Engineering Students' Guide to Air Pollution
Engineering Students' Guide to Air Pollution
Environmental Pollution
Faculty of Engineering
Oil and Gas Department
Dr. Saleem Ethaib Mohammad
2018-2019
Environmental Pollution
Air pollution
Many forms of atmospheric pollution affect human health and the environment at levels
from local to global. These contaminants are emitted from diverse sources, and some of
them react together to form new compounds in the air. Industrialized nations have made
important progress toward controlling some pollutants in recent decades, but air quality is
much worse in many developing countries, and global circulation patterns can transport
some types of pollution rapidly around the world.
Atmospheric composition
Earth’s atmosphere contains mainly several different gases and additionally aerosol
particles. Atmospheric gases are generally classified by their amount and residence time.
The residence time (or removal time or lifetime) is an average amount of time that a
particle or substance spends in a particular system (as the atmosphere). The residence
time can be defined as the amount of the compound in the atmosphere divided by the rate
at which this compound removed from the atmosphere.
Based on the quantity, major components and trace gases, while according to residence
time, constant and variable (and sometimes highly variable) gases can be distinguished
(Table 1.1).
The amount of atmospheric gases can be expressed by different measures.
Generally used terms are the concentration (kg m–3), the volume ratio (m3 gas per m3 air)
and mole fraction (mol mol–1).
For trace gases, this mixing ratio are commonly given in units of parts per million volume
(ppmv or simply ppm), parts per billion volume (ppbv or ppb), or parts per trillion
volume (pptv or ppt); 1 ppmv = 10–6 mol mol–1, 1 ppbv = 10–9 mol mol–1 and 1 pptv =10–
12
mol mol–1.
The abundances of constant gases has remained the same over geological timescales,
while residence time generally means years in case of variable gases and days in case of
highly variable gases (Table 1.2).
The main constituents of the dry atmosphere are nitrogen (78.084% by volume), oxygen
(20.946% by volume) and argon (0.934% by volume), but much lower concentrations
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other noble gases can also be found (Table 1.2). Concentrations of these gases do not
vary substantially in time and space (in the lower 80 km layer of the atmosphere) and
therefore they are called permanent gases.
Table 1.1: Classification of atmospheric gases
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Nitrogen (N2) is a relatively inert gas and fundamental to all living systems. Through the
nitrogen cycle nitrogen is removed from the atmosphere and becomes part of living
organisms. This process is realized by nitrogen fixation by soil bacteria, and by way of
lighting through precipitation. Nitrogen returns to the atmosphere mainly by biomass
combustion and denitrification.
As nitrogen, oxygen (O2) has also very important relations with life. Oxygen exchange
between the atmosphere and biosphere is realized by photosynthesis and respiration.
Argon (Ar) in the atmosphere is the third most abundant gas. Among noble gases, argon
was first detected in the atmosphere in 1894 by Lord Rayleigh and William Ramsay.
Water vapour (H2O) is a significant component of the atmosphere. Its concentration
varies over a wide range both spatially and temporally. Most of water vapour
concentrated in the lower atmosphere. The capacity of air to hold water vapour (called
saturation level) is a function only of the air temperature. The higher the temperature the
greater amount of water vapour can be held without condensation (Figure 1.1). The
highest atmospheric moisture content is observable over equatorial ocean area and
tropical rain forests, while the lowest water vapour concentrations can be measured over
cold, polar regions, and subtropical deserts.
Figure 1.1 Dependence of saturated water vapour pressure from air temperature.
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The volume of other gases compared to the main components, are very low, and therefore
they are called trace gases. Despite their low concentrations, these tracers (e.g. ozone
both in troposphere and stratosphere, carbon, nitrogen, sulphur compounds etc.) can be of
critical importance for several environmental issues (for example: greenhouse effect,
atmospheric pollution etc.).
Next to the different gases, Earth’s atmosphere contains a huge number of aerosol
particles. Aerosols are generally defined as suspension of solid particles or liquid droplets
in a gas. Their size are very small, the particle diameters in the range of 10–9–10–4 m.
Pure air is colourless and odourless. But various pollutants from natural and man-made
sources are entering the atmosphere daily and these disturb the dynamic equilibrium in
the atmosphere. This leads to air pollution when the normal properties of air are upset and
both man and environment suffer.
Natural sources of air pollution are:
• Volcanic activity, vegetation decay, forest fires emitting carbon monoxide, sulphur
dioxide and hydrogen sulphide and tiny particles of solids or liquids sprayed from the
seas and land by wind.
Man-made sources are:
• Gases, mist, particulates and aerosols emitted by industries and other chemical and
biological processes used by man.
Air Pollutants
In general, air pollutants, emitted from natural and anthropogenic sources, can be broadly
classified under two categories: primary and secondary pollutants.
The primary pollutants are those that are emitted directly from the sources. These are:
Inorganic gases – SO2, NO, CO, CO2, H2S. HF. Olefinic and Aromatic hydrocarbons;
Radioactive compounds.
The Secondary pollutants are those that are formed in the atmosphere by chemical
reactions among primary pollutants and atmospheric constituents. Examples are: SO3,
NO2, PAN (Peroxyacyl nitrate), O3, aldehydes, ketones, various nitrate and sulphate salts.
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Carbon Monoxide, CO
It is a colourless, odourless and tasteless gas which is injurious to our health. Each year
350 million tonnes of CO (275 million tonnes from human sources and 75 million tonnes
from natural sources) are emitted all over the world in which USA alone shares 100
million tonnes. Transportation accounts for 70 per cent of CO emission. That is to say,
diesel and petroleum engines in automobiles are primarily responsible for about 70 per
cent of CO emissions. The sources of carbon monoxide, CO are the chemical reactions:
Control of CO Pollution
The petroleum and diesel-fed automobiles account for major share of carbon monoxide
emission. Hence efforts for carbon monoxide pollution control are mainly aimed at
automobiles. Use of catalytic converters in the internal combustion engines of
automobiles helps in cleaning up the exhaust emissions. Such converters built into the
automobile engines promote oxidation-reduction cycles and ensure complete combustion
of carbon monoxide, nitrogen oxides and hydrocarbons. The following figure and flow-
sheet illustrate the action of catalytic converters: Use of catalytic converters in two stages
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helps in elimination of pollutants from exhaust gases before they are discharged into the
atmosphere.
