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TERP
VIPULORGANICS
SunACTIVE
Reactive Dyes For Textile
Colours.
that breathe life intoSurACTIVE
Reactive Dyes For Textile
SUNACTIVE COLD ‘M’ / HOT ‘H’ Dyes
Dyeing with Cold ‘M’ type & Hot ‘H’ Dyes:
Cold Brands: Are highly reactive and are employedin dyeing under mild alkaline conditions (30-40°C)
Hot Brands: Are less reactive and are employed both in dyeing and printing under stronger alkaline conditions and
high temperature (60-80°C).
Exhaustion (open beck, winch, jigger or package), pad-Jig fixation, pad-dry bake, pad batch and pad-dry steam are
common methods of application.
Dissolving of Dyestutt: The dyeis pasted with equal weight of cold water and dissolvedby using warm water at 50°C.
Dyeing Methods:
Exhaust Dyeing: Set the dye-bath at 30-35" C with common salt or glauber’s salt, enter the goods run for 10 mins.
Add the dissolved dye and run for 30 mins. Finally add the dissolved alkali and raise temp. (30-40°C) for cold brands
and (80-90°C) forhot brands. Finally goods are washed off,
Salt and Alkali Requirement for Hot Brand
Depth of Shade Sattg/ Soda Ashg/
((%on weight of goods)
upto 0.5 30 10
051-10 45 15
1.01-2 60 15
201-4 70 20
Above 4 90 20
Salt and Alkali Requirement for Cold Brand
Depth of Shade Soda Ash
((%on weight of goods) a
LR LR LR
151 20: 30:1
upto 0.5 25 5 3 2
051-20 35 5 4 2
2.01-4.0 45 40 8 4
Above 4 55 15 to 5
=== GaPRINTING COLD AND HOT BRAND:
Only hot brands are preferred for printing as stated below; however cold brand can also be printed
Cold Brand Hot Brand
Dye 40 Parts 40 Parts
Urea 50" 100“
Hot Water 300 * 300 *
Sodium Alginate (4% Paste) 585 * 520 *
Resist Salt 10 * 10 *
Soda-bi-car 15 30.
1000 Parts 1000 Parts
Print (With Soda-bi-carb), dry and steam for 10 mins. at 102°C, Washin cold and hot water & soap at boil with neutral
‘soap for better results,
SUNACTIVE DYES (VINYL SULPHONE BASED)
INTRODUCTION:-
These dyes possess very good light and wash fastness, easy to apply on cellulosic fibre by normal exhaust, batch-
wise, continuous and thermo-fixation process, suitable for printing and give briliant and attractive shades. They have
excellent white effect on dyed grounds by discharge and resist printing method, unfixed dyes are easily washed off
and have high stability in dry state andin neutral solution
The entire dyeing or printing process consists of mainly the following 3 stages:-
1. Application ofthe dyestuffto the fiber.
2, Fixation ofthe dyestuff on the fiber.
