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functions of insulation and cool-
ing, the oil serves as an important
carrier of information
 ABSTRACT
 As blood tests provide information         The diagnostic
                                            power of oil
 about a person’s state of health, oil
 analyses provide information about
 the condition of a transformer.
 Transformer oil testing has proven to
                                            analysis for power
 be an excellent tool for early defect
 LGHQWLͤFDWLRQ LQ SUHYHQWLYH PDLQWH-
 QDQFH RI RLOͤOOHG WUDQVIRUPHUV ,W
                                            transformers:
 has permitted extended service life
 by giving a measure of both oil and
 solid insulation condition, and by
 identifying the presence of incipient
                                            New
 thermal and dielectric faults. When
 performed regularly, oil analysis
 will help the asset manager run a
 cost-effective maintenance program
                                            developments
 for transformers.
 This column addresses some recent
 developments in oil analysis, such as
 sustainable alternatives for mineral
 oil, an alternative marker for analy-      1. Introduction
                                                                                           lishing the status of ageing and corrosion
 sis of paper degradation, and online
                                            Over the last decades a large variety of oil   for replacement and refurbishment issues
 transformer oil monitoring.
                                            analyses techniques have been developed        [1]. In the majority of oil-filled transform-
                                            and standardized. These techniques in-         ers mineral oil is used, and physical oil
 KEYWORDS                                   volve physical or chemical oil properties,     samples are taken in service for analysis
                                            electrical and environmental properties,       in the laboratory. This column addresses
 oil analysis, ester, cellulose paper,      and DGA (Dissolved Gas Analysis). The          some recent developments in oil analysis.
 degree of polymerization                   application of oil analysis may be linked to   The first one is related to sustainable alter-
                                            maintenance, lifetime extension, and estab-    natives for mineral oil, in particular esters.
66                                                                     TRANSFORMERS MAGAZINE | Volume 5, Issue 4 | 2018
                                                                                                                                     Jos WETZER
The second one deals with methanol as an                 basis, and have built a history that serves      properties, and interacts very well
alternative marker for analysis of paper                 as a reference for trending and analysis.        with mineral insulating oil. Under the
degradation, and the third one with the                  For esters, the methods for assessing the        combined effects of temperature, oxygen
benefits and drawbacks of online trans-                  condition can only be applied to a limited       and moisture, the cellulose polymer chains
former oil monitoring.                                   extent using IEC standards. IEC did issue        will break up and result in a weak and
                                                         a standard on new and unused natural es-         brittle material that has lost its mechanical
                                                         ters, such as FR3. But so far there are no       strength. Solid insulation in transformers
2. Natural esters as an                                  guidelines for esters in operating electrical    not only serves as an insulator, but also
alternative for mineral oil                              equipment. New knowledge rules need to           ensures mechanical stability, creation of
From the start, mineral oils have formed                 be applied, and a new history needs to be        space, the proper direction of oil flow, and
the insulation and cooling medium of                     built up. IEC TC 10 is presently working         so on.
liquid-filled transformers. For most ap-                 on such a standard. It is to be expected
plications, mineral oil is a proven, accept-             that, in the longer run, a similar standard      New insulating paper typically has a DP
able, cost-effective insulating and cooling              will be developed for the analysis of paper      value between 1000 and 1200, which
fluid. It has good thermal and dielectric                ageing through ester transformer oil.            corresponds to a high tensile strength. As
properties, and there is a lot of experience                                                              paper ages, its electrical properties do not
gained over the years.                                                                                    change significantly, but the mechanical
                                           3. Methanol as a marker for                                    properties are reduced drastically. As a
In recent years, manufacturers have intro- paper degradation                                              result, the mechanical strength of the
duced transformers with biodegradable                    Transformer insulation paper is generally        paper is reduced with time, and when a
liquids, in particular synthetic and nat-                recognized as the most significant lim-          DP value of about 200 to 300 is reached,
ural esters. The advantages are pri-                     iting factor in the thermal operating life       the mechanical strength has gone. The
marily related to safety properties                      of a transformer [2]. Not as much because        rate at which the DP value decreases
(thermal stability, flashpoint, smoke                    it is the dominant failure mechanism – it        in time during service depends mainly
generation) and environmental properties                 is not, but because paper degradation is         on the temperature in the transformer,
(biodegradable). It is further claimed that              an irreversible mechanism that will even-        on the amount of moisture and oxygen
they can absorb water without having a                   tually destroy the transformer and does          present, and on the acidity of the oil. The
detrimental effect on dielectric properties,             (practically) not allow repair or refurbish-     main cellulose degradation process is acid
and that they have a longer life expectancy              ment.                                            hydrolysis, which requires water and acids.
