Chemical Reactions - Class XII
Chemical Reactions - Class XII
SECTION
 B
 1            CHEMICAL REACTIONS
              	   TOPIC-1
                  Chemical Reactions an Equations
  	WORKSHEET-1
  Solutions                                                          Answering Tip
  	1.	Correct option : (d)                                       	 	 Keenly observe the necessary conditions for the
  		Explanation : During combustion of liquefied                      reactions during practical, prepare a list of type of
      petroleum gas (LPG), it forms CO2 and H2O.                      decomposition reactions, its necessary conditions
                                                                      and gases released and practise it.
  	2.	Rusting of iron.	                                      1
  	3.	Reaction in which a single reactant breaks down to         	5.	(a) (i) Physical state of reactants and products.
      give simpler products.                                     	   	(ii) 	Conditions such as temperature, pressure,
  	  	Thermal decomposition :                                         	      heat etc.
                                ∆
                                                                 	   	(iii)	 Catalyst involved.
  	      		     CaCO3     → CaO + CO2	 (Or any other)          	   	(iv)	 Change in state.	                       ½×4
  	      	Electrolytic decomposition :                           	(b)	Total mass of the elements present in the products
                                                                      in a chemical reaction has to be equal to the total
                     Electric current
  	      	    2 H2O → 2H2 + O2	                                 mass of elements present in the reactants.
                                                                                             or
  	      		       [CBSE Marking Scheme, 2016] 1 + 1 + 1
                                                                 	   	Mass can neither be created nor be destroyed in a
                                                                      chemical reaction.
  	4.	CaCO3 heat
                → CaO + CO2	                                  	                        [CBSE Marking Scheme, 2013] 1
                                                
  	      	2FeSO4 heat
                   → Fe2O3 + SO2 + SO3           Any one        	6.	    Process in which new substances with new
                                                                        properties are formed by the rearrangement of
                                                
  	      	2Pb(NO3)2 heat
                        → 2PbO + 4NO2 + O2                             atoms.
                   Sunlight                                      	(i)	Evolution of gas : The chemical reaction between
  	      	2AgCl → 2Ag + Cl2          
                                                                        zinc and dilute H2SO4.
                   Sunlight               Any one               	      	Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g) ↑
  	      	2AgBr → 2Ag + Br2          
                                                                	(ii)	Change in colour : The chemical reaction between
                  electricity
  	      	2H2O 
                   → 2H2 + O2                                            potassium iodide and lead nitrate.
                                                                 	      	Pb(NO3)2(aq) + 2KI(s) → 2KNO3(aq) + PbI2(s)
  	      	(or any other equation for above decomposition
          reaction.)                                             	      		     Colourless	                      Yellow
  		Note : No marks to be deducted if equations are              	 (iii)	Formation of precipitate : The chemical reaction
    not balanced.                          1+1+1                        between sulphuric acid and barium chloride.
                     [CBSE Marking Scheme, 2018]                 	      	BaCl2(aq) + H2SO4(aq) → 2HCl(aq) + BaSO4(s)
  
                                                                 	      		                               White precipitate
      Commonly Made Error                                        	(iv)	Change in temperature : The chemical reaction
                                                                         between quick lime and water.
  	 	 Usually students get confused in the necessary            		CaO(s) + H2O (l) → Ca(OH)2(aq) + Heat
       conditions and liberation of gases in the reaction.       	                                       1+1+1+1+1
  	WORKSHEET-2
  Solutions                                                              temperature copper (II) oxide is formed.
  	1.	Correct option : (d)	                                      	2.	Law of conservation of mass.
      Explanation : Chemical changes involve formation           	      	Mass can neither be created nor can it be destroyed
      of new compounds from one or more substances.                      during a chemical reaction.	                 ½+½
      On heating copper wire in presence of air at high
	WORKSHEET-3
Solutions                                                      	5.	(i) Substance X-Calcium Hydroxide.
                                                               	  	Ca(OH)2(aq) + CO2(g) ® CaCO3(s) + H2O(l)
	1.	(c) 2H2(g) + O2(g) ® 2H2O(l)                               			                           (White ppt.)
	    Explanation : It is because, the standard state for       	 (ii)	Calcium hydroxide is obtained by reaction of
     hydrogen and oxygen is gas and for water is liquid
     at reaction temperature.
                                                                      calcium oxide and water.
                                                               		CaO(s) + H2O(l) ® Ca(OH)2(aq) + Heat	 1 + 2
	2.	In a physical change, no new substance is formed.
	     	In a chemical change, new substance is formed.	 	       	6.	(i) Decomposition Reaction : Carbohydrates are
                                                  ½+½              broken down to form glucose.
                                                               	 (ii)	Oxidation Reaction : When an iron object is left
	3.	(i) ‘X’ is Copper (Cu), ‘Y’ is Copper oxide (CuO).	1
                                                                      in moist air for a considerable time, it gets covered
	(ii)	Oxidation and Reduction	                    ½+½
                 Heat                                                 with a red brown flaky substance called rust.
	(iii)	2Cu + O2    → 2CuO
                                                               	(iii)	Displacement reaction : More reactive metal
                 Heat
	     	CuO + H2    → Cu + H2O	         ½+½                         displaces less reactive metal from its salt solution.
	     		              [CBSE Marking Scheme, 2012]              	 (iv)	
                                                                     Displacement reaction : More reactive metal
                                                                     displaces less reactive metal from its salt solution.
	4.	(i) Exothermic Reaction
                                                               	(v)	Double displacement reaction : Reaction in which
	  	CaO + H2O → Ca(OH)2
                                                                    two compounds react by an exchange of ions to
		(ii) Double displacement reaction
                                                                    form two new compounds.	                   1×5
	  	BaCl2 + Na2SO4 → BaSO4 + 2NaCl 	 1½ + 1½
	  		                 [CBSE Marking Scheme, 2015]              	     		                  [CBSE Marking Scheme, 2016]
	WORKSHEET-4
Solutions                                                      	2.	In the absence of air, ZnO(s) and CO2(g) are formed.
	1.	Quick lime reacts with water vigorously to produce         	     	Chemical Equation :
    slaked lime and a large amount of heat.                                           Heat
                                                               	     	ZnCO3(s) Absence
                                                                                          → ZnO(s) + CO2(g) ½ + ½
	     	CaO(s)     + H2O (l) → Ca(OH)2 + Heat                                           of air
P-2                                                                                                    S C I ENC E - X
 	3.	(i) Na2CO3(s) + 2HCl(aq) → 2NaCl(aq) +                  	5.	(i) Change in colour : Reaction between lead
                        H2O(l) + CO2(g)                               nitrate solution and potassium iodide solution.
 	(ii)	CaO(s) + H2O(l) → Ca(OH)2(aq) + Heat                  	      	Pb(NO3)2(aq) + 2KI(aq) →PbI2(s) + 2KNO3(aq)
 	(iii)	Pb(NO3)2(aq)   +    NaCl(aq) → PbCl2(s) +            	      	In this reaction, colour changes from colourless to
                                   2NaNO3(aq)	 1+1+1                  yellow.
                                                              	(ii)	Change in temperature : Action of dilute sulphuric
 	       		                [CBSE Marking Scheme, 2014]
                                                                      acid on zinc.
 	4.	(a) (i) HCl is oxidized.	                         ½      	      	Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g)
 		(ii)	 MnO2 is reduced.	                             ½      	      	In this reaction, heat is evolved.
 	 (b)	(i)	 Oxidation : Gain of Oxygen or loss of Hydro-      	 (iii)	Formation of precipitate : Action of barium
            gen.	                                       1             chloride on sodium sulphate.
 		(ii)	 Reduction : Gain of Hydrogen or loss of Oxy-         	      	BaCl2(aq) + Na2SO4(aq) → BaSO4(s) + 2NaCl(aq)
            gen.	        [CBSE Marking Scheme, 2018] 1        	      		                               (ppt.)
                                                              	      		            [CBSE Marking Scheme, 2014] 1+1+1
     Commonly Made Error
                                                              	    6.	(i) 2NaOH(aq) + Zn(s) → Na2ZnO2(aq) + H2(g)
 	 	 Usually students get confused with the oxidised
      and reduced substances in the reaction.                 	(ii)	Ca(OH)2(aq) + CO2(g) → CaCO3(s) + H2O(l)
                                                              	      	CaCO3(s) + H2O(l) + CO2(g) → Ca(HCO3)2(aq)
     Answering Tip                                            	(iii)	Na2CO3(s) + H2SO4(dil) → Na2SO4(aq) + H2O(l)
 	 	 Students must remember that oxidation, a process                                                          + CO2(g)
      in which oxygen or an electronegative element           	(iv)	CaCO3 + 2HCl → CaCl2 + H2O + CO2
 		 is added, while reduction is a process in which
                                                              	(v)	CuO + 2HCl (dil) → CuCl2 + H2O 	                      	
      addition of hydrogen or an electropositive element
                                                                      	                                      1+1+1+1+1
      takes place.
 	WORKSHEET-5
 Solutions                                                    	5.	(i) 2Na + 2H2O → 2NaOH + H2
 	1.	Burning of candle is both physical and chemical          	  	It is an exothermic reaction.
     change. Burning of candle melts the wax and hence                         ∆
                                                              	(ii)	2FeSO4(s)  → Fe2O3 (s) + SO2(g) + SO3(g)
     physical state of wax has changed from solid to
     liquid. Again the wax combines with the atmosphere       		It is an endothermic reaction.	                 1½ + 1½
     oxygen and changes to carbon dioxide, heat and           	6.	(i) With dilute H2SO4 : H2 gas is evolved.
     light. Thus both the changes are accompanied in
                                                              	     	         Zn + H2SO4 → ZnSO4 + H2 ↑
     the burning of candle.	                          1
                                                              	(ii)	With dilute HCl : H2 gas is evolved.
 	2.	 Pb(NO3)2 + 2KI             → 2KNO3 + PbI2              	     	           Zn + 2HCl → ZnCl2 + H2 ↑
 	      	 (Lead      (Potassium       (Potassium (Lead        	(iii)	With dilute HNO3 : Zinc nitrate, nitrous oxide and
 	      	 nitrate)     iodide)         nitrate)   iodide)	1          water are formed.
                                                              	     	Here, HNO3, is an oxidising agent which oxidises
 	3.	(i) CaCO3(s) + 2HCl(aq) →CaCl2(s) + H2O(l)
                                                                     H2 gas to H2O.
                                           + CO2(g)           	     	4Zn + 10HNO3 → 4Zn(NO3)2 + 5H2O + N2O↑
 	(ii)	2Al(s) + 6HCl(aq) →2AlCl3(aq) + 3H2(g)                	 (iv)	With dilute NaCl : No chemical reaction takes
 	(iii)	MnO2 (s) + 4HCl(aq) →MnCl2 (aq) + 2H2O(l) +                 place.
                                          Cl2(g) 1+1+1        	 (v)	With dilute NaOH : Sodium Zincate is formed and
 			                       [CBSE Marking Scheme, 2014]               H2 gas is evolved.
                                                              	     	    Zn + 2NaOH → Na2ZnO2 + H2 ↑	           1×5
 	4.	(i) 2Al + 3H2SO4 → Al2(SO4)3 + 3H2                      	     		                  [CBSE Marking Scheme, 2013]
 	(ii)	Na2CO3 + 2HCl → 2NaCl + H2O + CO2	
 	(iii)	Ca(OH)2 + CO2 → CaCO3 + H2O	         1×3
 	     		              [CBSE Marking Scheme, 2013]
            	   TOPIC-2
                Types of Chemical Reactions-Corrosion and Rancidity
	WORKSHEET-7
Solutions                                                      	    	precipitate and the reaction in which precipitate is
                                                                     formed is called precipitation reaction.
	1.	Correct option : (c)                                       	    	Example : When sodium sulphate solution is mixed
		Explanation : The given reaction is a redox reaction               with barium chloride solution, a white precipitate
    because oxidation and reduction both take place                  of a substance (BaSO4) is formed.
    simultaneously. Also, it is a displacement reaction
    because hydrogen of NH3 has been displaced by              	    	Na2SO4(aq) + BaCl2(aq) → BaSO4(↓) + 2NaCl(aq)	
    oxygen.                                                                      [CBSE Marking Scheme, 2013] 1+1+1
	2.	In combination reactions, two substances combine
    to form one compound and in decomposition                  	5.	Rancidity.
    reactions, a compound breaks down into two or              	  	Anti-oxidants are substances which prevents
    more substances, so they are opposite to each                  oxidation, actually are reducing agents. When
    other.	                                           1            added to food, the fats and oils present in the
                                                                   food do not get oxidized easily, hence do not turn
	3.	The oxidation of oils or fats in a food resulting into         rancid and remain good to eat for longer time.
      bad smell and bad taste is called rancidity.	     1      	  		       [CBSE Marking Scheme, 2016] 1 + 1 + 1
	    	It can be prevented by :
	(i)	adding anti-oxidants.	                             1      	   6.	(i) Correct definition.
	(ii)	flushing with nitrogen gas.	                      1        (ii) rusting.
	    		                  [CBSE Marking Scheme, 2012]           	(iii)	Silver - black, copper - green.
                                                               	(iv)	Destruction of car bodies, bridges, railing, etc
	4.	
   On mixing the clear solution of two ionic                   	     		                                         (Any two)
   compounds, a substance which is insoluble in water,         	(v)	Painting, alloying, greasing etc	           (Any two)
   is formed. This insoluble substance is known as a           	     		                   [CBSE Marking Scheme, 2016] 5
P-4                                                                                                S C I ENC E - X
 	    	Detailed Answer :                                     	(iii)	Silver turns black as it reacts with H2S present in air
 	(i)	 Corrosion is a process in which metals, are                  and form a layer of Ag2S.
       deteriorated by action of air, moisture, chemicals    	(iv)	Corrosion of iron is a serious problem because it
       etc.                                                         leads to wastage of tonnes of iron every year and
 	(ii)	Corrosion of iron is called rusting.                         lot of money is spent to repair or replace it.
                                                             	(v)	The iron articles should be painted to prevent it
                                                                    from corrosion.	                     1+1+1+1+1
 	WORKSHEET-8
 Solutions                                                   		(iii) Iron : 	 Colour	— Reddish Brown
                                                             			          Chemical name	 — Ferric oxide.	1+1+1
 	1.	Correct option : (c)                                    	5.	(i) 2Mg + O2 → 2MgO
 	   	 Explanation : The substance which oxidises the        	     	MgO + H2O → Mg(OH)2
       other substances in a chemical reaction is known as
                                                             	     	Type of reaction : Oxidation reaction/Combination
       an oxidising agent. Likewise, the substance which
                                                                    reaction
       reduces the other substance in a chemical reaction
       is known as reducing agent.                           	     	(ii) CaCO3(s) → CaO(s) + CO2(g)
 	2.	Because heat is absorbed in this process.	          1   	     	(Lime stone)      (quick lime)
 	3.	Iron is more reactive than copper. Iron displaces       	     	Type of reaction : Decomposition reaction.	1½+1½
       copper from copper sulphate solution and forms        	6.	(i) Corrosion is a process in which metals, are
       iron sulphate, hence holes appear on the pot.                deteriorated by action of air, moisture, chemicals
       Chemical equation :                                          etc.
 		Fe(s) + CuSO4(aq) → FeSO4(aq) + Cu(s)	1½ + 1½            	     	Corrosion of iron is Rusting.
 	 4.	(i) Silver :	 Colour	— Black                           	(ii)	Silver - black, copper - green.
 			        Chemical name	 — Silver sulphide                 	(iii)	Car bodies, bridges, railing etc	       (Any two)
 		(ii) Copper :	 Colour	— Green                             	     	Painting, alloying, greasing etc	       (Any two)
 			        Chemical name	 — Copper oxide
 	WORKSHEET-9
 Solutions                                                   	     	When a single reactant on gaining energy
                                                                    decomposes to give two or more simpler products,
 	1.	Correct option : (a)                                           such a reaction is called a decomposition reaction.
 	  	Explanation : Exothermic reactions are the reactions
     in which heat is released along with the formation            	Example : CaCO ∆3     → CaO + CO 	   2        1½
                                                             	
     of products. When quick lime reacts with water,         	     		
     a large amount of heat is released along with the                                   [CBSE Marking Scheme, 2012]
     formation of calcium hydroxide. Similarly, the
     process of dissolving an acid or base in water is a     	5.	(i) Photochemical decomposition : A single
     highly exothermic reaction. Evaporation of water            reactant breaks down to give simpler products.
     and sublimation of camphor are endothermic
     reactions.                                              	  		                                         ½+½
 	2.	Hydrogen peroxide decomposes into H2O and O2            	  	White silver chloride changes to grey, as it
     in the presence of sunlight and hence to prevent            decomposes to silver and chlorine in presence of
     decomposition, they are kept in coloured bottles.           sunlight.	½
        2H O    Sunlight  2H2O + O2	                    1
 	     	 2 2 →                                               (ii)	2AgCl(s) Sunlight
                                                                                  → 2Ag(s) + Cl2(g)	             ½
                                                             	