In the first converter nitrogen oxides are reduced to nitrogen (+ ammonia) in presence of
finely divided catalyst platinum, and the reducing gases, carbon monoxide and
hydrocarbons. The production of ammonia is kept at a minimum under carefully
controlled conditions. In the second converter, air is introduced to provide an oxidizing
atmosphere for complete oxidation of carbon monoxide and hydrocarbon into carbon
dioxide and water in presence of finely divided platinum catalyst.
These reactions occur inside the automobile engines so that the exhaust gases consist of
NOx. The latter concentration in rural air is much less than in urban air. In air NOx is
converted into nitric acid, HNO3 by natural processes:
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This nitric acid is one of the constituents of acid rain discussed in a subsequent section.
From auto exhaust emissions NOx is removed as discussed above by means of catalytic
converters.
Domestic animals (cattle, buffaloes, etc.) contribute about 85 million tonnes of methane
to the atmosphere each year. Automobiles are significant sources of hydrocarbons.
In presence of ozone, carbon monoxide, nitrogen oxides and hydrocarbon participate in
photochemical reactions (in presence of sunlight). A chain reaction proceeds in which the
free radical R •CH2 is generated in the first step. Other free radicals which are formed are:
R CH2 •O2 in the second step by reaction with oxygen, R CH2 O; R CH2 •O in the third
step by reaction with nitric oxide; H•O2 in the fourth step by reaction with oxygen; a
stable aldehyde R CHO is another product at this stage; H•O• is formed in fifth step by
reaction with nitric oxide (nitrogen dioxide is another product here); and finally, the
starting free radical R •CH2 is regenerated by reaction with hydrocarbon, R CH3 thereby
sustaining the chain reaction.
The harmful products in the chain reaction are NO2 and aldehyde, R CHO. A side
reaction also follows by another route through the aldehyde, R CHO; it gives an injurious
end product, peroxy acyl nitrate (PAN) which is a strong eye irritant. These reactions lead
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Sulphur dioxide is a colourless gas with a pungent odour. It is produced from the
combustion of any sulphur-bearing material. Sulphur dioxide, SO2 is always associated
with a little of sulphur trioxide, SO3.
The first reaction above occurs in presence of ozone and water vapour. The product,
sulphuric acid is formed on aerosol (fine particle suspended in air as in smoke, fog, mist,
etc.) droplet. Sulphuric acid is one of the constituents of acid rain.
In winter climate sulphur oxides from thermal power plants along with other gases leads
to smog formation e.g. London smog. This is known as reducing smog in contrast with
photochemical smog which is known as oxidising smog (consisting of hydrocarbons,
nitrogen oxides and ozone). London smog (1952) is well-known for its disastrous effect.
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Heavy smog (SO2) conditions prevailed in London for five days which killed about 4,000
people. The causes of death were bronchitis, pneumonia, and other respiratory troubles
particularly among aged people.
The method is economical but the disposal of solid waste, calcium sulphate is a problem.
Alternatively, sulphur dioxide in aqueous solution is treated with citric acid salt and the
resulting solution is exposed to a stream of hydrogen sulphide gas whereby sulphur is
deposited. This sulphur can then be recovered and utilised. Thermal power plants, major
sources of man-made SOx pollution, are normally constructed with tall chimneys to
disperse the emissions over a wide area. This reduces the local problem but creates
problems for far away areas through acid rains.
Acid Rain
It has been described above that much of nitrogen oxides, NOx and sulphur oxides, SOX
entering the atmosphere are transformed into nitric acid (HNO3) and sulphuric acid
(H2SO4) respectively. These combine with hydrogen chloride, HCl from HCl emissions
(both by man-made and natural sources) and generate acidic precipitation, known as acid
rain.
Acid rain is a major environmental issue as it badly damages the environment. It damage
buildings and structural materials of marble, limestones, slate and mortar. These materials
become structurally weak as calcium carbonate reacts with sulphuric acid to form soluble
sulphate, which is leached out by rain water:
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In Greece and Italy invaluable stones and statutes have been partly dissolved by acid rain.
Besides these, acid rain damaged forests in Germany and lakes in Sweden and Canada.
Acid rain originated from U.K. but far away in Sweden, it damaged some 8,000 lakes of
which 4,000 are dead. Similarly, acid rain from USA damaged lakes and forests in
Canada.
In India, Taj Mahal is threatened by acid rain from Mathura refinery and other industries.
Soot
Soot particles originate from fuel combustion and consist of highly condensed product of
polycyclic aromatic hydrocarbon (PAH)—roughly 100 condensed aromatic rings. The
hydrogen content of soot is 1–3 per cent and oxygen content 5–10 per cent due to partial
surface oxidation. Due to large surface area, soot acts as a carrier for toxic organics e.g.,
benzo-α-pyrene and toxic trace metals e.g., beryllium, cadmium chromium, manganese,
nickel, vanadium, etc.
A soot particle has an average size 0.1–20 μ. The finer particles (< 3 μ) are the worst
causes of lungs damage due to their ability to penetrate deep in our respiratory tract and
thence in lungs where they remain for years and cause all sorts of diseases such as cough,
bronchitis, asthma, and finally cancer. Particulates cause increased corrosion of metals
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which assume serious dimensions in industrial and urban areas. They are responsible for
damage to buildings, sculptures, paintings, etc.
Particulates play key roles in the atmosphere. They reduce visibility by scattering and
absorption of solar radiation. They influence the climate through the formation of cloud,
rain and snow by acting as nuclei upon which water can condense into raindrops.
Atmospheric particulate levels can be correlated with the extent of precipitation over
cities and suburbs.
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Carbon dioxide is not the only culprit responsible for greenhouse effect and global
warming.
Other greenhouse gases are: methane, chloroflurocarbons (CFC), nitrous oxide, ozone
and watervapour. The relative contributions of these gases to greenhouse effect are:
carbon dioxide 50 per cent; Methane 19 per cent; Chloroflurocarbons 17 per cent; ozone
8 per cent; nitrous oxide 4 per cent; water vapour 2 per cent.
