MATERIAL SAFETY DATA SHEET
AMMONIUM CHLORIDE
Revision : 01 Date : 19.09.2017 MSDS Number : 017
Section 1 - Chemical P roduct and Company Identification
1.1 Product Name : AMMONIUM CHLORIDE
Synonyms : Ammonium Chloratum; Ammonium Chloridum; Ammonium Muriate; Sal
Ammoniac; Salmiac.
CAS No. : 12125-02-9
HS Code : 2827 10 00
Molecular Weight : 53.49 g/mol
Chemical Formula : NH 4Cl H 4ClN Hill
Product Code : A 2004
B rand : SMART-LAB
1.2 Manuf acturer :PT.Smart-Lab Indonesia
Address :Taman TeknoBangunMultiguna Blok M/36,BSD Sektor XI Serpong,
Tangerang - Indonesia
Website :www.smartlab.co.id
Email :sales@smartlab.co.id
For inf ormation :Telp: +62-21- 7588 0205(Hunting) , fax:+62-21-7588 0198
1.3 Application : General Chemical reagent
Emergency Telephone: +62-21-7588 0205(Hunting)
Section 2 - Hazards Identification
2.1 Classif ication of the substance or mixture
Classif ication according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Eye irritation (Category 2), H319
For the full text of the H-Statements mentioned in this Section, see Section 16
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
P ictogram
Signal word Warning
Hazard statement(s)
H302 Harmful if swallowed.
H319 Causes serious eye irritation.
P recautionary statement(s)
P 305 + P 351 + P 338 IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
PT.SMART-LAB IN DONESIA MSDS – AMMONIUM C HLO RIDE Page 1
MATERIAL SAFETY DATA SHEET
AMMONIUM CHLORIDE
Revision : 01 Date : 19.09.2017 MSDS Number : 017
Supplemental Hazard Statements none
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (P BT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Section 3 - Composition, Information on Ingredients
3.1 Substances
Synonyms : Salt ammoniac
Formula : NH 4Cl H 4ClN Hill
Molecular weight : 53.49 g/mol
CAS-No. : 12125-02-9
EC-No. : 235-186-4
Index-No. : 017-014-00-8
Hazardous ingredients according to Regulation (EC) No 1272/2008
Component Classif ication Concentration
Ammonium chloride
CAS-No. 12125-02-9
Acute Tox. 4; Eye Irrit. 2; H302, H319 <=100 %
EC-No. . 235-186-4
Index-No 017-014-00-8
For the full text of the H-Statements mentioned in this Section, see Section 16.
Section 4 - First Aid Measures
4.1 Description of f irst aid measures
G eneral advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and ef f ects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
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MATERIAL SAFETY DATA SHEET
AMMONIUM CHLORIDE
Revision : 01 Date : 19.09.2017 MSDS Number : 017
Section 5 - Firefighting Measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising f rom the substance or mixture
Nitrogen oxides (NOx), Hydrogen chloride gas
5.3 Advice f or f iref ighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further inf ormation
No data available
Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure
adequate ventilation. Avoid breathing dust. For personal protection see section 8.
6.2 Environmental precautions
P revent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3 Methods and materials f or containment and cleaning up
P ick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers
for disposal.
6.4 Ref erence to other sections
For disposal see section 13.
Section 7 - Handling and Storage
7.1 Precautions f or saf e handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. P rovide appropriate exhaust
ventilation at places where dust is formed. For precautions see section 2.2.
7.2 Conditions f or saf e storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Hygroscopic. Storage
class (TRGS 510): Non Combustible Solids
7.3 Specif ic end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Section 8 - Exposure Controls, P ersonal P rotection
8.1 Control parameters
8.2 Exposure control
Appropriat engineering controls
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MATERIAL SAFETY DATA SHEET
AMMONIUM CHLORIDE
Revision : 01 Date : 19.09.2017 MSDS Number : 017
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
the end of workday.
Personal protective equipment
Eye/f ace protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested
and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal
technique (without touching glove's outer surface) to avoid skin contact with this product.
Dispose of contaminated gloves after use in accordance with applicable laws and good
laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC
and the standard EN 374 derived from it.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740, Size M)
B ody Protection
Complete suit protecting against chemicals, The type of protective equipment must be
selected according to the concentration and amount of the dangerous substance at the specific
workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle r (US) or type
ABEKP 2 (EU EN 143) respirator cartridges. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
P revent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into
the environment must be avoided.
Section 9 - P hysical and Chemical P roperties
9.1 Inf ormation on basic physical and chemical properties
Appearance Form: Crystalline powder
Colour: colourless
Odour No data available
Odour Threshold No data available
pH 4.5 - 5.5 at 50.00000 g/l at 20.0 °C
Melting point/freezingpoint Melting point/range: 340 °C - lit.
