LAMISTAR R 92 BLACK TW , TWNGENC0117442 - 1

Safety Data Sheet

Issue Date 2020/02/14
Version 1

SECTION 1. IDENTIFICATION
Identification of the product LAMISTAR R 92 BLACK TW

Reference number TWNGENC0117442 - 1

Recommended uses and No information available

restrictions on use

Emergency Telephone Number Indonesia: (+62) 21 2956 8040(PT.TOYO INK INDONESIA)

Indonesia: 021 2956 8040(PT.TOYO INK INDONESIA)

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Physical and chemical hazards

Flammable liquids Category 2

Health hazards
Acute toxicity - Oral Category 5
Acute toxicity - Inhalation (Vapors) Category 4
Acute toxicity - Inhalation (Dusts/Mists) Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 1
Germ cell mutagenicity Category 1B
Carcinogenicity Category 1B
Reproductive toxicity Category 2
Specific target organ toxicity (single exposure) Category 3
Specific Target Organ Toxicity (Repeated Exposure) Category 2

Environmental hazards
Acute aquatic toxicity Category 3

GHS Label elements

Signal Word DANGER

Hazard Statements
H225 - Highly flammable liquid and vapor
H303 - May be harmful if swallowed
H315 - Causes skin irritation
H318 - Causes serious eye damage
H332 - Harmful if inhaled
H336 - May cause drowsiness or dizziness

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H340 - May cause genetic defects

H350 - May cause cancer
H361 - Suspected of damaging fertility or the unborn child
H373 - May cause damage to organs through prolonged or repeated exposure.
H402 - Harmful to aquatic life

Precautionary Statements
Precautionary Statements
P201 - Obtain special instructions before use
P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking
P233 - Keep container tightly closed
P240 - Ground/bond container and receiving equipment
P241 - Use explosion-proof electrical/ ventilating/ lighting/ equipment
P242 - Use only non-sparking tools
P243 - Take precautionary measures against static discharge
P260 - Do not breathe dust/fume/gas/mist/vapors/spray
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P264 - Wash hands thoroughly after handling
P271 - Use only outdoors or in a well-ventilated area
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection

Precautionary Statement - Response

P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
P308 + P313 - IF exposed or concerned: Get medical advice/attention
P314 - Get medical advice/attention if you feel unwell
P321 - Specific treatment
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P302 + P352 - IF ON SKIN: Wash with plenty of water and soap
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing
P310 - Immediately call a POISON CENTER or doctor
P312 - Call a POISON CENTER or doctor if you feel unwell
P362 + P364 - Take off contaminated clothing and wash it before reuse
P370 + P378 - In case of fire: Use suitable extinguishing media to extinguish

Precautionary Statement - Storage

P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P403 + P235 - Store in a well-ventilated place. Keep cool
P405 - Store locked up

Precautionary Statement - Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

No information available

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance/mixture Mixture

Chemical Name Chemical Name CAS No. Weight Approval number Note
Toluene Toluene 108-88-3 20 - 30% - -
Methyl ethyl Methyl ethyl 78-93-3 20 - 30% - -

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ketone(MEK) ketone(MEK)
Resin Resin Trade Secret 10 - 20% - -
Pigment Pigment Trade Secret 10 - 20% - -
Isopropyl alcohol Isopropyl alcohol 67-63-0 5 - 10% - -
1-Propanol 1-Propanol 71-23-8 5 - 10% - -
Propylene glycol Propylene glycol 108-65-6 3 - 5% - -
methyl ether acetate methyl ether acetate
Propylene glycol Propylene glycol 107-98-2 1 - 3% - -
monomethyl ether monomethyl ether
Stoddard solvent Stoddard solvent 8052-41-3 0.1 - <1% - -

SECTION 4. FIRST-AID MEASURES

Description of necessary first-aid measures
Inhalation Move victim to fresh air
Keep at rest
If breathing is irregular or stopped, administer artificial respiration
If symptoms persist, call a physician

Skin contact Remove contaminated clothing and shoes

Remove as much as possible by wiping
Wash off immediately with soap and plenty of water
Get medical attention immediately if symptoms occur

Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes
Get medical attention immediately

Ingestion Get medical attention immediately

Most Important No information available

Symptoms/Effects

Protection of first-aiders No information available

Notes to physician Treat symptomatically

SECTION 5. FIRE-FIGHTING MEASURES

Extinguishing media Carbon dioxide (CO2), Foam, Dry powder

Extinguishing Media Which Water jet

Must Not Be Used For Safety
Reasons

Specific hazards arising from See section 10 (Hazardous decomposition products)

the chemical

Specific methods Promptly remove flammables (wood, paper, oil, clothes, etc.) that may be ignited
from around the fire site.
Cool the closed container exposed to high temperature with water spray.

Special protective equipment for Wear personal protective equipment

fire-fighters Evacuate area and fight fire from a safe distance

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment, and emergency procedures

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For non-emergency Wear suitable protective clothing

personnel

For emergency responders Evacuate personnel to safe areas

Environmental precautions Avoid release to the environment.

Dispose of contents/ container to an approved waste disposal plant

Recovery and neutralization Take up with sand, earth or other non-combustible absorbent material
A lot of leakage things have the flow first stopped by earth and sand etc., and
need to be led to a safe place.
Keep in suitable, closed containers for disposal
Use only non-sparking tools

SECTION 7. HANDLING AND STORAGE

Handling
Technical measures Ensure adequate ventilation
Use only non-sparking tools
Avoid static electricity build up with connection to earth.
Take precautionary measures against static discharges
Flame retardant antistatic protective clothing
Antistatic boots
Keep away from open flames, hot surfaces and sources of ignition
Keep the residual product and waste-cloths that wiped this product, in a sealed
metal container until disposition.
Avoid contact with skin, eyes or clothing
Wear personal protective equipment

Advice on safe handling Wash hands before breaks and immediately after handling the product
Do not eat, drink or smoke when using this product

Storage
Technical measures/Storage Keep away from heat and sources of ignition
conditions

SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Engineering measures Ensure adequate ventilation

Exposure Guidelines
Chemical Name Taiwan - Taiwan - Taiwan - ACGIH - BEI
Occupational Occupational Occupational
Exposure Limits - Exposure Limits - Exposure Limits -
TWA STELs Ceilings
Toluene 100 ppm 125 ppm - 0.02 mg/L blood prior
376 mg/m3 470 mg/m3 to last shift of
workweek Toluene
0.03 mg/L urine end
of shift Toluene
0.3 mg/g creatinine
urine end of shift
o-Cresol with
hydrolysis
background
Methyl ethyl ketone(MEK) 200 ppm 250 ppm - 2 mg/L urine end of
590 mg/m3 737.5 mg/m3 shift MEK nonspecific
Isopropyl alcohol 400 ppm 500 ppm - 40 mg/L urine end of
983 mg/m3 1228.75 mg/m3 shift at end of

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workweek Acetone
background,
nonspecific
1-Propanol 200 ppm 250 ppm - -
491 mg/m3 613.75 mg/m3
Propylene glycol 100 ppm 125 ppm - -
monomethyl ether 369 mg/m3 461.25 mg/m3
Stoddard solvent 100 ppm 125 ppm - -
525 mg/m3 656.25 mg/m3

Personal protective equipment

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment

Hand protection Rubber/latex/neoprene or other suitable chemical resistant gloves

Eye protection Goggles

Skin and body protection Long sleeved clothing Chemical resistant apron Antistatic boots

Hygiene measures Handle in accordance with good industrial hygiene and safety practice

Other information Potential cancer hazard

Handle and open container with care
Keep locked up

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Physical State Liquid Color black
Odor solvent Odor Threshold No information available

Property
pH VALUE No information available
Melting point/range No information available
Boiling Point/Range No information available
Flash point -7 °C (the lowest flash point)
Evaporation rate No information available
Flammability (solid, gas) No information available
Upper/lower flammability or No information available
explosive limits
Vapor pressure No information available
Vapor density No information available
Specific Gravity No information available
Water solubility No information available
Solubility in other solvents No information available
Partition Coefficient No information available
(n-octanol/water)
Autoignition temperature No information available
Decomposition temperature No information available
Density No information available