 	3.	(i) Decomposition reaction                              	(iii)	Black and white photography.	                   1
 	(ii)	Displacement reaction
                                                             	      		                   [CBSE Marking Scheme, 2012]
 	(iii)	Double displacement reaction
                                                             	6.	(a) Corrosion.	                                     ½
 	(iv)	Combination reaction
 	(v)	Displacement reaction                                  	(b)	Conditions are : air and moisture.	             ½+½
 	 (vi)	Combination reaction	            ½+½+½+½+½+½         		Activity : (i) Take three test-tubes. Place clean iron
                                                                     nails in each test-tube.
 	4.	The chemical reaction in which a single product is      	(ii)	Pour some water in test-tube 1, cork it.
     formed from two or more reactants and energy is
                                                             	 (iii)	Pour water (boiled/distilled) in test-tube 2, add
     evolved, is known as combination reaction.
                                                                     some oil and cork it.
    	Example : 2Mg + O2 Burn→ 2MgO	            1½
 	                                                           	(iv)	  Put some anhydrous calcium chloride in test-tube 3
                                                                     and cork it.
	WORKSHEET-10
Solutions                                                  	4.	Gold and platinum.
	1.	Correct option : (c)                                   	(i)	Corrosion of aluminium is useful. A protective
                                                                 layer of aluminium oxide is formed on the surface
		Explanation : In beakers A and B, heat is given                of the metal which renders the metal passive and
    out, so temperature became high, hence it is an              prevents its further corrosion.
    exothermic reaction while in beaker C, heat is         	(ii)	Corrosion of iron is a serious problem. Every year
    absorbed from water, so temperature falls, hence it          large amount of money is spent to replace damaged
    is an endothermic process.                                   iron and steel structures. So, here, corrosion is a
	2.	It is a combination reaction.	                   1           serious problem.	                         1+1+1
	3.	A reaction is considered as double displacement        	    		                  [CBSE Marking Scheme, 2016]
    reaction if during the chemical reaction an
                                                           	5.	(i) At Cathode : Hydrogen gas (H2) 	                 ½
    exchange of ions takes place between two ionic
    substances.                                            	  	At Anode : Oxygen gas (O2)	                          ½
	  	Example : BaCl2 + Na2SO4 → BaSO4 + 2NaCl              	   (ii)	Since 2H2O Electric current
                                                                                 → 2H2 + O2
	  	In a displacement reaction, a more reactive element    	     	2 molecules of H2 combine with 1 mol of O2 to
    displaces or removes another less reactive element,           form H2O, so the volume of H2, liberated is double
    to form its compound. e.g. Fe + CuSO4 → FeSO4                than that of O2. 	                              1
    + Cu; whereas in a double displacement reaction,
                                                           	(iii)	When a burning splinter is brought near the
    the compounds react by exchanging their ions and
                                                                  mouth of the liberated gases, the burning splinter
    form two new compounds.	                   1½+1½
                                                                  extinguishes near the H2 gas while the burning
	  		                  [CBSE Marking Scheme, 2012]
                                                                  splinter keeps burning more near the O2 gas.	1
                                                           	     		                  [CBSE Marking Scheme, 2012]
	WORKSHEET-11
Solutions                                                  	4.	(i) Brown fumes, white residue.	             1
	1.	Correct option : (a)                                  	(ii)	Decomposition reaction	                    1
		Explanation : A dilute ferrous sulphate solution was     	    	2Pb(NO3)2 → 2PbO + 4NO2 + O2	             1
    gradually added to the beaker containing acidified     	    		                [CBSE Marking Scheme, 2012]
    permanganate solution. A permanganate solution
    is usually purple in colour. The light purple colour   	5.	(i) C is getting oxidized to CO, ZnO is getting
    of the solution fades and finally disappears. This            reduced to Zn.	                            ½+½
    is because Potassium permanganate (KMnO4)              	(ii)	As carbon is gaining oxygen and ZnO is losing
    is relatively an unstable compound, it tends to               oxygen.	                                        1
    decompose in the presence of ferrous sulphate
                                                           	(iii)	It is a redox reaction or oxidation and reduction
    (FeSO4). This changes the colour of the solution
    from purple to colourless. The FeSO4 gets oxidised            reaction.	
    to Fe2(SO4) as KMnO4 acts as a good oxidising                 CuO + H2 → Cu + H2O	1
    agent in an acidic medium                              	     		                  [CBSE Marking Scheme, 2012]
	2.	They get tarnished by reacting with atmospheric air
    to form silver sulphide.	                          1   	   6.	(i) 	 (a)	Due to the decomposition of silver chloride
                                                                        into silver and chlorine by sunlight.
	3.	(i) Yes, temperature rises as the beaker gets hot.
                                                                              Sunlight
    This is because large amount of heat is released or    			 2AgCl → 2Ag + Cl2	                                 1
    the reaction is exothermic.	                     1     		(b)	 Due to the oxidation of copper powder to
	(ii)	Combination reaction. Reaction in which a single                 copper oxide, brown colour turns into black.	 1
       product is obtained from two or more reactants.	1   			 2Cu(s) + O2(g) → 2CuO(s)
	(iii)	 CaO + H2O → Ca(OH)2 + heat	                   1   	 (ii)	(a)	 A chemical reaction in which the more reactive
	     	(Quick lime)        (Slaked lime)                               element displaces the less reactive element
	     		                 [CBSE Marking Scheme, 2012]                   from its compound is called displacement
                                                                       reaction.
P-6                                                                                             S C I ENC E - X
 			 CuSO4(aq) + Zn(s) → ZnSO4(aq) + Cu(s)	 1                 		(c)	 Combination reaction is a reaction in which
 		(b)	 A chemical reaction in which hydrogen is                      two or more than two substances combine and
        added or oxygen is removed is called reduction                form a single substance.
        reaction.                                              			 CaO + H2O → Ca(OH)2 + Heat	                 1
 			 ZnO + C → Zn + CO	                             1                                [CBSE Marking Scheme, 2012]
 	WORKSHEET-12
 Solutions                                                     	5.	(i) Any suitable exothermic reaction like
 	1.	Correct option : (b)                                      	    	CaO + H2O → Ca(OH)2 + heat	                     1
 		Explanation : Double displacement reaction is the           	(ii)	Oxidising agent : Cl2	                           ½
     reaction in which two different atoms or group of         	    	Reducing agent : H2S	                            ½
     atoms are mutually exchanged. Only in reaction            	(iii)	Rancidity, keep food in airtight containers.	 ½+½
     (Na2SO4 + BaCl2 ↓ BaSO4 + 2NaCl), sodium and
                                                               	     		                 [CBSE Marking Scheme, 2012]
     barium are mutually exchanged. Hence, correct
     option is (b).                                            	6.	(i) (a) Calcium oxide reacts vigorously with water
 	2.	To prevent the oil and fats of the chips from being                   and releases a large amount of heat.	     1
     oxidized or become rancid.	                       1       		(b)	 Calcium hydroxide (Slaked lime) i.e., Ca(OH)2
 	3.	Silver chloride (AgCl) and Silver bromide (AgBr)	 	                   is formed.	                               1
     	                                           ½+½           	 (ii)	(a)	 In small amount, solution becomes milky due
     2AgCl Sunlight    2Ag  + Cl   	               ½                      to the formation of calcium carbonate.
 	  	           →               2
                                                                                             Or
     2AgBr Sunlight
                → 2Ag + Br2	                      ½          			         Ca(OH)2 + CO2 → CaCO3 + H2O.	            1
 	  	
                                                               		(b)	 In excess, Milkiness disappears because cal-
 	    	Those reactions in which energy is absorbed (in                     cium carbonate changes to calcium hydrogen
       form of heat, light or electricity) to break down the               carbonate which is colourless in nature.
       reactants is called decomposition reaction.	       1
 	    		                   [CBSE Marking Scheme, 2012]         			  CaCO3 + H2O + CO2 → Ca(HCO3)2
                                                               		 	                     (Colourless)	                  1
 	 4.	Combination reaction : Single product is formed          	(iii)	Paint forms a protective coating on the surface of
      from two or more reactants.                                     iron so that, oxygen and moisture present in the
 	   	CaO + H2O → Ca(OH)2	                       1½                  air cannot have a direct contact with iron. 	   1
 		Decomposition reaction : A single reactant breaks           	    		                  [CBSE Marking Scheme, 2010]
      down to give simpler products.	
 	   	CaCO ∆3  → CaO + CO       2	              1½
 	    		                  [CBSE Marking Scheme, 2012]
qqq
 B
 2         ACIDS, BASES AND SALTS
              	   TOPIC-1
                  Acids and Bases
  	WORKSHEET-13
  Solutions                                                     	5.	(i) Solution Y is a stronger acid.
  	1.	Correct option : (c)                                      	(ii)	Strong acid : An acid which dissociates completely
                                                                       in water and produces a large amount of hydrogen
  	  	Explanation : Vanilla essence can be used as an
                                                                       ions. e.g., HCl.
      acid-base indicator by visually impaired students as
      it is an olfactory indicator whose odour changes in       		Weak acid : An acid which dissociates partially in
      acidic or basic media.]                                          water and produces small amount of hydrogen
                                                                       ions. e.g., CH3COOH.
  	2.	Formic acid (Methanoic acid), HCOOH.	      1                                 [CBSE Marking Scheme, 2016] 1 + 1 + 1
  	  		                [CBSE Marking Scheme, 2010]              	6.	(i) Tomato — Malic acid and citric acid
                                                                	(ii)	Vinegar — Acetic acid
  	3.	Acids which ionize completely in aqueous solution :       	(iii)	Tamarind — Tartaric acid and citric acid.	 1 + 1 + 1
      strong acids. 	                                 ½
                                                                	7.	(i) Scale for measuring [H+] concentration in a
  	  	Acids which ionize partially in aqueous
                                                                       solution is called pH scale.
      solution : weak acids	                          ½
  	  	Hydrochloric acid, nitric acid : strong acid	 ½+½         	     	Refer to below figure :
  	  	Acetic acid, formic acid : weak acid	         ½+½                                    Neutral
  	  		                  [CBSE Marking Scheme, 2012]             0 Acidic nature increasing 7 Basic nature increasing 14
  	4.	(i) Alkali.	                                        ½
                                                                                     +                                +
  	     	NaOH or KOH	                                     ½           Increasing in H ion           Decreasing in H
  	(ii)	Tooth decay starts when the pH of the mouth is                   concentration               concentration
        lower than 5·5. It can be prevented by using tooth
        pastes which are generally basic.	              1       	(ii)	pH of Neutral solution is 7.
  	(iii)	Bee-sting has acid that causes pain and irritation.    	    	pH of Acidic solution is 0 to below 7.
         Baking soda being alkaline, neutralizes acid and       	    	pH of Basic solution is 7 to 14.
         gives relief.	   [CBSE Marking Scheme, 2012] 1         	    		       [CBSE Marking Scheme, 2016] 1 + 2 + 2
  	WORKSHEET-14
  Solutions                                                         Commonly Made Error
  	1.	Correct option : (a)                                      	 	 Students usually get confused with the pH values.
  	  	Explanation : Lime juice is acidic in nature as the
      juice is obtained from lime, a citrus fruit. This             Answering Tip
      contains citric acid, and is therefore sour in taste.     	 	 Practice the different pH values mentioned with
  	2.	When milk changes into curd, its pH will decrease.             examples in the chapter.
      Because curd contains lactic acid, so H+ ion
      concentration increases and thus pH will decrease.	1        4	 . (i) B → 7	           (ii)	D → 11	
                                                                	 (iii)	C → 1	              (iv)	A → 4
  	3.	(i) Increase in the strength of alkali. So the nature     	 (v)	E → 9			                             ½ × 5 = 2½
         of solution will be basic.	                       1    		Arrangement : D, E, B, A, C or 11, 9, 7, 4, 1.	   ½
  	(ii)	Hydroxide ion or hydroxyl ion or OH– ion.	         1
  	(iii)	A paper impregnated with the universal indicator       	     5.	(i)	 (a) Solution of glucose will not conduct
         is generally used to measure the pH of a solution. 1                 electricity because it does not have ions.
  	     		                   [CBSE Marking Scheme, 2012]        	       	(b)	 Dil. HCl will conduct electricity because it
                                                                              produces H+ ions in water.	                ½+½
  P-8                                                                                                 S C I ENC E - X
 	(ii)	HCl is stronger because it gives rise to more H+           	7.	(i) Universal indicator is a mixture of many different
        ions than acetic acid.	                       1                  indication (or dyes) which give different colours
 	(iii)	The strength of the acid decreases.	          1                  at different pH values of the entire pH scale. The
 	     		                  [CBSE Marking Scheme, 2012]                   colour produced by universal indicator is used to
                                                                         find the pH value of acid or base by matching the
 	6.	                                                                    colour with the colours on pH colour chart.
                                                                  	(ii)	Solution A is acidic and will turn litmus solution
                         Colour change                                   from blue to red.
      Name of the                           Colour change
       solution              with                                 	     	Solution B is basic and will turn phenolphthalein
                        phenolphthalein    with blue litmus
                                                                         from colourless to pink.
     1. Sodium                                                    	(iii)	Green colour will be obtained.
        carbonate          turns pink          no change
                                                                  	     		        [CBSE Marking Scheme, 2016] 2 + 2 + 1
     2. Hydrochloric
        acid               no change           turns red
     3. Sodium
        chloride           no change           no change
 	WORKSHEET-15
 Solutions                                                         Commonly Made Error
 	1.	Correct option : (c)                                         	 	 Usually students get confused with the action of
 	    	Explanation : The role of calcium chloride taken in             wet or dry litmus paper and reason for the same.
       the guard tube is to absorb moisture from the gas.
       This is because calcium chloride is used as a drying        Answering Tip
       agent which absorbs moisture from the hydrogen
       chloride (HCl) gas.                                        	 	 The concept of ionization of acids in aqueous
 	2.	Hydrogen gas.	                                           1        medium to give hydrogen or hydronium ions
 	  3.	(i) The acid must slowly be added to water.	           1        should be kept in mind.
 	(ii)	Otherwise the mixture may splash out causing
       burns, as a lot of heat is generated in this process.	 1   	6.	Sweet tooth leads to tooth decay, which is caused
 	(iii)	Dilution of the acid.	                                1       by the action of bacteria on food particles remaining
                                                                      in the mouth and acid is formed. As a result, the
 	4.	Zn + 2NaOH → Na2ZnO2 + H2                                        pH of the mouth falls below 5.5 and the tooth
 		When a burning splinter is brought near the gas, it                enamel dissolves resulting in cavities. Toothpastes
     burns with a Pop Sound.                                          are generally basic, they neutralize the excess acid
 	  	Gas – Hydrogen / H2                                              produced in the mouth and prevent tooth decay.
 	  		      [CBSE Marking Scheme, 2018] 1 + 1 + 1                 	  		                 [CBSE Marking Scheme, 2018] 3
     Commonly Made Error                                          	 Ans.	(i) HCl will give rise to more H+ ions and
 	 	 Usually students get confused with the liberation of               CH3COOH produces less H+ ions on dissociation.
      gas in the reaction of zinc with acids and bases.                  The colour of pH paper depends on the
                                                                         concentration of H+ ion. Colour becomes red for
                                                                         high H+ concentration.	                       1
     Answering Tip                                                	(ii)	Aqueous solution of acids have H+ ions which
 	 	 Keenly observe the reactions during practicals, zinc               carry electric current through the solution.	 1
      reacts with both acids and bases to give out hydrogen
                                                                  	(iii)	(a) Most acidic : A, Most basic : C	      ½+½
      gas but remember the above said reactions are not
                                                                  	     	(b) C, B, D, A / C < B < D < A	           ½+½
      possible with all metals.
                                                                  	     	(c) In C- blue, In D- green	              ½+½
                                                                  	     		                   [CBSE Marking Scheme, 2012]
 	5.	Wet blue litmus paper	                       ½
 		  Reason : Hydrogen ions are produced by HCl in                 Answering Tip
     the presence of water.	                       1
                                                                  	 	 Do not overlook any part of a question and avoid
 	  	It has acidic nature.	                       ½
                                                                       being in a hurry to conclude the answer.
 	  	HCl + H2O → H3O+ + Cl–	                       1
 	  		                   [CBSE Marking Scheme, 2018]
	WORKSHEET-17
Solutions                                                     	(vi)	Liquid hydrogen is used as a fuel in rockets.	 ½ × 6
P-10                                                                                                S C I ENC E - X
 	(iii)	1M NaOH solution.                                     	(v)	As hydronium [H3O]+ ion.
 	(iv)	When the pH in the mouth is below 5.5, bacteria        	   		[CBSE Marking Scheme, 2016] 1 + 1 + 1 + 1 + 1
        present in the mouth produce acids by degradation
        of sugar and corrode the tooth enamel. It can
        be prevented by using toothpastes which are
        generally basic.
 	WORKSHEET-18
 Solutions                                                    	2.	At lower pH below 5.5, the calcium phosphate of
                                                                  enamel of tooth gets corroded, which leads to tooth
 	1.	Correct option : (b)
                                                                  decay.	                                           1
 	   	Explanation : Citric acid is an example of organic acid
      or edible acid.
 	3.
                           Stand
                                                          Delivery tube
                       Test-tube
                                                                  Burning of hydrogen
                                                                  gas with a pop sound
                         Dilute
                      sulphuric
                           acid                  Hydrogen
                                                 gas
                  Zinc granules                  bubbles
Soap solution
	WORKSHEET-19
Solutions                                                         	6.	Water of crystallization is the fixed number of
	1.	Correct option : (b)                                                 water molecules present in one formula unit of
	  	Explanation : Water of crystallisation is the fixed                  salt.	                                      1
    number of water molecules presenting one formula              	(i)	Five molecules of water.	                    ½
    unit of a salt. Potassium nitrate, barium sulphate,           	(ii)	Formula : CuSO4.5H2O	                       ½
    potassium chloride, sodium nitrate, baking soda, etc.,        	(iii)	When heated, its colour changes from blue to
    are the salts that do not contain water of crystallisation.          white.	        [CBSE Marking Scheme, 2012] 1
	2.	Baking soda.	                                             1
                                                                  	7.	(i) Distilled water does not conduct electricity
	3.	(i) Salt that contains water of crystallization.	      1
                                                                      because it does not contain any ionic compound
	(ii)	Washing soda — Na2CO3.10H2O
                                                                      like acids, bases or salts dissolved in it.
	     	Gypsum — CaSO4.2H2O
                                                                  	(ii)	When we overeat, excess of acid is produced in the
                                 1                                      stomach which causes burning sensation.
	     		Plaster of paris — CaSO4. H2O.	(Any two) 1 + 1
	     	                          2                                	(iii)	Copper vessels tarnish due to formation of basic
                           [CBSE Marking Scheme, 2012]                   copper carbonate which gets neutralized when
                                                                         rubbed with lemon and the copper vessel regains
	4.	(i) Bleaching powder : CaOCl2                                        its shine.
	(ii)	Ca(OH)2 + Cl2 → CaOCl2 + H2O                               	(iv)	Washing soda is sodium carbonate decahydrate
	(iii)	Two uses other than disinfection are :                           which when exposed to air loses 10 molecules of
	     	(a) Paper industries (b) Chemical Industries.                    water and changes to white powder.
	     		       [CBSE Marking Scheme, 2016] 1 + 1 + 1              	(v)	Sodium chloride is a salt of strong acid HCl and
	5.	(i) X = Chlorine gas, Y = Calcium oxychloride                      strong base NaOH, so it is neutral.
	(ii)	Ca(OH)2 + Cl2 → CaOCl2 + H2O                               	    	Sodium carbonate is a salt of weak acid H2CO3 and
	    	(Dry slaked (Chlorine) (Calcium (Water)                           strong base NaOH, so it is basic. 	1 + 1 + 1 + 1 +1
	    	lime)                    oxy-chloride)                      	    		                   [CBSE Marking Scheme, 2014]
	    	                     (Bleaching agent)	 1+1+1
	WORKSHEET-20
Solutions                                                         	4.	(i) Compound is NaHCO3/baking soda/sodium
                                                                      hydrogen carbonate	
	1.	Correct option : (d)
	  	Explanation : Sodium carbonate is a basic salt of             	    	Manufacture : NH3 + NaCl + H2O + CO2 →
    weak acid i.e. carbonic acid and a strong base i.e.                                            NH4Cl + NaHCO3
    sodium hydroxide.                                                                Heat
                                                                  	(ii)	2 NaHCO3 → Na2CO3 + H2O + CO2	
	2.	The colour of litmus in a solution of sodium                  	    		     [CBSE Marking Scheme, 2016] 1 + 1 + 1
    carbonate is blue.	                              1
	3.	Chemical formula : CaOCl2	                        ½           	5.	It is a salt produced by the neutralization reaction
                                                                      between a strong base (NaOH) and a weak acid
	     	Chemical equation :
                                                                      (H2CO3), hence it is a basic salt.	                1
	     	Ca(OH)2 + Cl2    → CaOCl2 + H2O	              1          	  	It is heated strongly to produce sodium carbonate.
	     	Uses :
	(i)	For bleaching cotton and linen in textile industry½              2NaHCO3 ∆      → Na2CO3 + H2O + CO2	             1
                                                                  	  	