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This shows that carbon dioxide accounts for 50 per cent of the greenhouse gases. The
shares of methane (19 per cent) and chloroflurocarbons (17 per cent) (gases from
refrigerators and air-conditioners) cannot be ignored.
OZONE HOLE
Ozone, (O3), triatomic allotrope of oxygen (a form of oxygen in which the molecule
contains three atoms instead of two as in the common form) that accounts for the
distinctive odour of the air after a thunderstorm or around electrical equipment. The
odour of ozone around electrical machines was reported as early as 1785; ozone’s
chemical constitution was established in 1872. Ozone is an irritating, pale blue gas that is
explosive and toxic, even at low concentrations. It occurs naturally in small amounts in
the Earth’s stratosphere, where it absorbs solar ultraviolet radiation, which otherwise
could cause severe damage to living organisms on the Earth’s surface. In the stratosphere,
the second region of the atmosphere, ozone is present in small quantities but it is
protective shield for the earth. Ozone strongly absorbs ultraviolet radiation from the sun
(295–320 nm) which is injurious for life on earth. Thus it protects living species on earth.
But recent human activities have injected some dangerous chemicals in the stratosphere
which consume ozone and reduce its concentration. This is the phenomenon of ozone
hole in the stratosphere.
Under certain conditions, photochemical reactions between nitrogen oxides and
hydrocarbons in the lower atmosphere can produce ozone in concentrations high enough
to cause irritation of the eyes and mucous membranes. Exhaust gases from jet aircrafts
and artificial satellites discharge nitric oxide (NO), nitrogen dioxide (NO2) etc., which
immediately react with ozone.
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In presence of ultraviolet radiation (200 nm) from the sun, CFC breaks up into
chlorinefree radical (Cl) which readily consumes ozone.
The free radical (Cl•) is regenerated and continues the chain reaction. It is estimated that
one molecule of CFC consumes one lakh molecules of ozone. The damage by CFC
continues for 100 years. Even if CFC production is stopped now all over the world, the
CFC that is already there in the stratosphere will continue to damage the ozone layer for
the next 100 years.
In 1979 ozone hole was observed in the sky over Antarctica–here ozone layer thickness
was reduced by 30 per cent. Later on ozone hole was discovered in the sky over the
thicklypopulated northern hemisphere. Here in winter ozone thickness was reduced by 4
per cent and in summer by 1 per cent. Ozone hole allows passage of ultraviolet radiation
to the earth where it causes skin cancer, eyesight defect, genetic disorder, etc., in the
biosphere (man, animal and plant). In Europe and USA there is an increase in the cases of
skin cancer among people while some million people are suffering from eye cataract
Water Pollution
The normal uses of water for public supply are–recreation (swimming, boating, etc.),
fish, other aquatic life and wild life, agriculture (irrigation), industry, navigation, etc. Any
change in the dynamic equilibrium in aquatic ecosystem (water
body/biosphere/atmosphere) disturbs the normal function and properties of pure water
and gives rise to the phenomenon of water pollution. The symptoms of water pollution of
any water body/ground water are:
• Bad taste of drinking water,
• Offensive smells from lakes, rivers and ocean beaches,
• Unchecked growth of aquatic weeds in water bodies (eutrophication),
• Dead fish floating on water surface in river, lake, etc.
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WATER POLLUTANTS
The large numbers of water pollutants are broadly classified under the categories:
1. Organic pollutants,
2. Inorganic pollutants,
3. Sediments,
4. Radioactive materials and
5. Thermal pollutants.
6. Biological pollutants
Organic Pollutants
These include domestic sewage, pesticides, synthetic organic compounds, plant nutrients
(from agricultural run-off), oil, wastes from food processing plants, paper mills and
tanneries, etc. These reduce dissolved oxygen (D.O.) in water. Dissolved oxygen (D.O.)
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is essential for aquatic life, the optimum level being 4–6 ppm (parts per million).
Decrease in D.O. value is an indicator of water pollution. The organic pollutants consume
D.O. through the action of bacteria present in water.
Oil pollution of the seas has increased over the years, due to increased traffic of oil
tankers in the seas causing oil spill and also due to oil losses during off-shore drilling. Oil
pollution reduces light transmission through surface water and hence reduces
photosynthesis by marine plants, decreases D.O. in water causing damage to marine life
(plants, fish, etc.) and also contaminates sea food which enters the human food chain.
Inorganic Pollutants
This group consists of inorganic salts, mineral acids, metals, trace elements, detergents,
etc. Acid mine drainage: Coal mines, particularly those which have been abandoned,
discharge acid (sulphuric acid) and also ferric hydroxide into local streams through
seepage. The acid on entering the waterbody destroys its aquatic life (plants, fish, etc.).
Sediments
Soil erosion, as a matter of natural process, generates sediments in water. Solid loadings
in natural water are about 700 times as large as the solid loading from sewage discharge.
Soil erosion is enhanced 5–10 times due to agricultural and 100 times due to construction
activities. Bottom sediments in aquatic bodies (streams, lakes, estuaries, oceans) are
important reservoirs of inorganic and organic matter, particularly trace metals e.g.,
chromium, copper, nickel, manganese and molybdenum.
Radioactive Materials
Radioactive pollution is caused by mining and processing of radioactive ores to produce
radioactive substances, use of radioactive materials in nuclear power plants, use of
radioactive isotopes in medical, industrial and research institutes and nuclear tests. The
discharge of radioactive wastes into water and sewer systems is likely to create problems
in future.
Thermal Pollutants
Coal-fired or nuclear fuel-fired thermal power plants are sources of thermal pollution.
The hot water from these plants is dumped as waste into nearby lake or river where its
temperature rises by about 10°C. This has harmful effect on aquatic life in the water body
whose D.O. is reduced and as a result, fish kill is quite common.
