the other stream contains the separated Molecular Sieve (CMS). In one bed at of handling the gas.

at of handling the gas. Both membrane and

oxygen, carbon dioxide, water vapor and operating pressure, the CMS absorbs PSA units produce nitrogen at precise
other gases. The generator separates the oxygen, carbon dioxide and water vapor. purities, flow rates and pressures. In
compressedair into component gasses by The other bed operating at low pressure addition to providing a significant cost
passing the air through semipermeable releases the captured oxygen, carbon savings, nitrogen generation in-house
membranes consisting of bundles of hollow dioxide and water. Cycling the pressures in represents a sustainable approach to the
fibers. Each fiber has a circular cross section the CMS beds causes all contaminants to supply of nitrogen. Gas industry sources
and a uniform bore through its center. be captured and released, while letting the indicate that an air separation plant uses
Compressed air is introduced into the bore nitrogen pass through. A final sterile grade 1976 kJ of electricity per kilogram of
of the membrane fibers at one end of the filter assures removal of any microbial nitrogen at 99.9%%. On-demand nitrogen
membrane module. Oxygen, water vapor and contamination. Users can easily set purities generation helps reduce the generation
other gases permeate the membrane fiber with a flow control valve. The DB-30 of greenhouse gases. Compared to third
wall and are discharged through a permeate nitrogen system, for example, produces a party supplied bulk nitrogen, generation
port at low pressure, while the nitrogen is flow of nitrogen of at least 1530 standard of 99.9% nitrogen in house with a PSA
contained within the membrane and flows ft3 at 99.9% purity. The unit can achieve system uses 28% less energy. This means
through the outlet port at operating pressure higher flow rates if gas of less purity is fewer greenhouse gases are created by the
(see Figure 1). The nitrogen gas steam is acceptable. As flow is reduced purity generation of electricity than with a typical
very dry, with dewpoints of at least -58°F increases up to 99.999% A built-in oxygen nitrogen generator. At a purity of 98%%,
(50°C). Membrane nitrogen generators need monitor measures the oxygen concentration the energy required for in-house nitrogen
no electricity to generate nitrogen so they of the nitrogen stream. The system requires consumes 62% less energy. Therefore,
can be used in Class One explosion-proof a minimum feed pressure of 110 psi and in-house generation creates 62% fewer
environments without any concerns. can operate at pressures up to 140 psi. The greenhouse gases from electrical power at
resulting nitrogen has a dewpoint as low as that purity.
For an example of how a PSA nitrogen -40°F (-40°C).
generator works, Parker equipment uses
high efficiency prefiltration to remove all Conclusion
contaminant from the compressed air Compared to other supply methods,
stream down to 0.01 micron. The filters are on-demand nitrogen generators provide
followed by dual beds filled with Carbon significant benefits by increasing the safety

Permeate

Outer side
dense

Fiber wall
porous

Pressurized air
Inner side
open n
sio
diffu
of
te
Ra

Retenate Slow Medium Fast

N2, Ar CO CO2, O2 H2O, H2, He

Figure 1 Gas Separation Membrane

Pressure Swing Adsorption (PSA) nitrogen generators

use a Carbon Molecular Sieve (CMS) material inside
a vessel that contains pressurized air to draw off the
nitrogen molecules.

4
How to Size a Tank Blanketing System
When determining the required amount of blanketing gas, it is necessary to
consider both the blanketing gas replacement for liquid loss during pump-
out and the condensation of tank vapors during atmospheric thermal cooling.
The maximum flow rate and desired purity determines the size of the nitrogen
generator required. Here are the steps to sizing a blanketing generator:

1. Determine the gas flow rate due to pump-out from the following table:
In Breathing Rate Due to Pump-Out (English)
Multiply Maximum Pump-Out Rate In By To Obtain
U.S. GPM 8.021 SCFH air required
U.S. GPH 0.134 SCFH air required
Barrels/hr 5.615 SCFH air required
Barrels/day 0.234 SCFH air required
Liters/min 2.118 SCFH air required
m3/hr 35.30 SCFH air required

In Breathing Rate Due to Pump-Out (Metric)

Multiply Maximum Pump-Out Rate In By To Obtain
U.S. GPM 0.215 Nm3/hr air required
U.S. GPM 0.258 Nm3/hr air required
Barrels/hr 0.151 Nm3/hr air required
Barrels/day 0.0063 Nm3/hr air required
Liters/min 0.057 Nm3/hr air required

2. Determine the gas flow rate due to atmospheric cooling from the following table:
In Breathing Rate Due to Thermal Cooling
Tank Capacity In Breathing Nitrogen Required
Barrels Gallons [m ]3
SCFH [Nm3/hr]
60 2,500 [9.5] 60 [1.6]
100 4,200 [15.9] 100 [2.7]
500 21,000 [79.5] 500 [13.4]
1,000 42,000 [159] 1,000 [26.8]
2,000 84,000 [318] 2,000 [53.6]
3,000 126,000 [477] 3,000 [80.4]
4,000 168,000 [636] 4,000 [107.2]
5,000 210,000 [795] 5,000 [134]
10,000 420,000 [1590] 10,000 [268]
15,000 630,000 [2385] 15,000 [402]
20,000 840,000 [3180] 20,000 [536]
25,000 1,050,000 [3975] 24,000 [643]
30,000 1,260,000 [4770] 28,000 [750]
35,000 1,470,000 [5560] 31,000 [830]
40,000 1,680,000 [6360] 34,000 [911]
45,000 1,890,000 [7150] 37,000 [992]
50,000 2,100,000 [7950] 40,000 [1070]
60,000 2,520,000 [9540] 44,000 [1180]
70,000 2,940,000 [11130] 48,000 [1290]
80,000 3,360,000 [12700] 52,000 [1400]
90,000 3,780,000 [14300] 56,000 [1500]
100,000 4,200,000 [15900] 60,000 [1600]
120,000 5,040,000 [19100] 68,000 [1800]
140,000 5,880,000 [22300] 75,000 [2000]
160,000 6,720,000 [25400] 82,000 [2200]
180,000 7,560,000 [28600] 90,000 [2400]

3. Add the requirements of 1 and 2 to select the appropriately sized nitrogen generator.

Source: Tyco