Page 1/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 18.03.2004 Reviewed on 18.03.2004
1 Identification of substance:
· Product details:
· Trade name: Curil T
· Elring article number: 246.948/252.867
· Application of the substance / the preparation Sealing compound
· Manufacturer/Supplier:
ElringKlinger AG
Max-Eyth-Straße 2
D-72581 Dettingen/Erms
· Informing department: 2ZEW Tel.: ++49/(0)7123/724-253
· Emergency information: Tel.: ++49/(0)7123/724-0
* 2 Composition/Data on components:
· Chemical characterization
· Description: Plastic Polyurethane, solved in Ethanol/Ethyl acetate/Special fuel
· Dangerous components:
CAS: 64-17-5 ethanol F; R 11 10-25%
EINECS: 200-578-6
EINECS: 265-151-9 Naphtha (petroleum), hydrotreated light Xn, F, N; R 11-38-51/53-65-67 10-25%
CAS: 141-78-6 ethyl acetate Xi, F; R 11-36-66-67 2.5-10%
EINECS: 205-500-4
CAS: 68410-23-1 Polyaminoamid Xi; R 41 <2%
CAS: 8006-64-2 Turpentine, oil Xn, N; R 10-20/21/22-36/38-43-51/53-65 <0.2%
EINECS: 232-350-7
CAS: 108-90-7 chlorobenzene Xn, N; R 10-20-51/53 <0.15%
EINECS: 203-628-5
· Additional information For the wording of the listed risk phrases refer to section 16.
* 3 Hazards identification
· Hazard designation:
F Highly flammable
· Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations
of the EU" in the latest valid version.
R 11 Highly flammable.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R 67 Vapours may cause drowsiness and dizziness.
· Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by
information furnished by supplier companies.
* 4 First aid measures
· General information
Take affected persons into the open air.
Instantly remove any clothing soiled by the product.
· After inhalation Supply fresh air; consult doctor in case of symptoms.
· After skin contact Wash with water and soap.
· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
· After swallowing
Call a doctor immediately.
Rinse out mouth and then drink plenty of water.
(Contd. on page 2)
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Page 2/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 18.03.2004 Reviewed on 18.03.2004
Trade name: Curil T
(Contd. of page 1)
5 Fire fighting measures
· Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· Special hazards caused by the material, its products of combustion or resulting gases:
Can be released in case of fire
Nitrogen oxides (NOx)
Carbon monoxide (CO)
Under certain fire conditions, traces of other toxic gases cannot be excluded, e.g.:
Isocyanate(Vapours)
Hydrogen cyanide (HCN)
· Protective equipment: Wear self-contained breathing apparatus.
6 Accidental release measures
· Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Keep away from ignition sources
Ensure adequate ventilation
· Measures for environmental protection: Do not allow to enter drainage system, surface or ground water.
· Measures for cleaning/collecting:
Ensure adequate ventilation.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Collect mechanically.
Dispose of the material collected according to regulations.
* 7 Handling and storage
· Handling
· Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
Use solvent-proof equipment.
· Information about protection against explosions and fires:
Use only in explosion-proof area.
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Fumes can combine with air to form an explosive mixture.
· Storage
· Requirements to be met by storerooms and containers:
Store in cool location.
Provide solvent resistant, sealed floor.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed containers.
Store container in a well ventilated position.
* 8 Exposure controls and personal protection
· Additional information about design of technical systems: No further data; see item 7.
· Components with limit values that require monitoring at the workplace:
64-17-5 ethanol
OES Long-term value: 1920 mg/m³, 1000 ppm
141-78-6 ethyl acetate
OES Long-term value: 1460 mg/m³, 400 ppm
· Additional information: The lists that were valid during the compilation were used as basis.
· Personal protective equipment
· General protective and hygienic measures
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
Do not smoke while working.
(Contd. on page 3)
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Page 3/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 18.03.2004 Reviewed on 18.03.2004
Trade name: Curil T
(Contd. of page 2)
Do not eat or drink while working.
Wash hands during breaks and at the end of the work.
· Breathing equipment:
Use breathing protection in case of insufficient ventilation.
Under the following conditions a respirator may be required:
When product vapor concentration exceeds the limits listed in section 8.
