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Red Dye SDS

Red Dye Safety Data Sheet.

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0% found this document useful (0 votes)
1K views20 pages

Red Dye SDS

Red Dye Safety Data Sheet.

Uploaded by

alphading
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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DYEGUARD® RED DX

(Version 9) Issue date: August 2014 M747


Material Safety Data Sheet
SECTION 1: IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

1.1. PRODUCT IDENTIFIER

Product Name: DYEGUARD® RED DX

1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST

Identified Uses: Manufacture of substance


Distribution of substance
Formulation & (re)packing of substances and mixtures
Uses in coatings
Use as a fuel
Use as a functional fluid
Lubricants
Laboratories

Uses advised against: This product is not recommended for any industrial, professional or consumer
use other than the Identified Uses above.

1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET

Supplier: John Hogg Technical Solutions


Mellors Road
Trafford Park
Manchester
M17 1PB
UK

Supplier General Contact: + 44 161 872 5611


E-mail: info@johnhogg.co.uk
Fax Number: + 44 161 848 8206

1.4. EMERGENCY TELEPHONE NUMBER

24 Hour Environmental / Emergency


Telephone: +44 (0)207 858 1228

SECTION 2: HAZARDS IDENTIFICATION

2.1. CLASSIFICATION OF SUBSTANCE OR MIXTURE

Classification according to Regulation (EC) No. 1272/2008 (CLP)


Flammable liquid: Category 3: H226: Flammable liquid and vapor.
Acute dermal toxicant: Category 4: H312: Harmful in contact with skin.
Skin irritation: Category 2: H315: Causes skin irritation.
Eye irritation: Category 2: H319: Causes serious eye irritation.
Target organ toxicant (respiratory irritant): Category 3: H335: May cause respiratory irritation.
Specific target organ toxicity following single exposure (Central Nervous System): Category: 3, H336: May cause
drowsiness or dizziness.
Carcinogen: Category 2, H351: Suspected of causing cancer.
Target organ toxicant (repeated exposure): Category 2: H373: May cause damage to organs through prolonged
or repeated exposure.
Chronic hazards to the aquatic environment: Category: 2, H411: Toxic to aquatic life with long lasting effects.

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DYEGUARD® RED DX
(Version 9) Issue date: August 2014 M747
Material Safety Data Sheet
Classification according to EU Directive 1999/45/EC (DPD)
R10: Flammable
R20/21: Harmful by inhalation and in contact with skin.
R38: Irritating to skin.
R40: Limited evidence of a carcinogenic effect.
R51/53: Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment
R67: Vapours may cause drowsiness and dizziness.

2.2. LABEL ELEMENTS

Label elements according to Regulation (EC) No. 1272/2008 (CLP)

Pictograms:

Signal Word: Warning

Hazard Statements:
H226: Flammable liquid and vapor.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H336: May cause drowsiness or dizziness.
H351: Suspected of causing cancer.
H373: May cause damage to organs through prolonged or repeated exposure.
H411: Toxic to aquatic life with long lasting effects.

Precautionary Statements (Prevention)


P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273: Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye protection/face protection.

Precautionary Statements (Response)


P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P331 Do NOT induce vomiting.

Precautionary Statements (Storage)


P405 Store locked up.

Precautionary Statements (Disposal)


P501: Dispose of contents/container to hazardous or special waste collection point.

2.3. OTHER HAZARDS

Material can accumulate static charges which may cause an ignition.

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DYEGUARD® RED DX
(Version 9) Issue date: August 2014 M747
Material Safety Data Sheet
SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS

3.2. MIXTURES

CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]

NAME
CAS No. REACH No. EU No. CLASSIFICATION CONTENT

C.I. SOLVENT RED 164


92257-31-3 Pre-Registered 296-120-8 Carc. Cat 2: H351 60 – 65%

XYLENES
1330-20-7 01-2119488216-32-xxxx 215-535-7 Flam. Liq. 3: H226, ca30%
Acute Tox. 4: H312,
Skin Irrit. 2: H315,
Eye Irrit. 2: H319,
STOT SE 3: H335,
STOT RE 2: H373,
Asp. Tox. 1: H304

HYDROCARBONS, C10, AROMATICS, >1% NAPHTHALENE


HYDROCARBONS, C10 – C13, AROMATICS, >1% NAPHTHALENE
------ 01-2119463588-24-xxxx 919-284-0} Carc. Cat 2: H351 ca10%
------ 01-2119451151-53-xxxx 926-273-4} Aspiration Cat 1: H304
STOT SE Cat 3: H336
(drowsiness and dizziness)
Aquatic Chronic Cat 2: H411

Reportable hazardous constituent(s) contained in UVCB- and/or multi-constituent substance(s) complying


with the classification criteria and/or with an exposure limit (OEL).

ETHYL BENZENE
100-41-4 ------- 202-849-4 Acute Tox. 4: H332, <5%
Flam. Liq. 2: H225

NAPHTHALENE
91-20-3 ------- 202-049-5 Acute Tox. 4: H302, <5%
Carc. 2: H351
Aquatic Chronic 1: H410

CLASSIFICATION ACCORDING TO DIRECTIVE 1999/45/EC

NAME
CAS No. REACH No. EU No. CLASSIFICATION CONTENT

C.I. SOLVENT RED 164


92257-31-3 Pre-Registered 296-120-8 Carc. Cat 3: R40 60 – 65%

XYLENES
1330-20-7 01-2119488216-32-xxxx 215-535-7 R10, Xn; R20/21,
Xi; R38 ca30%

HYDROCARBONS, C10, AROMATICS, >1% NAPHTHALENE


HYDROCARBONS, C10 – C13, AROMATICS, >1% NAPHTHALENE
------ 01-2119463588-24-xxxx 919-284-0} Carc. Cat 3; R40, ca10%
------ 01-2119451151-53-xxxx 926-273-4} Xn; R65, R66, R67,

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DYEGUARD® RED DX
(Version 9) Issue date: August 2014 M747
Material Safety Data Sheet
Reportable hazardous constituent(s) contained in UVCB- and/or multi-constituent substance(s) complying
with the classification criteria and/or with an exposure limit (OEL).