due to the reduced ageing rate of solid in-                                                               The process is accelerated by temperature,
sulation. Transformers with such fluids                  The winding insulation consists of oil           degradation byproducts and possible
are being introduced more and more,                      impregnated cellulose. Cellulose has             electrical fields. Figure 1 schematically
especially in applications where fire                    excellent electrical and mechanical              illustrates the degradation process [3].
safety and environmental protection
are important, and have reached a state
of maturity. There is a trend to use them
at ever increasing voltages and power
ratings, and today there are examples of
biodegradable fluids being used in high-
voltage and high-power transformers.
Apart from fulfilling the primary functions
of insulation and cooling, the oil serves as
an important carrier of information. From
physical and chemical analysis we assess
whether the oil still meets the required
specifications for continued use. With
DGA (Dissolved Gas Analysis) dormant
errors can be detected at an early stage.
This gives us, as it were, a glimpse into the
interior of the transformer without having
to open it and even without having to take
it out of operation. DGA is the most widely                     Figure 1. Schematic representation of the interaction between oil and paper
used technique worldwide for monitoring
the operating status of transformers.
                                                                Oil testing gives a measure of both oil
A drawback of changing from mineral
oil to esters is that is has an impact on                       and solid insulation condition,
                                                                                         dition, and helps
                                                                                                     he
transformer monitoring and diagnosis.
Most utilities have experience with min-
                                                                identify the presence of incipient
                                                                                          ncipient thermal
                                                                                                   therm
eral oil analysis as a standard diagnostic                      and dielectric faults
w w w . t ra n s fo r m e r s - m a g a z i n e . co m                                                                                             67
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In the last decade, research has indicated                                                         It does, by its nature, not allow immediate
                                                                                                   feedback or alert.
that methanol is a promising alternative as
a tracker for paper degradation                                                                    These days, however, modern sensing
                                                                                                   and diagnostic equipment allows to re-
                                                                                                   place sampling, transport and laborato-
                                                                                                   ry analysis of oil samples. Mobile on-site
                                                                                                   test methods are presently commercially
                                                                                                   available. By applying continuous on-line
                                                                                                   oil testing, in combination with intelligent
                                                                                                   electronic devices which can record and
                                                                                                   trend results and trigger alarms, we now
                                                                                                   have predictive diagnostic tools which
                                                                                                   can eliminate the risks associated with
                                                                                                   interval testing. On-line testing also elimi-
                                                                                                   nates the necessity of oil sampling and the
                                                                                                   associated issues related to contamination
                                                                                                   during sampling and storage. After all, the
                                                                                                   test results are only as reliable as the sam-
                                                                                                   ples obtained. One might suggest that this
                                                                                                   will eventually lead to the end of sampled,
                                                                                                   interval-based, oil testing practice [7].
                                                                                                   Will we exclusively use on-line predictive
                                                                                                   oil analysis in the future? To answer this
                                                                                                   question we need to understand the prin-
)LJXUH7\SLFDOFRUUHODWLRQVEHWZHHQ'3YDOXHDQGPDUNHUFRQFHQWUDWLRQVUDWLRV>@               ciples of both methods.
                                                                                                   The off-line analysis provides a wealth
For the above reasons, operators are             The CO2 and furfural concentrations are           of information from all kinds of analyses
keen to know the degree of polymeri-             more sensitive to DP variations in the low        (physical and chemical properties and
zation (the DP value) of the insulation          DP range (below 400, late degradation             DGA), and needs to be performed on a
paper. Sampling paper for analysis is            stages), whereas the MeOH concentration           regular basis. According to CIGRÉ [7], a
not a feasible option, not only because          is more sensitive to DP variations in             typical maintenance interval for DGA,
it requires opening the transformer, but         the high DP range (above 400, earlier             dependent on load, age and importance,
more importantly, because the sample             degradation stages). The methods may              varies from three months to two years.