3. Removal of any unfixed dyestuff from the fiber,
PREPARATION OF THE GOODS:-
The goods to be dyed or printed should be thoroughly desized, scoured and preferably mercerized or causticized to
retain deep and bright shades. Traces of residual chlorine, peroxide and alkali should be removed by treating the
goods with very dilute acetic acid
DYEING METHOD:-
1.Jigger Dyeing
Procedure:
Set the dye-bath at the required temperature and add well dissolved dye solution over two passages, followed by
Glauber salto common salt overtwo passages. Aftertwo more passages add required amount of alkali solution over
two passages and continue dyeing at prescribed temperature for further period of 60-90 mins. depending on the
depth ofthe shade
== HulaFollowing table gives the quantities of chemicals recommended:-
Dyeing temperature 40°C 60°C soc
Liquor ratio 12t0 | tte | 1:2t0 | t4to 12t0 | t4to
13 16 13 16 13 16
Glauber salt (Cal.) | g/l 50 50 50 50 50 50
or common salt
Caustic soda solution] coil | 4-6 34 35 23
(38° B'e/72"
Tw /32.5%)
+
Soda ash
or gl 5 5 5 5 25 15-20
Trisodium phosphate | g/l - 30 30 20-25 - -
Dyeing period (After
minutes final alkali addition) 90 60 60
PADDING PROCESS:-
1. One bath pad batch process:~
‘Awell scoured, cold fabric is padded at room temperature (25° C-30" C). Asitis desirable to replace the liquor at
faster rate, higher speed of fabric padding and smaller capacity trough is recommended. The liquor pick-up
should be 60-70% for cotton and 90-100% for viscose fabric. Speed ofthe padding should be adjusted in such a
way that whole lot of dye solution should be used up within 20-30 mins. Alkali should be added to the dye
solution ust before commencement ofthe padding,
1 (a)Long time pad batch process :-
Sodium silicate Sodium silicate Caustic soda solution
g/l (38°B'e/72" Tw/32.5% w/w) (cc)
"Bes Weight ratio Upto 30 g/ Above 30 g/1
Na,0: Sid, dyestutt dyestutt
37-40/69-77 1:33 135 13 18
40-47/77-82 1:33 120 1" 16
48-50/100-106 1:26 100 5 40
58-60/134-142 1:24 85 : 4
== Ge2. OneBath- > Pad- > Dry- > Steam Method:-
This process is carried out on a padding mangle attached with either hot fue or float dryer. To fixthe dyestutt, the.
dyed, dry materials steamed in the normal continuous steamer for 4-7 mins. at 100° -103° C. The steam should
be free from acia,
Following table will help to prepare padding liquor:~
‘SunActive dyes g/l 10 20 30 40 50 50-70
Urea’ gil 0-50 0-50 0-50 50-75 | 50-75 | 50-70
Sodium bi-carbonate gil 5 10 15 15-18 20 20-25
Resist salt gl 10 10 10 10 10 10
DIRECT PRINTING WITH SUNACTIVE DYESTUFFS
1. Steaming Method:-
Printing paste recipe:-
Xx Parts SunActive dyestuffis mixed with | 20 Parts Sodium bi-carbonate
50-100 Parts Urea 10 Parts Resist salt
200 Parts Water Y Parts Water or thickening and bulk to
500 Parts Thickening (Sodium Alginate) 1000 Parts
The above thickening could be replaced by half emulsioin thickening as follows:
Emulsion thickening:-
500 Parts Thickening (Sodium Alginate)
100 Parts Water
40 Parts Emulsifier
390 Parts Kerosene
1000 Parts
Print dry - steam at 103°C for 10-15 mins. in star ager or 5-7 mins. in a continuous steamer. Hot and cold washing -
soap atboil for 15-20 minutes with neutral detergent. Finally rinse hot and cold.
2. Cold silicate pad batch method:-
Print paste recipe is same as per steaming method, but the use of alkalis avoided. After printing and drying the fabric
is nip padded with 102-104" Tw sodium silicate solution (Na,0: SiO, 1:2.1)and4 -6 ccfltre Caustic soda - 72° Tw.
‘The batch is covered with Polythene sheet and kept for 20 hours.
AFTER TREATMENTS
1. Cold rinse with overflow.
2, Neutralising at about 40°C with 2-3 ccyltre of acetic acid (60%). (Not for silicate pad method)
3. Hot rinsing wih sodium hexametaphosphate 2-3 g/l at 60°C-70°C.
4, Soaping at boi with neutral detergent
5. Hot rinsing/Cold rinsing
== Guu enWHITE DISCHARGE PRINTING WITH SUNACTIVE DYESTUFF.
SunActive dyestuff are suitable for preparing wash and light fast discharge grounds. The fabric should be treated with
a mild oxidising agent before discharge printing. This will protect the ground from the reductive effect ofthe printing
paste.
