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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 30.01.2018 Revision: 30.01.2018

* SECTION 1: Identification of the substance/mixture and of the company/

undertaking
· 1.1 Product identifier
· Trade name: MR® 70 H Developer, system "hot"
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
· Life cycle stages
F Formulation or re-packing
IS Use at industrial Sites
· Sector of Use
SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites
· Product category PC14 Metal surface treatment products
· Process category
PROC7 Industrial spraying
PROC8a Transfer of substance or mixture (charging and discharging) at non-dedicated facilities
PROC13 Treatment of articles by dipping and pouring
· Environmental release category
ERC4 Use of non-reactive processing aid at industrial site (no inclusion into or onto article)
· Article category AC7 Metal articles
· Application of the substance / the mixture
Testing material for nondestructive surface crack detection
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
MR® Chemie GmbH
Nordstr. 61-63
59427 Unna (Germany)
Tel. +49 (0)2303 95151 0
Fax: +49 (0)2303 95151 10
post@mr-chemie.de
www.mr-chemie.de
· Further information obtainable from:
MR Chemie GmbH, Dep. safety data sheets, Tel.: +49/(0)2303/95151-38, QS@mr-chemie.de
· 1.4 Emergency telephone number:
24h- Emergency Contact Phone Number For Chemical Emergency, Spill, Leak, Fire, Exposure or
Accident (WISAG FMO Cargo Service GmbH & CO.KG)
Call Day or Night within USA and Canada: 1 800 424 9300
Outside USA and Canada: 001 703 527 3887
In-Country Emergency Number for:
Germany: 0800-181-7059
China: 4001 204937 (Mandarin)
Hong Kong: 800 968 793 (Cantonese)
India: 000 800 100 7141 (Hindi)
South Africa: 0 800 983 611 (English)

SECTION 2: Hazards identification

· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Aerosol 1 H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.

GHS07

Eye Irrit. 2 H319 Causes serious eye irritation.

(Contd. on page 2)
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Safety data sheet
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Trade name: MR® 70 H Developer, system "hot"

(Contd. of page 1)
STOT SE 3 H336 May cause drowsiness or dizziness.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS02 GHS07

· Signal word Danger

· Hazard-determining components of labelling:
acetone
2-Propanol
· Hazard statements
H222-H229 Extremely flammable aerosol. Pressurised container: May burst if heated.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
· Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
P501 Dispose of contents/container in accordance with local/regional/national/
international regulations.
· Additional information:
EUH066 Repeated exposure may cause skin dryness or cracking.
Buildup of explosive mixtures possible without sufficient ventilation.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

* SECTION 3: Composition/information on ingredients

· 3.2 Chemical characterisation: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
CAS: 67-64-1 acetone 20-30%
EINECS: 200-662-2 Flam. Liq. 2, H225
Reg.nr.: 01-2119471330-49-XXXX Eye Irrit. 2, H319; STOT SE 3, H336
CAS: 74-98-6 propane 20-30%
EINECS: 200-827-9 Flam. Gas 1, H220
Reg.nr.: 01-2119486944-21-XXXX Press. Gas (Comp.), H280
CAS: 67-63-0 2-Propanol 20-30%
EINECS: 200-661-7 Flam. Liq. 2, H225
Reg.nr.: 01-2119457558-25-XXXX Eye Irrit. 2, H319; STOT SE 3, H336
(Contd. on page 3)
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Trade name: MR® 70 H Developer, system "hot"

(Contd. of page 2)
CAS: 106-97-8 butane (containing ≤ 0,1 % butadiene (203-450-8)) 10-20%
EINECS: 203-448-7 Flam. Gas 1, H220
Reg.nr.: 01-2119474691-32-XXXX Press. Gas (Comp.), H280
CAS: 78-93-3 butanone 1-5%
EINECS: 201-159-0 Flam. Liq. 2, H225
Reg.nr.: 01-2119457290-73-XXXX Eye Irrit. 2, H319; STOT SE 3, H336
· Propellant: Propane-Butane
· Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

· 4.1 Description of first aid measures
· General information:
Immediately remove any clothing soiled by the product.
Seek medical advice if symptoms occurs or in cases of doubt.
· After inhalation:
Supply fresh air; consult doctor in case of complaints.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Not relevant - aerosol can.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· Information for doctor:
Grease with skin-cream to restore fat film in order to prevent skin inflammation.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

· 5.1 Extinguishing media
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
foam.
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixture
In case of fire, the following can be released:
Carbon monoxide (CO)
· 5.3 Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.