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Biological Pollutants
Bacteria (for example Salmonella, Shigella, Campylobacter, Vibrio cholerae), Viruses
(for example hepatitis A, rotavirus, enteroviruses), Protozoa (for example Entamoeba
histolytica, Giardia lamblia, Cryptosporidium parvum) and Parasites such as helminths
and their eggs (e.g. Ascaris (roundworm), Ancylostoma (hookworm), Trichuris
(whipworm)
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Disinfection
After the water has been filtered, a disinfectant (for example, chlorine, chloramine) may
be added in order to kill any remaining parasites, bacteria, and viruses, and to protect the
water from germs when it is piped to homes and businesses.
Water Quality Standards
The analyses required of water samples depend on the intended use of the water. For
example, if its intended use is drinking, water should meet certain quality criteria with
respect to the appearance, (turbidity, colour), potability (taste, odour), health (bacteria,
nitrates, chlorides, etc.) and toxicity (metals, organics). These and similar criteria are
established by health or other regulating agencies to ensure that the water quality in a
resource is suitable for the proposed use.
Turbidity is a measure of the cloudiness or haziness in water caused by suspended solids
(eg sediment, algae). Turbidity is expressed in Nephelometric Turbidity Units (NTU) and
is measured using a relationship of light reflected from a given sample.
pH is an indicator of acidity or alkalinity. Neutral water has a pH of 7, acidic solutions
have values between 0-6 and alkaline solutions have values between 8-14.
Alkalinity is a measure of the buffering capacity of water, or the capacity of the water to
neutralise acids and resist pH change. Alkalinity within water bodies is consumed as acid
is released from acid sulfate soils. Adding limestone contributes alkalinity to waters,
helping to neutralise any acid released from the sediments. .
Salinity is a measure of the amount of dissolved salts in the water. Saline water conducts
electricity more readily than freshwater, so electrical conductivity (EC) is routinely used
to measure salinity. As salinity increases, it may become toxic to native freshwater
organisms.
Nutrients–Total nitrogen (TN) and total phosphorus (TP) are the total amount of
nitrogen and phosphorus present in the water body. Nitrogen can be present in different
forms (e.g. organic nitrogen in plant material, ammonia, nitrate and nitrite).
Chlorophyll a is the main photosynthetic pigment in green algae. The concentration of
chlorophyll gives an indication of the volume of aquatic plants present in the water
column.
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Metal During concentration events (ie evaporation and low inputs) the concentration of
metals are expected to increase, alternatively during flooding events the volume of metals
will be diluted and expected to reduce.
Based on the criteria, quality standards are set, which reflect the current state of
knowledge of various water constituents. These standards are continuously revised as
more and more is learnt about the effects of water constituents on proposed uses. Hence,
these standards should not be used as absolute limits, but only as guidelines that can be
used for preliminary judgements.
Table 5.1 summarizes several quality criteria and their standards for drinking water as
suggested by the following agencies:
(1) Indian Council of Medical Research (ICMR)
(2) World Health Organization (WHO)
(3) United States Public Health Service (USPHS)
Table 5.1: Standards for Drinking Water
A – Recommended maximum concentrationa (mg/L except where shown otherwise)
B – Maximum permissible concentrationb (mg/L except where shown otherwise)
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Wastewater Treatment
Water pollution is caused by municipal sewage (84 per cent) and industrial sewage (16
per cent). Though the latter has fewer loads on water body, it contains toxic matter
(inorganic and organic) which are more hazardous.
Wastewater Quality Indicators
Since all natural waterways contain bacteria and nutrients, almost any waste compounds
introduced into such waterways will initiate biochemical reactions (such as shown
above). Those biochemical reactions create what is measured in the laboratory as the
biochemical oxygen demand (BOD).
Such chemicals are also liable to be broken down using strong oxidizing agents and these
chemical reactions create what is measured in the laboratory as the chemical oxygen
demand (COD).
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Both the BOD and COD tests are a measure of the relative oxygen-depletion effect of a
waste contaminant.
Both have been widely adopted as a measure of pollution effect. The BOD test measures
the oxygen demand of biodegradable pollutants whereas the COD test measures the
oxygen demand of oxidizable pollutants.
Municipal Wastewater Treatment
Sewage treatment plants, in general, depend on biological decomposition of non-toxic
organic wastes using bacteria. Such biological decomposition is carried out under aerobic
conditions i.e., in presence of plenty of oxygen.
The process, commonly used for municipal waste water, is shown in Fig. 5.1.
In the first stage, solid wastes are removed from water by screening–any scum
(suspended matter) is removed and the sludge (muddy solid or sediment) allowed settling
at the bottom.
The residual liquid is exposed to biological oxidation of soluble organic materials
through a bed of microbes in activated sludge.
Then the solids are removed after sedimentation.
Finally the liquid effluent is subjected to chlorination for destroying pathogenic micro-
organisms. Now this effluent is fairly clean and suitable for domestic use.
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large amount of water, the softening solution may fill with excess calcium and
magnesium ions, requiring the solution be recharged with sodium ions.
Chemical Stabilization
This process works in a similar fashion as chemical oxidation. Sludge is treated with a
large amount of a given oxidant, such as chlorine. The introduction of the oxidant slows
down the rate of biological growth within the sludge, and also helps deodorize the
mixture. The water is then removed from the sludge. Hydrogen peroxide can also be used
as an oxidant, and may be a more cost-effective choice.
Biological treatment
Use microorganisms, mostly bacteria, in the biochemical decomposition of wastewaters
to stable end products. More microorganisms, or sludges, are formed and a portion of the
waste is converted to carbon dioxide, water and other end products. The petroleum
wastewater was treated by various biological methods successfully such as activated
sludge reactors or biofilm-based reactor to remove the organic pollutants. The biological
oxidation processes depend on the compositions of the petroleum wastewater. However,
these processes have some disadvantages such as the extreme sludge production, and low
capacity to COD removals. Generally, biological treatment methods can be divided into
aerobic and anaerobic methods, based on availability of dissolved oxygen. In anaerobic
systems, the products of chemical and biochemical reactions produce displeasing colors
and odors in water. Thus, the oxygen availability was important in water to reduce
displeasing colors and odors.
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Soil pollution
Soil pollution is defined as the presence of toxic chemicals (pollutants or contaminants)
in soil, in high enough concentrations to pose a risk to human health and/or the
ecosystem. In the case of contaminants which occur naturally in soil, even when their
levels are not high enough to pose a risk, soil pollution is still said to occur if the levels of
the contaminants in soil exceed the levels that should naturally be present.