Preparation of the white discharge printing paste.
20 Parts Rongolite C
10 Parts Titanium dioxide (1:1)
8 Parts Discharge Salt W/Leucotrop W (BASF)
40 Parts Thickening
20 Parts Caustic soda-38°B'e/72°Tw
2 Parts Water
100 Parts
Print- > dry at 90° C -> steam 15-20 minutes in a star ager at 100° -103°C. Then the materials rinsed twice in cold
water-hotrinse at 40°C -> soap at 90°C with a neutral detergent. Finally hot and cold rinse,
RESIST PRINTING UNDER SUPRA DYESTUFF
The printing paste used for resist printing is highly acidic, the suitable acid resistant thickener should be used. British
Gunv/Indalca AGBV are acid resistant hence are suitable choice for resist printing,
Printing recipe
100 Parts Uncooked starch (1:1)
100 Parts Citric acid
10 Parts Optical Brightner (Resistant to acid)
500 Parts Thickening
290 Parts Water/Thickening
1000 Parts
Print -> dry - > nip pad through following dye solution at room temperature (25-30°C)
x Parts SunActive dyestutt
200 Parts Boiling water
100 Parts Urea
10 Parts Resistsalt
60 Parts Sodium bi-carbonate (just before padding)
y Parts Water
1000 Parts
== GeSUNACTIVE ‘HE’ DYES
They have high substantvity and superior exhaustion properties and are mainly used for dyeing of cottons by batch-
wise method on conventional machines HE dyes are mainly suited for dyeing of mixed shade as they are less
sensitive to variation in Liquor to goods ratio and concentration of electrolytes in the dye bath as compared to cold or
hot brands.
The main advantage of HE dyes are excellent build-up, high fixation, good compatibility, consistency of colour yield
and excellent wetfastness properties.
HE dyes are applied by same method using same recipe as used for dyeing of Hot brand mainly by exhaust on winch
or Jigger. Dyeing results are even and fastness properties are better. These are suitable for dyeing hosiery, knitwear
and blends where cellulose part of polyester/cellulose isto be dyed. "HE" dyes are suited for dyeing mixed shades as
they are less sensitive to variation in liquor ratio and concentration of sat.
Method of Application
1. Piece Goods Dyeing
oye 10% 20% GO FIXING 50% 50% xINe
tg SNTSAITSALT ALKALI ‘Addtion 4g SALT OYE DYE AL Aestion
eal f x
ral |
sal «|
sal oly ¥ v
910 2 a aos 070 Towns, «8402304 BDTG COs
‘Standard method for application to all types of
pilece goods on jiggers.
for dyeing unmorcerised and mercerised
on circulating machines or winches.
som sam CAUSTIC ove 20% 53% 39% FANG
1c S00A OYE OVE SODA Ration = SATSAT SAT AKA
sal |
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sly ¥ ¥ sold.
‘Suitable for dyeing unmercerised material on Suitable for mercerised piece goods on winches.‘SUNACTIVE BIFUNCTIONAL DYESTUFF
The SunActive Bifunctional Dyestuffs are used for Exhaust dyeing at a low temperature. These dyestufts have very
high exhaustion properties, better levelling properties and a very good alkaline stability. These dyes can also be
applied by cold pad batch method, hence these dyes arereal energy saving dyes.
DYEING METHODS:-
(i) EXHAUST DYEING: Dyestuffs dissolved in water and run for 20 mts. Salts introduced and temperature raised
t0 60°C in about 20 mts. Alkali is introduced at 60° C and temperature is maintained for 60 mts.
The following parameteris applied
Glauber's Sait-50 grv/l
Soda Ash-20 grvl
(ii) PADDING METHOD:
(1) Pad [SunActive Bifunctional Dyes + Urea + Sodium Silicate 85 grv/
(134 - 142" Tw Na, 0: SiO,’ 1 :2.1) + Caustic Soda 33% 4 gr]
= Batch (20 hours) - Wash.