SECTION 6: Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
(Contd. on page 4)
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Trade name: MR® 70 H Developer, system "hot"

(Contd. of page 3)
See Section 13 for disposal information.

SECTION 7: Handling and storage

· 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.
· Information about fire - and explosion protection:
Do not spray onto a naked flame or any incandescent material.
Keep ignition sources away - Do not smoke.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C,
e.g. electric lights. Do not pierce or burn, even after use.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles:
Store in a cool location.
Observe official regulations on storing packagings with pressurised containers.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Protect from heat and direct sunlight.
· 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
67-64-1 acetone
IOELV (EU) Long-term value: 1210 mg/m³, 500 ppm
WEL (Great Britain) Short-term value: 3620 mg/m³, 1500 ppm
Long-term value: 1210 mg/m³, 500 ppm
AGW (Germany) Long-term value: 1200 mg/m³, 500 ppm
2(I);Y, DFG, EU, AGS
74-98-6 propane
AGW (Germany) Long-term value: 1800 mg/m³, 1000 ppm
4(II);DFG
67-63-0 2-Propanol
WEL (Great Britain) Short-term value: 1250 mg/m³, 500 ppm
Long-term value: 999 mg/m³, 400 ppm
AGW (Germany) Long-term value: 500 mg/m³, 200 ppm
2(II);DFG, Y
106-97-8 butane (containing ≤ 0,1 % butadiene (203-450-8))
WEL (Great Britain) Short-term value: 1810 mg/m³, 750 ppm
Long-term value: 1450 mg/m³, 600 ppm
Carc (if more than 0.1% of buta-1.3-diene)
AGW (Germany) Long-term value: 2400 mg/m³, 1000 ppm
4(II);DFG
78-93-3 butanone
IOELV (EU) Short-term value: 900 mg/m³, 300 ppm
Long-term value: 600 mg/m³, 200 ppm
WEL (Great Britain) Short-term value: 899 mg/m³, 300 ppm
Long-term value: 600 mg/m³, 200 ppm
Sk, BMGV
(Contd. on page 5)
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Trade name: MR® 70 H Developer, system "hot"

(Contd. of page 4)
AGW (Germany) Long-term value: 600 mg/m³, 200 ppm
1(I);DFG, EU, H, Y
· DNELs
67-64-1 acetone
Dermal Long-term - systemic effects, worker 186 mg/kg bw/day (worker)
Inhalative Long-term - systemic effects, worker 1,210 mg/m³ (worker)
Long-term - local effects, worker 2,420 mg/m³ (worker)
67-63-0 2-Propanol
Dermal Long-term - systemic effects, worker 888 mg/kg bw/day (worker)
Inhalative Long-term - systemic effects, worker 500 mg/m³ (worker)
78-93-3 butanone
Dermal Long-term - systemic effects, worker 1,161 mg/kg bw/day (worker)
Inhalative Long-term - systemic effects, worker 600 mg/m³ (worker)
· PNECs
67-64-1 acetone
Aquatic compartment, freshwater 10.6 mg/L (freshwater)
Aquatic compartment - marine water 1.06 mg/L (marine water)
Aquatic compartment- sediment in freshwater 30.4 mg/kg sed dw (sediment fresh water)
Aquatic compartment sediment in marine water 3.04 mg/kg sed dw (sediment marine water)
Terrestrial compartment - soil 29.5 mg/kg dw (soil)
67-63-0 2-Propanol
Aquatic compartment, freshwater 140.9 mg/L (freshwater)
Aquatic compartment - marine water 140.9 mg/L (marine water)
Aquatic compartment- sediment in freshwater 552 mg/kg sed dw (sediment fresh water)
Aquatic compartment sediment in marine water 552 mg/kg sed dw (sediment marine water)
Terrestrial compartment - soil 28 mg/kg dw (soil)
Sewage treatment plant 2,251 mg/L (sewage treatment plant)
Oral secondary poisoning 160 mg/kg food (food secundary poisoning)
78-93-3 butanone
Aquatic compartment, freshwater 55.8 mg/L (sediment fresh water)
Aquatic compartment - marine water 55.8 mg/L (marine water)
Aquatic compartment- sediment in freshwater 284.74 mg/kg sed dw (sediment fresh water)
284.7 mg/kg sed dw (sediment marine water)
Terrestrial compartment - soil 22.5 mg/kg dw (soil)
Oral secondary poisoning 1,000 mg/kg food (food secundary poisoning)
· Ingredients with biological limit values:
67-64-1 acetone
BGW (Germany) 80 mg/l
Untersuchungsmaterial: Urin
Probennahmezeitpunkt: Expositionsende bzw. Schichtende
Parameter: Aceton
(Contd. on page 6)
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Trade name: MR® 70 H Developer, system "hot"