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Incineration
Burning is a very effective method of reducing the volume and weight of solid waste. In
modern incinerators the waste is burned inside a properly designed furnace under very
carefully controlled conditions. The combustible portion of the waste combines with
oxygen, releasing mostly carbon dioxide, water vapour, and heat.
Incineration can reduce the volume of uncompacted waste by more than 90 percent,
leaving an inert residue of ash, glass, metal, and other solid materials called bottom ash.
The gaseous by-products of incomplete combustion, along with finely divided particulate
material called fly ash, are carried along in the incinerator airstream.
Fly ash includes cinders, dust, and soot. In order to remove fly ash and gaseous by-
products before they are exhausted into the atmosphere, modern incinerators must be
equipped with extensive emission control devices. Such devices include fabric baghouse
filters, acid gas scrubbers, and electrostatic precipitators. (See also air pollution control.)
Bottom ash and fly ash are usually combined and disposed of in a landfill. If the ash is
found to contain toxic metals, it must be managed as a hazardous waste.
Energy recovery
The energy value of refuse can be depending on the paper content, and the heat given off
during incineration can be recovered by the use of a refractory-lined furnace coupled to a
boiler. Boilers convert the heat of combustion into steam or hot water, thus allowing the
energy content of the refuse to be recycled. Incinerators that recycle heat energy in this
way are called waste-to-energy plants. Instead of a separate furnace and boiler, a water-
tube wall furnace may also be used for energy recovery. Such a furnace is lined with
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vertical steel tubes spaced closely enough to form continuous sections of wall. The walls
are insulated on the outside in order to reduce heat loss. Water circulating through the
tubes absorbs heat to produce steam, and it also helps to control combustion temperatures
without the need for excessive air, thus lowering air pollution control costs.
Waste-to-energy plants operate as either mass burn or refuse-derived fuel systems. A
mass burn system uses all the refuse, without prior treatment or preparation. A refuse-
derived fuel system separates combustible wastes from noncombustibles such as glass
and metal before burning. If a turbine is installed at the plant, both steam and electricity
can be produced in a process called cogeneration.
Waste-to-energy systems are more expensive to build and operate than plain incinerators
because of the need for special equipment and controls, highly skilled technical
personnel, and auxiliary fuel systems. On the other hand, the sale of generated steam or
electricity offsets much of the extra cost, and recovery of heat energy from refuse is a
viable solid-waste management option from both engineering and an economic point of
view. About 80 percent of municipal refuse incinerators in the United States are waste-to-
energy facilities.
Composting
Another method of treating municipal solid waste is composting, a biological process in
which the organic portion of refuse is allowed to decompose under carefully controlled
conditions. Microbes metabolize the organic waste material and reduce its volume by as
much as 50 percent. The stabilized product is called compost or humus. It resembles
potting soil in texture and odour and may be used as a soil conditioner or mulch.
Composting offers a method of processing and recycling both garbage and sewage sludge
in one operation. As more stringent environmental rules and siting constraints limit the
use of solid-waste incineration and landfill options, the application of composting is
likely to increase. The steps involved in the process include sorting and separating, size
reduction, and digestion of the refuse.
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The decomposable materials in refuse are isolated from glass, metal, and other inorganic
items through sorting and separating operations. These are carried out mechanically,
using differences in such physical characteristics of the refuse as size, density, and
magnetic properties. Shredding or pulverizing reduces the size of the waste articles,
resulting in a uniform mass of material. It is accomplished with hammer mills and rotary
shredders.
Sanitary landfill
Land disposal is the most common management strategy for municipal solid waste.
Refuse can be safely deposited in a sanitary landfill, a disposal site that is carefully
selected, designed, constructed, and operated to protect the environment and public
health. One of the most important factors relating to landfilling is that the buried waste
never comes in contact with surface water or groundwater. Engineering design
requirements include a minimum distance between the bottom of the landfill and the
seasonally high groundwater table. Most new landfills are required to have an
impermeable liner or barrier at the bottom, as well as a system of groundwater-
monitoring wells. Completed landfill sections must be capped with an impermeable cover
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to keep precipitation or surface runoff away from the buried waste. Bottom and cap liners
may be made of flexible plastic membranes, layers of clay soil, or a combination of both.
Recycling
Separating, recovering, and reusing components of solid waste that may still have
economic value is called recycling. One type of recycling is the recovery and reuse of
heat energy, a practice discussed separately in Incineration. Composting can also be
considered a recycling process, since it reclaims the organic parts of solid waste for reuse
as mulch or soil conditioner. Still other waste materials have potential for reuse. These
include paper, metal, glass, plastic, and rubber, and their recovery is discussed here.
Separation
Before any material can be recycled, it must be separated from the raw waste and sorted.
Separation can be accomplished at the source of the waste or at a central processing
facility. Source separation, also called curbside separation, is done by individual citizens
who collect newspapers, bottles, cans, and garbage separately and place them at the curb
for collection. Many communities allow ―commingling‖ of nonpaper recyclables (glass,
metal, and plastic). In either case, municipal collection of source-separated refuse is more
expensive than ordinary refuse collection.
In lieu of source separation, recyclable materials can be separated from garbage at
centralized mechanical processing plants. Experience has shown that the quality of
recyclables recovered from such facilities is lowered by contamination with moist
garbage and broken glass. The best practice, as now recognized, is to have citizens
separate refuse into a limited number of categories, including newspaper; magazines and
other wastepaper; commingled metals, glass, and plastics; and garbage and other
nonrecyclables. The newspaper, other paper wastes, and commingled recyclables are
collected separately from the other refuse and are processed at a centralized material
recycling facility, or MRF (pronounced ―murf‖ in waste-management jargon). A modern
MRF can process about 300 tons of recyclable wastes per day.