SECTION 10. STABILITY AND REACTIVITY

Stability No information available

Possibility of hazardous No information available

reactions

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Conditions to avoid No information available

Materials to avoid No information available

Hazardous decomposition No information available

products

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure See Section 4

Acute toxicity Classification based on data available for ingredients

Chemical Name Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity
(inhalative)
Toluene LD50 = 2600 mg/kg (Rat) LD50 = 12000 mg/kg LC50 = 12.5 mg/L (Rat) 4
JAPAN_GHS (Rabbit) JAPAN_GHS h JAPAN_GHS

Methyl ethyl ketone(MEK) LD50 = 2737 mg/kg (Rat) LD50 = 5000 mg/kg LC50 = 11700 ppm (Rat) 4
RTECS (Rabbit) JAPAN_GHS h JAPAN_GHS
LD50 = 2483 mg/kg (Rat) LD50 = 6480 mg/kg
JAPAN_GHS (Rabbit) RTECS

Isopropyl alcohol LD50 = 1870 mg/kg (Rat) LD50 = 4059 mg/kg LC50 = 72600 mg/m3 (Rat)
JAPAN_GHS (Rabbit) JAPAN_GHS 4 h JAPAN_GHS

1-Propanol LD50 = 1870 mg/kg (Rat) LD50 = 4049 mg/kg LC50 > 13548 ppm (Rat) 4
NLM_CIP (Rabbit) NZ_CCID h NLM_CIP

Propylene glycol methyl ether LD50 = 8532 mg/kg (Rat) LD50 > 5 g/kg (Rabbit) -
acetate NLM_CIP NLM_CIP

Propylene glycol monomethyl LD50 = 5000 mg/kg (Rat) LD50 = 13 g/kg (Rabbit) LC50 > 7559 ppm (Rat) 6
ether JAPAN_GHS NLM_CIP h OECD_SIDS

Japan_GHS: Japan GHS Basis for Classification Data (NITE-CHRIP)

NLM_CIP: National Library of Medicine - ChemID plus database
NZ_CCID: New Zealand Chemical Classification and Information Database
OECD_SIDS: Organisation for Economic Co-operation and Development - Screening Information Data Sets
RTECS: Registry of Toxic Effects of Chemical Substances

Skin corrosion/irritation Classification based on data available for ingredients

Serious eye damage/eye Classification based on data available for ingredients

irritation

Respiratory sensitization Classification based on data available for ingredients

Skin sensitization Classification based on data available for ingredients

Germ cell mutagenicity Classification based on data available for ingredients

Carcinogenicity Classification based on data available for ingredients

Reproductive toxicity Classification based on data available for ingredients

Specific target organ toxicity Classification based on data available for ingredients
(single exposure)

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Specific Target Organ Toxicity Classification based on data available for ingredients
(Repeated Exposure)

Aspiration hazard Classification based on data available for ingredients

SECTION 12. ECOLOGICAL INFORMATION

Environmental hazards Classification based on data available for ingredients
Chemical Name Fish(96h) Crustacea(48h) Algae(72h)
Toluene LC50 50.87 - 70.34 mg/L EC50 5.46 - 9.83 mg/L EC50 = 12.5 mg/L
(Poecilia reticulata) EPA (Daphnia magna) EPA (Pseudokirchneriella
LC50 = 28.2 mg/L (Poecilia subcapitata) EPA
reticulata) EPA EC50 = 11.5 mg/L (Daphnia
LC50 = 54 mg/L (Oryzias magna) IUCLID
latipes) EPA
LC50 11.0 - 15.0 mg/L
(Lepomis macrochirus) EPA
LC50 = 5.8 mg/L
(Oncorhynchus mykiss) EPA
LC50 14.1 - 17.16 mg/L
(Oncorhynchus mykiss) EPA
LC50 5.89 - 7.81 mg/L
(Oncorhynchus mykiss) EPA
LC50 = 12.6 mg/L
(Pimephales promelas) EPA
LC50 15.22 - 19.05 mg/L
(Pimephales promelas) EPA