	(ii)	As an oxidising agent in a chemical industry.	 ½            	  	Sodium carbonate is recrystallized to produce
	(iii)	For disinfecting water.	                       ½               washing soda.
	     		                 [CBSE Marking Scheme, 2012]              		  Na2CO3 + 10H2O        → Na2CO3.10H2O	1
                                                                  	  		                   [CBSE Marking Scheme, 2012]
P-12                                                                                                 S C I ENC E - X
 	6.	CaCO3 + 2HCl ¾® CaCl2 + H2O + CO2 	           1         	      	Activity : (i) Heat a few crystals of copper sulphate
 	  	Marble is calcium carbonate and on reacting with                in a dry boiling tube.
     HCl releases CO2.                                       	(ii)	Add 2-3 drops of water on the sample of copper
 	  	Ca(OH)2 + CO2 ¾® CaCO3 + H2O                                  sulphate obtained after heating.
 	  	(Lime water)             (White ppt)                    	      	After heating, water is removed and salt turns
 	  	Lime water turns milky due to the formation of                  white.
     white precipitate of CaCO3. On passing excess
                                                             	      	If crystals are moisten again with water, blue colour
     CO2, milkiness disappears because Ca(HCO3)2 is
                                                                     reappears. Water of crystallization is fixed number
     formed, which is soluble in water.	           1
                                                                     of water molecules present in one formulae unit
 	  	CaCO3 + H2O + CO2 ¾® Ca(HCO3)2	               1
                                                                     of a salt. Five water molecules are present in one
 	  	                             Soluble in water
                                                                     formula unit of copper sulphate.
 	  		                 [CBSE Marking Scheme, 2012]
                                                             	(b)	Calcium sulphate hemihydrate – CaSO4.½H2O
 	WORKSHEET-21
 Solutions                                                                            1
                                                                  4.	(i) (a) CaSO4.     H2O
 	1.	Correct option : (c)                                    	                        2
 	  	Explanation : The common salt obtained is an            	    	(b) CaSO4.2H2O	                  ½+½
     important raw material for various materials of         	(ii)	By mixing with water	
     daily use, such as sodium hydroxide, baking soda,                    1         1
                                                                   CaSO4. H2O + 1 H2O → CaSO4.2H2O 	 1
     washing soda and many more.                             	    	       2         2
 	2.	When baking soda is heated, it decomposes to            	(iii)	For making toys, for supporting fractured bones.	1
     produce sodium carbonate, water and CO2 gas.	 1         	     		                 [CBSE Marking Scheme, 2012]
    soda (sodium hydrogen carbonate) and a mild                  CO2	       [CBSE Marking Scheme, 2012] ½
    edible acid such as tartaric acid.
	2.	(a) Copper sulphate crystals (CuSO4.5H2O)             	5.	(i) Plaster of Paris / Calcium sulphate hemihydrate
                                                                       1
	  	5 molecules of water are present in one formula           CaSO4. H2O.	                                     1
                                                                       2
    unit of copper sulphate. When heated, its loses its
    water and salt turns white.	                     1                         Heat             1        1
                                                              (ii)	CaSO4.2H2O 373
                                                                                 K
                                                                                     → CaSO4.     H2O + 1 H2O	1
	(b)	Basic Salt :                                         	                                     2        2      	
		(i) 	 Base — KOH (Potassium hydroxide)	       ½         	(iii)	Used as a plaster for supporting fractured bones.½
		 	 Acid — H2SO4 (Sulphuric acid)	             ½         	     	Used for making toys / statues / decorative items.½
		   (ii)	 Base — NH4OH (Ammonium hydroxide)	 ½           	     		                  [CBSE Marking Scheme, 2012]
		 	 Acid — HCl (Hydrochloric acid)	            ½
                                                          	6.	(a) The common name of CaOCl2 is Bleaching
			                   [CBSE Marking Scheme, 2012]
                                                              powder.	                                       ½
	  3.	(i) X – Sodium hydrogen carbonate or baking soda.   	  	By passing chlorine into dry slaked lime (Ca(OH)2)
          Y – CO2                                         	     	    Ca(OH)2 + Cl2 
                                                                                    → CaOCl2 + H2O	              1
	(ii)	NaHCO3 + HCl → NaCl + H2O + CO2↑                   		Two uses :
			                                          1+1+1        		(i)	 Used for bleaching cotton and linen in the
			                     [CBSE Marking Scheme, 2013]
                                                                   textile industry and wood pulp in paper
                                                                   industry etc.	                                ½
	4.	Baking powder.	                            ½          		(ii)	 It is used for disinfecting drinking water.	 ½
	  	Baking soda and tartaric acid.	         ½+½
                                                          	(b)	Washing Soda : Na2CO3.10H2O	                     ½
	  	On heating or mixing with water, sodium
    bicarbonate reacts with hydrogen ion from acid        	   	By heating baking soda, sodium carbonate is
    and releases CO2 that makes the cake soft and              obtained, its recrystallization gives washing soda.1
    fluffy.	                                    1                2NaHCO3 Heat
                                                                            → Na2CO3 + H2O + CO2	      ½
                                                          	     	
                                                          	     	Na2CO3 + 10H2O → Na2CO3.10H2O	       ½
                                                          	     		             [CBSE Marking Scheme, 2012]
qqq
P-14                                                                                          S C I ENC E - X
CHAPTER
SECTION
 B
 3          METALS AND NON-METALS
              	   TOPIC-1
                  Properties of Metals and Non-Metals
  	WORKSHEET-23
  Solutions                                                       Answering Tip
  	   1.	Correct option : (c)                                    	 	 Learn and understand the different physical and
                                                                      chemical properties of metals and non-metals with
  	  	Explanation : Metals in their pure state have a
                                                                      unique reactions.
      shining surface and thus, dullness property is not
      shown by metals.                                           	6.	(i) Non-metals are electron acceptors, they cannot
  	2.	Metal – mercury, Non-metal – bromine.	      ½+½                   supply electrons so as to convert H+ ion to H2(g).
                                                                 	(ii)	Like metals, hydrogen can lose an electron to form
  	3.	Three properties of sodium are :
                                                                        positive H+ ion.
  	(i)	Sodium is so soft that it can be cut with a knife.	   1   	(iii)	Aluminium is covered with a strong protective
  	(ii)	It has low density.	                                 1          layer of oxide which protects the metal from further
  	(iii)	It has low melting points.	                         1          corrosion.	                                  1+1+1
  	   4.	(a) 	(i) Oxides of metal are basic / amphoteric.	   ½   	7.	(a)
  			 Oxides of non-metal are acidic/neutral.	               ½     S.             Metals                Non-Metals
  		(ii) 	Metals are good conductors whereas non-                  No.
              metals are poor conductors.	                   1
                                                                    1.   Lose electrons to form Gain electrons to
  	(b)	Iodine and Mercury.	                                ½+½           positive ions/ are elec- form negative ions/
  	5.	(i) X — Carbon, Y — Diamond, Z — Graphite                          tropositive in nature.   are electronegative
  	(ii)	Non-metal                                                                                 in nature.
  	(iii)	Tin.	                            1+1+1                     2.   React with dilute acids Do not react with
  	     		              [CBSE Marking Scheme, 2016]                      to liberate hydrogen gas. dilute acids .
                                                                    3.   Generally metal oxides Generally non-met-
  Commonly Made Error                                                    are basic in nature.   al oxides are acidic
  	 	 Usually students get confused with different                                             in nature.
       physical and chemical properties of metals and non-       	 (b)	(i)	 Painting
       metals.                                                   		(ii)	 Oiling
                                                                 		(iii)	Galvanization
                                                                 		(vi)	Alloying      (or any other)
                                                                  [CBSE Marking Scheme, 2018] 5
  	WORKSHEET-24
  Solutions                                                       Commonly Made Error
  	   1.	Correct option : (a)                                    	 	 Usually students get confused with different
  	     	Explanation : The ability of metals to be drawn into         physical properties of metals.
         thin wires is called ductility.
  	2.	Gallium.	                                             1     Answering Tip
  	3.	(i) Gold and silver are most malleable metal and           	 	 Learn and understand all the physical properties of
         most ductile metal.                                          metals.
  	(ii)	Silver is the best conductor of heat and lead is the     	4.	(i) 4Al + 3O2 → 2Al2O3, Aluminium oxide	    1
         poorest conductor of heat.                              	(ii)	3Fe + 4H2O → Fe3O4 + 4H2, Ferric oxide	   1
  	(iii)	Metal with highest melting point : Tungsten, iron.
                                                                 	(iii)	Ca + 2H2O → Ca(OH)2 + H2, because hydrogen
  	     	Metal with lowest melting point : Gallium, Cesium.	
                                      ½ + ½ + ½ + ½ +½ + ½              sticks to calcium.	                       1
            	   TOPIC-2
                Ionic compounds, Metallurgy and Corrosion
	WORKSHEET-25
Solutions
	    1.	Correct option : (a)                                                        +
	  	Explanation : Sodium and potassium are extracted
                                                                                                       Cathode
    by electrolytic reduction. Metals obtained after
                                                                                                       (Pure metal)
    electrolytic reduction are in pure form. But, copper
    and gold are in impure form after extraction. Copper
    and gold are refined by electrolytic refining methods.             Anode
	2.	Reduction of iron oxide to iron by aluminium is                  (Impure                            Solution of
    called thermite reaction.	                          1              metal)                           metal salt
	     	     Fe2O3 + 2Al → 2Fe + Al2O3 + Heat.                   Anode mud                              (Electrolyte)
                                                                             Electrolytic refining
	    3.	Electrolytic Refining : This method is widely used    	
        as purification of metals like zinc (Zn), copper      		 (Electrolytic refining of copper with explanation)
        (Cu), aluminium (Al), chromium (Cr), tin (Sn), lead
                                                              		                    [CBSE Marking Scheme, 2014] 3
        (Pb), nickel (Ni) and gold (Au).
	      	In this process, impure metal is used as anode, a     Commonly Made Error
        strip of pure metal is used as cathode and soluble
        salt of metal is used as electrolyte. On passing      	 	 Usually students get confused between anode,
        electric current through the electrolyte, cations          cathode and the electrolyte.
        move towards cathode, gain electrons and pure
        metal gets deposited on cathode.                       Answering Tip
	      	In electrolytic refining of copper, the impurities    	 	 Carefully understand the electrolytic reductions of
        left behind at anode called anode mud contains             metals. Practice drawing a well-labelled diagram.
        valuable metals such as gold and silver which can
        be recovered in the native state.
P-16                                                                                              S C I ENC E - X
 	4.	(i) Calcium (20) – 2, 8, 8, 2   Oxygen (8) – 2, 6 	   1    	5.	Calcination : Heating the ore strongly in limited
                                          –2                        amount of oxygen.
       Ca + O              (Ca2+) O                                                Heat
                                                                  	ZnCO3 → ZnO + CO2
 		                                        	         1          	
 	(ii)	Constituents metals of bronze – copper, tin.	 1          		Reduction : Converting ZnO to Zn with the help
 	    		                [CBSE Marking Scheme, 2012]                of carbon.
                                                                	 	ZnO + C → Zn + CO	              1+½+1+½
                                                                	 		              [CBSE Marking Scheme, 2013]
     Commonly Made Error
 	 	 Usually students get confused in writing the              	6.	(i) Diagrams (activity 3.5 fig. 3.1)
      electronic configuration, drawing the dot structure,      		Procedure
      cations and anions.                                       	    	Observation : Heat is transferred from one end of
                                                                      metal wire to the free end of wire which melts the
     Answering Tip                                                    wax and pin falls. Shows metals conduct heat.
                                                                	(ii)	Ore     HgS cinnabar
 	 	 Learn to write the electronic configuration and
                                                                	    	Roasting : 2HgS(s) + 3O2(g) → 2HgO(s) +
      understand the concept of sharing in ionic
                                                                      2SO2(g)
      compounds. Electron donating atoms become                                               ∆
      cations and electron receiving atoms become anions.       	    	Reduction : 2HgO(s)     → 2Hg(l) + O2(g)      5
                                                                                          [CBSE Marking Scheme, 2018]
 	WORKSHEET-26
 Solutions                                                      	4.	(i) A large amount of energy is required to break
                                                                      the strong inter-ionic attraction.
 	     1.	Correct option : (c)
 	  	Explanation : Sulphur is present in air and silver         	(ii)	When ionic compounds is present in molten state,
     gets tarnished after the reaction of sulphur. Because            crystal structure deforms and they can easily
                                                                      conduct electricity with the mobile ions.
     of formation of layer of silver sulphide silver articles
     become black on prolonged exposure to air.                 	(iii)	Due to the strong force of attraction between the
 	2.	Paint forms a protective coating on the surface                   positive and negative ions.	              1+1+1
     of iron. So, oxygen and moisture present in the            	     		                 [CBSE Marking Scheme, 2012]
     air cannot have a direct contact with the metal.
     Therefore, surface gets protected against rusting.	 1      	5.	Cinnabar (HgS) is an ore of mercury.
                                                                	  	When Cinnabar, HgS is heated in air, it is first
 	3.	(i) Self reduction                                             converted into HgO, HgO is then reduced to Hg
                  Heat                                              on further heating.
            2HgO 
                   → 2Hg + O2
 	      	                                                                                          ∆
                          Heat
            2Cu 2O + Cu 2S 
                             → 6Cu + SO2                   1    	     		          2HgS + 3O2	 
                                                                                               → 2HgO + 2SO2
 	     	                                  	
                                                                                                   ∆
 	(ii)	Reduction using carbon                                   			                     2HgO	 
                                                                                               → 2Hg + O2
 	     	ZnO + C → Zn + CO                                      	     		                    [CBSE Marking Scheme, 2016]
 	     	Sometimes, some highly reactive metals are used
                                                                	 etailed Answer :
                                                                D
        as reducing agents.
 	     	e.g., 3MnO2 + 4Al → 3Mn + 2Al2O3 + heat                	     	Cinnabar (HgS) is an ore of Mercury.
 	     	or Fe2O3 + 2Al → 2Fe + Al2O3 + heat	            1      	     	The metals being less reactive can be obtained by
 	(iii)	Electrolytic reduction                                         reducing their oxides to metals by heating alone.
 	     	e.g., Na, Mg and Ca are obtained by electrolysis of     	     	So, when Cinnabar is heated in air, it first changes
        their molten chlorides.	                         1             into its oxide and then into mercury metal.
 	     		                  [CBSE Marking Scheme, 2012]                                          Heat
                                                                	    	2HgS(s)	 +	 3O2(g)	 
                                                                                            → 	 2HgO(s)	 +	2SO2(g)
     Commonly Made Error                                        	    	(Cinnabar)	(Air)	                Mercury	Sulphur
 	 	 Students often get confused between the methods
                                                                	    		       	     	                  oxide	dioxide
      of reduction of metals.
                                                                                             ∆
                                                                	    		     2HgO(s)	        → 	2Hg(l)	 +	O2(g)
     Answering Tip
                                                                	    	 Mercuric   (II) oxide	     Mercury metal	   Oxygen
 	 	 Make a list of less, moderate and highly reactive                                                           1+1+1
      metals and learn the different processes involved in
      their reduction.
	    	Labelled diagram of electrolytic refining of copper    	      	In electrolytic refining of copper, the impurities
                         –
                   Key– +e
                                                                     left behind at anode called anode mud contains
                     –                                               valuable metals such as gold and silver which can
                                                                     be recovered in the native state.
     Cathode                      Anode
                                       Acidified                                     +
                                       copper
                      Cu   2+          sulphate                                                          Cathode
                                       solution                                                          (Pure metal)
                       Cu
                                        Tank
                                                                        Anode
                                        Impurities                    (Impure                            Solution of
                                        (anode mud)                     metal)                           metal salt
                       [CBSE Marking scheme, 2018] 5              Anode mud                             (Electrolyte)
	 etailed Answer :
D                                                                                Electrolytic refining
	(i)	A metal is obtained from its carbonate ore by
       converting it into its oxide by the process of            Commonly Made Error
       Calcination.
                                                             	 	 Usually students get confused with the order of
	    	
     In Calcination, the ore is heated to a high                  the steps in extraction and sulphide ore extraction
     temperature in the absence of air.                           technique.
                ∆
	    	ZnCO3(s)  → ZnO(s) + CO2(g)
                                                                 Answering Tip
	    	
     The metal oxides obtained by calcination are
     converted into the free metal by using reducing         	 	 Understand the concept of ore extraction and the
     agents like carbon, aluminium which depend upon              order of the steps involved in the extraction and
     the reactivity of the metal.                                 the equation separately for sulphide and oxide ores.
                                                                  Diagrams are equally important.
	    	               ZnO + C → Zn + CO.
	    	
     Impure Zn obtained is refined by electrolysis
     process.
	WORKSHEET-27
Solutions
	   1.	Correct option : (c)                                  	4.	Steps :
	  	Explanation : In the process of galvanization, iron is   	 (i)	Roasting : Sulphide ores are converted into oxides
    covered by a coat of zinc. This layer of zinc prevents         by heating strongly in the presence of excess air.	1
                                                                                    Heat
    iron from getting rusted.                                        2ZnS + 3O2 → 2ZnO + 2SO2	                         ½
                                                             	      	
	2.	Because aluminium has greater affinity for oxygen
    than for carbon, therefore carbon cannot reduce          	    (ii)	Reduction : Metal oxides are then reduced to the
                                                                       corresponding metal by using suitable reducing
    alumina (Al2O3) to aluminium.	                       1
                                                                       agent (carbon).	                              1
	3.	(i) Aluminium (Al)	                            ½         	        	ZnO + C → Zn + CO	                           ½
	(ii)	Iron (Fe)	                                   ½         	        		                [CBSE Marking Scheme, 2012]
	(iii)	Fe2O3 + 2Al → 2Fe + Al2O3 + Heat.	         1         	5.	The metal is copper. The metal has corroded because
	(iv)	Use : To join railway tracks or cracked machine            of being exposed to moist air. Green compound is
       parts.	        [CBSE Marking Scheme, 2012] 1              basic copper carbonate [CuCO3. Cu(OH)2]
P-18                                                                                               S C I ENC E - X
 		Two ways to prevent this process :                          	7.	The two reactive metals are sodium (Na) and
 	 	Painting, Greasing, Oiling, Galvanizing 	 (Any two)            potassium (K). Sodium reacts with chlorine.	 1 + 1
 	 		                                          1+1+1
                                                               	    	Na 	    → 	     Na+       + e–
 	6.	(i) Metal X is obtained simply by heating their           		2, 8, 1 		           2, 8
     oxides with carbon. e.g., mercury is obtained from
                                                               				                   (Sodium cation)
     cinnabar.
                                                               		Cl         + e → Cl–
                                                                               –
       	2HgS(s) + 3O2(g) Heat
                             → 2HgO(s) + 2SO2(g)
 	                                                             		2, 8, 7 		           2, 8, 8
 	     	2HgO(s) Heat
                  → 2Hg(l) + O2(g) 	                      1    				                   (Chloride anion)
                                                                                                            –
 	(ii)	Metals in the middle of activity series can be                Na +      Cl            [Na+]     Cl
                                                               		                                               	     1
       obtained by heating with carbon, e.g.,
                                                               	    	Ionic compounds have high melting and boiling
        ZnO(s) + C(s) Heat
                          → Zn(s) + CO(g)	             1
 	     	                                                             points.	
 	(iii)	Metals high in the reactivity series are obtained by   	    	They are good conductors of electricity.
        electrolytic reduction of molten ores e.g., in NaCl    	    	They are generally soluble in water and insoluble
 	     	NaCl → Na+ + Cl–                                            in organic solvents.
                                                               	    	They are solid, hard and brittle.	   4×½ = 2
 	     	Na + e– → Na (at cathode)
                                                               	    		                  [CBSE Marking Scheme, 2012]
 	     	2Cl– → Cl2 + 2e– (at anode)	                    1
 	     		                 [CBSE Marking Scheme, 2014]
qqq
 B
 4              CARBON COMPOUNDS
                  	   TOPIC-1
                      Carbon and its Properties, Homologous Series and
                      IUPAC Names
  	WORKSHEET-28
  Solutions                                                         	5.	Carbon cannot form C4+ cation because removal
                                                                        of 4 electrons from a carbon atom would require a
  	        1.	Correct option : (b)                                      large amount of energy.	                          ½
  	         	Explanation : Carbon is present in the atmosphere      	  	Carbon cannot form C4– anion because it would be
             in the form of carbon dioxide gas (CO2) in air (only       difficult for the nucleus with 6 protons to hold on
             0.03%). Carbon also occurs in the earth’s crust in         to 10 electrons.	                                 ½
             the form of minerals like carbonates. It also occurs   	  	Hence, carbon atoms share electrons forming
             in the form of fossil, organic compounds, wood,            covalent compounds	                                 1
             cotton and wool, etc. products.
                                                                    	  	Covalent compounds do not form ions/ charged
  	2.	A homologous series is the family of organic                      particles and therefore do not conduct electricity.	½
      compound having the same functional group, and                	  	Inter molecular forces of attraction are weak, hence
      the successive (adjacent) members of which differ                 low melting and boiling points.	                  ½
      by CH2 unit or 14 mass unit.	                   1             	  		                   [CBSE Marking Scheme, 2017]
  			                     [CBSE Marking Scheme, 2016]               Detailed Answer :
                                                                    	    	Atomic number of carbon is six. This means that it
  	3.	  A group of organic compounds having the
                                                                          has four electrons in its outermost shell and it needs
        same functional group and similar structures
                                                                          four more electrons to attain noble gas electronic
        in which any two successive members differ by
                                                                          configuration. It does not form C4+ cation, as the
        – CH2.	                                          1
                                                                          removal of four valence electrons will require a
  	(i)	All members have similar chemical properties	 ½
                                                                          huge amount of energy. The cation formed will
  	(ii)	There is gradation in the physical properties.	 ½
                                                                          have six protons and two electrons. This makes it
  	    		                                    (or any other)               highly unstable. Carbon is unable to form C4– anion
  		    Name — Ethanoic acid/Acetic acid	               ½                 as its nucleus with six protons will not be able to
  	    	Formula — CH3COOH	                              ½                 hold ten electrons. Thus, carbon achieves noble
  	    		                  [CBSE Marking Scheme, 2017]                    gas electronic configuration by sharing its four
                                                                          electrons with other elements, i.e. it forms covalent
  	4.	The compounds that are formed due to sharing of                     compounds.
        electrons between two atoms/compounds having                	(i)	 Covalent compounds are bad conductors of
        covalent bonds.	                                1                 electricity due to lack of free electrons.
  	    	Ionic compounds are formed due to transfer of               	(ii)	Covalent compounds are formed by covalent bonds
        electrons from one atom to another/compounds                      and it has been found that the intermolecular forces
        having ionic bonds/compounds having attraction                    of attraction in covalent compounds are weak.
        between oppositely charged ions	                1                 Thus, their melting and boiling points are quite low.
  	(i)	They are poor conductors of electricity	        ½            	    	They cannot ionize producing ions in molten state
  	(ii)	They have low melting and boiling point. 	     ½                  which are mainly require to conduct electricity.	     	
  	    		                                  (or any other)                 	                                              3+1+1
  	    		                 [CBSE Marking Scheme, 2017]
6.
  P-20                                                                                                   S C I ENC E - X
     		                                                                                                                   	