(2) Pad [SunActive Bifunctional Dyes + Urea + NaHCO, (10 - 20 grit]
= dry-normal steam for 5 mts, or Thermofix at 140°C for 4 mts.
-Wash
These dye stuff can also be used for printing by steaming and/or by Silicate method.
(i) Print (dyestuff + alkali) - dry -steam,
(i) Print (dyestuff + alkali) - dry - Thermofix at 150°C for 3 to 5 min,
(i) Print (dyestuf)- dry - Nip pad through Sodium Silicate - Batch (20 hours)
The print is washed by cold water to remove unfixed dyes and then washed with suitable detergent then
‘washed with cold water tll itis colourless.
1, Normal method 2. Constant temperature mettod 3, Al-in° method
ope eet ead
if TT AyAFTER TREATMENT:-
‘A thorough soaping and washing is required to clear off the unfixed dye and to obtain maximum fastness
properties and brightness of shade.
Washing off is done by thoroughly rinsing in cold water followed by hot water.
Then itis soaped at boil for 15 mins. using 2 gpl detergent. Finally again its rinsed in hot water and cold water
subsequently.
ABBREVIATIONS:-
Light 1 to 7 in increasing order where 7 represents highest fastness.
Washing & 1 to 5 in increasing order where 5 represents highest fastness.
others
Dischargeability : G- Good
M - Moderate
P - Poor
Substantivity © Suitable
A Not suitable
L- Low
M - Medium
H- High
This information mentioned herein is provided in good faith but without warranty. Itis the responsibility of the user to
test our products to their suitability for any application,
‘No statement is intended or should be construed as a recommendation to infringe any patent and the responsibility to
observe any such patent right rest with the user.
(without Guarantee)
== GuanSunACTIVE’
Reactive Dyes For Textile
“M" DYES (Dichloro Triazine) Nea
een — is
= “] [+] +] «
‘Yellow MBG.
Golden Yellow.
Red M8B 45 45 2 3 H P 80
ee = - :
Blue MR 5 45 4 1 H P 100SunACTIVE’
Reactive Dyes For Textil
“H” DYES (Monochloro Triazine) (2)
HR 6 45 5 3 M G 120
Orange 12
RedBrownHaR | 5 5 45 | 45 L P 90
Black HN 6 | 45) 3 4 L Pp 80
a =:
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56 | 5 4 4 H P 100
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40SunACTIVE’
Reactive Dyes For Textle
PEG enn
Eee eis
‘Yellow P8G.
‘Yellow P6G
Orange
Red PX4B 5 45 34 3 M M 100
Browlgsh 56 4 45 2 M M 100
Brown 11
1SunACTIVE
Reactive Dyes For Textile
BUNS tess e
aca A KCAL
Yellow GR 6 5 5 1 H G 120
Yellow GL 6 45 | 45 1 M M 100
Orange 107
Orange 3R. 56 5 5 1 H G 120
Red C2G 4 5 5 1 L G 100
Red HRBL 56 | 45 5 23° «+H P 100
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Yoh Fasess ZA, rpontrte e)—lpSutsanity Gl) Pepraton Mena on s20
Dschargeabily F2) sowaity
P vecrageity ¢ @SunACTIVE’
Reactive Dyes For Textle
“VINYL SULPHONE BASED" DYES Pua) Qe
alo &.