(Contd. of page 5)
67-63-0 2-Propanol
BGW (Germany) 25 mg/l
Untersuchungsmaterial: Vollblut
Probennahmezeitpunkt: Expositionsende bzw. Schichtende
Parameter: Aceton

25 mg/l
Untersuchungsmaterial: Urin
Probennahmezeitpunkt: Expositionsende bzw. Schichtende
Parameter: Aceton
78-93-3 butanone
BMGV (Great Britain) 70 µmol/L
Medium: urine
Sampling time: post shift
Parameter: butan-2-one
BGW (Germany) 2 mg/l
Untersuchungsmaterial: Urin
Probennahmezeitpunkt: Expositionsende bzw. Schichtende
Parameter: 2-Butanon
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
Filter AX-P2
For good ventilation provide, this can be achieved by local or space exhaust. If the concentration
lies over the job limit values, then, a certified respirator suitable for this purpose must be used.
· Protection of hands:
Check the permeability prior to each anewed use of the glove.
For the protection against chemicals in areas with heightened risk of injury (mechanical hazard) no
recommendation for a suitable glove material can be given.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
Butyl rubber, BR
Fluorocarbon rubber (Viton)
Recommended thickness of the material: ≥ 0.5 mm
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
Value for the permeation: Level ≤ 4
Supplier for suitable protection gloves:
ASD ArbeitsSicherheit Dortmund
Torstr. 101 - 37355 Niederorschel OT Rüdigershagen
Tel.: 02301 / 919543 - Fax: 02301 / 9453893
E-Mail: m.schnellhardt@t-online.de - http://www.arbeitssicherheitdortmund.de
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Tightly sealed goggles
(Contd. on page 7)
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(Contd. of page 6)
· Body protection: Protective work clothing

SECTION 9: Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Aerosol
Colour: White suspension.
· Odour: Characteristic
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in condition
Melting point/freezing point: Undetermined.
Initial boiling point and boiling range: Not applicable, as aerosol.
· Flash point: -80 °C
Basis: propellant
· Flammability (solid, gas): Not applicable.
· Ignition temperature: Not determined - aerosol.
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of
explosive air/vapour mixtures are possible.
· Explosion limits:
Lower: 1.5 Vol %
Upper: 13 Vol %
· Vapour pressure at 20 °C: 8,300 hPa
Basis: propellant
· Density at 20 °C: 0.86 g/cm³
Basis: active substance
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
water: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:
Dynamic: Not determined.
Kinematic: Not determined.
Organic solvents: 90.8 %
VOC (EU) 90.8 %
Solids content: <5 %
· 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

· 10.1 Reactivity No further relevant information available.
(Contd. on page 8)
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(Contd. of page 7)
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
Danger of bursting of the aerosol can during overheating
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11: Toxicological information

· 11.1 Information on toxicological effects
· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
67-64-1 acetone
Oral LD50 5,800 mg/kg (rat)
Dermal LD50 20,000 mg/kg (rbt)
67-63-0 2-Propanol
Oral LD50 5,045 mg/kg (rat)
Dermal LD50 12,800 mg/kg (rbt)
Inhalative LC50/4 h 30 mg/l (rat)
106-97-8 butane (containing ≤ 0,1 % butadiene (203-450-8))
Inhalative LC50/4 h 658 mg/l (rat)
78-93-3 butanone
Oral LD50 3,300 mg/kg (rat)
Dermal LD50 5,000 mg/kg (rbt)
· Primary irritant effect:
· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation
Causes serious eye irritation.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure
May cause drowsiness or dizziness.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

