5000 g/t clinker for wet/long dry kilns is from the process point of view only.
If all dust goes to the cement, the chlorine limit is usually around 1000 gr/t clinker.

Hot Meal Evaluation for SP/PC Kilns


2.400 frequent
blockages
2.200

2.000

1.800

1.600
% Cl

1.400

1.200

1.000

0.800

0.600

0.400

0.200

0.000
0.000 0.500 1.000 1.500 2.000 2.500 3.000 3.500 4.000 4.500 5.000 5.500 6.000
% SO3

437656658.xls HGRS/CTS/TPT 09/16/2019

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