ETHYL BENZENE
100-41-4 ------- 202-849-4 F:R11, Xn:R20 <5%

NAPHTHALENE
91-20-3 ------- 202-049-5 Xn;R22, <5%
Xn;Carc. Cat. 3;R40,
N;R50/53

Note: See Section 16 for full text of R-Phrases and H-Statements

SECTION 4: FIRST AID MEASURES

4.1. DESCRIPTION OF FIRST AID MEASURES

INHALATION
In event of over-exposure remove individual to fresh air, taking steps necessary to protect the rescuer.
Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek
immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use
mouth-to-mouth resuscitation.

SKIN CONTACT
Remove contaminated clothing as soon as possible. Wash exposed skin thoroughly with soap and water. If
irritation persists, consult a physician. Launder contaminated clothing before re-use. Badly contaminated leather
shoes or clothing should be discarded.

EYE CONTACT
Immediately wash with fresh water for at least 15 minutes and seek MEDICAL ATTENTION IMMEDIATELY.

INGESTION
Seek immediate medical attention. Do not induce vomiting.

4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Itching, pain, redness, swelling of skin. Breathing difficulties.

4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED
If ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.
This light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very high
exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart-
stimulating substances like epinephrine. Administration of such substances should be avoided.

SECTION 5: FIRE FIGHTING MEASURES

5.1. EXTINGUISHING MEDIA

Suitable Extinguishing Media: Use dry chemical, foam or carbon dioxide (CO2) to extinguish flames.

Unsuitable Extinguishing Media: Straight streams of water.

5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE

Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon.

5.3. ADVICE FOR FIREFIGHTERS

Fire Fighting Instructions: FLAMMABLE. Evacuate Area. Prevent run-off from fire control or dilution from
entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in
enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and
to protect personnel.

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DYEGUARD® RED DX
(Version 9) Issue date: August 2014 M747
Material Safety Data Sheet
Unusual Fire Hazards: Hazardous material. Fire-fighters should consider protective equipment indicated in
Section 8.

5.4. FLAMMABILITY PROPERTIES

Flash point: >28°C


Upper / Lower Flammable Limits: 7.0 – 0.96 % volume in air
Autoignition Temperature: >425°C

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES

NOTIFICATION PROCEDURES
In the event of a spill or accidental release, notify relevant authorities in accordance will all applicable regulations.

PROTECTIVE MEASURES
Avoid contact with spilled material. See Section 5 for fire fighting information. See Section 8 for advice on the
minimum requirements for personal protective equipment. See the Hazard Identification Section for Significant
Hazards. Additional protective measures may be necessary, depending on the specific circumstances and/or the
expert judgement of the emergency responders.
Small spills: normal antistatic work clothes are usually adequate.
Large spills: full body suit of chemical resistant, antistatic material is recommended.

6.2. ENVIRONMENTAL PRECAUTIONS


Large spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers,
basements or confined areas.

6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP


Land Spill: Remove all sources of ignition. Stop leak if you can do so without risk. Do not touch or walk through
spilled material. Water spray may reduce vapour, but may not prevent ignition in enclosed spaces. Absorb with
earth, sand or other non-combustible material and recover as much of the product itself as possible by such
methods as vacuuming, using an approved vacuum pump powered by a flame proof motor. Recover residual
fluids by use of absorbent materials. Remove contaminated items including contaminated soil and place in proper
containers for disposal.

Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Remove from the
surface by skimming or with suitable absorbents.

6.4. REFERENCES TO OTHER SECTIONS


See Section 6.1.

SECTION 7: HANDLING & STORAGE

7.1. PRECAUTIONS FOR SAFE HANDLING

Avoid contact with skin. Avoid contact with eyes. Prevent exposure to ignition sources, for example use non-
sparking tools and explosion-proof equipment. Prevent small spills and leakage to avoid slip hazard. Material can
accumulate static charges which may cause an electrical spark (ignition source). Use proper bonding and/or
ground procedures. However, bonding and grounds may not eliminate the hazard from static accumulation.
Consult local applicable standards for guidance.

Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static
accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a
semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or
semiconductive, the precautions are the same. A number of factors, for example liquid temperature, presence of
contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid.

7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES

The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container
closed. Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool,

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DYEGUARD® RED DX
(Version 9) Issue date: August 2014 M747
Material Safety Data Sheet
well-ventilated area. Storage containers should be earthed and bonded. Fixed storage containers, transfer
containers and associated equipment should be earthed and bonded to prevent accumulation of static charge.

Suitable Containers/Packing: Tank Trucks; Railcars; Barges; Drums


Suitable Materials and Coatings (Chemical Compatibility): Carbon Steel; Stainless Steel; Polyester; Teflon
Unsuitable Materials and Coatings: Butyl Rubber; Natural Rubber; Ethylene-propylene-diene monomer
(EPDM); Polystyrene; Polyethylene; Polypropylene; Polyacrylonitrile

7.3. SPECIFIC END USES


Section 1 informs about identified end-uses.

SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. CONTROL PARAMETERS

EXPOSURE LIMIT VALUES

Exposure limits/standards (Note: Exposure limits are not additive)

Substance Standard 8 hour TWA STEL (15min)


ppm mg/m³ ppm mg/m³

Xylenes Supplier 100 434


Mixed Xylenes Austria 50 221 100 442
Mixed Xylenes Belgium 50 221 100 442
Mixed Xylenes Canada - Québec 100 434 150 651
Mixed Xylenes Denmark 25 109 50 218
Mixed Xylenes European Union 50 221 100 442
Mixed Xylenes France 50 221 100 442
Mixed Xylenes Germany (AGS) 100 440 200 (1) 880 (1)
Mixed Xylenes Germany (DFG) 100 440 200 880
Mixed Xylenes Hungary 221 442
Mixed Xylenes Italy 50 221 100 442
Mixed Xylenes Japan 100
Mixed Xylenes Poland 100
Mixed Xylenes Singapore 100 434 150 651
Mixed Xylenes Spain 50 221 100 442
Mixed Xylenes Sweden 50 200 100 450
Mixed Xylenes Switzerland 100 435 200 870
Mixed Xylenes The Netherlands 210 442
Mixed Xylenes USA - NIOSH 100 435 150 (1) 655 (1)
Mixed Xylenes USA - OSHA 100 435
Mixed Xylenes United Kingdom 50 220 100 441
Ethyl Benzene Austria 100 440 200 880
Ethyl Benzene Belgium 100 442 125 551
Ethyl Benzene Canada - Québec 100 434 125 543

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DYEGUARD® RED DX
(Version 9) Issue date: August 2014 M747
Material Safety Data Sheet
Ethyl Benzene Denmark 50 217 100 434
Ethyl Benzene European Union 100 442 200 884
Ethyl Benzene France 20 88,4 100 442
Ethyl Benzene Germany (AGS) 100 440 200 (1) 880 (1)
Ethyl Benzene Germany (DFG) 20 88 40 (1) 176 (1)
Ethyl Benzene Hungary 442 884
Ethyl Benzene Italy 100 442 200 884
Ethyl Benzene Japan
Ethyl Benzene Poland 200 400
Ethyl Benzene Singapore 100 434 125 543
Ethyl Benzene Spain 100 441 200 884
Ethyl Benzene Sweden 50 200 100 450
Ethyl Benzene Switzerland 100 435 100 435
Ethyl Benzene The Netherlands 215 430
Ethyl Benzene USA - NIOSH 100 435 125 (1) 545 (1)
Ethyl Benzene USA - OSHA 100 435
Ethyl Benzene United Kingdom 100 441 125 552

Remarks:
European Union: Bold-type: Indicative Occupational Exposure Limit Values and Limit Values for Occupational
Exposure
France: Bold type: Restrictive statutory limit values
Germany (AGS): (1) 15 minutes average value
Germany (DFG): (1) 15 minutes average value
Spain: Ethyl Benzene - skin
Italy: skin
USA – NIOSH: (1) 15 minutes average value
Biological Limits

Substance Specimen Sampling Time Limit Determinant Source


Mixed Xylenes Creatinine in End of Shift 650 mmol/mol Methyl hippuric UK BMGV
urine acid

DERIVED NO EFFECT LEVEL (DNEL)/DERIVED MINIMAL EFFECT LEVEL (DMEL)

Worker
Substance Name Dermal Inhalation
Mixed Xylenes 180 mg/kg bw/day DNEL, Chronic 77 mg/m3 DNEL, Chronic
Exposure, Systemic Effects Exposure, Systemic Effects

Consumer
Substance Name Dermal Inhalation Oral
Mixed Xylene 108 mg/kg bw/day DNEL, 14.8 mg/m3 DNEL, 1.6 mg/kg bw/day
Chronic Exposure, Chronic Exposure, DNEL, Chronic
Systemic Effects Systemic Effects Exposure, Systemic
Effects

Note: The Derived No Effect Level (DNEL) is an estimated safe level of exposure that is derived from toxicity data
in accord with specific guidance within the European REACH regulation. The DNEL may differ from an
Occupational Exposure Limit (OEL) for the same chemical. OELs may be recommended by an individual
company, a governmental regulatory body or an expert organization, such as the Scientific Committee for

John Hogg Technical Solutions Limited P 7 of 20


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DYEGUARD® RED DX
(Version 9) Issue date: August 2014 M747
Material Safety Data Sheet
Occupational Exposure Limits (SCOEL) or the American Conference of Governmental Industrial Hygienists
(ACGIH). OELs are considered to be safe exposure levels for a typical worker in an occupational setting for an 8-
hour work shift, 40 hour work week, as a time weighted average (TWA) or a 15 minute short-term exposure limit
(STEL). While also considered to be protective of health, OELs are derived by a process different from that of
REACH.

PREDICTED NO EFFECT CONCENTRATION (PNEC)

Substance Name Aqua Aqua Aqua Sewage Sediment Soil Oral


(fresh (marine (intermittent treatment (secondary
water) water) release) plant poisoning)
Mixed Xylenes 0.327 0.327 0.327 mg/l 6.58 mg/l 12.46 mg/kg 2.31 mg/kg NA
mg/l mg/l (dry wt)

8.2. EXPOSURE CONTROLS

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider: Use explosion-proof ventilation equipment. Adequate ventilation should be
provided whenever the material is heated or mists are generated.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use with
this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level
which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use,
and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be
considered for this material include:
Half-face filter respirator Type A filter material, European Committee for Standardization (CEN) standards EN
136, 140 and 405 provide respirator masks and EN 149 and 143 provide filter recommendations.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour
warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer
data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the
glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect
and replace worn or damaged gloves.
If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with forearms is
likely, wear gauntlet-style gloves. Nitrile, CEN standards EN 420 and EN 374 provide general requirements and
lists of glove types.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling
the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment
to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good
housekeeping.

ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.

8.1. CONTROL PARAMETERS

EXPOSURE LIMIT VALUES

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Material Safety Data Sheet

Exposure limits/standards (Note: Exposure limits are not additive)

Substance Standard 8 hour TWA STEL (15min)


ppm mg/m³ ppm mg/m³

Hydrocarbons, C10, Supplier 17 100


aromatics, >1% naphthalene
Hydrocarbons, C10–C13, Supplier 8 50
aromatics, >1% naphthalene
Naphthalene Austria 10 50
Naphthalene Belgium 10 53 15 80
Naphthalene Canada - Québec 10 52 15 79
Naphthalene Denmark 10 50 20 100
Naphthalene European Union 10 50
Naphthalene France 10 50
Naphthalene Germany (AGS) 0,1 0,5 inhalable 0,1 0,5 inhalable
aerosol aerosol
Naphthalene Germany (DFG)
Naphthalene Hungary 50
Naphthalene Italy 10 50
Naphthalene Japan
Naphthalene Poland 20 50
Naphthalene Singapore 10 52 15 79
Naphthalene Spain 10 53 15 80
Naphthalene Sweden 10 50 15 80
Naphthalene Switzerland 10 50
Naphthalene The Netherlands 50 80
Naphthalene USA - NIOSH 10 50 15 (1) 75 (1)
Naphthalene USA - OSHA 10 50
Naphthalene United Kingdom (10) (53) (15) (80)

Remarks:
European Union: Indicative Occupational Exposure Limit Values, proposal [5] (for references see bibliography)
Germany (AGS): (1) 15 minutes average value
Spain: skin
USA – NIOSH: (1) 15 minutes average value
United Kingdom: The UK Advisory Committee on Toxic Substances has expressed concern that, for the OELs
shown in parentheses, health may not be adequately protected because of doubts that the limit was not soundly-
based. These OELs were included in the published UK 2002 list and its 2003 supplement, but are omitted from the
published 2005 list.

Biological Limits

Substance Specimen Sampling Time Limit Determinant Source


Naphthalene Creatinine in End of Shift 4µmol/mol 1-Hydroxypyrene UK BMGV
urine

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DERIVED NO EFFECT LEVEL (DNEL)/DERIVED MINIMAL EFFECT LEVEL (DMEL)

Worker
Substance Name Dermal Inhalation
Hydrocarbons, C10, aromatics, 12.5 mg/kg bw/day DNEL, Chronic 150 mg/m3 DNEL, Chronic
>1% naphthalene Exposure, Systemic Effects Exposure, Systemic Effects
Hydrocarbons, C10-C13, 12.5 mg/kg bw/day DNEL, Chronic 151 mg/m3 DNEL, Chronic
aromatics, >1% naphthalene Exposure, Systemic Effects Exposure, Systemic Effects

Consumer
Substance Name Dermal Inhalation Oral
Hydrocarbons, C10, aromatics, 7.5 mg/kg bw/day DNEL, 32 mg/m3 DNEL, 7.5 mg/kg bw/day
>1% naphthalene Chronic Exposure, Chronic Exposure, DNEL, Chronic
Systemic Effects Systemic Effects Exposure, Systemic
Effects
Hydrocarbons, C10-C13, 7.5 mg/kg bw/day DNEL, 32 mg/m3 DNEL, 7.5 mg/kg bw/day
aromatics, >1% naphthalene Chronic Exposure, Chronic Exposure, DNEL, Chronic
Systemic Effects Systemic Effects Exposure, Systemic
Effects

Note: The Derived No Effect Level (DNEL) is an estimated safe level of exposure that is derived from toxicity data
in accord with specific guidance within the European REACH regulation. The DNEL may differ from an
Occupational Exposure Limit (OEL) for the same chemical. OELs may be recommended by an individual
company, a governmental regulatory body or an expert organization, such as the Scientific Committee for
Occupational Exposure Limits (SCOEL) or the American Conference of Governmental Industrial Hygienists
(ACGIH). OELs are considered to be safe exposure levels for a typical worker in an occupational setting for an 8-
hour work shift, 40 hour work week, as a time weighted average (TWA) or a 15 minute short-term exposure limit
(STEL). While also considered to be protective of health, OELs are derived by a process different from that of
REACH.

PREDICTED NO EFFECT CONCENTRATION (PNEC)

Substance Name Aqua Aqua Aqua Sewage Sediment Soil Oral


(fresh (marine (intermittent treatment (secondary
water) water) release) plant poisoning)
Hydrocarbons, C10, NA NA NA NA NA NA NA
aromatics, >1%
naphthalene
Hydrocarbons, C10- NA NA NA NA NA NA NA
C13, aromatics, >1%
naphthalene

8.2. EXPOSURE CONTROLS

ENGINEERING CONTROLS

The level of protection and types of controls necessary will vary depending upon potential exposure conditions.
Control measures to consider: Use explosion-proof ventilation equipment. Adequate ventilation should be
provided whenever the material is heated or mists are generated.

PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications,
handling practices, concentration and ventilation. Information on the selection of protective equipment for use with
this material, as provided below, is based upon intended, normal usage.

Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level
which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use,
and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be
considered for this material include:

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DYEGUARD® RED DX
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Material Safety Data Sheet
Half-face filter respirator Type A filter material, European Committee for Standardization (CEN) standards EN
136, 140 and 405 provide respirator masks and EN 149 and 143 provide filter recommendations.