· 12.1 Toxicity
· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Do not allow product to reach ground water, water course or sewage system.
Water hazard class 1: weakly water-endangering
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
(Contd. on page 9)
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(Contd. of page 8)
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

· 13.1 Waste treatment methods
· Recommendation
Eliminate the pure, unchanged substance in accordance with local regulations.
Must not be disposed together with household garbage. Do not allow product to reach sewage
system.
· Waste disposal key:
For this product no waste key number can be specified, because only the intended purpose permits
an allocation. The waste key number is to be specified in arrangement with the regional waste
disposal.
The indications for Waste key reflect the pure unmodified product and are only a recommendation.
· European waste catalogue
08 02 99 wastes not otherwise specified
15 01 04 metallic packaging
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.

SECTION 14: Transport information

· 14.1 UN-Number
· ADR, IMDG, IATA UN1950
· 14.2 UN proper shipping name
· ADR 1950 AEROSOLS
· IMDG AEROSOLS
· IATA AEROSOLS, flammable
· 14.3 Transport hazard class(es)
· ADR

· Class 2 5F Gases.
· Label 2.1
· IMDG, IATA

· Class 2.1
· Label 2.1
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.5 Environmental hazards:
· Marine pollutant: No
· 14.6 Special precautions for user Warning: Gases.
(Contd. on page 10)
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(Contd. of page 9)

· Danger code (Kemler): -

· EMS Number: F-D,S-U
· Stowage Code SW1 Protected from sources of heat.
SW22 For AEROSOLS with a maximum capacity
of 1 litre: Category A. For AEROSOLS with a
capacity above 1 litre: Category B. For WASTE
AEROSOLS: Category C, Clear of living quarters.
· Segregation Code SG69 For AEROSOLS with a maximum capacity of
1 litre: Segregation as for class 9. Stow "separated
f rom " c lass 1 ex cept f or divis ion 1.4. For
AEROSO LS with a c apacity above 1 litre:
Segregation as for the appropriate subdivision of
class 2. For WASTE AEROSOLS: Segregation as
for the appropriate subdivision of class 2.
· 14.7 Transport in bulk according to Annex II
of Marpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· Transport category 2
· Tunnel restriction code D
· IMDG
· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E0
Not permitted as Excepted Quantity
· UN "Model Regulation": UN1950, AEROSOLS, 2.1

SECTION 15: Regulatory information

· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· Directive 2012/18/EU
· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Qualifying quantity (tonnes) for the application of lower-tier requirements 150 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 40
· National regulations:
· Waterhazard class:
W ater hazard class 1: slightly hazardous for water.(In accordance with classification
VwVwS,appendix 4)
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

The data in this safety data sheet are based on our knowledge at the time of the revision.The
information should give you reference points for a safe handling of the product specified in this
safety data sheet. The data are not transferable to other products. If the product specified in this
safety data sheet is mixed or processed with other materials, the data cannot be transferred without
examination.
(Contd. on page 11)
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(Contd. of page 10)

· Relevant phrases
The wording of the listed risk phrases are those of the individual raw materials.
H220 Extremely flammable gas.
H225 Highly flammable liquid and vapour.
H280 Contains gas under pressure; may explode if heated.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
· Recommended restriction of use
Existing national and local laws concerning chemicals are to be considered.
· Department issuing SDS:
MR Chemie GmbH, Dep. safety data sheets, Tel.: +49/(0)2303/95151-38
· Contact:
MR Chemie GmbH, Dep. safety data sheets, Tel.: +49/(0)2303/95151-38, QS@mr-chemie.de
· Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the
International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Gas 1: Flammable gases – Category 1
Aerosol 1: Aerosols – Category 1
Press. Gas (Comp.): Gases under pressure – Compressed gas
Flam. Liq. 2: Flammable liquids – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
· * Data compared to the previous version altered.
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