At a typical MRF, commingled recyclables are loaded onto a conveyor. Steel cans (―tin‖
cans are actually steel with only a thin coating of tin) are removed by an electromagnetic
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separator, and the remaining material passes over a vibrating screen in order to remove
broken glass. Next, the conveyor passes through an air classifier, which separates
aluminum and plastic containers from heavier glass containers. Glass is manually sorted
by colour, and aluminum cans are separated from plastics by an eddy-current separator,
which repels the aluminum from the conveyor belt.
Reuse
Recovered broken glass can be crushed and used in asphalt pavement. Colour-sorted
glass is crushed and sold to glass manufacturers as cullet, an essential ingredient in
glassmaking. Steel cans are baled and shipped to steel mills as scrap, and aluminum is
baled or compacted for reuse by smelters. Aluminum is one of the smallest components
of municipal solid waste, but it has the highest value as a recyclable material. Recycling
of plastic is a challenge, mostly because of the many different polymeric materials used
in its production. Mixed thermoplastics can be used only to make lower-quality products,
such as ―plastic lumber.‖
In the paper stream, old newspapers are sorted by hand on a conveyor belt in order to
remove corrugated materials and mixed papers. They are then baled or loose-loaded into
trailers for shipment to paper mills, where they are reused in the making of more
newspaper. Mixed paper is separated from corrugated paper for sale to tissue mills.
Although the processes of pulping, de-inking, and screening wastepaper are generally
more expensive than making paper from virgin wood fibres, the market for recycled
paper should improve as more processing plants are established.
Rubber is sometimes reclaimed from solid waste and shredded, reformed, and remolded
in a process called revulcanization, but it is usually not as strong as the original material.
Shredded rubber can be used as an additive in asphalt pavements, and discarded tires may
be employed as swings and other recreational structures for use by children in ―tire
playgrounds.‖ In general, the most difficult problem associated with the recycling of any
solid-waste material is finding applications and suitable markets. Recycling by itself will
not solve the growing problem of solid-waste management and disposal. There will
always be some unusable and completely valueless solid residue requiring final disposal.
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Thermal pollution
Thermal pollution is defined as sudden increase or decrease in temperature of a natural
body of water which may be ocean, lake, river or pond by human influence. This
normally occurs when a plant or facility takes in water from a natural resource and puts it
back with an altered temperature. Usually, these facilities use it as a cooling method for
their machinery or to help better produce their products.
2. Soil Erosion: Soil erosion is another major factor that causes thermal pollution.
Consistent soil erosion causes water bodies to rise, making them more exposed to
sunlight. The high temperature could prove fatal for aquatic biomes as it may give rise to
anaerobic conditions.
3. Deforestation: Trees and plants prevent sunlight from falling directly on lakes, ponds
or rivers. When deforestation takes place, these water bodies are directly exposed to
sunlight, thus absorbing more heat and raising its temperature. Deforestation is also a
main cause of the higher concentrations of greenhouse gases i.e. global warming in the
atmosphere.
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4. Runoff from Paved Surfaces: Urban runoff discharged to surface waters from paved
surfaces like roads and parking lots can make water warmer. During summer seasons, the
pavement gets quite hot, which creates warm runoff that gets into the sewer systems and
water bodies.
5. Natural Causes: Natural causes like volcanoes and geothermal activity under the
oceans and seas can trigger warm lava to raise the temperature of water bodies.
Lightening can also introduce massive amount of heat into the oceans. This means that
the overall temperature of the water source will rise, having significant impacts on the
environment.
3. Loss of Biodiversity: A dent in the biological activity in the water may cause
significant loss of biodiversity. Changes in the environment may cause certain species of
organisms to shift their base to some other place while their could be significant number
of species that may shift in because of warmer waters. Organisms that can adapt easily
may have an advantage over organisms that are not used to the warmer temperatures.
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4. Ecological Impact: A sudden thermal shock can result in mass killings of fish, insects,
plants or amphibians. Hotter water may prove favorable for some species while it could
be lethal for other species. Small water temperature increases the level of activity while
higher temperature decreases the level of activity. Many aquatic species are sensitive to
small temperature changes such as one degree Celsius that can cause significant changes
in organism metabolism and other adverse cellular biology effects.
6. Increases Metabolic Rate: Thermal pollution increases the metabolic rate of organisms
as increasing enzyme activity occurs that causes organisms to consume more food than
what is normally required, if their environment were not changed. It disrupts the stability
of food chain and alter the balance of species composition.
7. Migration: The warm water can also cause particular species of organisms to migrate
to suitable environment that would cater to its requirements for survival. This can result
in loss for those species that depend on them for their daily food as their food chain is
interrupted.
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Marine Pollution
Marine environment is submitted to contamination that comes in many different forms,
such as toxic chemicals (e.g., organic compounds, DDT, PCB, metals, pharmaceuticals,
gas), solid waste (e.g., plastics), increased nutrient (e.g., nitrates and phosphates) and
sediment inputs due to human activities (e.g., industry, agriculture, deforestation, sewage
discharge, aquaculture), radioactivity, oil spills, and discarded fishing nets. Marine
contamination changes the physical, chemical, and biological characteristics of the
oceans and coastal zones, and potentially threatens marine organism, ecosystems, and
biodiversity and affects thus the quality and productivity of marine ecosystems. In this
context, the contamination causing damage or negative impact on marine ecosystem is
called pollution. The ultimate effect of pollution on marine resources depends on the
form, intensity (acute or chronic), and location of the contamination, with some marine
environments, ecosystems, and species being more sensitive than others to pollution.
Direct discharge
Pollutants enter rivers and the sea directly from urban sewerage and industrial waste
discharges, sometimes in the form of hazardous and toxic wastes.
Inland mining for copper, gold, etc., is another source of marine pollution. Most of the
pollution is simply soil, which ends up in rivers flowing to the sea. However, some
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minerals discharged in the course of the mining can cause problems, such as copper, a
common industrial pollutant, which can interfere with the life history and development of
coral polyps. Mining has a poor environmental track record. For example, according to
the United States Environmental Protection Agency, mining has contaminated portions of
the headwaters of over 40% of watersheds in the western continental US. Much of this
pollution finishes up in the sea.