Methyl ethyl ketone(MEK) LC50 3130 - 3320 mg/L EC50 4025 - 6440 mg/L -
(Pimephales promelas) EPA (Daphnia magna) EPA

EC50 = 5091 mg/L (Daphnia

magna) IUCLID
EC50 > 520 mg/L (Daphnia
magna) IUCLID

Isopropyl alcohol LC50 > 1400000 ug/L EC50 = 13299 mg/L (Daphnia EC50 > 1000 mg/L
(Lepomis macrochirus) EPA magna) IUCLID (Desmodesmus subspicatus)
IUCLID
LC50 = 9640 mg/L
(Pimephales promelas)
IUCLID
LC50 = 11130 mg/L
(Pimephales promelas)
IUCLID

1-Propanol LC50 = 4480 mg/L EC50 3339 - 3977 mg/L -

(Pimephales promelas) (Daphnia magna) EPA
IUCLID
EC50 = 3642 mg/L (Daphnia
magna) IUCLID

Propylene glycol methyl ether LC50 = 161 mg/L EC50 > 500 mg/L (Daphnia -
acetate (Pimephales promelas) magna) IUCLID
IUCLID

Propylene glycol monomethyl LC50 = 20.8 g/L (Pimephales EC50 = 23300 mg/L (Daphnia -
ether promelas) IUCLID magna) IUCLID
LC50 4600 - 10000 mg/L
(Leuciscus idus) IUCLID

EPA: United States Environmental Protection Agency

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IUCLID: International Uniform Chemical Information Database

Persistence and degradability No information available

Bioaccumulative potential No information available

Mobility in soil No information available

Hazardous to the ozone layer Classification based on data available for ingredients

Other information No information available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Method
Waste from residues/unused To discard the container after using up the contents
products Dispose of in accordance with federal, state and local regulations

Contaminated packaging Empty containers should be recycling or disposal in accordance with the law

SECTION 14. TRANSPORT INFORMATION

ADR/RID ICAO/IATA IMDG/IMO

UN number 1210

UN Proper shipping name PRINTING INK

UN Classification Class 3: Flammable liquids

Packaging group II

Marine pollutant No

Special safety measures Ground and bond containers when transferring material

SECTION 15. REGULATORY INFORMATION

Domestic Regulations

Toxic Chemical Substances Control Act Not Applicable (Class1, Class2, Class3, Class4)

Taiwan Occupational Safety and Health Act

Chemical Name Hazradous and Harmful Substances
Propylene glycol monomethyl ether Listed
Toluene Listed
Carbon black Listed
Isopropyl alcohol Listed
1-Propanol Listed
Methyl ethyl ketone(MEK) Listed
Stoddard solvent Listed
Propylene glycol methyl ether acetate Listed

OTHER INFORMATION
No information available

International Regulations

Basel Convention - Hazardous Wastes

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Not Listed

Montreal Protocol - Ozone Depleting Substances

Not Listed

Stockholm Convention - Persistent Organic Pollutants (POPs)

Not Listed

Rotterdam Convention - Chemicals Subject to Prior Informed Consent (PIC)

Not Listed

SECTION 16. OTHER INFORMATION

Legend
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
TWA: Time weighted average STEL: Short term exposure limit
Ceiling: Maximum limit value

Literary reference Classification according to Regulation (EC) No. 1272/2008 [CLP]

ACGIH (American Conference of Governmental Industrial Hygienists)
IARC (International Agency for Research on Cancer)

Manufacturer Same as Supplier

Prepared By

Issue Date 2020/02/14

Revision Date -

- The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its
publication.
- The information given is designed only as a guide for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered as a warranty or quality specification. The information relates only to
the specific material designated and may not be valid for such material used in combination with any other material or
in any process, unless specified in the text.
- When you export this product or the chemical substances including this product, please certainly obey the law of the
export destination countries. If you have any questions, please contact our sales division.

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