C989C989M Hlja5316
C989C989M Hlja5316
for the
     Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.
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                                                                           C989/C989M − 18a
        TABLE 3 Alkali and Strength Limits of Reference Portland                        mortar, be the result for that batch. Otherwise, the average of
                    Cement for Slag Activity Tests                                      tests of the five most recent reference cement-mortar batches
Total Alkalies (Na2O + 0.658 K2O)                      min %           0.60             shall be used.
                                                       max %           0.90
Compressive Strength, MPa, min, 28 daysA                           35 [5000 psi]
                                                                                           10.1.6 Report—The report should include the following:
A
  The minimum strength limit is based solely on the strength of the Test Method
                                                                                           10.1.6.1 Slag activity index, %,
C109/C109M mortar cubes, as required in Specification C150/C150M, regardless               10.1.6.2 Compressive strength at 7 and 28 days, of slag
of the strength of the flow-controlled Specification C989/C989M mortar cubes.           cement-reference cement mortar,
                                                                                           10.1.6.3 Compressive strength at 7 and 28 days, of portland
                                                                                        cement mortar,
                                                                                           10.1.6.4 Total equivalent alkalies of the reference cement
used. Sufficient cement shall be reserved to avoid changing                             (Na2O + 0.658 K2O),
reference cement more often than every two months. After the                               10.1.6.5 Reference portland cement type (Type I or Type II).
initial testing to determine compliance with the compressive                               10.1.7 Precision—The single and multilaboratory state-
strength requirement of Table 3, the reference cement shall be                          ments are based on slag activity index tests using one slag
re-qualified at least every six months.                                                 cement, in duplicate, at 7 and 28 days after fabrication of
                                                                                        samples. The same slag cement and CCRL reference cement
  NOTE 8—Different reference cements may produce different Slag                         were used at each of 22 laboratories (Note 9).
Activity Index results. Reference portland cement meeting the require-
ments of 10.1.2 is available from CCRL.5                                                   NOTE 9—The precision of this test method was determined from an
                                                                                        interlaboratory study (ILS) under the jurisdiction of ASTM Subcommittee
  10.1.3 Preparation of Specimens—Prepare mortars in accor-
                                                                                        C09.27. The ILS program was conducted in 2015. Practice C670 was
dance with Test Method C109/C109M, except that sufficient                               followed for the design and analysis of the data. The details are given in
water shall be used in each batch to produce mortar at a flow                           RR:C09-1048.6
of 105 to 115 % as defined in Test Method C1437. The                                       10.1.7.1 The single-laboratory standard deviation has been
proportions of dry ingredients shall be as follows:                                     found to be 1.65 % at 7 days and 2.62 % at 28 days. Therefore,
  Reference Cement Mortar:                                                              the slag activity indices of properly conducted tests based on
     500 g portland cement                                                              single batches of mortar mixed on the same day would not be
     1375 g graded standard sand                                                        expected to differ by more than 4.6 % at 7 days and 7.3 % at
  Slag Cement-Reference Cement Mortar:                                                  28 days in more than one case in 20.
     250 g portland cement                                                                 10.1.7.2 The multilaboratory standard deviation has been
     250 g slag cement                                                                  found to be 6.88 % at 7 days and 4.78 % at 28 days Therefore,
     1375 g graded standard sand                                                        the slag activity indices of properly conducted tests of single
  10.1.3.1 Mix a reference cement batch each day that a slag                            batches by different laboratories would not be expected to
cement-reference cement batch is mixed until at least five                              differ by more than 19.3 % at 7 days and 13.4 % at 28 days in
batches have been mixed with the reference cement.                                      more than one case in 20.
Thereafter, reference cement batches need not be mixed more
often than once a week whenever slag cement is being                                       10.2 Slag Cement Density and Specific Gravity—Determine
produced or shipped.                                                                    in accordance with Test Method C188.
  10.1.4 Test Ages—Determine the compressive strength of                                  10.3 Amount of Slag Cement Retained on a 45-µm (No. 325)
mortar specimens at 7 and 28 days age in accordance with Test                           Sieve—Determine in accordance with Test Method C430.
Method C109/C109M.                                                                         10.4 Slag Cement Fineness by Air Permeability—Determine
  10.1.5 Calculation—Calculate the slag activity index to the                           in accordance with Test Methods C204.
nearest percent for both 7 days and 28 days as follows:
                                                                                           NOTE 10—In Test Methods C204, the applicable b is 0.9.
                     Slag activity index, % 5 ~ SP/P ! 3 100                   (1)
                                                                                          10.5 Sulfate Ion in Slag Cement Reported as SO3—
where:                                                                                  Determine as sulfur trioxide in accordance with Test Methods
SP = average compressive strength of slag cement-reference                              C114, except the sample need not be completely decomposed
        cement mortar cubes at designated ages, MPa [psi], and                          by acid.