For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.
Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour
warning properties are poor, or if air purifying filter capacity/rating may be exceeded.

Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer
data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the
glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect
and replace worn or damaged gloves.
If prolonged or repeated contact is likely, chemical-resistant gloves are recommended. If contact with forearms is
likely, wear gauntlet-style gloves. Nitrile, CEN standards EN 420 and EN 374 provide general requirements and
lists of glove types.

Eye Protection: If contact is likely, safety glasses with side shields are recommended.

Skin and Body Protection: Any specific clothing information provided is based on published literature or
manufacturer data. If prolonged or repeated contact is likely, chemical, and oil resistant clothing is recommended.

Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling
the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment
to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good
housekeeping.

ENVIRONMENTAL CONTROLS
See Sections 6, 7, 12, 13.

SECTION 9: PHYSICAL & CHEMICAL PROPERTIES

9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid


Colour: Dark Red
Odour: Distinctive (Aromatic Hydrocarbon)
Odour Threshold: No data available

pH: No data available


Melting Point: -39°C [Technical literature]
Freezing Point: <-15°C [In-house method]
Initial Boiling Point / and Boiling Range: 137°C (278.6F) - 215°C (419F) [Technical literature]
Flash Point [Method]: >28°C (82.4F) [ASTM D-56]
Evaporation Rate (n-butyl acetate = 1): 0.85 [Technical literature]

Flammability (Solid, Gas): No data available


Upper/Lower Flammable Limits
(Approximate volume % in air): UEL: 7.0 LEL: 0.9 [Technical literature]
Vapour Pressure: No data available
Vapour Density (Air = 1): < 1 at 101 kPa [Calculated]
Relative Density (at 15 C): 0.801 - 1.101 [With respect to water] [Calculated]

Solubility(ies): Water Essentially insoluble


Partition coefficient
(n-Octanol/Water Partition Coefficient): No data available
Auto-ignition Temperature: >425°C (797°F) [Extrapolated]
Decomposition Temperature: No data available
Viscosity: (20°C) approx. 250 cPs [In-house method]
(40°C) approx. 100 cPs [In-house method]
Explosive Properties: None
Oxidizing Properties: None

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9.2. OTHER INFORMATION

Density: (15°C) approx. 1.00 kg/dm3 [In-house method]

SECTION 10: STABILITY & REACTIVITY

10.1. REACTIVITY: See sub-sections below.

10.2. CHEMICAL STABILITY: Material is stable under normal conditions.

10.3. POSSIBILITY OF HAZARDOUS REACTIONS. Not expected.

10.4. CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.

10.5. INCOMPATIBLE MATERIALS: Strong oxidisers.

10.6. HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1. INFORMATION ON TOXICOLOGICAL EFFECTS

COMPONENTS: XYLENES

Acute Toxicity (Oral LD50): 4300 mg/kg Rat – harmful if swallowed

Acute Toxicity (Dermal LD50): >1700 mg/kg Rabbit - Low acute toxicity by the dermal route

Acute Toxicity (Inhalation LC50): 5000 ppmV (gas) Rat 4 hours – Harmful by inhalation

Skin Irritation: Test scores meet criteria for classification – Irritating

Serious Eye Damage/Irritation: Test scores meet criteria for classification – Risk of serious damage to eyes

Respiratory Sensitisation: Not determined - Not expected to be a respiratory sensitizer

Skin Sensitisation: Not Sensitising

Germ Cell Mutagenicity (In Vitro): Gene Mutation: Negative - Not mutagenic

Germ Cell Mutagenicity (In Vivo): Chromosome aberration: Negative - Not mutagenic

Carcinogenicity: <75 pmm Inhalation. Mouse


Highly unlikely to be carcinogenic and are not classifiable as carcinogens

Reproductive Toxicity: Not expected to be a reproductive toxicant


Not developmental toxicants

STOT – Single Exposure: May be irritating to the respiratory tract

STOT – Repeated Exposure: Concentrated, prolonged or deliberate exposure may cause organ damage.

Aspiration Hazard: Kinematic viscosity < = 20.5 mm2/s.


May be fatal if swallowed and enters airways. Based on physico-chemical
properties of the materials

Inhalation
Harmful by inhalation. Vapours irritate the respiratory system, and may cause coughing and difficulties in
breathing.
Ingestion
Harmful: may cause lung damage if swallowed. Nausea, vomiting.

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Skin Contact
Irritating to skin
Eye Contact
May cause severe irritation to eyes. Irritating and may cause redness and pain.

Target Organs
Kidneys, Liver, Central nervous system.

COMPONENTS: HYDROCARBONS, C10, AROMATICS, >1% NAPHTHALENE


HYDROCARBONS, C10 – C13, AROMATICS, >1% NAPHTHALENE

Acute Toxicity (Oral LD50): >5000 mg/kg Rat - Low acute toxicity by the oral route

Acute Toxicity (Dermal LD50): >2000 mg/kg Rabbit - Low acute toxicity by the dermal route

Acute Toxicity (Inhalation LC50): >4500 mg/m3 Rat - Low acute toxicity by the inhalation route

Skin Irritation: Very slight erythema -barely perceptible (1) – Not irritating
Very slight oedema -barely perceptible (1) – Not irritating

Serious Eye Damage/Irritation: Not Irritating.