 	WORKSHEET-29
 Solutions                                                    	(i)	The parent chain should have the most number of
                                                                    carbon atoms.
 	   1.	Correct option : (b)                                  	(ii)	The branching cannot be done from the first on
 	  	Explanation : Ethane has 7 covalent bonds. One                 the last atom carbon atom of the structure.	1+1+1
     bond is between two carbon atoms and rest of the         	    		                  [CBSE Marking Scheme, 2015]
     six are between hydrogen atoms.
 	2.	The molecular formula of first two consecutive
                                                              	4.	(a) Carbon compounds form covalent bonds/
     members of this series is :
                                                                   do not dissociate into ions/do not have charged
 	  	CH3Cl (Chloromethane)                                         particles (ions)	                            ½
 	      	C2H5Cl (Chloroethane)	                     ½+½       	(b)	Cyclohexane
 	3.	Isomers are the compounds which have the same                              H    H    H     H
        molecular formula but different structural formula.                            C               C
                                                                             H                                 H
 somers of Butane :
             H     H   H     H                                                    C                        C
    (i)
               |     |       |   |                                            H        C               C       H
             H— C—C— C—C —H
                                                                                   H       H       H       H
               |     |       |   |
               H     H       H   H                            	       	Total no. of single bonds = 18
 	       	           n-butane                                 	       	(OR any other cycloalkane with corresponding
     (ii)	            H|                                               number of bonds)	                    1 + 1 +1
                                                                                      —
                                                                                      —
                                                                                                                         —
                                                                                                                         —
                                                                                                                             —
              |       |       |                                       H—C—C—C—H                            H — C —C —C — H
     (ii) H — C — C — C — Br
                                                                                                                             —
                                                                           H H                                      H        H
             |        |       |
                                                                	        (Propanal)                                  (Propanone)     	   2
	       	    H        H       H
	       	 Halogen atom – Br                                     	(iii)	Electron dot structure of propanal :
             H        H                                                                   H           H        O
                                                                                                      
                                                                                                            
              |       |
    (iii) H — C — C — C —
                        —C —H                                                         H   C           C            C H
                                                                                          
                                                                                                  
                                                                                                           
                                                                                                                   
                        —
                                                                                                      
             |        |
                                                                                          H           H
	       	    H        H
                                                                	      	Electron dot structure of propanone :
	       	   Triple bond – C ≡ C –
                                                                                         H O  H
	       	           [CBSE Marking Scheme, 2015] 1+1+1                                                       
                                                                                      H   C           C        C     H
    Commonly Made Error
                                                                                      
                                                                                              
                                                                                                       
                                                                                                               
                                                                                                              
	 	 Students get confused and do mistakes while                                          H                    H         	2
     writing the structure, name and also with the
     functional group involved.                                     Commonly Made Error
                                                                	 	 Students get confused in writing isomeric structures
    Answering Tip                                                    and make mistake while drawing electron dot
                                                                     structures.
	 	 Please understand the basic concept of alkane,
     alkene and alkynes with their general formula. Then
                                                                    Answering Tip
     make a list of the compounds involved in the above
     and also learn different functional groups. Drawing        	 	 Learn the concept of isomerism and write structures
     structures and practicing them is mandatory.                    accordingly.
	WORKSHEET-30
Solutions                                                           Commonly Made Error
	     1.	Correct option : (c)                                   	 	 Students write irrelevant stories. Be specific. Read
	  	Explanation : Pentane contains four C—C and                      question carefully and write only what is asked.
    twelve C—H covalent bonds. Therefore, total 16
    covalent bonds.
                                                                    Answering Tip
	2.	The molecular formula for two consecutive                   	 	 Do not overlook any part of a question and avoid
    members of this series are :                                     being in a hurry to conclude the answer.
	      	CH3Br (Bromomethane)
                                                                	4.	
	      	C2H5Br (Bromoethane)	                         ½+½
                                                                (i) Ethane : C2H6
	3.	(i) Vegetable oil is converted into saturated fat.	 ½                                         H                 H
	 (ii)	The reaction is Hydrogenation	                       1                                     x                  x
	 (iii)	Vegetable oil is liquid and saturated fat is solid at             H H
                                                                                                           x
                                                                                                  C                      x
                                                                                          x
        room temperature	                                   1          H C C H        H                              C       H
                                                                                                           x
	 (iv)	 Nickel acts as a catalyst.	                        ½              H H                     x                  x
	      		                   [CBSE Marking Scheme, 2018]
                                                                                                  H                 H
                                                                	                                                                	 ½+½
P-22                                                                                                                S C I ENC E - X
 	    (ii)	Ethene : C2H4                                           	(ii)	Conc. H2SO4 acts as a dehydrating agent.	                   1
                                                                                              Conc H 2SO 4
                                       H        H
                                                                   	
                                                                      	CH3CH2OH              
                                                                                                 443K
                                                                                                           →    C2H4 + H2O	          1
                                                                       S.            Covalent                    Ionic
     H C         C H     H            C        C       H
                                                                       No.          Compounds                  Compounds
                                                           ½+½
 		                                  [CBSE Marking Scheme, 2015]       (i)      They are readily          They are not soluble in
                                                                                soluble in organic        organic solvent.
                                                                                solvent.
     Commonly Made Error
                                                                       (ii)     They do not ionize.       They ionize in organic
 	 	 Students often make mistake while drawing electron                                                  medium.
      dot structures.
                                                                       (iii)    They are bad              They are good
     Answering Tip                                                              conductor of heat         conductor of heat and
                                                                                and electricity.          electricity.
 	 	 Understand the basic concepts involved in drawing
      the dot structure. Make sure that you have dots for              (iv)     They have weak force They have strong force
      all shared bonds.                                                         of attraction between of attraction between
                                                                                the molecule.         the molecule.                  4
 	       5.	(i) Ethene
             H                   H
                     C   C
 		
  H                              H	1
 	WORKSHEET-31
 Solutions                                                                                                H
                                                                                                           |
 	       1.	Correct option : (b)                                                                 — C— H
                                                                                             H—C —
 	  	Explanation : The nearest inert gas from carbon                                                 |
     is Neon and it is an element which attempts to                                                  H
     attain the electronic configuration of its nearest
                                                                   	           	The first member of alkynes is ethyne and its
     noble gas while attaining a fully-filled outermost
                                                                                structure is given below :
     shell.
                                                                   	           	              H—C ≡ C—H	           1+1+½+½
 	2.	The molecular formula for first two consecutive
     member of this series is :                                        Commonly Made Error
 	           	CH3OH (Methanol)                                     	 	 Students get confused and do mistake while writing
 	           	C2H5OH (Ethanol)	                            ½+½          the structure and its name.
 	3.	 A homologous series is a series of organic
      compounds that belongs to the same family (i.e.,                 Answering Tip
      possesses the same functional group) and show                	 	 Drawing structures               and   practicing   them    is
      similar chemical properties. The members of this                  mandatory.
      series are called homologous as they differ from             	4.	
                                                                      A homologous series is a series of organic
      each other by the number of CH2 units in the main               compounds which belong to the same family (i.e.
      carbon chain.                                                   possess same functional group) and show similar
 	  	General Formula                                                  chemical properties. The members of this series are
 	  	Alkenes : CnH2n,           Alkynes : CnH2n-2                     called homologous and differ from each other by
      Structures  :                                                   the number of CH2 units in the main carbon chain.
 	  	
                                                                      Molecular    formula     of    two    consecutive
 	  	The first member of alkenes is ethene and its
                                                                      members of homologous series of aldehydes is
      structure is given below.
                                                                      CH3-CHO and CH3-CH2-CHO.
	WORKSHEET-32
Solutions                                                              Carboxylic acid                      – COOH
P-24                                                                                                      S C I ENC E - X
 	(iii)	Regular gradation in physical properties.	           ½    	(ii)	 Low melting and boiling point compared to ionic
 	(iv)	Successive member differ by – CH2.	                   ½           compound.
                                                                  	(iii)	Poor conductors of electricity.
      (b)        O   C       O                                    	(b)	Carbon is a versatile element because it forms
 	          	                        	1                                  covalent bonds with large number of elements
                                                                         and has catenation capacity to form compounds
 	          		               [CBSE Marking Scheme, 2012]                 by chain of bonds with itself.	          3+2
                                                                  	     		                 [CBSE Marking Scheme, 2015]
 	 6.	(a) Three physical              properties   of    carbon
      compounds are :
 	(i)	Catenation property.
 	WORKSHEET-33
 Solutions                                                        	4.	(i) Methane	
                                                                                                            H
 	     1.	Correct option : (c)                                                  H                           .
 	  	Explanation : Unsaturated hydrocarbons have                                                            x
                                                                                   —
     multiple covalent bonds (double or triple bond) like                  H—C—H                  H .x      C    x. H
     alkene and alkyne.
                                                                                   —
                                                                                                            x.
 	2.	Ethane (C2H6)                                                              H
 	  	Propane (C3H8)	                              ½+½                                                       H
                         OR                                                                                                    1½
                                                                  	(ii)	Ethane
                                                                                                       H         H
                                                                          H    H                       .         .
                                                                                                       x         x
                                                                          —
                                                                                                            X
                                                                      H—C—C—H             x. H         C         C      x. H
                                                                                                            X
                                                                          —
                                                                                                       x.        x.
                                                                          H    H
                                                                                                       H         H
                                         [Topper Answer, 2017]
                                                                                                                               1½
	WORKSHEET-34
Solutions                                                 	5.	(i) Propanal (aldehyde);	                              ½+½
	     1.	Correct option : (d)                                                 H H H
                                                                                                  —
	  	Explanation : A series of compounds in which the
                                                                              H—C—C—C—
                                                                                     —O
    same functional group substitutes for hydrogen in
                                                                                           —
    a carbon chain is called as homologous series. The                               H     H
    option (d) follows the generic formula CnH2n, while
    others follow the generic formula CnH2n+2.            	(ii)	
                                                               Propanone (Ketone);	                                  ½+½
	2.	Propane (C3H8)                                                                   H            H
                                                                                                  —
	  	Butane (C4H10)	                             ½+½
                                                                              H—C—C—C—H
	3.	An atom or a group of atoms/heteroatoms which
                                                                                           —
                                                                                           —
                                                                                                  —
    determines the chemical properties of an organic                                 H     O      H
    compound is called functional group.	          1
                                                          	(iii)	
                                                                Isomers (same molecular formula but different
    	Name            Structural         Functional              structural formula/different functional group)	 1
                      Formula             Group           			                            [CBSE Marking Scheme, 2016]
    Ethanol          H   H                 – OH
                                                          	6.	(i) Hydrogenation reaction : It is the process
               H—C—C—O—H                                      in which unsaturated compound reacts with
                                                              hydrogen in presence of nickel as a catalyst to
                     H   H                                    form saturated compound.
                                                          R                   R                                  R   R
    Ethanoic         H    O            – COOH                                                                    |   |
      acid                                                                               Nickel
               H — C — C — OH              O                     C =C         + H2                       H — C — C —H
                                                                                                                 |   |
                     H                   — C — OH         R                   R                                  R   R
	       		           [CBSE Marking Scheme, 2015] 1 + 1        Vegetable Oil                                 Vegetable Ghee
P-26                                                                                                   S C I ENC E - X
 	(iv)	Combustion reaction : Ethanol is highly                  	 (v)	Saponification reaction : It is the reaction in which
       inflammable liquid, i.e., it catches fire very easily.         an ester reacts with sodium hydroxide to form
 	    	It burns with blue flame in presence of oxygen to              sodium salts of acid and alcohol.
       form carbon dioxide and water.                              	 	CH3COOC2H5         +        NaOH	             →
     C2H5OH        +     3O2	        →                          	    	Ethyl ethanoate        Sodium hydroxide
 		    Ethanol          Oxygen                                  			                         CH3COONa + C2H5OH
 			                                  2CO2      + 3H2O                          	        Sodium ethanoate	 Ethanol 1
                             Carbon dioxide         Water 1                               [CBSE Marking Scheme, 2014]
 	WORKSHEET-35
 Solutions
 	    1.	Correct option : (d)                                       Answering Tip
 	      	Explanation : Any atom apart from carbon and           	 	 Keenly observe experimental tests done during
         hydrogen is called heteroatom.                              practicals, understand and then learn the tests.
                                                                     Make a list of experimentally done tests used for
 	2.	(i) C3H6,	        (ii) C5H8.	                ½+½                distinguishing organic compounds with different
                            [CBSE Marking Scheme, 2016]              functional groups and practice them.
 	3.	(i) Test 1 (Litmus Test) : Take two strips of blue         	   4.	(i) C2H4O4 : CH3–COOH - ethanoic acid
       litmus paper. Place a drop each of the alcohol and       	(ii)	C2H5OH : ethanol
       carboxylic acid on these strips separately. The blue     	(iii)	X is CH3COOC2H5 - ethyl acetate [ethyl ethanoate
       litmus paper turns red in the case of carboxylic acid           -ester]	                               1+1+1
       and remains unaffected in the case of alcohol.	 1
 	(ii)	Test 2 (Sodium hydrogen carbonate test/sodium            	5.	(i) All the members of a series have the same
       carbonate test) : A pinch of sodium hydrogen                    functional group, similar structure and same
       carbonate or sodium carbonate is added to both                  general formula.	             (Any two) ½ + ½
       test tubes, separately.                                  	 (ii)	CH3OH, C2H5OH	½+½
 	    	If brisk effervescence with the evolution of a           	(iii)	The physical properties are determined by alkyl
       colorless gas is observed, it indicates the presence            group/hydrocarbon part/part other than the
       of carboxylic acid. 	                              ½            functional group.	                            ½
 	    	If no change is observed then it confirms the            	 (iv)	The chemical properties are determined by
       presence of the alcohol.	                          ½            functional group such as –OH group, or any other
 	(iii)	Test 3 (Ester test or any other suitable test)	                example from any other homologous series.	 ½
 	     		                                 (Any two) ½ + ½       			                       [CBSE Marking Scheme, 2015]
                             [CBSE Marking Scheme, 2015]        	   6.	(a) (i) CH3 — CH2 — CH2 — CH — CH3	               1
 Detailed Answer :                                                                                   |
 	(ii)	We can distinguish between an alcohol and a              			                                  Br
        carboxylic acid on the basis of their reaction with     	(ii)	CH3 — CH — CH3
        sodium carbonate and sodium hydrogen carbonate.                          |
        Carboxylic acids reacts with sodium carbonate and
        sodium hydrogen carbonate to evolve CO2 gas that        			            CH3	                                      1
        turns lime water milky.                                 	(iii)	CH3CH2CH2CHO	                                     1
 	     	Alcohol, on the other hand, do not react with           	(iv)	HC ≡ C – CH2 – CH2 – CH2 – CH3	                    1
        sodium carbonate and sodium hydrogen carbonate.         	(b)	  Electrons dot structure of ethanoic acid
 	(iii)	Alcohol reacts with sodium metal to produce                            H
        hydrogen gas with rapid effervescence. On the
        other hand, carboxylic acid does not show this type              H    C      C       O      H
        of chemical reaction with sodium metal.	 1½+1½
     Commonly Made Error
                                                                	       	      H     O             	                1
 	 	 Students usually get confused between various             	       		                [CBSE Marking Scheme, 2012]
      distinguishing tests for functional groups.
            	   TOPIC-2
                Carbon Compounds, Soap and Detergents
	WORKSHEET-37
Solutions                                                     	 (iii)	Propanol is oxidised to Propanoic acid.	    1
                                                              			                        [CBSE Marking Scheme, 2016]
	   1.	Correct option : (a)
	     	Explanation : Hydrogenation       reaction means       	4.	In hard water, soap reacts with calcium and
      addition of hydrogen to double bonds of                     magnesium salts which are present in hard water
                                                                  and form insoluble substances called scum.	   1
      unsaturated compounds found in oil in the
                                                              		Detergents are ammonium or sulphonate salts
      presence of catalysts such as palladium or nickel to        of long chain carboxylic acids. The charged
      give saturated hydrocarbons.                                end of these compounds do not form insoluble
                                                                  precipitates with calcium and magnesium ions in
	2.	Acetic acid or vinegar. 	                                     hard water.	     [CBSE Marking Scheme, 2012] 2
			                   [CBSE Marking Scheme, 2012] 1
                                                              	5.	Molecular formula of ethyne = C2H2
	3.	(i)	 It is a substance which can give oxygen to other
                                                                     Electronic formula = H        C    C    H
         substances.	1
	
  (ii)	CH3 —CH2 —CH2 —OH 
                                   Alkaline KMnO4 + Heat
                                                 →   	     	Structural formula = H — C —
                                                                                                — C — H	       	
                               OR Acidified K Cr O + Heat
                                             2   2   7
                                                                     	         [CBSE Marking Scheme, 2015] 1+2
			      Propanol	
                                 CH 3 -- CH 2 -- C -- OH      	6.	(i) Soaps are the sodium or potassium salts of
                                                 ||               long chain carboxylic acids while detergents are
                                                 O     1          the ammonium of sulphonate salts of long chain
                                   Propanoic acid                 carboxylic acids.
P-28                                                                                               S C I ENC E - X
 	(ii)	The dirt is oily in nature and when soap is added       		Cleansing Action of Soap : When soap is dissolved
       to water, its molecules form structures called                 in water, it forms a colloidal suspension. In this
       micelles in which carbon chain of the molecules                colloidal suspension, the soap molecules cluster
       dissolves in 	                                                 together to form micelles and remain radially
       the oil while the ionic end dissolves in water and             suspended in water with the hydrocarbon end
       faces outside. The micelles thus help in dissolving            towards the centre and the ionic end directed
       the dirt in water. (Note : 1 mark to be awarded if             outward. The dirt particles always adhere to the
       only labelled diagram of micelle is given)                     oily or greasy layer present on the skin or clothes.
 	    	Ca2+ and Mg2+ present in hard water form                       When a dirty cloth is dipped into a soap solution,
       insoluble substance (scum) with soap.                          its non-polar hydrocarbon end of micelles gets
 	    	Two problems :                                                 attached to the grease or oil present in dirt and
 	    	(a)	 Non-biodegradable                                         polar end remains in water layer.
 		(b)	 Water pollution / soil pollution                       	     	The mechanical action of rubbing subsequently
 			 (Note : 1 mark to be awarded for any one of                      dislodges the oily layer from the dirty surface
            the problems.)	                                           shaping it into small globules. A stable emulsion of
                           [CBSE Marking Scheme, 2017]                oil in water is formed. The emulsified oil or grease
 Detailed Answer :	                                                   globules bearing the dirt can now be readily washed
                                                                      with water.
            S.No.           Soap             Detergents        	     	Soaps do not form lather when the water is hard.
             (i)      They are sodium These are sodium                When soap is added to hard water, calcium and
                      salts of long chain or      potassium           magnesium salts present in water displace sodium
                      fatty acids.        salts of sulphonic          or potassium ions from the soap molecules forming
                                          acids of hydro-             an insoluble substance called scum.
                                          carbons.             		Problems that aries due to use of detergents instead
             (ii)     Soaps cannot be Detergents work                 of soap :
                      used with hard well with hard            	(i)	  Detergents      being   non-biodegradable,      they
                      water.          and soft water                  accumulate in the environment causing pollution.
                                      both.                    	(ii)	In soil, the presence of detergents leads to pH
             (iii)    They are fully They are non-bi-                 changes making soil infertile.
                      biodegradable. odegradable.              	(iii)	The entry of detergents into food chain leads to
                                                                      bioaccumulation in living beings and leads to
             (iv)     They take time to They       dissolve           serious health issues.	                  (Any two) 5
                      dissolve in water. faster in water.
 	WORKSHEET-38
 Solutions                                                     	   2.	Correct option : (c)
 	   1.	Correct option : (b)                                   	     	Explanation : In esterification, RCOOH, – H is
 	     	Explanation : Compounds with –OH functional                   replaced by – R’ of R’OH in the presence of acid to
        group are ended with suffix –ol.                              form RCOOR’.
 	3.
 	