P = average compressive strength of reference cement
                                                                                          10.6 Sulfide Sulfur in Slag Cement—Determine in accor-
        mortar cubes at designated age, MPa [psi].
                                                                                        dance with Test Methods C114.
   The reference cement-mortar strength used to calculate a
slag activity index shall, when a reference cement mortar is                              10.7 Calcium Sulfate Expansion of Mortar—If calcium
mixed on the same day as a slag cement-reference cement                                 sulfate is added to slag cement measure in accordance with
                                                                                        Test Method C1038/C1038M.
                                                                                          10.8 Chloride Content of Slag Cement—Determine in ac-
    5
     The sole source of commercially available reference portland cement known to       cordance with Test Methods C114.
the committee at this time is CCRL, 4441 Buckeystown Pike, Suite C; Frederick,
Maryland 21704; www.CCRL.us. If you are aware of alternative suppliers, please
                                                                                           6
provide this information to ASTM International Headquarters. Your comments will              Supporting data have been filed at ASTM International Headquarters and may
receive careful consideration at a meeting of the responsible technical committee,1     be obtained by requesting Research Report RR:C09-1048. Contact ASTM Customer
which you may attend.                                                                   Service at service@astm.org.
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                                                                      C989/C989M − 18a
  10.9 Air Content of Slag Cement Mortar—Determine in                                  NOTE 12—Guidance on preparing the manufacturer’s report is provided
accordance with Test Method C185, except use 350 g of slag                          in Appendix X4.
cement in the standard mortar batch. Calculate using the
appropriate density of the slag cement.                                             13. Manufacturer’s Statement
   10.10 Aluminum Oxide Content of Slag Cement—Determine                               13.1 At the request of the purchaser, the manufacturer shall
in accordance with Test Methods C114.                                               state in writing the nature, amount, and identity of any
                                                                                    processing or other additions made to the slag cement.
   10.11 Total Equivalent Alkalies of Slag Cement—Determine
in accordance with Test Methods C114.                                               14. Package Marking and Shipping Information
11. Rejection and Rehearing                                                            14.1 When the slag cement is delivered in packages, the
                                                                                    classification of the slag cement, the name and brand of the
   11.1 The purchaser has the right to reject material that fails
                                                                                    manufacturer, and the mass of the slag cement contained
to conform to the requirements of this specification. Rejection
                                                                                    therein shall be plainly marked on each package. Similar
shall be reported to the producer or supplier promptly and in
                                                                                    information shall be provided in the shipping invoices accom-
writing. In case of dissatisfaction with the results of the tests,
                                                                                    panying the shipment of packaged or bulk slag cement. All
the producer or supplier is not prohibited from making a claim
                                                                                    packages shall be in good condition at the time of inspection.
for retesting.
  NOTE 11—In the event of a Slag Activity Index dispute, the purchaser              15. Storage
should request a sample of the producer’s reference cement for retest.
                                                                                      15.1 The slag cement shall be stored to permit easy access
12. Certification                                                                   for proper inspection and identification of each shipment and in
   12.1 Upon request of the purchaser, a manufacturer’s report                      a suitable weather-tight building that will protect the slag
shall be furnished at the time of shipment stating the results of                   cement from dampness and minimize quality deterioration.
tests listed in Section 10 made on samples of the material taken
during production or transfer and certifying that the slag                          16. Keywords
cement conforms to applicable requirements of this specifica-                         16.1 blast-furnace slag; granulated blast furnace slag; slag
tion.                                                                               activity index; slag cement
APPENDIXES
(Nonmandatory Information)
  X1.1 When slag cement is used in concrete with portland                           the particular cement used. The results of the slag activity test
cement, the levels and rate of strength development will                            do not provide quantitative predictions of strength performance
depend importantly on the properties of the slag cement, the                        in concrete. Performance in concrete will depend on a large
properties of the portland cement, the relative and total                           number of factors including the properties and proportions of
amounts of slag cement and portland cement, and the concrete                        the slag cement, the portland cement, and other concrete
curing temperatures.                                                                ingredients, concrete temperatures, and curing conditions; and
                                                                                    other conditions.