Respiratory Sensitisation: Not determined - Not expected to be a respiratory sensitizer

Skin Sensitisation: Guinea pig maximization test (GPMT): Guinea Pig - Not Sensitising

Germ Cell Mutagenicity (In Vitro): Gene Mutation: Negative - Not mutagenic

Germ Cell Mutagenicity (In Vivo): Chromosome aberration: Negative - Not mutagenic

Carcinogenicity: NOAEL 600 mg/kg Oral Rat


1800 mg/m3 Inhalation Rat
Suspected of causing cancer

Reproductive Toxicity: Three-generation study: NOAEC 7800 mg/m3 Inhalation. Rat


Not expected to be a reproductive toxicant
Maternal toxicity: NOAEL 150 mg/kg Oral Rat
Not developmental toxicants

STOT – Single Exposure: May cause drowsiness or dizziness

STOT – Repeated Exposure: Not expected to cause organ damage from prolonged or repeated exposure

Aspiration Hazard: Kinematic viscosity ≤ 20.5 mm2/s.


May be fatal if swallowed and enters airways. Based on physico-chemical
properties of the materials

Inhalation
No specific health warnings noted.
Ingestion
Harmful: may cause lung damage if swallowed. Pneumonia may be the result if vomited material containing
solvents reaches the lungs.
Skin Contact
May cause defatting of the skin, but is not an irritant. Not a skin sensitiser. Repeated exposure may cause skin
dryness or cracking.
Eye Contact
No specific health warnings noted.
Route of entry
Skin and/or eye contact.

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COMPONENT: C.I. SOLVENT RED 164

Carcinogenicity:

Many azo dyes have been found to be carcinogenic in laboratory animals, effecting the liver, urinary bladder and
intestines. Specific toxicity effects in humans have not been established but some dyes are known to be
mutagenic.

OTHER INFORMATION
For the product itself:
Vapour concentrations above recommended exposure levels are irritating to the eyes and the respiratory tract,
may cause headaches and dizziness, are anaesthetic and may have other central nervous system effects. Small
amounts of liquid aspirated into the lungs during ingestion or from vomiting may cause chemical pneumonitis or
pulmonary edema. Very high exposure (confined spaces / abuse) to light hydrocarbons may result in abnormal
heart rhythm (arrhythmias). Concurrent high stress levels and/or co-exposure to high levels of hydrocarbons
(above occupational exposure limits), and to heart-stimulating substances like epinephrine, nasal decongestants,
asthma drugs, or cardiovascular drugs may initiate arrhythmias.

Contains:
This product contains ethylbenzene: Caused cancer in laboratory animal studies. The relevance of these findings
to humans is uncertain.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity:
The product is not expected to be hazardous to the environment.

COMPONENTS: XYLENES

12.1. TOXICITY

Acute Toxicity (Fish LC50 96 hours): 4.2 mg/l Onchorhynchus mykiss (Rainbow trout)

Acute Toxicity
(Aquatic Invertebrates EC50 48 hours): 2.9 mg/l Daphnia magna

Acute Toxicity
(Aquatic Plants EC50 72 hours): 4.4 mg/l Pseudokirchneriella Subcapitata

Chronic Toxicity
(Fish Early Life Stage 96 hours): NOEC 3.3 mg/l Menidia Menidia

Chronic Toxicity
(Aquatic Invertebrates 48 hours): 6.8 mg/l Daphnia magna NOEC

12.2. PERSISTENCE AND DEGRADABILITY

Degradability: The product is readily biodegradable.

Phototransformation: Air photolysis – Half-life 1.09 days.


Transformation due to photolysis not expected to be significant.
Stability (Hydrolysis): Transformation due to hydrolysis not expected to be significant.

Biodegradation: Water Degradation 70%: 28 days. Readily biodegradable in water

12.3. BIOACCUMULATIVE POTENTIAL

Bioaccumulation Factor: Potential to bioaccumulate is low

Partition Coefficient: Octanol-Water – log Kow 3.12 [calculated]

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12.4. MOBILITY IN SOIL

The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces.

12.5. RESULTS OF PBT AND VPVB ASSESSMENT

Not Classified as PBT/vPvB by current EU criteria.

12.6. OTHER ADVERSE EFFECTS

No adverse effects are expected.

COMPONENTS: HYDROCARBONS, C10, AROMATICS, >1% NAPHTHALENE


HYDROCARBONS, C10 – C13, AROMATICS, >1% NAPHTHALENE

12.7. TOXICITY

Acute Toxicity (Fish LC50 96 hours): 2.0 – 5.0 mg/l Onchorhynchus mykiss (Rainbow trout)

Acute Toxicity
(Aquatic Invertebrates EC50 48 hours): 1 – 10 mg/l Daphnia magna

Acute Toxicity
(Aquatic Plants EC50 72 hours): 4 – 11 mg/l Pseudokirchneriella Subcapitata

Acute Toxicity
(Microorganisms EC50 48 hours): 0.473 mg/l Tetrahymena pyriformis

Chronic Toxicity
(Fish Early Life Stage): 28 days 0.103 mg/l NOELR

Chronic Toxicity
(Aquatic Invertebrates): 21 days 0.180 mg/l Daphnia magna NOELR

Acute Toxicity (Terrestrial): Scientifically unjustified. Substance is a hydrocarbon UVCB.


Standard tests for this endpoint are intended for single substances
and are not appropriate for the risk assessment of this complex
substance.

12.8. PERSISTENCE AND DEGRADABILITY

Degradability: The product is easily biodegradable.

Phototransformation: Scientifically unjustified. Standard tests for atmospheric oxidation half-lives


are intended for single substances and are not appropriate for this complex
substance.
This substance does not have the potential to undergo photolysis in water and
soil, and this fate process will not contribute to a measurable degradative loss
of this substance from the environment.