Land runoff
Surface runoff from farming, as well as urban runoff and runoff from the construction of
roads, buildings, ports, channels, and harbors, can carry soil and particles laden with
carbon, nitrogen, phosphorus, and minerals. This nutrient-rich water can cause fleshy
algae and phytoplankton to thrive in coastal areas; known as algal blooms, which have
the potential to create hypoxic conditions by using all available oxygen. In the coast of
southwest Florida, harmful algal blooms have existed for over 100 years. These algal
blooms have been a cause of species of fish, turtles, dolphins, and shrimp to die and
cause harmful effects on humans who swim in the water.
Polluted runoff from roads and highways can be a significant source of water pollution in
coastal areas. About 75% of the toxic chemicals that flow into Puget Sound are carried by
stormwater that runs off paved roads and driveways, rooftops, yards and other developed
land.
Ship
Ships can pollute waterways and oceans in many ways. Oil spills can have devastating
effects. While being toxic to marine life, polycyclic aromatic hydrocarbons (PAHs),
found in crude oil, are very difficult to clean up, and last for years in the sediment and
marine environment.
An oil spill in the sea will undergo a series of chemical, biological, and physical
processes which will lead to the degradation of the oil. The speed of these processes
depends to a large extent on the character of the oil, the ambient temperature, and other
environmental conditions. Heavy oils, i.e., oils with a high portion of hydrocarbons with
high molecular weight, will degrade more slowly than lighter oils. In addition, at high
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Discharge of cargo residues from bulk carriers can pollute ports, waterways, and oceans.
In many instances vessels intentionally discharge illegal wastes despite foreign and
domestic regulation prohibiting such actions. An absence of national standards provides
an incentive for some cruise liners to dump waste in places where the penalties are
inadequate. It has been estimated that container ships lose over 10,000 containers at sea
each year (usually during storms). Ships also create noise pollution that disturbs natural
wildlife, and water from ballast tanks can spread harmful algae and other invasive species
Atmospheric pollution
Another pathway of pollution occurs through the atmosphere. Wind-blown dust and
debris, including plastic bags, are blown seaward from landfills and other areas.
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Because deep sea mining is a relatively new field, the complete consequences of full-
scale mining operations are unknown. However, experts are certain that removal of parts
of the sea floor will result in disturbances to the benthic layer, increased toxicity of the
water column, and sediment plumes from tailings. Removing parts of the sea floor
disturbs the habitat of benthic organisms, possibly, depending on the type of mining and
location, causing permanent disturbances. Aside from direct impact of mining the area,
leakage, spills, and corrosion would alter the mining area's chemical makeup.
Types of pollution
Acidification
The oceans are normally a natural carbon sink, absorbing carbon dioxide from the
atmosphere. Because the levels of atmospheric carbon dioxide are increasing, the oceans
are becoming more acidic. The potential consequences of ocean acidification are not fully
understood, but there are concerns that structures made of calcium carbonate may
become vulnerable to dissolution, affecting corals and the ability of shellfish to form
shells.
Eutrophication
Eutrophication is an increase in chemical nutrients, typically compounds containing
nitrogen or phosphorus, in an ecosystem. It can result in an increase in the ecosystem's
primary productivity (excessive plant growth and decay), and further effects including
lack of oxygen and severe reductions in water quality, fish, and other animal populations.
Plastic debris
Marine debris is mainly discarded human rubbish which floats on, or is suspended in the
ocean. Eighty percent of marine debris is plastic – a component that has been rapidly
accumulating since the end of World War II. The mass of plastic in the oceans may be as
high as 100,000,000 tonnes.
Toxins
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Examples of persistent toxins are PCBs, DDT, TBT, pesticides, furans, dioxins, phenols,
and radioactive waste. Heavy metals are metallic chemical elements that have a relatively
high density and are toxic or poisonous at low concentrations. Examples are mercury,
lead, nickel, arsenic, and cadmium. Such toxins can accumulate in the tissues of many
species of aquatic life in a process called bioaccumulation.
Underwater noise
Marine life can be susceptible to noise or the sound pollution from sources such as
passing ships, oil exploration seismic surveys, and naval low-frequency active sonar.
Sound travels more rapidly and over larger distances in the sea than in the atmosphere.
Marine animals, such as cetaceans, often have weak eyesight, and live in a world largely
defined by acoustic information. This applies also to many deeper sea fish, who live in a
world of darkness. Between 1950 and 1975, ambient noise at one location in the Pacific
Ocean increased by about ten decibels (that is a tenfold increase in intensity).
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Noise Pollution
Noise is part of our environment. With progress in industrialization, the noise level has
been rising continuously. In the 19th century the development of the steam engines,
petrol engine and machines in factories resulted in increasingly noisy environment. In the
20th century this was further accelerated by introduction of diesel engine, jet engines,
turboprop, high tech machineries, construction site machineries and automobile traffic.
Noise has been recognized as one of the dimensions of pollution which brings about
degradation of the environment and creates health and communication hazards.
SOUND AND HUMAN ACOUSTICS
Sound consists of wave motion in an elastic medium such as air, water or solids (e.g.,
metals, plastics, wood, bricks, etc.). Sound waves travel through the medium from the
source to the recipient or listener.
The rate of the oscillation of the medium is known as the frequency of the sound, the unit
being Hertz (Hz) or cycles per second. The frequency is a measure of the pitch of the
sound received by the listener. High frequencies mean high pitched sounds which are
more irritating to the individual than low frequencies. The second parameter of sound is
sound pressure which is measure in Newton per sq. meter (N/m2). The third parameter on
sound is its intensity, expressed in watts per sq. metre i.e., the quantum of sound energy
that flows through unit area of the medium in unit time.
The human ear receives sound waves which set tip oscillations in the ear drum (tympanic
membrane). These oscillations cause movement of three small bones in the middle ear
behind the ear drum. These then pass through the fluid in the inner ear to the auditory
nerve and finally transmitted to the brain. The oscillations or sound are identified and
interpreted in the brain, which can select sounds into different categories—speech, music,
noises, etc.