       	
                                                                                                         [Topper Answer, 2017] 3
                                                                    OR
	          	In esterification, a carboxylic acid and alcohol react to form ester in presence of acid. It is reverse of saponification.
                                   +
                              H
	      	RCOOH + R’OH → RCOOR’ + H2O
	      		                             Ester
	      	In saponification, an ester reacts with a strong base or an acid to give soap and alcohol.
	      	RCOOR’ + NaOH → RCOONa + R’OH	                                                                                     2
	      		                         Soap
	 (i)	Use of esters :
	      	As esters have fragrant odours, they are used as a constituent of perfumes, essential oils, food flavourings etc.
	 (ii)	Use of saponification process :
	      	In the manufacturing of soap used as cleansing agent.	                                                             1
	5.	CH3COOH + C4H9OH ¾® CH3COOC4H9 + H2O 	6.	(i) Soap molecules have two ends– one end is
			 Acid	                Alcohol	             Ester                     the hydrocarbon chain which is water repellent,
       H O                        H H H H                               where as the other end is the ionic part which it
           —
               —
               —
                                                                        micelle.	                                         1
       H                          H H H H                        	 (ii)	These micelles are formed because their
  Ethanoic acid                        Butanol                          hydrocarbon chains come together and the polar
	Process is Esterification.	                         1+ 1 + 1           ends are projected outwards.	                     1
                                                                 	(iii)	Micelle formation in ethanol will not occur because
   Commonly Made Error                                                  the hydrocarbon chain end of the soap will dissolve
 	 	 Students often write incorrect formula.                           in ethanol.	                                      1
                                                                 	(iv)	 Soaps in the form of micelle are able to clean
   Answering Tip                                                        dirty clothes having oily spots, as the oily dirt is
                                                                        collected in the centre of the micelle, which forms
 	 	 Be clear with concepts and how the reaction occurs.               an emulsion in water and on rinsing, the water
      In the above reaction a water is removed from                     washes away the micelles with dirt attached to
      reactants (acid and alcohol) to form ester. Cautiously            them.	                                            2
      count the number of carbon atoms present and then          			                        [CBSE Marking Scheme, 2016]
      write the name.
	WORKSHEET-39
Solutions                                                                    of soap molecules in water in which hydrocarbon
                                                                             ends are directed towards the centre and ionic ends
	     1.	Correct option : (a)                                                are directed outwards.
	          	Explanation : A micelle is a spherical aggregation
P-30                                                                                                          S C I ENC E - X
 	2.	It is unsaturated compound because they have                	6.	(i) The force of attraction between the molecules
     more carbon. It burns with sooty or smoky flame.                  of covalent compounds are not strong as ionic
                                                                       compounds. So, they have low melting and low
 	                    [CBSE Marking Scheme, 2012] 1
                                                                       boiling points.	                                1
                                                                 	(ii)	Esters are organic compounds which have sweet
 	3.	CH3COOH + Na2CO3 ¾®                                               smell.
                      Sodium carbonate                           	    	Activity :
                2CH3COONa + H2O + CO2                            	    	Aim : To demonstrate esterification process using
 		 	                      Water Carbondioxide                         ethanol and acetic acid.	                       1
 		CH3COOH + NaHCO3 ¾®                                           		Materials Required : Beakers, water, test-tube,
 			    Sodium hydrogen CH3COONa + H2O + CO2                           ethanol, ethanoic acid, conc. H2SO4.
 		 	      carbonate                Water Carbon
                                                                          Test-tube
                                                                         cantaining
                                                      dioxide
                                                                           ethanol
 		CH3COOH+ NaOH ¾® CH3COONa + H2O
                                                                        ethanoic acid                     Beaker
 			     Sodium hydroxide	                Water
                                                                        conc. H2SO4
 		2CH3COOH + 2 Na ¾® CH3COONa + H2
                                                                                                             Wire
 	  		           Sodium                Hydrogen gas
                                                                                                            gauge
 		                    (Any three reaction) 1+1 +1                         Water
 			                 [CBSE Marking Scheme, 2016]
 	4.	(i) Esters.	                                            ½
 		Chemical Equation :	
                  O                                                     Tripod
                                                                                     Burner
                                                                        stand
                  —
                  —
           CH3 — C — OH + CH3CH2OH
                                               Conc. H2SO4         		Procedure :
                     O
                                                                 	(a)	Take 2 ml of ethanol in a test-tube.	         1
                     —
                     —
 		CH3 — C — O — CH2 — CH3 +H2O                        1         	(b)	Add 2 ml of ethanoic acid into it.
                                                                 	(c)	Add few drops of conc. H2SO4.
 		   Product’s chemical name—Ethyl ethanoate	         ½
                                                                 	(d)	Warm it in a beaker containing water.
 	(ii)	Conc. H2SO4 acts as a dehydrating agent. (Helps
      in the removal of water formed in the reaction.)	 1        	(e)	Observe the smell of the products formed.
 			                     [CBSE Marking Scheme, 2016]             	   	Observation : Pleasant fruity smelling compound
                                                                      (called ester) is formed.	                    1
 	5.	(i) Ethene		                                          ½     	   	Chemical Reaction :
 	                   Conc. H2 SO4 + Heat
                                                                 	    	CH3COOH(l) + C2H5OH(l) Conc.H
                                                                                                  2 SO 4
                                                                                                             →
    (ii)	C2H5OH      443 K
                                        → H2C = CH2 + H2O	½
                                                                 	     Ethanoic acid Ethanol
 			
                                            Ethene               	    		                   CH3COOC2H5        + H 2O
 	(iii)	Conc. H2SO4 acts as a dehydrating agent/removes          	    	                   Ethyl ethanoate      Water	 1
         water from the reactant.		                        1
                                                                 	    	Conclusion : Carboxylic acid reacts with alcohol in
 	 (iv)	Ethane/C2H6 will be formed.		                      1           presence of conc. H2SO4 which act as a dehydrating
 			                           [CBSE Marking Scheme, 2016]             agent to from esters.
 	WORKSHEET-40
 Solutions                                                       	3.	Ethanol, C2H5OH	1
                                                                                 Conc.H SO
 	   1.	Correct option : (c)                                     		C2H5OH 
                                                                             2 4
                                                                                 → CH2 = CH2 + H2O	                    1
 	     	Explanation : Ethanol (C2H5OH) reacts with               			                             Ethene
        sodium to form sodium ethoxide (C2H5ONa) along
                                                                 		
                                                                  Role of conc. H2SO4 : It act as a dehydrating
        with liberation of hydrogen gas.
                                                                   agent.	
 	     	2C2H5OH + 2Na → 2C2H5ONa + H2 ↑
                                                                                       [CBSE Marking Scheme, 2016] 1
 	2.        N    N
       	                 	   [CBSE Marking Scheme, 2012] 1
	6.	When any molecule like H2 adds to unsaturated                          Vegetable Oil                                Vegetable Ghee
    hydrocarbon because of double and triple bond in                                               [CBSE Marking Scheme, 2015] 2
    the presence of Ni as catalyst, it is called addition
    reaction.	
	WORKSHEET-41
Solutions                                                            	5.	
                                                                                 O
	        1.	Correct option : (c)
                                                                                 —
                                                                                 —
    2.
                                                                                                               O
                                                                                                               —
                                                                                                               —
                                                                                                      CH3 — C — OCH2CH3 + H2O
                                             [Topper Answer, 2017]                                       Ethyl acetate                    Water
                                                                     	       	Reverse reaction = Saponification	      2+1
     Commonly Made Error                                             	       		                 [CBSE Marking Scheme, 2015]
	 	 Students write vague answers.
                                                                         Commonly Made Error
                                                                     	 	 Generally students get confused and write the
    Answering Tip
                                                                          reaction and their structures incorrectly.
	 	 Learn the reactions, how they react, step by step,
     changes involved, product formed. Carefully                         Answering Tip
     observe reactions done during practicals.
                                                                     	 	 Be clear with concepts and how the reaction occurs.
                                                                          In the above reaction a water is removed from
	3.	(i) 2CH3COOH + 2Na ¾® 2CH3COONa + H2                                  reactants (acid and alcohol) to form ester. Cautiously
		             Sodium ethanoate/Sodium acetate ½ + ½                      count the number of carbon atoms present and then
                                                                          write the name.
	 (ii)	CH 3 COOH + NaOH ¾® CH3COONa + H2O
                                                                                                         Conc.H SO
		             Sodium ethanoate/Sodium acetate ½ + ½                       6.	(a) (i) CH3CH2OH  2
                                                                                                 443 K
                                                                                                       4
                                                                                                         →
                                                                     	
	(iii)	CH3COOH + C2H5OH ¾® CH3COOC2H5 + H2O                          	      		                                       CH2 = CH2 + H2O 1
		                        Ethyl ethanoate/Ester ½ + ½                                                Alkaline KMnO
                                                                      (ii) CH3CH2OH 4 → CH3COOH	
                                                                     		                                                                           1
			                     [CBSE Marking Scheme, 2016]
                                                                                                  Sunlight
                                                                     	    (b)	(i) CH4 + Cl2 
                                                                                               → CH3Cl + HCl	                                     1
	4.	X : C2H5OH, Y : H2 gas	               ½+½                                                NaOH
		  2C2H5OH + 2Na ¾® 2C2H5ONa + H2↑	      1                            	(ii)CH3COOC2H5 
                                                                                              H2 O
                                                                                                   → C2H5OH+ CH3COONa 	
                                                                                                   
                                                                     	                                                            	
		  Ethene, C2H4.	                        ½+½
                                                                             	                                                  1
			                   [CBSE Marking Scheme, 2016]
                                                                     	      	(iii) CH4 + 2O2 → CO2 + 2H2O + light + heat energy 	 	
                                                                             	                                                                    1
P-32                                                                                                               S C I ENC E - X
 	WORKSHEET-42
 Solutions                                                                     R                    R                        H     H
                                                                                                                             |     |
 	         1.	Correct option : (a)                                                                       Ni catalyst
                                                                                        C =C    + H2                    R — C — C —R
 	          	Explanation : Mineral acids like nitric acid, sulphuric                                         Heat            |     |
             acid are stronger than carboxylic acid as they can                R                    R                        R     R
             ionize 100% in their solution.
                                                                                   Vegetable oil                          Vanaspati ghee
     	2.                                                                           (Liquid state)                          (Solid state)
                                                                           	        	The essential condition for the reaction is presence
                                                                                     of nickel as a catalyst and temperature.
                                           [Topper Answer, 2017]           	        	Change observed in the physical property during
                                                                                     hydrogenation is the change of the unsaturated
         Commonly Made Error                                                         compound from the liquid state to the
 	 	 Students write irrelevant stories. Be specific. Read                           corresponding saturated compound in the solid
      question carefully and write only what is asked.                               state. Its boiling and melting point will increase.
                                                                           	        	                   [CBSE Marking Scheme, 2015] 1+2
         Answering Tip
                                                                           	5.	The name of the compound formed is Ethene and
 	 	 Remember that salts of calcium and magnesium are
      responsible for hardness of water, which result in                       its structural formula is :
      scum.                                                                                                 H    H
                                                                                                            |    |
                                                                                                        H—C=C—H
 	3.	(i) 2CH3COOH + Na2CO3 → 2CH3COONa + H2O
                                                                            	       	Chemical equation :
 	          		                                           + CO2 1                                         Conc H SO
 	(ii)	CH4 + 2O2 → CO2 + 2H2O	                                   1         	        	CH3CH2OH  2
                                                                                                443 K
                                                                                                      4
                                                                                                        → CH2=CH2+H2O
 	WORKSHEET-43
 Solutions                                                                          is replaced by —O— alkyl or aryl group to form
                                                                                    an ester. Esters are represented by the formula
 	         1.	Correct option : (b)                                                  R1COOR2 where R1 and R2 represent an alkyl or
 	          	Explanation : While cooking, if the bottom of the                      aryl group.
             vessel is getting blackened on the outside, then it       	           	Preparation of esters : When carboxylic acids are
             means that the fuel is not burning completely.                         heated with alcohols in the presence of an acid
 	2.	CH3COOH + NaHCO3 → CH3COONa                                                    catalyst, esters are produced.
                                                                                       O                                O
 	   	                                     + H2O+CO2
                                                                                R– C           + R'OH                     R– C      + H2 O
 			                   [CBSE Marking Scheme, 2012] 1
 	3.	Esters are the derivatives of carboxylic acids which                               O –H                                     O–R'
     contain —COOR group. The –OH group in an acid
    	      	Cleansing Action of Soap : A soap molecule              		(ii) CH3COOH + KHCO3 → CH3COOK + H2O + 		
            consists of two dissimilar parts :                        	                                 CO2 1
    	(i)	A short ionic part comprising the carboxylate salt-        	        	(iii) CH4 + Cl2 → CH3Cl + HCl	                       1
         - COO–Na+ which is water soluble.                          	(b)	(i) CH3CH2COOH : propanoic acid	                         ½
    	(ii)	A long hydrocarbon chain which is hydrophobic.            	        	(ii) CH3CH2CH2Br : 1-bromo propane	                 ½
    	      	When soap is dissolved in water, it forms a colloidal
                                                                    	(c)	Electron dot structure of ethene (C2H4) :	
            suspension. In this colloidal suspension, the soap
            molecules cluster together to form micelles and                                        H           H
                                                                                                   . .         . .
            remain radially suspended in water with the
            hydrocarbon end towards the centre and the ionic
                                                                                             . .
                                                                                                         . .
                                                                                                         . .
                                                                                                                       . .
                                                                                         H         C            C            H
            end directed outward. The dirt particles always                                                                        1
            adhere to the oily or greasy layer present on the
            skin or clothes. When a dirty cloth is dipped into      	        	                           [CBSE Marking Scheme, 2012]
	WORKSHEET-44
Solutions                                                               	    	In pure oxygen, ethyne undergoes complete
                                                                              combustion and high temperature suitable for
	       1.	Correct option : (c)                                               welding is attained.	                          1
	         	Explanation : The beaker becomes hot because it is       	        	Whereas air contains less percentage/amount of
           an exothermic reaction.                                            oxygen which results in incomplete combustion of
                                                                              ethyne and the temperature required for welding
    	2.                                                                       is not attained.	                              1
                                                                    	        	                   [CBSE Marking Scheme, 2015]
                                                                    	 etailed Answer :
                                                                    D
                                                                    	     	Electron dot structure of ethyne is :
                                           [Topper Answer, 2017]                           H C C H
                                                                    	        	No, the mixture of ethyne and air cannot be used
                                   NaOH                                       for welding because when ethyne is burnt in air,
	       3.	(i) CH3COOC2H5 
                             → C2H5OH                                         it gives a sooty flame. This is due to incomplete
	         		                        + CH3COONa                                combustion caused by limited supply of air.
	(ii)	CH3COOH + NaHCO3 → CH3COONa + H2O                                      However, if ethyne is burnt with oxygen, it gives
                                                                              a clean flame with temperature 3000°C because of
	    		                             + CO2                                     complete combustion. This oxy-acetylene flame is
                   Sunlight
                                                                              used for welding. It is not possible to attain such a
	 (iii)	CH4 + Cl2       → CH3Cl + HCl	                  1+1+1
                                                                              high temperature without mixing oxygen.	 1 + 2
	4.	
                  ..                         ..                     	5.	(i) Ethanol is oxidised to ethanoic acid with the
             .           .           .                .
           H . C .. .. C . H   /   H .    C .. .. C   . H               help of acidified K2Cr2O7.
                                                                    	        	CH3CH2OH  +  2[O] —→ CH3COOH + H2O
                                                            	   1
P-34                                                                                                                 S C I ENC E - X
 	(ii)	Ethanol reacts with sodium metal to form sodium        	6.	2CH3COOH + 2Na → 2CH3COONa + H2O.	
       ethoxide and hydrogen gas.                             	   	 (A)	                (B)
 	       	2C2H5OH + 2Na —→ 2C2H5ONa + H2                      		   CH3COOH + C2H5OH → CH3COOC2H5 + H2O
 	(iii)	Ethene is formed when ethanol is heated at 443        	   		           (C)	       (D)
        K with concentrated sulphuric acid. Concentrated      	   	CH3COOC2H5 + NaOH → CH3COONa
        sulphuric acid acts as a dehydrating agent in this                                       + C2H5OH
        reaction and removes a molecule of water.             	(A)	CH3COOH
                          H SO                                	(B)	CH3COONa
          CH CH2OH 
                     2   4
                           → CH2 = CH2 + H2O 1+1+1
                                                              	(C)	C2H5OH
 	       	 3        443 K
[CBSE Marking Scheme, 2014] (D) CH3COOC2H5 [CBSE Marking Scheme, 2018] 5
 	WORKSHEET-45
 Solutions                                                    	3.	The oxidizing agents used for the conversion of
                                                                  ethanol to ethanoic acid are alkaline potassium
                                                                  permanganate (KMnO4) and acidified potassium
 	     1.	CH3CH2OH KMnO
                     4 [ O]
                                → CH3COOH                         dichromate (K2Cr2O7).	                        1
 	       	Ethanol                Ethanoic acid
                                                                  S.                                       Ethanoic
 	   		                [CBSE Marking Scheme, 2014] 1                         Test          Ethanol
                                                                  No.                                        Acid
 	2.	(i) The carboxylic acid involved in the reaction is
     acetic acid (CH3COOH).                                        (i)   Litmus Test    No change in Blue litmus
                            H    O                                                      colour of litmus solution turns
                             |   ||                                                     solution.        red.
                         H — C — C — OH
                                                                  (ii)   Reaction with No brisk         Brisk
                             |
                                                                         sodium        effervescence.   effervescence
                            H
                                                                         carbonate                      due to
 	(ii)	The alcohol involved in the reaction is ethanol                                                  evolution of
       (CH3CH2OH).                                                                                      CO2.
                            H    H
                                                              	  		                                                1+1
                             |   |
                                                              	4.	(i) Ethanol reacts with ethanoic acid in the presence
                         H — C — C — OH                           of acid catalyst to give ethyl ethanoate.
                             |   |
                                                                    CH3COOH + CH3CH2OH        Acid
                                                                                                          →
 	                          H    H                            	    	                            cataltyst
qqq
P-36                                                                                         S C I ENC E - X
CHAPTER
SECTION
 B
 5         PERIODIC CLASSIFICATION OF ELEMENTS
              	   TOPIC-1
                  Periodic Laws and their Limitations
  	WORKSHEET-46
  Solutions                                                    	(b	X has 6 valence electrons it belongs to group 16.	 1
                                                               	(c)	Valency will be 2. To acquire noble gas
  	1.	Correct option : (b)                                          configuration it will gain 2 electrons.	          1
  		  Explanation : It was found that the Law of Octaves       	   		                   [CBSE Marking Scheme, 2018]
      was applicable only upto calcium, as after calcium
      every eighth element did not possess properties              Commonly Made Error
      similar to that of the first.
                                                               	 	 Usually students get confused with the group
  	2.	It states that “Properties of elements are periodic
                                                                    and period to which they belong to. They also get
      function of their atomic number.”	                1
                                                                    confuse with the valency.
  	3.	(i) Henry Moseley
  	(ii)	Atomic number                                              Answering Tip
  	(iii)	Modern Periodic Law : Properties of elements are      	 	 Understand the basic concepts involved in the
         the periodic functions of their atomic numbers.            separation of periods and groups in the modern
  	               [CBSE Marking Scheme, 2014] 1 + 1 + 1             periodic table. After writing the electronic
                                                                    configuration, check the number of energy shells
  	4.	(i) Aim of Classification : For systematic and
         simplified study of elements and their com-                and this will be equal to the period number. Then
         pounds.	                                         ½         check for how many outermost (valence) electrons
  	(ii)	Basic property : Atomic Number.	                  ½         are there and then write the Group to which it
  	(iii)	Modern periodic Law : The properties of elements           belongs. From the valence electrons we can write
         are a periodic function of their atomic number.	 ½         the valency of that element.
  	 (iv)	Metals are found on the left side and centre of the
         Modern Periodic Table.	                          ½    	6.		(i) To study the properties of elements and to keep
  	(v)	Metalloids are found in a zig-zag manner between             the elements with similar properties together.	1
         the metals and the non-metals.	                  ½
                                                               	  (ii)	Chemical properties of elements and atomic
  	(vi)	Non-metals are found on the right side of the
                                                                       number.	                                         1
         Modern Periodic Table.	                          ½
  	     		                  [CBSE Marking Scheme, 2015]        	 (iii)	Metals lies on extreme left, metalloids lie in the
                                                                       middle and non-metals lie on the right side.	    2
  	5.	X : 2, 8, 6                                              	 (iv)	They should be placed in the same slot. Since they
  	(a)	Since ‘X’ has three energy shells and period                    have same numbers of electrons.	
       number of an element is equal to the number of          	                        [CBSE Marking Scheme, 2011] 1
       energy shells. X belongs to 3rd period.	    1
  	WORKSHEET-47
  Solutions                                                          in properties between metals and non-metals are
                                                                     called metalloids.
  	1.	Correct option : (c)                                     	(ii)	Boron, silicon, germanium and arsenic.	
  		  Explanation : Mendeleev arranged the known
                                                                                                     1+½+½+½+½
      elements according to increasing order of their atomic
      masses because according to him, fundamental             	4.	(i) Electronic Configuration — 2, 8, 2
      property of an element was atomic mass.                  	    	Valency — 2.
  	2.	There are seven horizontal rows in the modern            	(ii)	Metal
      periodic table. These rows are called periods.	½ + ½     	    	There are two electrons in its outermost shell and it
  	3.	(i) Borderline elements which are intermediate                 easily loses them to form a positive ion.
	WORKSHEET-48
Solutions                                                   	6.	(i) In the periodic table, elements are placed
                                                                according to their electronic configuration. If
	1.	Correct option : (a)
                                                                an element has only one shell in its electronic
	    	Explanation : Many gaps for the undiscovered
                                                                configuration, it is placed in the first period.
       elements were left in the periodic table by
       Mendeleev. For instance, the elements scandium       	    	If the element has two shells then it is placed in the
       (Sc), gallium (Ga), and germanium (Ge) were not            second period, and so on. Vertical columns in the
       known at Mendeleev’s time, but he had predicted            periodic table are called groups.
       their existence in advance of their discovery.       	    	There are eighteen groups and in a group, all
	2.	There are 18 vertical columns in the modern periodic          the elements have same number of valence
       table and these are known as groups.	          ½+½         electrons.	                            1+1
	3.	(a) (i) K (Potassium — 2, 8, 8, 1)
                                                            	(ii)	They will be placed at the same slot as their atomic
	(ii)	Be and Ca in same group because both have same
                                                                  number is same, valence electron and valency are
       number of valence electrons in their outermost
       shell. The number of this group is 2.                      same and have same chemical properties.	           1
	(b)	           Ca	        X                                                            [CBSE Marking Scheme, 2012]
	    	Valency 2	           1
                                                            	7.	(a) Atomic mass	1
	    	 Thus, the formula of the compound is Ca1X2 =
       CaX2	                                        1+1+1   	 (b)	(i)	 He could classify all the 63 elements known at
                           	