Stability (Hydrolysis): Scientifically unjustified. The chemical constituents that comprise


hydrocarbons, C10 -C13, aromatics, >1% naphthalene consist entirely of
carbon and hydrogen and do not contain hydrolyzable groups. As such, they
have a very low potential to hydrolyze. Therefore, this degradative process
will not contribute to their removal from the environment.

Biodegradation: Water Degradation 57 – 61%: 28 days. Readily biodegradable in water

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12.9. BIOACCUMULATIVE POTENTIAL

Bioaccumulation Factor: Scientifically unjustified. Substance is a hydrocarbon UVCB. Standard tests


for this endpoint are intended for single substances and are not appropriate
for this complex substance.

Partition Coefficient: Scientifically unjustified. Substance is a UVCB. Standard tests for this
endpoint are intended for single substances and are not appropriate for this
complex substance.

12.10. MOBILITY IN SOIL

Adsorption/Desorption Coefficient:
Scientifically unjustified. Substance is a hydrocarbon UVCB. Standard tests
for this endpoint are intended for single substances and are not appropriate
for this complex substance.

Henry's Law Constant: Not determined. Volatilisation is dependent on Henry's Law constant (HLC)
which is not applicable to complex substances.

12.11. RESULTS OF PBT AND VPVB ASSESSMENT

Not Classified as PBT/vPvB by current EU criteria.

12.12. OTHER ADVERSE EFFECTS

No adverse effects are expected.

COMPONENT: C.I. SOLVENT RED 164

No ecological data available.

SECTION 13: DISPOSAL CONSIDERATIONS

Disposal recommendations based on material as supplied. Disposal must be in accordance with current
applicable laws and regulations, and material characteristics at time of disposal.

13.1. WASTE TREATMENT METHODS


Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised
incineration at very high temperatures to prevent formation of undesirable combustion products.

REGULATORY DISPOSAL INFORMATION

European Waste Code: 14 XX XX

NOTE: These codes are assigned based upon the most common uses for this material and may not reflect
contaminants resulting from actual use. Waste producers need to assess the actual process used when
generating the waste and its contaminants in order to assign the proper waste disposal code(s).

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue
and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums
should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers
should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in
accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER
SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.

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SECTION 14: TRANSPORT INFORMATION

SYMBOLS FOR TRANSPORT

LAND (ADR/RID)
14.1. UN Number: 1993
14.2. UN Proper Shipping Name (Technical Name):
FLAMMABLE LIQUID, N.O.S. (Xylenes, Naphthalene Solution)
14.3. Transport Hazard Class(es): 3
14.4. Packing Group: III
14.5. Environmental Hazards: Yes
14.6. Special Precautions for users:
Classification Code: F1
Label(s) / Mark(s): 3
Hazard ID Number: 30
Hazchem EAC: 3Y
Transport Document Name: UN1993, FLAMMABLE LIQUID, N.O.S. (Xylenes, Naphthalene Solution), 3,
PG III

INLAND WATERWAYS (ADNR/ADN)


14.1. UN (or ID) Number: 1993
14.2. UN Proper Shipping Name (Technical Name):
FLAMMABLE LIQUID, N.O.S. (Xylenes, Naphthalene Solution)
14.3. Transport Hazard Class(es): 3
14.4. Packing Group: III
14.5. Environmental Hazards: Yes
14.6. Special Precautions for users:
Hazard ID Number: 30
Label(s) / Mark(s): 3 (N2)
Transport Document Name: UN1993, FLAMMABLE LIQUID, N.O.S. (Xylenes, Naphthalene Solution), 3
(N2), PG III

SEA (IMDG)
14.1. UN Number: 1993
14.2. UN Proper Shipping Name (Technical Name):
FLAMMABLE LIQUID, N.O.S. (Xylenes, Naphthalene Solution)
14.3. Transport Hazard Class(es): 3
14.4. Packing Group: III
14.5. Environmental Hazards: Yes
14.6. Special Precautions for users:
Label(s): 3
EMS Number: F-E, S-D
Transport Document Name: UN1993, FLAMMABLE LIQUID, N.O.S. (Xylenes, Naphthalene Solution), 3,
PG III, (23°C c.c.)

SEA (MARPOL 73/78 Convention - Annex II):


14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not classified according to Annex II

AIR (IATA)
14.1. UN Number: 1993
14.2. UN Proper Shipping Name (Technical Name):
FLAMMABLE LIQUID, N.O.S. (Xylenes, Naphthalene Solution)
14.3. Transport Hazard Class(es): 3
14.4. Packing Group: III

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14.5. Environmental Hazards: Yes
14.6. Special Precautions for users:
Label(s) / Mark(s): 3
Transport Document Name: UN1993, FLAMMABLE LIQUID, N.O.S. (Xylenes, Naphthalene Solution), 3,
PG III

SECTION 15: REGULATORY INFORMATION

REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONS

15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE


SUBSTANCE OR MIXTURE
Applicable EU Directives and Regulations:

Regulation (EC) No. 1272/2008 (the CLP Regulation)


Regulation (EC) No. 1907/2006 (REACH)
Directive 2006/121/EC
Directive 67/548/EEC
Directive 1992/32/EEC
Directive 1999/45/EC

15.2. CHEMICAL SAFETY ASSESSMENT

REACH Information: A Chemical Safety Assessment has been carried out for XYLENES by supplier.

SECTION 16: OTHER INFORMATION

REVISION COMMENTS: Safety Data Sheet updated in accordance with ECHA Guidance on compilation of safety
data sheets, Sept 2011. All sections have revised information.

R PHRASES (full text):


R10: Flammable
R11: Highly flammable
R20: Harmful by inhalation.
R20/21: Harmful by inhalation and in contact with skin.
R38: Irritating to skin.