   X1.2 The reference cement used to test slag activity in this
specification must have a minimum 28-day strength of 35 MPa                            X1.3 Concrete strengths at 1, 3, and even 7 days may tend
[5000 psi] and an alkali equivalent between 0.6 and 0.9 %.                          to be lower using slag cement-portland cement combinations,
Performance of the slag cement with other portland cements                          particularly at low temperatures or at high slag cement per-
may be significantly different. The slag-activity test also can be                  centages. Concrete proportions will need to be established
used to evaluate relative hydraulic activity of different slag                      considering the importance of early strengths, the curing
cements with a specific cement or of different shipments of the                     temperatures involved and the properties of the slag cement,
same slag cement. Such comparisons will be improved if all                          the portland cement, and other concrete materials. Generally a
tests are made with a single sample of cement. To properly                          higher numerical grade of slag cement can be used in larger
classify a slag cement, the reference portland cement must                          amounts and will provide improved early strength perfor-
conform to the limits on strength and alkali content. Even                          mance; however, tests must be made using job materials under
within these limits, performance will depend to some extent on                      job conditions.
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                                                                            C989/C989M − 18a
   X2.1 General—Concrete manufactured with high percent-                                ages. Data from studies of laboratory exposure of mortars to
ages of slag cement is generally considered to have greater                             sodium and magnesium sulfate solutions provide the following
resistance to attack by sulfates than do portland cements, based                        general conclusions.
largely upon comparisons of these mixtures with similar                                    X2.3.1 The combinations of slag cement and portland
mixtures containing ordinary (Type I) portlands. These high                             cement, in which the slag cement content was greater than 60
volume slag cement mixtures (containing 60 % or more slag)                              to 65 %, had high sulfate resistance, always better than the
are widely used for sulfate and sea-water resistant concretes                           portland cement alone, irrespective of the Al2O3 content of the
throughout the world.                                                                   slag cement. The improvement in sulfate resistance was
   X2.2 Sulfate Resistance of Portland Cements—The sulfate                              greatest for the portland cements with the higher C3A contents.
resistance of concrete is dependent upon a number of factors,                             X2.3.2 The low alumina (11 %) slag cement tested in-
including mortar permeability and the type and concentration                            creased the sulfate resistance independently of the C3A content
of the sulfate solutions involved. Others, directly related to the                      of the portland cement. To obtain adequate sulfate resistance,
cement characteristics, include calcium hydroxide concentra-                            higher slag cement percentages were necessary with the higher
tion and the tricalcium aluminate (C3A) content. Specification                          C3A portland cements.
C150/C150M provides limits on the C3A for sulfate-resistant                               X2.3.3 The high alumina (18 %) slag cement tested, ad-
cements. Specification C150/C150M Type V requirements                                   versely affected the sulfate resistance of portland cements
provide for a limit on the tetracalcium aluminoferrite (C4AF)                           when blended in low percentages (50 % or less). Some tests
plus twice the C3A. The Specification C150/C150M table of                               indicated rapid decreases in resistance for cements in the 8 and
Optional Physical Requirements includes a maximum limit on                              11 % C3A ranges with slag cement percentages as low as 20 %
expansion of Type V cement in mortar bars when tested by Test                           or less in the blends.
Method C452. When this option is selected, the standard limits
on tricalcium aluminate and on tetracalcium aluminoferrite                                 X2.3.4 Tests on slag cement (7 to 8 % alumina) in Ontario
plus twice the tricalcium aluminate do not apply. Test Method                           (3) have shown that a 50:50 combination by mass with Type I
C1012/C1012M can be used to measure the effects of exposure                             portland cement (having up to about 12 % C3A) is equivalent
to external sulfate environments on mortar or concrete.                                 in sulfate resistance to the Type V cement used in that study.
  X2.3 Effect of Slag Cement on Sulfate Resistance—The use                                 X2.4 Tests for Sulfate Resistance—When the relative sulfate
of slag cement will decrease the C3A content of the cementing                           resistance of a specific portland cement-slag cement combina-
materials and decrease the permeability and calcium hydroxide                           tion is desired, tests should be conducted in accordance with
content of the mortar or concrete. Tests have shown that the                            Test Method C1012/C1012M (4). Studies by Subcommittee
alumina content of the slag cement also influences sulfate                              C01.29 on sulfate resistance using Test Method C1012/
resistance (1, 2),7 and that high alumina content can have a                            C1012M, as reported by Patzias (5), recommended the follow-
detrimental influence at low slag cement-replacement percent-                           ing limits for expansion of portland cement and slag cement
                                                                                        combinations at six months of exposure:
    7
      The boldface numbers in parentheses refer to a list of references at the end of     Moderate sulfate resistance — 0.10 % max
this standard                                                                             High sulfate resistance — 0.05 % max
  X3. EFFECTIVENESS OF SLAG CEMENT IN PREVENTING EXCESSIVE EXPANSION OF CONCRETE DUE TO ALKALI
                                         SILICA REACTION
  X3.1 General—If properly proportioned in concrete                                        X3.3 Mitigating ASR with Slag Cement—Slag cement miti-
mixtures, slag cement has been shown to prevent excessive                               gates ASR by reducing the total alkalies in the system and by
expansion due to alkali-silica reaction.                                                consuming alkalies in the hydration reaction, making them
                                                                                        unavailable for the alkali silica reaction. The percentage of slag
   X3.2 ASR in Concrete—Alkali silica reaction occurs in
                                                                                        cement required to mitigate alkali silica reaction is dependent
concrete if certain siliceous aggregates are placed in a highly
                                                                                        on the reactivity of the aggregate and the alkali loading of the
alkaline environment and, in the presence of water, form an
                                                                                        concrete. For concretes containing very reactive aggregates or
expansive gel. When this gel forms, tensile stresses develop in
the concrete around the expanding gel which can cause the                               for concretes with a high alkali loading, higher percentages of
concrete to crack. The extent of the reaction is directly related                       slag cement may be required to insure mitigation. For more
to the alkalinity of the solution, the reactivity of the aggregate,                     information on ASR mitigation, including test methods, see
and the availability of water, which fuels the reaction.                                Guide C1778.