Short term filter device:
Filter A
· Protection of hands: Solvent resistant gloves
· Material of gloves
Butyl rubber, BR
Recommended thickness of the material: ≥ >0.5 mm
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies
from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove
material can not be calculated in advance and has therefore to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection: Safety glasses
* 9 Physical and chemical properties:
· General Information
Form: Pasty
Colour: Green
Odour: Product specific
· Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: 80-120°C
· Flash point: -5°C
· Ignition temperature: 250°C
· Self-inflammability: Product is not selfigniting.
· Danger of explosion: Product is not explosive. However, formation of explosive air/steam mixtures is possible.
· Critical values for explosion:
Lower: 1.0 Vol %
Upper: 15.0 Vol %
· Vapour pressure at 20°C: 31 hPa (prEN 13016-1)
· Density at 20°C 1.00 g/cm3
· Solubility in / Miscibility with
Water: Partly soluble
· Viscosity:
dynamic at 20°C: ca. 30000 mPas
10 Stability and reactivity
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Dangerous reactions
Reacts with alkaline metals
Reacts with alkaline earth metals
Reacts with strong oxidizing agents
· Dangerous products of decomposition: No dangerous decomposition products known
(Contd. on page 4)
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Page 4/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 18.03.2004 Reviewed on 18.03.2004
Trade name: Curil T
(Contd. of page 3)
* 11 Toxicological information
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
Naphtha (petroleum), hydrotreated light
Oral LD50 >2000 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rbt)
Inhalative LC50/4 h >5 mg/l (rat)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: Irritant effect.
· Sensitization: No sensitizing effect known.
· Additional toxicological information:
Inhalation of concentrated vapours as well as oral intake will lead to anaesthesia-like conditions and headache, dizziness,
etc.
12 Ecological information:
· General notes:
At present there are no ecotoxicological assessments.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
13 Disposal considerations
· Product:
· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Take to special waste combustion plant.
· European waste catalogue
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS
(PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS
08 04 00 wastes from MFSU of adhesives and sealants (including waterproofing products)
08 04 09 waste adhesives and sealants containing organic solvents or other dangerous substances
· Uncleaned packagings:
· Recommendation:
Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
Non contaminated packagings can be used for recycling.
* 14 Transport information
· Land transport ADR/RID (cross-border)
· ADR/RID-GGVS/E Class: 3 (F1) Flammable liquids.
· Kemler Number: 33
· UN-Number: 1866
· Packaging group: III
· Label 3
· Designation of goods: 1866 RESIN SOLUTION, special provision 640H
· Maritime transport IMDG:
· IMDG Class: 3
(Contd. on page 5)
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Page 5/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 18.03.2004 Reviewed on 18.03.2004
Trade name: Curil T
(Contd. of page 4)
· UN Number: 1866
· Label 3
· Packaging group: III
· EMS Number: F-E,S-E
· Marine pollutant: No
· Correct technical name: RESIN SOLUTION
· Air transport ICAO-TI and IATA-DGR:
· ICAO/IATA Class: 3
· UN/ID Number: 1866
· Label 3
· Packaging group: III
· Correct technical name: RESIN SOLUTION
* 15 Regulatory information
· Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials
(GefStoffV)
· Code letter and hazard designation of product:
F Highly flammable
· Risk phrases:
11 Highly flammable.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
67 Vapours may cause drowsiness and dizziness.
· Safety phrases:
2 Keep out of the reach of children.
7/9 Keep container tightly closed and in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
23 Do not breathe fumes.
24 Avoid contact with skin.
51 Use only in well-ventilated areas.
· Special designation of certain preparations:
Contains Turpentine, oil. May produce an allergic reaction.
· National regulations
· Technical instructions (air):
Class Share in %
III 10-25
NK 25-50
· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product
features and shall not establish a legally valid contractual relationship.
· Relevant R-phrases
10 Flammable.
11 Highly flammable.
20 Harmful by inhalation.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
36 Irritating to eyes.
36/38 Irritating to eyes and skin.
(Contd. on page 6)
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Page 6/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 18.03.2004 Reviewed on 18.03.2004
Trade name: Curil T
(Contd. of page 5)
38 Irritating to skin.
41 Risk of serious damage to eyes.
43 May cause sensitisation by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
65 Harmful: may cause lung damage if swallowed.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
· Department issuing data specification sheet: 2ZEW
· Contact: Mr. Anhorn
· * Data compared to the previous version altered.
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