1160
EMERGENCY CALLS:
Manager, Technical services
Telephone : 966-(2)-661333 x 2420
MATERIAL SAFETY DATA SHEET
1- IDENTIFICATION
Product Name : PETROMIN ENGINE OIL
2- COMPOSITION
Additivated Lubricating Oil: Complex combinations of hydrocarbons obtained (from vacuum distillation) by
solvent extraction and dewaxing processes; mainly consisting of saturated hydrocarbons having carbon
numbers C15-C50 and special additive package incorporated and Kerosene in small quantity.
3- HAZARDS
Human:
Inhalation - Short-term exposures to vapors and oil mists cause irritation of the respiratory tract. Long-term
exposures can cause lung fibrosis preceded by broncho-pulmonary symptoms in concentrations over 5 mg/m 3
(TLV).
Ingestion - Low oral toxicity: toxicity by ingestion: Grade O; LD 50 > 15g/Kg (oral-rat). Intestinal absorption is
very low. Accidental intake of large amounts causes irritation of the gastrointestinal tract, nausea, vomiting and
diarrhea.
Contact/Skin - Low skin toxicity: LD 50 > 5g/Kg (rat), level considered to be harmless in short-term exposures.
Long-term exposures produce smarting, redness, irritation and dermatitis due to defatting of the keratyn layer.
No skin sensitization has been registered in animal tests or human cases.
Eyes - Repeated exposure to vapors or liquid cause irritation.
Environment:
Combustible. Lighter than water; it can obstruct sewers and water intakes.
4- FIRST-AID
Skin : Flush with plenty of soap and water
Eyes : Flush with plenty of water for at least 15 minutes.
Ingestion : Do not induce vomiting. If conscious, have the victim drink
Water or milk.
Inhalation : Remove the victim to fresh air; administer oxygen if
Necessary. Call for medical attention.
5- FIRE PRECAUTIONS
Extinguishing Media Suitable : Foams, dry chemicals, CO2, nylons and powders
Non-suitable : Water, may be ineffective
Protection Equipment : Heat resistant suit and gloves. Self-contained breathing
apparatus.
Special Risks : NP
Special Measures : Not required
Combustion Products : CO2, H2O, CO (in defect of air), nitrogen, sulfur and phosphorus
Oxides
6- ACCIDENT PRECAUTIONS
Precautions for the Environment:
Hazard of physical fouling to coasts, soils, etc. due to low solubility and high viscosity of the oils. Avoid the
material entering water intakes.
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Clean-up Method:
Treat as an accidental oil spill or leak; avoid dispersion of the material with mechanical barriers. Remove with
physical or chemical treatment.
Personal Precautions : Avoid prolonged contact with contaminated clothes or with the product
Personal Protection : Gloves and goggles or face shield
7- STORAGE AND HANDLING
Handling:
General Precautions : Avoid prolonged contact and inhalation of mists and vapors
From heated oils
Specific Conditions : Safety goggles and gloves should be used
Storage:
Storage Conditions : Containers properly labeled and sealed, placed in cool and
Well ventilated areas
Incompatible Materials : Strong oxidants
Dangerous Practices : NP
8- PERSONAL PROTECTION
Inhalation
Low vapor pressures: The product is slightly volatile at room temperature and does not present special risks. In
presence of heated oils, wear protective masks to avoid vapor inhalation.
Skin : Gloves
Eye : Safety goggles
Other : Showers and eye-washers in the working area.
Specific Hygiene Measures : Good work practices to minimize exposure and adoption of good
Personal hygiene measures avoid the presence of skin rash and oil
Acne
Exposure Controls : TLV (typical base oil) = 0.016 PPM at 20ºC (saturated vapor
Concentration); TLV/TWA (ACGIH) = 5mg/m3 (oil mist);
TLV/STEL (ACGIH) = 10mg/m3 (oil mist
9- PHYSICAL AND CHEMICAL PROPERTIES
Color : Blue
Specific Gravity (at 15º C) : 0.874 (typical)
Flash Point : 128º C
Explosive Properties : NP
Oxidizing Properties : NP
Water Solubility : Insoluble (100 PPM max. H2O)
Solubility : Organic solvents
Vapor Density : 17.7 (air=1)
Viscosity at 100º C : 6.2 cSt (typical)
Pour Point : -21º C (typical)
10- STABILITY AND REACTIVITY
Stability : Stable at room temperature
Polymerization Risk : NP
Materials to Avoid : Strong oxidants react with oils and organic materials
Hazardous Decomposition Products : NP
Condition to Avoid : Exposure to open flames
11- TOXICOLOGICAL INFORMATION
Routes of Exposure : Contact with skin, eyes and inhalation. Ingestion is not
Frequent.
Acute and chronic Effects : No malignant acute effects are known. Chronic effects due
To repeated exposures are irritation, dermatitis and acne.
Carcinogenicity : NP
Reproductive Toxicity : No evidences
Medical Conditions which Increase
Hazard to Exposure : Respiratory tract deficiencies and dermatological problems
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12- ECOLOGICAL INFORMATION
Pollutant Potential:
Persistence and Degradability- the material is oily and viscous and floats on water. It presents a high
physical fouling potential, mainly in sea-spills; by contact, destroys small acuatic organisms and makes living
difficult for upper organisms, not allowing the sunlight to reach underlying marine ecosystems, affecting its
normal development.
Mobility/Bioaccumulative Potential- it does not present bioaccumulative problems in living organisms or
incidence in the tropic food chain, although it may cause long-term adverse effects in the acuatic environment,
due to its high physical fouling potential.
Eco toxicological Effect:
Dangerous for acuatic life in high concentrations (spills).
13- DISPOSAL
Disposal Methods (surplus): Recycling and recovery of base oils when possible
Disposal (waste) : Only in specific prepared and controlled areas. Avoid releasing
oils to sewers because they can destroy water treatment plant
Microorganisms. Do not attempt to clean containers since
residue is difficult to remove; dispose in a safe way.
Handling (waste) : Labeled and sealed containers. Avoid direct contact with waste
oils.
14- TRANSPORTATION
Special Precautions : Stable at room temperature and during transport. Store in
Cool well ventilated areas.
UN Number : NP
ADR (TPC)/RID (TPF) Classification : -
IATA-DER Classification : -
IMDG Classification : -
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is to the best of our knowledge and belief, accurate and reliable
as of the date indicated. However no representation, warranty or guarantee is made as to its accuracy, reliability or
completeness.
It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular
use.
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