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Chemical Process Calculations

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114 views5 pages

Chemical Process Calculations

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Florence
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1. Strawberries contain about 15 % Solids and 85 % water.

To make a strawberry jam, crushed


strawberries and sugar are mixed in a 45:55 ratio, and the mixture is heated to evaporate water
until the residue contain one-third water by mass. Calculate how many grams of strawberries are
needed to make a kilogram of jam.

F2, sugar W, H2O

F1, crushed strawberries

15 % Solids Mixer Evaporator P, Jam

85 % water 1/3 water by mass



= 

Required: g of F1 per kg P

Basis: 1 kg of P (1000 g)

Solid balance @ whole system

0.15 F1 + F2 = iiiL

F1 = 
F2

F1 = 485.83 g of strawberries

2. Fresh feed stream flowing at 100 kg/h contains 20 wt% KNO3 and the balance water. The fresh
feed stream is combined with a recycle stream and is fed to an evaporator. The concentrated
liquid solution leave the evaporator containing 50 wt % KNO3 is fed to a crystallizer. The crystals
obtained from the crystallizer is wet and contains 4 wt % water. The liquid from the crystallizer
constitute the recycle stream and contains 0.6 kg KNO3 per 1 kg water. Calculate:
a) Weight of product crystal collected
b) Weight of water removed in the evaporator.
c) Weight of the recycled stream
F = 100 kg/h W, H2O

20 wt % KNO3

80 wt% water 50 % wt% KNO3


Evaporator Crystallizer
C

P KNO3

4 % H2O

0.6 Kg KNO3 / Kg H2O % H2O

Required: C, W, R

Basis: 1 hr operation

KNO3 balance @ whole system

0.2(100) = (1 – 0.04)(P )

P = 20.83 kg

OMB @ whole system

100 = W + 20.83

W = 79.17 kg
@ crystallizer
OMB: C = 20.83 + R
ith
KNO3 balance: 0.5(C ) = 0.96(20.83) + th
R
R = 76.68 kg

3. A stream of air at 40 oC and 1 atm has a dew point of 20 oC. Determine the following:
a. Molar humidity
b. Absolute humidity
c. Relative Humidity
d. % Humidity
e. % (mole) water vapor

 tᄀᄀ
ln (Pv) = 18.3036 -
ᄀt
at 40 oC, Pv = 54.75 mm Hg
at 20 oC, Pv = 17.19 mm Hg

Pp = Pv at 20 oC

t
Hm = hi t
= 0.023

th
Habs = Hm( tᶈ
L = 0.023( L = 0.014

t
RH =  t 
x 100 = 31.40 %
t t.h2t iti
%H = t th th2 thᶈ
x 100 =  t  x 100 = 29.62 %
hi  t 

t
% H2O = hi
x 100 = 2.26 %

4. Dry air containing at 90 oC and 1 atm is humidified by spraying water and gas mixture leaves the
humidifier saturated 60 oC and 1 atm. Calculate the moles of water added per 100 moles of dry air
entering.

Dry air Saturated air

90 oC, 1 atm Humidifier 60 oC, 1 atm

E L

Required: W/100 mole dry air

Hm E = 0

Using Antoine eq. At 60 oC, Pv = 148.39 mm Hg

t
Hm L = hi t
= 0.243

t ii t tᶈ t t
ii t tᶈ
= (0.243 – 0) t tᶈ
x ii t tᶈ
= ii t tᶈ

5. Contaminated air contains 3 mol% acetone and 2 mol% water vapor. The air was sent to an
absorber to completely remove the acetone using water as absorber. The air leaving the absorber
contains 0.5 mol % water and the liquid leaving the system contains 19 wt% acetone and 81 wt %
water. Calculate the weight of water used per 100 mol of contaminated air
Contaminated air E
3 mol % C3H6O
2 mol % H2O air, L
0.5 mol % H2O
Absorber 99.5 mol % dry air
R
19 wt % C3H6O S H2O
81 wt % water

Required: S / 100 mols of E

Basis: 100 mols of E

Dry air balance: (1 – 0.03 - 0.02)(100) = 0.995(L)


L = 95.5 mol
Acetone recovered: 0.03(100) = 3 mols

0.19(R ) = 3(58)

R = 915.8 g

Water balance

S = 0.81(915.8) + 0.005(95.5)(18)

S = 750.4 g

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