                                                                       that time.
	4.	 (i) Cations are Na and Al (Sodium and Aluminium)       		(ii)	 He left gaps for the yet to be discovered
	    	Anions are Cl and O (Chlorine and Oxygen)                        elements.
	(ii)	Inert elements are He and Ne (Helium and Neon)	       		(iii)	 He predicted the properties of such elements. 	
                [CBSE Marking Scheme, 2015] 1 + 1 + 1                  	                               (any two) 1 × 2
                                                            	 (c)	(i)	 Position of isotopes
	5.	(i) Mercury                                             		(ii)	 Irregular increase in atomic masses in going
	(ii)	Bromine                                                          from one element to the next, making the
	(iii)	Helium or Neon or Argon. 	 (Any one) 1 + 1 + 1                  prediction of undiscovered elements difficult.
                                                            		(iii)	 Position of Hydrogen.	            (any two) 1 × 2
                        [CBSE Marking Scheme, 2015]
                                                                                       [CBSE Marking Scheme, 2018]
P-38                                                                                               S C I ENC E - X
  Commonly Made Error                                            Answering Tip
 	 	 Students write irrelevant stories. Be specific. Read   	 	 Do not overlook any part of a question and avoid
      question carefully and write only what is asked.            being in a hurry to conclude the answer.
             	   TOPIC-2
                 Periodic Elements and Periodic Properties
 	WORKSHEET-49
 Solutions                                                   Detailed Answer :
                                                             	     	In the modern periodic table, there are 18 vertical
 	1.	Correct option : (c)
                                                                    columns known as Groups and 7 horizontal rows
 		Explanation : There are 18 vertical columns, known
                                                                    known as Periods.
     as groups and 7 horizontal rows in Modern Periodic
     Table.                                                  	     	Metallic character increases on moving down
                                                                    a group in the Modern Periodic table. As we
 	2.	Due to the presence of 2 electrons in the valence              move down the group, the electrostatic attraction
     shell and similar chemical properties.                         between the nucleus and the outermost electron
 	                      [CBSE Marking Scheme, 2015] 1               decreases due to increase in the distance between
                                                                    them. This happens because; on moving down the
                                                                    group a new shell is added. So, the valence electron
 	3.	The distance from centre of nucleus to outermost
                                                                    can be easily lost by the element, thereby metallic
     shell of an atom is atomic radius.
                                                                    character increases on moving down a group.
 	  	Atomic radius decreases across a period because
     electron is added in the same shell. So attraction      	     	The size of atomic radius decreases on moving
     between nucleus and valence shell increases due                left to right in a horizontal row. When, we move
     to which outermost shell is pulled in closer to the            across a period, the number of electrons in the same
     nucleus.	      [CBSE Marking scheme, 2015] 1 + 2               shell increases. This leads to greater electrostatic
                                                                    attraction between the nucleus and the outermost
 	4.	(i) Atomic radius decreases	               ½                   electron. This increased attraction pulls the
 		Reason : Nuclear charge increases which tends to                 outermost electron closer to the nucleus, thereby
     pull the electrons closer to the nucleus.	  1                  decreasing the atomic size.	                         3
                                                             	Ans.	(i) A and B belong to group 1 and 2 because they
 	(ii)	Atomic radius increases	                    ½
                                                                    form basic oxides. C belongs to group 13 as it has 3
 		Reason : Number of shells increases on going
       down the group.	                            1                valence electrons. D belongs to group 14 as it forms
                          [CBSE Marking Scheme, 2017]               almost neutral oxide. E and F belong to group 15 and
                                                                    16 as they form acidic oxides, G belongs to group 17
 	Ans.	Vertical Column — Groups	                       ½            as it has 7 valence electrons, and H to group 18. They
                                                                    belong to 3rd period of the periodic table.
 	    	Horizontal Rows — Periods	                      ½
                                                             	(ii)	H belongs to noble gas
 	(i)	Metallic character increases.                          	(iii)	A has largest atomic radius
 		Reason : Ability to lose electrons increases on           	(iv)	E and F are likely to be non–metals
       moving down the group due to increase in distance
                                                             	(v)	D is likely to be metalloid or semi–metal.	              	
       between the nucleus and the valence electrons/
                                                                                                             1+1+1+1+1
       decrease in the attraction between the nucleus and
       the valence electrons.	                          1        Commonly Made Error
 	(ii)	Atomic radius decreases.                              	 	 Students write irrelevant stories. Be specific. Read
 		Reason : The nuclear charge increases on moving                question carefully and write only what is asked.
       from left to right across a period resulting in
       increase in the attraction between the nucleus and        Answering Tip
       the valence electrons.	                          1    	 	 Do not overlook any part of a question and avoid
                            [CBSE Marking Scheme, 2017]           being in a hurry to conclude the answer.
	WORKSHEET-51
Solutions                                                  	2.	2nd period has 8 elements, 5th period has 18
                                                                elements.                                      ½ + ½	
	1.	Correct option : (b)                                   	 3.	(a) (i) Valency : The combining power or the com-
		Explanation : Carbon is an essential element for all               bining capacity of an atom is called its valency.
    organic compounds and belongs to group 14.
P-40                                                                                            S C I ENC E - X
 		(ii)	 Atomic size: Atomic size or atomic radius is 	        	4.	Vertical columns of the periodic table are known as
           the distance between the centre of the nucleus             groups.
           and the outermost shell of an isolated atom.        	(i)	The number of valence electrons remains constant
 	(b)	On moving from left to right in the periodic table,             when we move down the group.
      valency increases up to 4 and then decreases.            	(ii)	The number of occupied shells increases down the
 		   The electrons present in the last shell determine               group.
 		the valency of a particular element.                        	(iii)	The size of atom increases down the group.
 	   	If the number of valence electrons is less than or       	(iv)	The metallic character of elements increases down
      equal to 4, valency = number of valence electrons.              the group.
 	   	If the number of valence electrons is more than 4,       	(v)	The effective nuclear charge decreases down the
      valency = 8 - number of valence electrons                       group.	                                    ½×6=3
 	   	Atomic size decreases along a period. This is because    	   5.	No. of periods : 7.	                              ½
      on moving across a period, the number of valence
                                                               	     	Valency across a period increases from 1 to 4, then
      shells remains the same and the electrons increase
                                                                      decreases from 4 to zero.	                        1
      by one unit. As a result, the nuclear charge increases
      and thus, the atomic radius decreases.	                  	     	Metallic character of elements across a period
                                                                      decreases.	                                       ½
 		                                          1 + 1 + ½ + ½	
                                                               	     	Valency remains the same down a group	            ½
                                                               	    	Atomic size of elements increases down a group.	 ½
6.
 	WORKSHEET-52
 Solutions                                                     	     	Since the atomic radius decreases along a period,
                                                                      the atomic radius of calcium is smaller than that of
 	1.	Correct option : (b)                                             potassium. 	                                     ½
 		Explanation : The elements of 2nd period contain            	(iii)	The formula of oxide of calcium is CaO, because
     two shells, K and L shell.                                       the valency of calcium as well as that of oxygen
 	2.	(i) Magnesium : 2, 8, 2	                    ½                    is 2. 	      [CBSE Marking Scheme, 2016] ½+½
 	  	(ii) Calcium    : 2, 8, 8, 2.	              ½
                                                               	   4.	(i) The electronic configuration (2, 8, 2) of the
 	3.	(i) It is a metal.	                                 ½
                                                                      element ‘M’ suggests that it belongs to group 2
 	    	Since it has two electrons in its outermost shell/             and period 3 of the modern periodic table and its
       two valence electrons, which it can lose easily. 	½            valency is 2.	                              ½+½
 	(ii)	K (19) is placed before Ca (20) in the same period/
       fourth period.	                                   ½
	 	 Basically students should understand the basic                     (vi)     The formula of              ACl2      BCl3
                                                                                 their chlorides
     concept of how the elements are arranged in the
     periodic table, across the period and down the          			                [CBSE Marking Scheme, 2016] 6 × ½ = 3
     group, their position, electronic configurations,
                                                             	    6.	(i) Two elements of group 1 are Na, K / Sodium,
     no. of shells, valence electrons. Valence electrons             potassium. 	                                  2×½
     are the electrons of outermost orbit. Correctly find    	      	Electronic configurations Na = 2,8,1; K = 2,8,8,1	 	
     the number of valence electrons. While writing                  	                                             2×½
     the formula of the compound formed, first find          	(ii)	  	Similarity : Both have one valence electron / One
     the valence electrons of both elements and then                 electron in outermost shell.	                    ½
     interchange their valency as subscript of the           	 (iii)	Oxide – Na2O / K2O.	                             ½
     compound’s formula.                                                                 [CBSE Marking Scheme, 2016]
	WORKSHEET-53
Solutions                                                    	 (ii)	Formula with hydrogen- H2X or H2S	
                                                                                        xx
	1.	Correct option : (d)
		Explanation : In the Modern Periodic Table, the
    atomic radii decrease with increasing the atomic
                                                                          H      . x
                                                                                        X    x .
                                                                                                   H
    number from left to right. The atomic number of          		                   xx
                                                                                               	         ½+½
    F, O, and N are 9, 8, and 7, respectively so atomic
                                                             	 (iii)	Sulphur; non-metal. 	               ½+½
    radius will decrease from N to F.                                                 [CBSE Marking Scheme, 2016]
	2.	Atomic number of X = 2 + 8 + 7 = 17
	  	Atomic number of Y = 2 + 8 + 8 + 3 = 21	 ½ + ½           	 6.	Atomic number of X	= Mass number of X – No. of
                                                                  	                   		              neutrons ½
	3.	(i) Electronic Configuration − 2,8,2.	           ½       				 = 35 – 18 = 17 	                             ½
	(ii)	Metal, as it can easily lose electrons (from outer     		Therefore, 	Electronic configuration of
       most orbit) 	                              ½+½        			                    X	 = 2, 8, 7 	             ½
	(iii)	(a) X Y	               (b) X Z                        			       Group number	 =17 	                     ½
	     	 2 2	                     2 1	                ½       			               Period	 = 3
                                                             			              Valency	 = 8 – 7 = 1	       ½+½
		 Compound – XY 	               XZ2	             ½+½
                                                                                  [CBSE Marking Scheme, 2016]
                         [CBSE Marking Scheme, 2016]
                                                                                               OR
	4.	(i) Electronic Configuration of X(19) − 2,8, 8, 1. 	 ½
	(ii)	Fourth Period, Valency 1. 	                 ½+½
	(iii)	Basic oxide (X2O).	    	                          ½
	(iv)	 X2O + H2O ¾® 2 XOH.	                       ½+½
                           [CBSE Marking Scheme, 2016]
P-42                                                                                                     S C I ENC E - X
 	WORKSHEET-54
 Solutions                                                    (vi) B
                                                                   	 e < Mg < Ca < Rb
                                                                                                    [Topper Answer, 2016]
 	1.	Correct option : (c)
 		Explanation : Na and K are in the same group whereas
                                                              	5.	(i) Na/Sodium.
     Na and Mg belong to same period. In a group from
                                                              		Reason : The atomic size decreases from left to
     top to bottom, atomic radius increase whereas it
                                                                    right due to the increase in the nuclear charge.
     decreases in period from left to right. Hence, the
     order would be K> Na >Mg and K> Ca> Mg.                  	(ii)	Al/Aluminium.
                                                              	    	Reason : The tendency to lose electrons decreases
 	2.	Group 1 elements have 1 valence electron while
                                                                    from left to right.
     Group 2 elements have 2 valence electrons.	 ½+½
                                                              	                [CBSE Marking Scheme, 2015] 1½ + 1½
 	3.	(i) X (7) = 2,5. Group 15; Period 2 	           ½        Detailed Answer :
 	     	Y(8 ) = 2,6. Group 16; Period 2 	            ½        	(i)	Na will have the largest atomic radius as atomic size
 	     	Z(9) = 2,7. Group 17; Period 2 	             ½             goes on decreasing along a period from left to right.
 	(ii)	X> Y>Z	                                       ½
                                                                   It is due to increase in nuclear charge (number
 	(iii)	XZ3	                                         1
                            [CBSE Marking Scheme, 2016]            of protons in nucleus) which pulls the electrons
                                                                   towards it, i.e., force of attraction between nucleus
 	4.	(i) Ca = 2, 8, 8, 2 	                         ½               and valence electrons increases, therefore atomic
 	(ii)	Valence electrons in Rb = 1 	               ½               size decreases.
 	(iii)	Five 	                                     ½          	(ii)	Al is least reactive because reactivity of an element
 	(iv)	Metal 	                                     ½                depends upon the ability of its atoms to donate or
 	(v)	Rb is biggest in size 	                      ½                accept electrons. Tendency to lose electrons along a
 	(vi)	Be < Mg < Ca < Rb.	                         ½                period generally decreases with decrease in atomic
                           [CBSE Marking Scheme, 2016]              size, i.e., the force of attraction between the valence
                            OR                                      electrons and the nucleus increases, therefore
                                                                    electrons cannot be removed easily.	              1+2
                                                              	6.	(i) Valence electrons in ‘D’ = 5 and Valency of
                                                                  ‘D’ = 3. 	                                   1
                                                              	(ii)	‘A’ will have largest atomic radii because atomic
                                                                     radius decreases across a period from left to right. 	1
                                                              	(iii)	‘A’ will form the most basic oxide as it is most
                                                                     metallic. 	      [CBSE Marking Scheme, 2016] 1
 	