H STATEMENTS (full text):


Flam. Liq. 2 H225: Highly flammable liquid and vapor; Flammable Liquid, Cat 2
Flam. Liq. 3 H226: Flammable liquid and vapor; Flammable Liquid, Cat 3
Acute Tox. 4 H312: Harmful in contact with skin; Acute Tox Dermal, Cat 4
Skin Irrit. 2 H315: Causes skin irritation; Skin Corr/Irritation, Cat 2
Eye Irrit. 2 H319: Causes eye irritation; Serious Eye Damage/Irr, Cat 2
STOT SE 3 H335: May cause respiratory irritation; Target Organ Single, Resp Irr
STOT RE 2 H373: May cause damage to organs through prolonged or repeated exposure; Target Organ,
Repeated, Cat 2

CLASSIFICATION & METHOD TO DETERMIN CLASSIFICATION ACCORDING TO REGULATION (EC)


1272/2008 [CLP]:
Flam. Liq. 3 H226 – In house test data
Acute Tox. 4 H312 – Calculation Method
Skin Irrit. 2 H315 – Calculation Method
Eye Irrit. 2 H319 – Calculation Method
STOT SE 3 H335 – Calculation Method
STOT RE 2 H373 – Calculation Method

LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE (BUT NOT NECESSARILY ARE) USED IN
THIS SAFETY DATA SHEET:

AICS Australian Inventory of Chemical Substances


AIHA WEEL American Industrial Hygiene Association Workplace Environmental Exposure Limit
ATE Acute Toxicity Estimate

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ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways
ASTM ASTM International, originally known as the American Society for Testing and Materials
(ASTM)
CEN European Committee for Standardisation
C&L Classification and Labelling
CLP Classification Labelling Packaging Regulation ; Regulation (EC) No 1272/2008
CAS# Chemical Abstracts Service number
COM European Commission
CMR Carcinogen, Mutagen, or Reproductive Toxicant
CSA Chemical Safety Assessment
CSR Chemical Safety Report
DNEL Derived No Effect Level
DPD Dangerous Preparations Directive 1999/45/EC
DSD Dangerous Substances Directive 67/548/EEC
DSL Domestic Substance List (Canada)
DU Downstream User
DUCC Downstream Users of Chemicals Co-ordination platform
EEA European Economic Area (EU + Iceland, Liechtenstein and Norway)
ECB European Chemicals Bureau
ECHA European Chemicals Agency
EC-Number EINECS and ELINCS Number (see also EINECS and ELINCS)
EINECS European Inventory of Existing Commercial Substances
ELINCS European List of notified Chemical Substances
ENCS Existing and new Chemical Substances (Japanese inventory)
EN European Standard
EP European Parliament
EQS Environmental Quality Standard
ES Exposure Scenario
ext-SDS Extended Safety Data Sheet (SDS with ES attached)
EU European Union
Euphrac European Phrase Catalogue
EWC European Waste Catalogue (replaced by LoW – see below)
GES Generic Exposure Scenario
GHS Globally Harmonized System
HH Human Health
IATA International Air Transport Association
ICAO-TI Technical Instructions for the Safe Transport of Dangerous Goods by Air
IECSC Inventory of Existing Chemical Substances in China
IMDG International Maritime Dangerous Goods
IMSBC International Maritime Solid Bulk Cargoes
IT Information Technology
IUCLID International Uniform ChemicaL Information Database
IUPAC International Union for Pure Applied Chemistry
JRC Joint Research Centre
KECI Korean Existing Chemicals Inventory
Kow octanol-water partition coefficient
LC50 Lethal Concentration to 50 % of a test population
LD50 Lethal Dose to 50% of a test population (Median Lethal Dose)
LE Legal Entity
LoW List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm )
LR Lead Registrant
M/I Manufacturer / Importer
MS Member States
MSDS Material Safety Data Sheet
N/A Not applicable
N/D Not determined
NE Not established
NDSL Non-Domestic Substances List (Canada)

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NZIoC New Zealand Inventory of Chemicals
OC Operational Conditions
OECD Organization for Economic Co-operation and Development
OECD-WPMNM OECD Working Party on Manufactured Nanomaterials
OEL Occupational Exposure Limit
OH Occupational Health
OR Only Representative
OSHA European Agency for Safety and Health at work
PBT Persistent, Bioaccumulative and Toxic substance
PEC Predicted Effect Concentration
PICCS Philippine Inventory of Chemicals and Chemical Substances
PNEC(s) Predicted No Effect Concentration(s)
PPE Personal Protection Equipment
(Q)SAR Qualitative Structure Activity Relationship
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No
1907/2006
RID Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP REACH Implementation Project
RMM Risk Management Measure
SC Supply Chain
SCBA Self-Contained Breathing Apparatus
SDS Safety Data Sheet
SIEF Substance Information Exchange Forum
SME Small and Medium sized Enterprises
STOT Specific Target Organ Toxicity
(STOT) RE Repeated Exposure
(STOT) SE Single Exposure
SVHC Substances of Very High Concern
TLV Threshold Limit Value (American Conference of Governmental Industrial Hygienists)
TSCA Toxic Substances Control Act (U.S. inventory)
UIC Union des Industries Chimiques
UN United Nations
UVCB Substances of Unknown or Variable composition, Complex reaction products or Biological
materials
VCI Verband der Chemischen Industrie
vPvB Very Persistent and Very Bioaccumulative

DISCLAIMER:
This product should be stored, handled and used in accordance with good industrial hygiene practices and in
conformity with any legal regulations. This information is based on our present state of knowledge and is intended
to describe the product from the point of view of safety requirements. It should not be construed as guaranteeing
specific properties.

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