Initial boiling point and boiling range No data available
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MATERIAL SAFETY DATA SHEET
AMMONIUM CHLORIDE
Revision : 01 Date : 19.09.2017 MSDS Number : 017
Flash point Not applicable
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper/lower flammability or No data available
explosive limits No data available
Vapour pressure 1.0 mmHg at 160.4 °C
Vapour density No data available
Relative density No data available
Water solubility soluble
P artition coefficient: noctanol/water No data available
Auto-ignition temperature No data available
Decomposition temperature No data available
Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available
9.2 Other saf ety information
Bulk density 500 kg/m3
Section 10 - Stability and Reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Exposure to moisture may affect product quality
10.5 Incompatible materials
Strong acids, Strong bases, Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
Hazardous decomposition products formed under fire conditions. - Nitrogen oxides (NOx), Hydrogen
chloride gas
In the event of fire: see section 5
Section 11 - Toxicological Information
11.1 Inf ormation on toxicological ef f ects
Acute toxicity
LD50 Oral - Rat - 1,650 mg/kg(Ammonium chloride).
Skin corrosion/irritation
Skin - Rabbit(Ammonium chloride)
Result: No skin irritation
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MATERIAL SAFETY DATA SHEET
AMMONIUM CHLORIDE
Revision : 01 Date : 19.09.2017 MSDS Number : 017
Serious eye damage/eye irritation
Eyes - Rabbit(Ammonium chloride)
Result: Eye irritation
Respiratory or skin sensitisation
Will not occur(Ammonium chloride)
G erm cell mutagenicity
No data available(Ammonium chloride)
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available(Ammonium chloride)
Specif ic target organ toxicity - single exposure
No data available(Ammonium chloride)
Specif ic target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available(Ammonium chloride)
Additional Inf ormation
RTECS: BP 4550000
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.(Ammonium chloride)
Section 12 - Ecological Information
12.1 Toxicity
Toxicity to fish
LC50 - Cyprinus carpio (Carp) - 209.00 mg/l - 96 h(Ammonium chloride)
LC50 - Oncorhynchus mykiss (rainbow trout) - 3.98 mg/l - 96 h(Ammonium chloride)
NOEC - Oncorhynchus mykiss (rainbow trout) - 57 mg/l - 96 h(Ammonium chloride)
Toxicity to daphnia and other aquatic invertebrates
LC50 - Daphnia magna (Water flea) - 161 mg/l - 48 h(Ammonium chloride)
Growth inhibition NOEC - Daphnia magna (Water flea) - 0.1 mg/l - 216 h(Ammonium chloride)
12.2 Persistence and degradability
No data available
12.3 B ioaccumulative potential
No data available
12.4 Mobility in soil
No data available
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MATERIAL SAFETY DATA SHEET
AMMONIUM CHLORIDE
Revision : 01 Date : 19.09.2017 MSDS Number : 017
12.5 Results of PB T and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (P BT), or very persistent and very bioaccumulative (vP vB) at levels of 0.1% or higher.
12.6 Other adverse ef f ects
Toxic to aquatic life.
No data available
Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chem scrubber.
Contaminated packaging
Dispose of as unused product.
Section 14 - Transport Information
14.1 UN number
ADR/RID: - IMDG: - IATA: -
14.2 UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
14.3 Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
14.4 Packaging group
ADR/RID: - IMDG: - IATA: -
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
Further inf ormation
No data available
Section 15 - Regulatory Information
15.1 Saf ety, health and environmental regulations/legislation specif ic f or the substance or mixture
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.2 Chemical saf ety assessment
For this product a chemical safety assessment was not carried out
Section 16 - Additional Information
Full text of H-Statements referred to under sections 2 and 3.
H302 Harmful if swallowed.
H319 Causes serious eye irritation
PT.SMART-LAB IN DONESIA MSDS – AMMONIUM C HLO RIDE Page 7
MATERIAL SAFETY DATA SHEET
AMMONIUM CHLORIDE
Revision : 01 Date : 19.09.2017 MSDS Number : 017
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
P ersonal P rotection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Further information
The above information is believed to be correct but does not purport to be all inclusive and shall be used onlyas
a guide. The information in this document is based on the present state of our knowledge and is applicable to
the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties
of the product. PT. Smartlab Indonesia Corporation and its Affiliates shall not be held liable for any damage
resulting from handling or from contact with the above product. See www.sigmaaldrich.com and/or the reverse
side of invoice or packing slip for additional terms and conditions of sale.
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