 	WORKSHEET-55
 Solutions                                                    	4.	
 	1.	Correct option : (c)                                      Sr. No.      Property           P             Q
 		Explanation : Mg and Ca are alkaline earth metals              (i)    No. of elec-          3              4
     whereas Na and K are alkali metals. Alkali metals                   trons in the         11             12
     are more electropositive compared to alkaline earth                 atom                 19             20
     metals and can easily lose electrons. Out of Na and                                               (any one pair) ½
     K, K will easily lose electrons because of bigger size
                                                                 (ii)    Size of the      Bigger          Smaller
     and less electronic attraction.                                                                                    ½
                                                                         atom
 	2.	Atomic number of X = 2 + 8 + 2 = 12
 	  	Atomic number of Y = 2 + 8 + 6 = 16	            ½+½         (iii)   Metallic           More       Less metallic
                                                                                                                        ½
                                                                         character         metallic
 	3.	(a) Non-metals
                                                                 (iv)    Tendency to        More            Less
 	(b)	(i) Increases                                                      lose electrons
 	   	(ii) Decreases
 	              [CBSE Marking Scheme, 2015] 1 + 1 + 1            (v)     Formula of          P2 O           QO
                                                                                                                        ½
                                                                         oxides
                                                                 (vi)    Formula of          PCl            QCl2
                                                                                                                        ½
                                                                         chlorides
	WORKSHEET-56
Solutions                                                        Answering Tip
	1.	Correct option : (b)                                        	 	 Basically students should understand the basic
		Explanation : As we move from left to right in                     concept of how the elements are arranged in the
       periodic table, metallic characters’ decreases and            periodic table, across the period and down the
       non-metallic characters’ increases.                           group, their electronic configurations, stability,
                                                                     reactivity, family and other properties. Then they
	2.	X and Y will show similar chemical properties as
                                                                     should recollect the element in the modern periodic
       these have same valence electrons.
                                                                     table and answer the questions.
			                         X	= 2, (1)
                                                                	5.	Electronic configuration of Q = 2, 8, 3
	     		                    Y	 = 2, 8, (1)         ½ + ½	
                                                                			              Valency of Q	= 3	                    1
	3.	(i) E	                                               ½
	(ii)	B	                                                 ½      	     	Electronic Configuration of R = 2, 8, 5
	(iii)	C	                                                ½      			              Valency of R	= 8 – 5 = 3	            1
	(iv)	B, because atomic radius decreases from left to right     	     	Electronic configuration of P = 2, 8, 1
       due to increase in the nuclear charge.	            1     	     	Electronic configuration of S = 2, 8, 7	       1
	(v)	Noble gases.	                                       ½      			                  Formula	 : PS/NaCl
                                                                	6.	(i)Valency of group 1 elements = 1
	4.	(i) They all belong to group 2 because all three
                                                                	     	Valency of oxygen = 2
    have 2 electrons in their outermost shell.
                                                                	     	Oxides of group 1 elements :
	(ii)	Be is least reactive because it has 2 shells and due to   	     	Formula of the oxides of group 1 is M2O, where M
      more nuclear change it is not easy to take electrons             is the group 1 element and O is oxygen.
      from it.                                                  	(ii)	Valency of group 13 elements = 3
	(iii)	Ca is the element having largest atomic radius           	     	Valency of halogens = 1
       because it has 4 shells.	              1+1+1             	     	Halides of group 13 elements :
                                                                	     	Formula of the halides of group 13 is MX3,
	                          [CBSE Marking Scheme, 2015]
                                                                       where M is the group 13 element and X is
                                                                       halogen.	
    Commonly Made Error
                                                                	(iii)	Valency of group 2 elements = 2
	 	 Usually students get confused with element                 	     	Valency of group 16 elements = 2
     arranged in groups and periods in the periodic table
                                                                	     	Compounds of group 2 and group 16 elements :
     and their periodic properties.
                                                                	     	Formula of the compounds of group 2 and 16 is
                                                                       MN, where M is the group 2 element and
                                                                	     	N is the group 16 element.	               1+1+1
P-44                                                                                                S C I ENC E - X
         Commonly Made Error                                           		 group, their position, electronic configurations, no.
                                                                          of shells, valence electrons. Valence electrons are
 	 	 Usually students get confused with the position
                                                                          the electrons of outer most orbit. Correctly find
      of elements arranged in groups and periods of the
                                                                          the number of valence electrons. While writing
      periodic table. They also confuse with the valence
                                                                          the formula of the compound formed, first find
      electrons, formula of compound these elements
                                                                          the valence electrons of both elements and then
      form.
                                                                          interchange their valency as subscript of the
                                                                          compound’s formula.
         Answering Tip
 	 	 Basically students should understand the basic
      concept of how the elements are arranged in the
      periodic table, across the period and down the
 	WORKSHEET-57
 Solutions                                                             	4.	
                                                                       	     	             Valency     1              1
                                                                       	     	So, the formula of the compound formed when
                       Valency                                                elements A and D combine is AD. 	             1+1+1
                                  1            1
                                                                       	5.	(i) Element E will form covalent compounds by
 	            	So, the formula of the compound formed when
                                                                              sharing its four valence electrons.
               elements A and B combine is BA.
                                                                       	(ii)	Element D is a metal with valency three.
         (iii)          B. + A             B   A
                                                                       	(iii)	Element B is a non-metal with valency three.
                                              +       –                	(iv)	We know that the size of elements decreases on
                      Lewis Structure :   B       A                           moving left to right in a period. Therefore, element
 	          	                                             	    1+1+1          D is greater than element E.
                                                                       	(v) 	The name of the family to which elements C and F
                                                                              belong is the noble gas family (group 18).	
                                                                       	     	                                ½+½+½+1+½
	WORKSHEET-59
Solutions                                                         	4.	(i) 12.	                 		                          ½
	1.	Correct option : (b)                                          	 (ii)	2.			                                             ½
                                                                  	 (iii)	Be. 			                                          ½
		Explanation : Atomic number 14 is for Silicon
    element which is a metalloid and exhibit properties           		      Because Be has two electrons in its valence shell.
    of both metals and non-metals. It has 4 electrons                     Given element also has two electrons in its valence
    in its valence shell so tends to form covalent acidic                 shell.
    oxide like non-metals.                                        	      	Since valence electrons determine the chemical
                                                                          property, hence the given element has same
	2.	Valency is same i.e. 1.	                            1                 chemical properties as that of Be. 	1½
                          [CBSE Marking Scheme, 2012]                                        [CBSE Marking Scheme, 2012]
	3.	(i) Z.	                                              ½
                                                                  	5.	(i) The position of elements X in the modern periodic
	(ii)	Halogens.	½                                                       table is group number 17 and period number 3. The
	(iii)	Magnesium and nitrogen.	                     ½+½                 position of element Y in the modern periodic table
	(iv)	Silicon.	                                          ½              is group number 2 and period number 4. Electronic
	(v)	X has bigger size than P because X has less effective              configuration of element X = 2, 8, 7.
       nuclear charge.	                                  ½        	    	It has 3 shells so period number 3.
  Commonly Made Error                                             	    	Halogens are kept in group 17.
	 	 Students usually get confused with elements                  	    	Electronic configuration of element Y = 2, 8, 8, 2
     arranged in groups and periods in the given table.           	    	It has 4 shells so period number is 4.
                                                                  	    	The valence shell has 2 electrons so the group
 Answering Tip                                                          number is 2.	                                      1½
	 	 Students should understand the basic concept of              	(ii)	Formula of the compound :
     how the elements are arranged in the periodic                	    	Valency of element Y 	 Valency of element X
     table, across the period and down the group, their           			              2	             	        1
     electronic configurations, stability reactivity, family      	    	\	      YX2			                                     1½
     and other properties.
P-46                                                                                                   S C I ENC E - X
     Commonly Made Error                                        	(ii)	4Be (Beryllium) and 20Ca (Calcium) belong to the
                                                                       same group, because they have same number of
 	 	 Students usually get confused with the position                  valence electrons.
      of elements arranged in groups and periods of
                                                                	     	Be = 2, 2 and Ca = 2, 8, 8, 2
      the periodic table. They also get confused with the
      formula of compound.                                      	(iii)	Beryllium (Be) and Fluorine (F) have same period
                                                                       i.e., second period which has 2 shells (K and L)
 	6.	(i) 19K (Potassium) is the element that has one                   whereas Potassium (K) and Calcium (Ca) also
     electron in the outermost shell.                                  belong to same period i.e., fourth period which
 	      	Electronic configuration = 2, 8, 8, 1                         have 4 shells (K, L, M and N).	1+1+1
 	WORKSHEET-60
 Solutions                                                      	4.	There are 7 horizontal rows known as periods, that
                                                                    the modern periodic table has.
 	1.	Correct option : (c)                                       	  	In periods, the number of valence electrons
 		Explanation : Elements of the same group have                    increases from left to right and due to decrease
     same number of valence electrons hence valency                 in atomic size, the force of attraction between
     will remain same.                                              the valence electrons and the nucleus increases.
 	2.	Electronegativity increases across a period.	 1                Metallic character decreases along the period due
                         [CBSE Marking scheme, 2012]                to decrease in tendency to lose electrons.
                                                                	  	Atomic size generally increases from top to bottom
 	3.	(i) Element ‘A’ is a metal because it is present in            in a group due to the addition of a new shell i.e.,
        group I (1 valence electron) and can lose electron          number of shells goes on increasing down the
        easily.	                		                         1        group.	                                          3
 	(ii)	Element B has larger size than ‘C’ because it has        	5.	(i) Element — E		                         1
        more number of shells than ‘C’.                         	(ii)	K L M	          		                      1
   	   	Also, B lies in the third period and has three shells   	     	2 8 6
        whereas C lies in second period and has two             	(iii)	X and Z.	      		                      1
        shells.	                		                         1                        [CBSE Marking Scheme, 2012]
 	(iii) 	‘C’ being an element of 3rd group has three valence
        electrons, therefore its valency is 3.	            1
 	     	                      [CBSE Marking Scheme, 2014]
                                                                                                               qqq
 B
 6         LIFE PROCESSES
              	   TOPIC-1
                  Nutrition
  	WORKSHEET-61
  Solutions                                                 	5.	Three event which occur during photosynthesis :
  	1.	Correct option : (c)                                  	(i)	Absorption of light energy by chlorophyll.
  		Explanation : Autotrophs take in food from the          	(ii)	Conversion of light energy to chemical energy and
      outside world and convert them into stored forms             splitting of water molecules into hydrogen and
      of energy. This material is taken in the form of             oxygen : Photochemical reaction.
      carbon dioxide and water which is converted into
      carbohydrates in the presence of sunlight and         	(iii)	Reduction of carbon dioxide to carbohydrates :
      chlorophyll.                                                 Dark reaction. 	                          1+1+1
                                                            	                           [CBSE Marking Scheme 2016]
  	2.	Glucose/Amino acid                         1
                                                            	6.	Photosynthesis takes place in the grana and stroma
  	  		                [CBSE Marking Scheme, 2018]                 of the chloroplast (Plastid) in green parts of plants.
  	3.	Conditions necessary for autotrophic nutrition are    	     	The raw materials required for this process are
      : Sunlight, chlorophyll, carbon dioxide and water.           carbon dioxide and water in the presence of
      The by-products are carbohydrates, in the form               sunlight and chlorophyll.
      of starch and oxygen. The source of by-product        	     	Carbon dioxide enters the leaves through stomata
      (oxygen) is water.	                        1+1+1             and cells of the roots absorbs water from the soil.
  	4.	It is the mode of nutrition in which an organism      	     	Balanced equation for photosynthesis :
      cannot make its own food and depends on other                                        Chlorophyll
      organisms for food. All the animals including man,    		6CO2 + 6H2O 
                                                                           Sunlight
                                                                                    → C6H12O6 + 6O2
      most bacteria and some fungi have heterotrophic
      mode of nutrition and these organisms are called      	          	The by-products in this process is the evolution of
      heterotrophs.                                                     oxygen gas.                     1+1+1+1+1
  	  	Holozoic, Saprophytic and Parasitic.	           3
  	  		                 [CBSE Marking Scheme, 2014]
  	WORKSHEET-62
  Solutions                                                 	          	are generally basic, they neutralize the excess acid
                                                                        produced in the mouth and prevent tooth decay.3
  	1.	Correct option : (d)                                  	                            [CBSE Marking Scheme 2018-19]
  		Explanation : The autotrophic mode of nutrition
      requires carbon dioxide, water, chlorophyll and
      sunlight.                                             	5.	
  	2.	Saliva moistens the ingested food with mucus,             S.              Name of the         Name of Secretions
      sterilises it with lysozyme and partially digests         No.               glands
      starch part of food into sugar with the help of
      salivary amylase or ptyalin.	                     1       (i)      Salivary glands          Saliva contains enzyme,
  	3.	Digestion starts in the buccal cavity in the mouth.                                         ptyalin
      The enzyme secreted in buccal cavity is salivary          (ii)     Gastric glands           Secretes gastric juice,
      amylase. Salivary amylase helps in breakdown of                                             HCl, mucus, pepsin.
      starch into maltose and dextrin.	          1+1+1
                                                                (iii)    Liver                    Bile juice.
  	4.	Sweet tooth leads to tooth decay, which is
                                                                (iv)     Intestinal glands        Intestinal juice.
      caused by the action of bacteria on food particles
      remaining in the mouth and acid is formed.                (v)      Pancreas                 Pancreatic juice which
      The pH of the mouth falls below 5.5 and the tooth                                           contains trypsin, lipase
                                                                                                  and amylase.
  	  	enamel dissolves resulting in cavity. Toothpastes
                                                            	  		           	                         (Any three) 1 + 1 + 1
                                                            			                               [CBSE Marking Scheme, 2012]
  P-48                                                                                                   S C I ENC E - X
 	    6.	(a) (i) Starch (ii) ATP
                                                                   Ingested food                           Food
     (b)	                    Food particle                                          Fresh food
                                                                                                          vacuole
                                                        Contractive particle Lysosome vacuole
                                                         vacuole                             Old food           Undigested
                                                                                              vacuole            particle
                           A                          B                C                  D               E
      	                                      Holozoic nutrition in Amoeba
 	   	Protozoans like Amoeba capture food with the help of temporary finger-like processes called pseudopodia.
 	   	As soon as Amoeba comes in contact with a food particle or prey, it throws pseudopodia all around the food
      particle. The tips of encircling pseudopodia fuse and the prey comes to lie in a vesicle or phagosome. This
      method of intake of food is called circumvallation. Amoeba can also ingest food by other methods like import
      circumfluence and invagination.
 	(c)	In Paramecium, the food is taken in at a specific spot and is moved to this spot by the movement of cilia, which
      cover the entire surface of the cell.	              	                  [CBSE Marking Scheme, 2014] 1 + 3 + 1
 	WORKSHEET-63
 Solutions                                                                  	4.	Small intestine.	                                ½
 	1.	Correct option : (b)                                                   	  	Secretions of liver and pancreas mixes with food.
                                                                                Pancreatic enzymes make it alkaline. Bile juice
 		Explanation : These are saprotrophs and digestion
                                                                                from liver too helps in it. Bile salts break the fat
     in saprotrophs takes place before ingestion. They
                                                                                present in the form of large globules into smaller
     break down and convert complex organic molecules
                                                                                ones, increasing the efficiency of enzyme action.
     present in dead and decaying matter into simpler
                                                                                Enzymes like trypsin digests proteins and lipase
     substances outside their body.
                                                                                breaks down fats. Intestinal juice convert proteins
 	2.	Digestion of fats takes place in small intestine with                      to amino acids, complex carbohydrate to glucose
     the help of bile juice which acts as emulsifiers and                       and fat into fatty acids and glycerol.	         2½
     breaks down the larger fat droplets into smaller                       	  		                   [CBSE Marking Scheme, 2012]
     ones. They are then acted upon by lipase enzyme
     found in pancreatic juice, which converts them into
                                                                            	5.	They are called as Villi.
     monoglycerides and fatty acids.	                    1
                                                                            	(i)	Villi are richly supplied with blood vessels which
 	3.	(i) Small intestine.                                                          take the absorbed food to each and every cell of the
 	(ii)	Herbivores have longer, small intestine for                                 body.
       digestion of cellulose while carnivores have a                       	(ii)	It also absorbs water.
       shorter small intestine for early digestion of meat.	
                                                                            	(iii)	They increase the surface area for the absorption of
       	                                              1+2
                                                                                   food.	 [CBSE Marking Scheme, 2013] 1 + 1 + 1
 	    		                  [CBSE Marking Scheme, 2013]
6. (a)
Oesophagus
                                         Diaphragm
                                      Gall bladder
                                      (stores bile)
                                                                                     Stomach
                                          Bile duct
                                                Liver                                Small
                                         Pancreas                                    intestine
	WORKSHEET-64
Solutions                                                          	(v)	HCl and Enzymes–pepsin, mucus.	
                                                                   	           [CBSE Marking Scheme, 2012] 1 + 1 + 1
	1.	Correct option : (d)
		Explanation : The sequence of organs in human                    	 4.	(a) (i) Dilute HCl makes the medium acidic.	 1
    alimentary canal are mouth, oesophagus, stomach,
                                                                   	   	(ii) It activates the enzyme pepsin.	        1
    small intestine, large intestine and anus.                     	(b)	CO2 and water.	 [CBSE Marking Scheme, 2012] 1
	2.	Gastric glands are present in the wall of stomach
    which releases hydrochloric acid, mucus and                    	5.	(i) Helps in mixing the food thoroughly with more
    protein digesting enzyme pepsin.	              1                      digestive juice by peristalsis.	               1
	  		                  [CBSE Marking Scheme, 2014]                 	(ii)	Creates an acidic medium, which facilitates the
                                                                          action of the enzyme pepsin.	                  1
	3.	(i) Small intestine                                            	(iii)	Protects the inner lining of the stomach from the
	(ii)	Pancreatic juice                                                    action of the acid.	                           1
	(iii)	Liver                                                       	                           [CBSE Marking Scheme, 2011]
	(iv)	Large intestine
	WORKSHEET-65
Solutions                                                          	(ii)	The purpose of making urine is to filter out waste
                                                                          products (urea or uric acid) from the blood.	  1
	1.	Correct option : (b)                                           	    		                  [CBSE Marking Scheme, 2012]
		Explanation : If salivary amylase is lacking in the
    saliva, the process of starch digestion will get disturb       	4.	(i) Trypsin + Proteins → Amino acids
    as salivary amylase helps in digestion of starch.              	(ii)	Amylase + Carbohydrates → Simple sugars
	2.	HCl of gastric juice disinfects the food and acidifies
                                                                   	(iii)	Lipase + Fats → Fatty acids + Glycerol.
    it for proper functioning of proteolytic enzyme
    pepsin.	                                               1       	     		       [CBSE Marking Scheme, 2012] 1 + 1 + 1
                                                                   Detailed Answer :
	3.	(i) The food coming from the stomach is acidic and
                                                                   	    	Trypsin, chymotrypsin, pancreatic amylase
    has to be made alkaline for the pancreatic enzyme
                                                                         and lipase are the main enzymes present in the
    to act. Bile juice accomplishes this. Bile salts break-
                                                                         pancreatic juice. They help in the break down of
    down larger globules of fats into smaller globules
                                                                         food components as follows :
    increasing the efficiency of enzyme action.	         2
P-50                                                                                                  S C I ENC E - X
 	     	Trypsin acts upon proteins and converts it into          	6.	Just before Starch test — Pale yellow
        peptids and amino acids, pancreatic amylase
                                                                 	  	Just after Starch test – Blue black
        converts starch into disaccharide and other simple
                                                                                           Chlorophyll
        sugars while pancreatic lipase acts upon fats and        	    	6CO2 + 6H2O 
                                                                                    Sunlight
                                                                                             → C6H12O6 + 6O2
        converts it into fatty acids and glycerol.               	    	
                                                                          O2 is obtained from water (H2O), as splitting of
 	5.	(i) The cake will have a bitter taste because of the                 water results in formation of hydrogen (used for
        formation of Na2CO3/sodium carbonate while                        making glucose) and oxygen (by-product).
        baking/heating                            ½+½                                  [CBSE Marking Scheme, 2018-19] 3
 	(ii)	By adding tartaric acid                         1
 	(iii)	The liberated CO2 gas                          1
 	     		                 [CBSE Marking Scheme, 2018]
             	   TOPIC-2
                 Respiration
 	WORKSHEET-66
 Solutions                                                       	Detailed Answer :
                                                                 	    	A physical process by which oxygen is taken in and
 	1.	Correct option : (b)
                                                                       carbon dioxide is given out is called breathing.
 		Explanation : The breakdown of pyruvate to give
     carbon dioxide, water and energy takes place in             	    	Breathing in humans involves three steps :
     mitochondria.                                              	(i)	Inspiration : When we breathe in, ribs move up and
 	2.	The respiratory pigment in human being is                          flatten the diaphragm due to which the chest cavity
     haemoglobin. Haemoglobin is present in RBC’s of                    becomes larger. As a result air is sucked into the
     blood in humans.	                       ½+½                        lungs and fills the expanded alveoli.
 	3.	Breathing is the process of letting in oxygen from         	 (ii)	 Gaseous exchange : Haemoglobin binds with
        air into the lungs and CO2 out of the lungs.                    the oxygen and carries it along the blood in the
 	     	Mechanism : Involuntary, rate controlled by                     body. As blood passes through the tissues of the
        brain. Outward and inward movement of ribs                      body, oxygen from the blood diffuses into the cell,
                                                                        whereas carbon dioxide which is produced during
        increases or decreases the space of thoracic
                                                                        respiration diffuses into the blood and is carried to
        cavity, action assisted by diaphragm continuous
                                                                        the lungs for expiration.
        inhalation and exhalation of the air.                   	 (iii)	Expiration : Ribs move down and diaphragm
 	                          [CBSE Marking Scheme, 2016]                 becomes dome-shaped decreasing the chest cavity.
                                                                        Thus, pushing the air out from lungs.              3
 	   4.	(i) Take two healthy potted plants which are nearly the same size.
 	(ii)	Keep them in a dark room for three days.
 	(iii)	Now place each plant on separate glass plates. Place a watch glass containing potassium hydroxide by the side of
        one of the plants. The potassium hydroxide is used to absorb carbon dioxide. When the leaves of both the plants
        were tested for starch, it was found that the leaves of the plant kept in bell jar (b), which is without potassium
        hydroxide gave the positive test of starch. This shows that CO2 is essential for photosynthesis.
Bell Jar
                                Watch glass
                           containing potassium
                                hydroxide
                                                           (a)                       (b)
 	     	           Experimental set up (a) With potassium hydroxide (b) Without potassium hydroxide.                      3
      6.	(i)
                            Nasal passage
                                                                     Trachea
                             Mouth cavity
                                Pharynx
                                   Larynx                                Rings of cartilage
Lung
                                 Bronchi                                       Ribs
                                  Bronchioles
                                    Alveolar sac
	              	                                        Diaphragm                             	4
	(ii)	So that there is sufficient time for oxygen to be absorbed and for CO2 to be released. 	                   1
	    		                                                    	                            [CBSE Marking Scheme, 2012]
	WORKSHEET-67
Solutions                                                     Answering Tip
	1.	Correct option : (d)                                     	 	 Always be specific and give clear and complete
		Explanation : Yeast is unicellular eukaryote which              answers. Incomplete and vague answers must be
    carries out ethanol fermentation. In the first phase,         pointed out.
    glucose is converted into pyruvate (glycolysis) in
                                                             	4.	
                                                                The exchange of gases takes place between the
    the cytoplasm of the cell. Due to limited oxygen
                                                                blood capillaries that surround the alveoli and the
    availability, pyruvate remains in cytoplasm where
    pyruvate decarboxylase and alcohol dehydrogenase            gases present in the alveoli. Thus, alveoli are the
    enzymes carry out the second phase of anaerobic             site for exchange of gases. The lungs get filled up
    respiration and produce ethanol and carbon                  with air during the process of inhalation as ribs are
    dioxide.                                                    lifted up and diaphragm is flattened. The air that is
	2.	Aerobic respiration occurs in mitochondria of the           rushed inside the lungs fills the numerous alveoli
    cell.	                                             1        present in the lungs. Each lung contains 300–350
	3.	A terrestrial organism can obtain oxygen directly           million alveoli. These numerous alveoli increase
    from the air and have slow breathing rate but;              the surface area for gaseous exchange making the
    aquatic organisms have to obtain oxygen for                 process of respiration more efficient.	             3
    respiration which is dissolved in water. Since, the      	5.	
                                                                Plants perform two processes all together,
    amount of oxygen dissolved in water is fairly low as
                                                                photosynthesis and respiration. Photosynthesis
    compared to the amount of oxygen in air, the rate of
                                                                takes place during day time when there is enough
    breathing in aquatic organisms is much faster.	    3
                                                                sunlight. During this process, the green tissue of the
    Commonly Made Error                                         plants exposed to light makes glucose in presence
	 	 Students often write vague answer. It seems they           of chlorophyll pigment, water and carbon dioxide.
     are unaware of the concept of rate of breathing.           During this process oxygen is released and it is
                                                                possible only in presence of sunlight.	              2
P-52                                                                                            S C I ENC E - X
 	    	Respiration is another process which is carried out by   	(ii)	Oxygen                  	                           ½
       all animals and plants. This is a continuous process     	    	By splitting of water (photolysis)
       where glucose is broken down to CO2 and H2O and
       energy is released in the form of ATP molecules. This    		2H2O splits
                                                                        → H2 + O2 	                                     1
       is continued regardless of daylight or darkness.	 1
                                                                	(iii)	
                                                                      They take up CO2 at night through stomata, which
 	6.	(i) 	2                                                           open during night and produce an intermediate
          (b) Cuticle                                                 organic acid which is acted upon by the energy
                                                                      absorbed by chlorophyll during the day and
                                                                      breaks up to release of CO2. The CO2 so produced
                                                                      internally is used in photosynthesis during day
                                           (a) Chloroplast            when stomata are closed.	1½
                                                                		