would have to be taken from the hot-             be regarded complementary. For early              Once a defect is observed, the same sam-
spot location. The breakdown strength            warning, the MeOH approach would be               ple may be used for additional analysis,
of the insulating paper is determined            better, but close to the end of paper life, the   and the sample frequency may be in-
by the weakest link in the chain, which          furfural content may give a more accurate         creased. Interpretation is performed by an
is the hotspot location. This is located         picture. It should be noted, however,             expert (or a team of experts).
inside the winding package close to the          that research is still ongoing to arrive
core.                                            at a reliable empirical relation between          The on-line analysis is predominantly
                                                 MeOH and DP value. At present, all three          based on DGA monitoring, and ranges
Therefore, the DP value is determined            methods have some challenges based                from simple fault detectors to full DGA
indirectly from the byproducts in the            on their advantages and disadvantages.            monitoring systems, and may be performed
oil that result from breaking up of the          Table 1 gives an overview of the three            continuously. The first interpretation can
cellulose chains. The byproduct para-            methods discussed [3].                            be made by knowledge rules embedded in
meters used so far for assessing the DP                                                            software. In order to fully benefit from this
value are the CO2 concentration, the                                                               feature it is important to ensure that oil is
CO2/CO ratio and the furfural content.
                                                 4. Online monitoring of                           drawn from and returned to chosen points
In the last decade research has indicated        transformer oil                                   in the oil circulation circuit so as to ensure
that methanol (MeOH) is a promising              For critical transformer units where pre-         representative sampling. It is also impor-
alternative as a tracker for paper degra-        mature or unexpected failure would have           tant that the oil is suitably conditioned
dation [4, 5].                                   significant consequential costs one may           prior to testing to ensure measurement
                                                 consider to increase the oil sampling             consistency. As mentioned earlier, on-line
The assessment is based on the strong            frequency for coping with defects that            analysis may be used for fault detection or
correlation between CO2 concentration,           develop fast. This allows maintenance             for a full DGA analysis.
the CO2/CO ratio, the furfural content           engineers to timely recognize incubating
(2-FAL) and the MeOH content on the              defects and take corrective action before         Fault detectors usually operate on only
one side, and the DP value on the other          they mature, however at the expense of            one or two key parameters. As hydro-
[4]. This is illustrated in Figure 2.            cost, manpower and logistic complexity.           gen is produced in all fault mechanisms,
68                                                                            TRANSFORMERS MAGAZINE | Volume 5, Issue 4 | 2018
It is anticipated that on-line oil analysis will                                                        monitoring will find its way on a limited
                                                                                                        scale, focusing on strategic applications.
increasingly be applied for high-value stra-                                                            It is unlikely that on-line monitoring will
tegic transformers, but will not be able to                                                             replace off-line analysis at a significant
                                                                                                        scale in the foreseeable future, unless the
replace laboratory oil analysis in the fore-                                                            parameters of the business case dramatic-
                                                                                                        ally change.
seeable future
                                                                                                        Conclusion
measuring dissolved hydrogen serves                      sampling and laboratory analysis) and          Transformer oil testing has proven to be
as an excellent fault indicator. Similarly,              the benefits (e.g. the failures prevented      an excellent tool for early defect iden-
moisture is a very useful indicator of the               by timely detection). Expensive and stra-      tification in preventive maintenance of
overall condition of (and risks associated               tegic high-voltage transformers will have      oil-filled transformers. It has permitted
with) both oil and solid insulation. These               a better monitoring business case then         extended service life by giving a measure
are therefore regarded as key parameters.                medium-voltage commodities.                    of both oil and solid insulation condition,
Fault detectors combined with intelligent                                                               and by identifying the presence of incipi-
logic systems allow to timely intervene in               Also, one has to take into account that on-    ent thermal and dielectric faults. When
critical situations, but do not have the pre-            line systems need maintenance and cali-        performed regularly, oil analysis will help
dictive power of a full analysis.                        bration, and tend to have a lower accuracy     the asset manager run a cost-effective
                                                         then laboratory analysis.                      maintenance program for transformers.