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                                                                          C989/C989M − 18a
  X4.1 To provide uniformity for reporting the results of tests                          X4.2 The identity information given should unambiguously
performed on slag cements under this specification, as required                        identify the cement production represented by the Mill Test
by Section 12 of Specification C989/C989M entitled                                     Report and may vary depending upon the manufacturer’s
“Certification,” an example Mill Test Report is shown in Fig.                          designation and purchaser’s requirements.
X4.1.
Plant: Example Slag Cement ASTM C989 Grade 100 December 7, 20xx
CHEMICAL
                                                                                                                         A
Sulfate Sulfur (as SO3), %                         2.7
                                                                                                                         A
Aluminum Oxide (as Al2O3)                          10.5
                                                                                                                         A
Chloride (Cl), %                                   0.011
                                                                                                                         A
Total equivalent alkalies (Na2O + 0.658 K2O), % 0.52
PHYSICAL
Compressive StrengthB
                                                                                                                         A
   7 Day (psi)                                     3669
                                                                                                                         A
   28 Day (psi)                                    5695
Fineness
    Blaine (m2/kg)                                 495                                                                   A
We certify that the above described slag cement, at the time of shipment, meets the chemical and physical requirements
of ASTM C989 – xx or (other) _______ specification.
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                                                                         C989/C989M − 18a
   X4.3 The Manufacturer’s Certification statement may vary                            mally performed on slag cements meeting Specification C989/
depending upon the manufacturer’s procurement order, or legal                          C989M. Purchaser reporting requirements should govern if
requirements, but should certify that the slag cement shipped is                       different from normal reporting by the manufacturer or from
represented by the certificate and that the cement conforms to                         those recommended here.
applicable requirements of the specification at the time it was
tested (or retested) or shipped.                                                         X4.5 Slag cements may be shipped prior to later-age test
                                                                                       data being available. In such cases, the test value may be left
   X4.4 The sample Mill Test Report has been developed to                              blank. Alternatively, the manufacturer can generally provide
reflect the chemical and physical requirements of this specifi-                        estimates based on historical production data. The report
cation and recommends reporting all analyses and tests nor-                            should indicate if such estimates are provided.
REFERENCES
(1) Locher, F. W., “The Problems of the Sulfate Resistance of Slag                     (4) Hooton, R. D., and Emery, J. J., “Sulfate Resistance of a Canadian
    Cements,” Zement-Kalk-Gips, No. 9, September, 1966.                                    Slag Cement,” ACI Materials Journal, Vol 87, No. 6, November–De-
(2) Van Aardt, J. H. P., and Visser, S., “The Behavior of Mixtures of                      cember 1990.
    Milled Granulated Blast-Furnace Slag and Portland Cement in Sulfate                (5) Patzias, T., “The Development of ASTM Method C1012/C1012M
    Solutions,” Bulletin 47, National Building Research Institute, South                   with Recommended Acceptance Limits for Sulfate Resistance of
    Africa, 1967.                                                                          Hydraulic Cements,” Cement, Concrete, and Aggregates, Vol 13, No.
(3) Chojnacki, B., “Sulfate Resistance of Blended (Slag) Cement,” Report                   1, ASTM, 1991.
    EM-52, Ministry of Transport and Communications, Ontario, Canada
    1981.
SUMMARY OF CHANGES
            Committee C09 has identified the location of selected changes to this standard since the last issue
          (C989/C989M – 18) that may impact the use of this standard. (Approved Dec. 15, 2018.)
            Committee C09 has identified the location of selected changes to this standard since the last issue
          (C989/C989M – 17) that may impact the use of this standard. (Approved March 15, 2018.)
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