                                                                 Desert plants. [Xerophytic CAM plants]	1
 	WORKSHEET-68
 Solutions
                                                                	4.	(a) Glucose In Cytoplasm
                                                                                         → Pyruvate
 	1.	Aquatic organisms like fishes obtain oxygen from
                                                                          In absence of oxygen
     water present in dissolved state through their gills.              
                                                                               → Ethanol + CO2 + Energy 1½
     Since the amount of dissolved oxygen in water is           	(b)	Fishes take in water through the mouth and force
     fairly low compared to the amount of oxygen in the              it past the gills where the dissolved oxygen is taken
     air. Hence, the rate of breathing is much faster in             up by the blood.	                                   1
     aquatic organisms than in terrestrial organisms.	 1
                                                                	(c)	Alveoli 	                                         ½
 	2.	Adenosine triphosphate (ATP). It is produced during
     respiration in living organisms in mitochondria.	1         		Functions : They contain an extensive network of
 	3.                                                                 blood vessels which exchange gases.	              ½
                                                                	   	They increase surface area of absorption of gases.	½
     S. No. Aerobic respiration        Anaerobic
                                                                	(d)	Haemoglobin	                                      ½
                                       respiration
                                                                	   	Role : Due to high affinity for O2, it helps in its
     (i)     Oxygen is utilized    Oxygen is not                     transport from alveoli to the tissue	             ½
             for the breakdown     required.                    	   		                  [CBSE Marking Scheme, 2018]
             of respiratory sub-
             strate.                                            	   5.	Breathing : Breathing is the process of taking in
     (ii)    It takes place in     It takes place in                   oxygen-rich air and giving out carbon dioxide-
             cytoplasm (glycoly-   cytoplasm only.                     rich air. Breathing in is ‘inhalation’ and breathing
             sis) and inside mi-                                       out is ‘exhalation’. The breathing mechanism of
             tochondria (Krebs                                         lungs is controlled by the diaphragm and the inter-
             cycle).                                                   costal muscles. Diaphragm is a membrane which
                                                                       separates the thoracic chamber from the abdominal
     (iii)   End products are End products are
                                                                       cavity. When diaphragm moves down, the lungs
             carbon dioxide and lactic acid or etha-
                                                                       expand and air is inhaled. When diaphragm moves
             water.             nol and carbon di-
                                                                       up, the lungs contract and air is exhaled. Inhalation
                                oxide.
                                                                       involves bringing in air from outside the body into
     (iv)    More energy is re- Less energy is re-                     the lungs. When we breathe in, the size of our chest
             leased.            leased.                                increases. This happens because when air enters,
     (v)     Complete oxidation There is incomplete                    the lungs expand and the ribs move outwards.
             of glucose happens. oxidation of glu-                     Simultaneously, the diaphragm contracts and
                                 cose.                                 becomes flat. Thus, the size of our chest increases.
                                                                       Exhalation involves removal of CO2 from the
                                 (Any Three) 1 + 1 + 1
                                                                       body. When we breathe out, the size of our chest
Ribs Lung
Diaphragm
                                                                         Diaphragm
                                                                          contracts                    Diaphragm
                                                                                                         relaxes
Breathing in Man 5
            	   TOPIC-3
                Circulation and Transportation
	WORKSHEET-69
Solutions                                                            plants by physical forces such as transpiration pull.
                                                              		Transport in phloem : Phloem tissue helps in
	1.	Correct option : (a)
                                                                transport of food. Here, food is transported in both
		Explanation : Valves ensure that blood does
    not flow backwards when the atria or ventricles             upward and downward directions. Transport of
    contract. Semilunar valves, the valves present              food in phloem requires energy in the form of ATP.
    between ventricles and their attached vessels,            	(b)	
                                                                  The transport of soluble products of photosynthesis
    serve to prevent the backflow of blood to ventricles          to other parts of plant through phloem is known as
    from their respective attached vessels. Likewise,
                                                                  translocation.	                           1+1+1
    atrioventricular (AV) valve between atrium and
    ventricle directs the flow of blood and prevents any       	   5.	
    backflow into atria.
                                                                          S. No.           Artery                      Vein
	2.	(i) Phloem	              (ii) Xylem.	           ½+½
                                                                            (i)       Wall is thick.        Wall is thin.
	3.	The loss of water in the form of vapour from
    the aerial parts of the plants is known as                              (ii)      Valves absent.        Valves present.
    transpiration.	                            1
                                                                           (iii)      Blood flows from Blood flows from
	    	Functions :                                                                     heart to different different organs to
	(i)	It helps in the absorption and upward movement                                   organs.            heart.
     of water and minerals dissolved in it from roots to
                                                                            (iv)      The flow of The flow of blood
     the leaves.	                                     1
                                                                                      blood is fast, is slow, steady and
	(ii)	It also helps in temperature regulation.	         1                             jerky and with with less pressure.
	    		                  [CBSE Marking Scheme, 2012]                                  great pressure.
	4.	(a) Transport in xylem : Xylem tissue helps in                                 (Any three) [CBSE Marking Scheme, 2016]
      transport of water and minerals. Here, water is         	                                                  1+1+1
      transported upwards from roots to aerial parts of
P-54                                                                                                        S C I ENC E - X
                                                     Aorta
 	6.	(a) 	
                                 Vena Cava                                    Pulmonary arteries
                                 from upper
                                 body                                         Pulmonary veins
                              Vena Cava
                              from lower
                              body
                                      Right
                                      ventricle                               Left ventricle
                                       Septum
                                       (Dividing wall)
                                                                                              	4
 	   (b) (i)	 As ventricle has to pump blood into various organs. Therefore it has wall thicker them that of atria.
      (ii) Since the blood emerges from the heart under high pressure.	                                             1
 	WORKSHEET-70
 Solutions                                                     		Detailed Answer :
                                                               	(i)	Capillaries.
 	1.	Correct option : (b)                                      	(ii)	
 		Explanation : Hippocampus, Exocoetus, Anabas
     belong to class pisces. Fishes have two chambered
     heart and exhibit single circulation while three
     chambered heart of amphibian and reptiles and                  Pulmonary
                                                                                           Lung              Pulmonary vein
     four chambered heart of birds and mammals exhibit              artery to lungs
                                                                                         capillaries         from lungs
     double circulation.
 	2.	It is the loss of water in the vapour form from the
     aerial exposed parts of a plant.	                 1
	WORKSHEET-71
Solutions                                                         	     4.	(i) Since ventricles have to pump blood into
                                                                           various organs, they have thicker muscular walls
	1.	Correct option : (a)
                                                                           than atria do.	                              1
		Explanation : The anterior vena cava collects
      deoxygenated blood from the head, chest, and arms           	(ii)	The lining of alimentary canal has muscles that
      and enters the right atrium while the inferior vena                contract rhythmically in order to push the food
      cava collects blood from the lower body regions.                   forward. These are peristaltic movements.	      1
      Both venae cavae pass the deoxygenated blood to             	(iii)	In desert plant, stomata open at night and absorb
      the right atrium. Therefore, blood from tissues is                 CO2 and store it as an intermediate compound,
      rich in carbon dioxide.                                            that is converted into carbohydrate during the day
	2.	(i) Plasma                                                           time.	            [CBSE Marking Scheme, 2012] 1
	(ii)	Haemoglobin present in RBCs. 	              ½+½
	3.	                                                              	5.	Xylem (vessels) of roots, stems and leaves are inter-
                                                                      connected to form a continuous column. Roots
    S. No.   Blood Vessels               Function                     also take up mineral salts actively, water moves
                                                                      in and as a result by creating pressure pushes the
     (i)     Arteries         They carry blood away from              water up. Transpiration pull creates a suction force
                              the heart to various organs of          for pulling water up.	                             3
                              the body.                           	  		                  [CBSE Marking Scheme, 2014]
     (ii)    Veins            They collect blood from
                              different organs and bring it       	 6.	(a) Plasma, red blood cells, white blood cells,
                              back to the heart.                       platelets	                              (Any two) 2
     (iii)   Capillaries      Exchange of material between        	(b)	Lungs → Left side of the heart → aorta → body
                                                                       organs	                                             1
                              the blood and surrounding
                                                                  	(c)	Prevent back flow of blood.	                        1
                              cells takes place across the thin
                                                                  	(d)	Artery has thick elastic wall and vein is thin walled/
                              walls of capillaries.
                                                                       valves are present in the veins and not in arteries.
	       		           [CBSE Marking Scheme, 2012] 1 + 1 + 1        	   		                 [CBSE Marking Scheme, 2018] 1
	WORKSHEET-72
Solutions                                                         	4.	
                                                                     The components of xylem tissue (tracheids
                                                                     and vessels) of roots, stems and leaves are
	1.	Correct option : (a)
                                                                     interconnected to form a continuous system of
		Explanation : In a plant, the xylem is responsible for
                                                                     water conducting channels that reaches all parts of
    transport of water.
                                                                     the plant. Transpiration creates a suction pressure,
	2.	Transpiration	           [CBSE Marking Scheme, 2016] 1           as a result of which water is forced into the xylem
                                                                     cells of the roots. Then there is a steady movement
	   3.	(i) This allows a highly efficient supply of oxygen,          of water from the root xylem to all the plant parts
       and meet their high energy needs (as they are                 through the interconnected water conducting
       warm–blooded animals).	                           1           channels.	                                        3
	(ii)	Because they have to pump blood throughout the
       body or into various organs.	                     1        	5.	Differences between Xylem and Phloem :
	(iii)	To allow cellulose to be digested. 	              1             S. No.         Xylem               Phloem
	     		                   [CBSE Marking Scheme, 2012]
                                                                        (i)     Xylem tissue helps Phloem tissue helps
                                                                                in the transport of in the transport of
                                                                                water and minerals. food.
P-56                                                                                                   S C I ENC E - X
     (ii)    Water is transported   Food is transported                                Pulmonary Vein
             upwards from roots     in both upward and                                          ¯
             to all other plant     downward direc-                                       Left Auricle
             parts.                 tions.                                                      ¯
                                                                                         Left Ventricle
     (iii)   Transport in xylem     Transport of food                                           ¯
             occurs with the help   in phloem requires                               Truncus Arteriosus
             of simple physical     energy in the form                                          ¯
             forces such as tran-   of ATP.                                         Systemic Circulation
             spiration pull.                                  	    	The blood from the systemic circulation comes to
                                                 1+1+1             the right auricle. From the right auricle, the blood is
                                                                    pumped into the right ventricle. The right ventricle
 	Ans.	The heart is the key organ of cardiovascular system,
                                                                    pumps the blood to lungs, through pulmonary
       which acts as a muscular pump. It is organized with
       a set of arteries and blood vessels which regulates          artery. Oxygenation of blood takes place in alveoli
       the blood flow systematically.                               in lungs. The oxygenated blood, from the lungs,
                                                                    comes to the left auricle through pulmonary vein.
 		The following flow chart shows the circulation of
                                                                    From left auricle, the blood is pumped into the left
       blood through the heart :
                                                                    ventricle. Finally, the left ventricle pumps the blood
                          Systemic Vein                             into the systemic circulation.
                                ¯                             	    	In our body two types of circulatory system
                         Sinus Venosus                              completes together the whole cardiovascular
                                ¯                                   system.
                          Right Auricle                       	(i)	First is the transport of blood for the exchange of
                                ¯                                   gases (Oxygen and Carbon dioxide) which includes
                         Right Ventricle                            the connection of heart to liver.
                                ¯                             	(ii)	Second, includes the transport and distribution
                        Pulmonary Artery
                                                                    of oxygenated blood from heart to all the other
                                ¯
                                                                    body parts.
                              Lungs
                                ¯
             	   TOPIC-4
                 Excretion
 	WORKSHEET-69
 Solutions                                                    	     	The four substances reabsorbed from initial filtrate
 	1.	Correct option : (d)                                            are :
                                                              	     	(i) Amino acid (ii) glucose (iii) salts (iv) major
 		Explanation : Nephrons are the structural and                     amount of water.	                               1+2
        functional filtration unit of kidney that serve in    	4.	Nitrogenous waste present in urine is uric acid or
        filtration, reabsorption and secretion. Ureters are          urea.
        small muscular tubes that extend from the kidney
                                                              	     	The basic filtration unit of kidney is nephron.
        and carry urine into the urinary bladder. The
        urethra is a canal that carries urine from bladder    		Urine production is regulated by :
        and expels it out of body. Neurons are structural     	(i)	amount of excess water in the body.
        and functional unit of nervous system.                	(ii)	amount of dissolved wastes that need to be excreted.
 	2.	Respiratory unit of lungs — Alveoli                      	     		                                           1+1+1
 	     	Excretory unit of kidneys — Nephrons	         ½+½     	5.	(i) Many plants store waste materials in the vacuoles
                                                                     of mesophyll cells and epidermal cells. When old
 	3.	Kidney → Ureters → Urinary bladder → Urethra.                   leaves fall, the waste materials are excreted along
     Glucose, amino acids, salts and major amount of                 with the leaves.
     water.	      [CBSE Marking Scheme 2016] 1 + 2            	(ii)	Gaseous waste is removed through stomata in
                                                                     leaves.
 Detailed Answer :
 	    	The pathway of urine starting from the organ of its    	(iii)	Excess of water is also excreted from the plant
       formation is :                                                body through the stomatal pores. The process of
 	    	Kidney → Ureters → Urinary bladder → Urethra.                 elimination of water is called transpiration.	     3
Urinary bladder
                                                                                   Urethra
         	                                                                                       	3
	(b)	Vital functions of kidney :
		(i)	 To regulate right amount of water in body.
	   	(ii)	 Helps in filtering out nitrogenous waste like urea from blood.	              [CBSE Marking Scheme, 2016] 2
	WORKSHEET-74
Solutions                                                      	(ii)	Function of nephron is filtration, reabsorption and
	1.	Correct option : (c)                                               secretion.	                                     1
		Explanation : Kidneys are the paired organ where             	 (iii)	Function of artificial kidney : Helps to remove
      urine formation takes place. Small muscular tube,                harmful wastes, extra salts and water, control
      called as ureter, extend from kidneys and carry                  blood pressure. Maintain the balance of sodium
      blood to urinary bladder. The urethra is a small tube            potassium salts in a patient whose kidneys have
      that extends from the urinary bladder to an external             failed. 	                            (Any one) 1
      opening.
                                                               			                       [CBSE Marking Scheme, 2014]
	2.	The amount of urine produced depends on the
      amount of excess water and dissolved wastes
                                                               	4.	(a) Process involved in removal of nitrogenous
      present in the body. Some other factors such as
                                                                    harmful metabolic waste from the body.	    1
      habitat of an organism and hormone such as
      Antidiuretic hormone (ADH) also regulates the            	(b)	Nephron.	                                  1
      amount of urine produced.	                          1    	 (c)	Diagram of Human Excretory System.	
	3.	(i)                                                        	     	Labelling of the following parts :
           Bowman's        Capillaries                         	(i)	Kidney
            capsule Glomerulus                                 	(ii)	Ureter
                                                               	(iii)	Urinary bladder
                                                                                               Left kidney
    Renal Artery
                                                                                                 Ureter
                                       Collecting duct
             Venule
Urinary bladder
qqq
	                                                        	 3
        Uriniferous tubule with its blood vessels
P-58 S C I ENC E - X