The sensitivity of the ear varies from person to person. With ageing, people lose hearing
power gradually. A young person, 18 year old, with normal hearing, has audio range
between 20 Hz and 20,000 Hz. The audio sense is sharpest in the frequency range 2000
8500 Hz.
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As mentioned before, sound pressure and sound intensity are two important parameters of
noise. The common scientific acoustic unit is the Decibel (dB). It is not an absolute
physical unit like volt, meter, etc. but is a ratio, expressed in logarithmic scale relative to
a reference sound pressure level.
The reference intensity used is the threshold of hearing which means sound which can be
first heard at a sound pressure of 2×10–5 Newton per sq. meter or sound intensity of 10–12
watts per sq. meter. Noise meters have been designed for noise measurement from low to
high frequencies, characteristic of human ear capacity. These meters record the dB scale
for routine measurement of general noise levels. Refined noise meters have been
developed to take care of peak noise levels, duration of noise exposure and quality of
noise which are aspects of specified noise situation.
NOISE CLASSIFICATION
There are broadly three categories of noise:
(i) Transport noise,
(ii) Occupational noise, and
(iii) Neighbourhood noise.
Transport Noise
Transport noise can be further sub-divided into (i) Road traffic noise, (ii) Aircraft and
(iii) Rail traffic noise.
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Aircraft Noise
The noise levels have peak values when aircrafts fly low and overhead or take off and
land at airports.
Rail Traffic
It is less of a nuisance as compared to the previous types of traffic noise.
Occupational Noise
Industrial workers are exposed to noisy working environment for 48 hours a week (8 hrs.
a day for 6 days a week). Some typical occupational noise levels are given below:
Table 8.2: Occupational Noise Level
Millions of workers suffer from progressive hearing damage and become prone to
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accidents under their working conditions. Their working efficiency is also affected.
Neighbourhood Noise
Loud TV and radio sets, loud cassettes, loudspeakers in public functions, disco music,
etc., are sources of neighbourhood noise which disturb and irritate the general public and
alsoharm the patients.
NOISE POLLUTION HAZARDS
The human ear drum is struck by noise in the form of airborne mechanical energy. While
the tolerable conversation level is 65 dB at a distance of 1 metre, 125 dB gives the
sensation of pain in the ear and 150 dB might be a killer.
High intensity noise for continuous periods is the major cause for ear damage. If a noise
level exceeding 90 dB in the mid-frequency range reaches the ear for more than a few
minutes, then the sensitivity of the ear is reduced.
Noise pollution can cause pathological or psychological disorders. High frequencies or
ultrasonic sound above the audible range can affect the semi-circular canals of the inner
ear and make one suffer from nausea and dizziness. Mid-audible frequencies can lead to
resonance in the skull and thereby affect the brain and nervous system. Moderate
vibration can also cause pain, numbness and cyanosis (blue colouration) of fingers while
severe vibration results damage to bones and joints in the bands with swelling and
stiffness.
In industrial and other establishments the general impact of noise pollution is lower
efficiency, reduced work rate and higher potential for accidents and injuries.
In residential areas even low frequency noise of 50–60 dB at night disturbs sleep,
particularly among the aged people, causing adverse effect on health.
Children, exposed to excessive noise, show signs of behavioural disorder which in later
age develop into destructive nature and neurotic disorders in the adult.
Excessive noise is one of the major factors for chronic exhaustion and tension in our
daily lives. This may explain why more and more people tend to become addicted to
alcohol, tobacco and drugs.
Noise pollution has also impact on travel of migratory birds from winter to tropical
climate.
PERMISSIBLE NOISE LEVELS
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In this age many people work and live in environment where the noise level is not
hazardous. But over the years they suffer from progressive hearing loss and
psychological hazards. The maximum permissible noise levels are summarised as
follows:
Table 8.3: Maximum Permissible Noise Levels
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Increased distance between source and receiver by zoning of noisy industrial areas, bus
terminals and railway stations, aerodromes etc. away from the resi-dential areas would go
a long way in minimising noise pollution. There should be silence zones near the
residential areas, educational institu-tions and above all, near hospitals.
(4) Sound Insulation at Construction Stages:
(a) Sound travels through the cracks that get left between the door and the wall. For
reducing noise, this space (jamb frame gap) should be packed with sound absorbing
material.
(b) Sound insulation can be done by constructing windows with double or triple panes of
glass and filling the gaps with sound absorbing materials.
(c) Acoustical tiles, hair felt, perforated plywood etc. can be fixed on walls, ceil-ings,
floors etc. to reduce noise (especially for sound proof recording rooms etc.)
(5) Planting of Trees:
Planting green trees and shrubs along roads, hospitals, educational institutions etc. help in
noise reduction to a considerable extent.
(6) Legislative Measures:
Strict legislative measures need to be enforced to curb the menace of noise pol-lution.
Some of these measures could be:
(a) Minimum use of loudspeakers and amplifiers especially near silence zones.
(b) Banning pressure horns in automobiles.
(c) Framing a separate Noise Pollution Act.
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Radioactive Pollution
Radioactive pollution occurs when there is presence or depositions of radioactive
materials in the atmosphere or environment, especially where their presence is accidental
and when it presents an environmental threat due to radioactive decay. The destruction
caused by the radioactive materials is because of the emissions of hazardous ionizing
radiation (radioactive decay) like beta or alpha particles, gamma rays or neurons in the
environment where they exist.
Radioactivity
The process by which certain elements undergo spontaneous disintegration, accompanied
by emission of radiations, is known as radioactivity. The elements are called radioactive
elements. Examples are: uranium, thorium, radium etc.
and mass 4 units so that they are identical with helium nuclei . Alpha particles have
ionizing power i.e., they produce ion pairs their course in air.
Beta particles (β): These are identical with electrons. They are more penetrating than α-
rays i.e., they travel a little further than the latter in air but are absorbed by a thin layer of
metal e.g., aluminium foil. The ionizing power of the β-particles is less than that of α-
rays.
Gamma rays (γ): These consist of short-wave electromagnetic radiation or photons
emitted by a nucleus in an excited state. Gamma rays, being electromagnetic in nature,
have no mass and so cannot be thought of as particles. Their penetrating power is greater
than those of α- and β-particles. Thus while α-particles are stopped in air (3–9 cm) or thin
Al-foil (5 mm thick), γ rays can pass through 25cm of iron and 8 cm of lead.
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