aK’) chs
Violet oF e7 | 4 | 45 | 34 | m | m | 100
Violet 5
Biue BB
Blue R 7 | 58) 5 4 | Hn | P | 100
Blue 19
Blue sR 67 | 4 | 34 45 H | M | 100
Blue 28
Turg. Blue G 6 45 5 34 H G 100
Blue 21
Green 6B 7 | 34) 4 | 23) H | M | 100
Blue 38
Blue H2GL 6 | 6 5 | 23 | H | @ | 100
Bue 203,
Blue RGB 6 4 5 23 H 6 100
Blue 250
Brown GR 6 | 5 | 45) 1 H | 6 80
Brown 18
Black RL 56 45 5 34 H uM 100
Black 31
Black B 5 | 45 | 5 1 H | a | 150
Black 5
Deep Black 5 45, 45 23 H G 120
N-150
Black WNN 5 | 45 | 5 | 23) H | G | 120
Black Mix
YEH Wasting Mead: on 54011 JRE Light Fasmess J, Hyper er) gli Sutstvey Ql) Perspraton Metot: OW 54020
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13, 2
cure ce cectSunACTIVE’
Reactive Dyes For Texte
= CGS =) Fastnes:
ea aes
Yellow HESG
Yellow HEAG 7
Golden
Yellow 84
OrangeHER = 4s | 5 0 4 4 | HH | Poo
Orange 84
sey s | 5 | 45 | 3 | H | P | 140
Red 120
Red HE7B. 45 45 45 34 H P 150
Red 141
Red 152
Tug BlueHA 6 | 45 «45 0 «4 OM |G 100
Blue 71
NayBlucHER | 5 | 45 | 45 3 | H | G | 150
Blue 171
NayBlueHE2R 5 | 45 45 3 | H | G | 150
Blue 172
GreenHEaB | 45 | 45 | 45 | 2 | H | P | 100
Green 19
Blue HEGN 5 |) 45 5 1 H | P 100
Blue 198
Blue HERD 6 | 45/45) 4 > H | 6 8
Blue 160
14,SunACTIVE’
Reactive Dyes For Texte
“BI-FUNCTIONAL’ ‘ME’ DYES
Ceo ees sled
Yellow 3RF 150% 5 4 5 3 H G 120
Red F6BL 150% 5 45) 45 3 M Pp 100
Scarlet RED
Blue BRF 56 4 4 3 H G 100
| BlackHFGR 45 | 45 0 45° «1 H | M | 120
15SunACTIVE’
Reactive Dyes For Texte
AVStCl=N Sc PALA IO
R. Red 5 45 4 2 H P 100
VRGBN
R. Ultra a
i, Ultra, 56 5 5 4 H M 100
| | R.UtraRedVAGBN 56 | 45 | 45 0 4 | =H | P | 100
R. Deep Black 56) 45 45 4 H M 100
R. Black GSP 5 5 45 | 2 H @ | 120
(R. BLACK F3DBP)
{EDF Vstintabot on sior1 Je unerasness JB nico etc) sbety i) Pesorton ato: 0 S4z0
vscpity © seisity
16SunACTIVE’
Reactive Dyes For Texte
SunActive RR
For warm exhaust suitable for medium shades, cost effective & higher productivity.
Fastness to
Prey
i Yellow RR 4 | 45) 4 | 45 H | @ | 100
MM
SunActive LX
For warm exhaust suitable for pale shades with perfect reproducibility
oa Q
A
eon Pere ar) gre
| velox 5 | 5 | 45 45 | H | M | 420
|| Red ix s | 5 45 45) | P | 120
|| Blue Lx 5 |) 45 45 45 HM 120
i NewiX 4545 5H M100
17SunACTIVE’
Reactive Dyes For Textle
SunActive ED
Multifunctional warm exhaust for deep shades with cost effective and higher productivity.
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VIPULORGANICS
Interconnected Chemistry
Vipul Organics Lic, 102, Andher Industrial Estate, O'f Voora Desai Road, Andhor (W), Mumbai - 400 053, Inca,
4912266189989 0 4912266199977175 @infoBipuorganics.com —Owwusizuorganics.com EB wiaefacebook comMipuOrpanics
BeLvanvtacurng Unit | PALGHAR | AMBERNATH | AHMEDNAGAR | NAVI MUMBAI | TARAPUR