Complete DGA monitoring benefits from
the DGA analysis advantages to the full.                 Transformer oil testing is firmly entren-      New sustainable fluids are being de-
However, it does not monitor all physi-                  ched in the condition-based maintenance        veloped as an alternative for mineral oils.
cal and chemical properties, the costs rise              practice. The results of oil analyses form     Esters have become available with sim-
with the number of key gases to be ana-                  an important part of the condition infor-      ilar dielectric and thermal properties, but
lysed, and complex situations still requi-               mation feeding maintenance and replace-        with superior safety and environmental
re an expert interpretation. The decision                ment decisions. As such, oil analysis is in-   properties. Further work is needed in or-
to use an on-line monitoring system in-                  creasingly integrated in decision support      der to develop guidelines for using ester
volves a trade-off between the costs (costs              systems such as health and risk indexing       analysis for diagnostic and maintenance
of automated monitoring versus interval                  software [8]. It is very likely that on-line   applications.
7DEOH2YHUYLHZRIWHVWPHWKRGVIRU'3YDOXHGHWHUPLQDWLRQDIWHU>@
          Test                         Advantages                             'LVDGYDQWDJHV                             Challenges
                            Laboratory or online test;             Limited information on cellulose          'LI¿FXOWWRGHWHUPLQHVRXUFH
                                                                   ageing;                                   location, type of degradation,
                                                                                                             degree of egress/ingress;
      CO2 & CO              &DQEHXVHGDVDÀDJWR               Origin can be solid insulation or oil; May be dependent on
                            indicate cellulose ageing                                                     manufacturer / design
                                                                   Gases may escape, depending on
                                                                   WKHEUHDWKLQJFRQ¿JXUDWLRQ
                            Laboratory test;                       Thermal instability furans;               Proper interpretation requires
                                                                                                             knowledge on the insulation
                            Estimates DP value;                    Detection limited at higher DP            system
                                                                   values
         2-FAL
                            Empirical relation between
                            2-FAL and DP;
                            Sensitive for late
                            degradation (low DP)
                            Laboratory test;                       Requires knowledge on paper               (VWDEOLVKLQJXQLWVSHFL¿FHPSLULF
                                                                   type, partitioning factors, size,         equations still in development
                            Estimates DP value;                    GHVLJQEUHDWKLQJFRQ¿JXUDWLRQ
      Methanol
                            Empirical relation between
                            MeOH and DP;
                            Linear & sensitive for early
                            degradation (high DP)
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For determining the ageing status of paper     [3] N. Perjanik, Weidmann Introduces        [6] CIGRÉ, Guide for transformer
insulation, methanol analysis has been         Methanol and Ethanol in Oil Testing,        maintenance, CIGRÉ brochure 445,
developed as an alternative for furfural       NETA Powertest Conference, 2018             WG A2.34, 2011
analysis. It turns out that methanol
has superior properties for identifying        [4] M. Duval, Transformers with low         [7] M. Kuises, W. Morse, Has transfor-
the early phases of paper degradation.         degree of polymerization, Transformers      mer oil testing reached its sell by date?,
However, further development is                Magazine, Vol. 1, Issue 3, 2014             Energize, April 2005
needed to arrive at empiric relations for
interpretation.                                [5] A. Schaut and S. Eeckhoudt, Iden-       [8] J. Wetzer, Transformer health and
                                               tification of early-stage paper degrada-    risk indexing, Transformers Magazine,
It is anticipated that on-line oil analysis    tion by methanol, CIGRÉ Conference,         Vol. 5, Issue 2, 2018
will increasingly be applied for high-value    2012, paper A2-107
strategic transformers, but will not be able
to replace laboratory oil analysis in the
foreseeable future: for large numbers of
medium-voltage commodities the bene-                  Author
fits will not balance the costs.                                           Dr. Jos Wetzer from the Netherlands is senior principal
                                                                           consultant “Asset Management” with DNV GL - Energy,
                                                                           stationed in Arnhem, The Netherlands. He obtained
Acknowledgement                                                            a M.Sc. degree in Electrical Engineering (cum laude)
The author gratefully acknowledges the                                     and a Ph.D. degree in Technical Sciences, both from the
support of Walter Hulshorst and Pieter                                     Eindhoven University of Technology. After obtaining his
de Bijl of DNV GL. They have delivered                                     Ph.D. degree he worked as an associate professor at the
valueable contributions to the field of                                    Eindhoven University of Technology for 14 years. His
power transformer oil analysis.                       activities included research, education and consultancy in the field of High-
                                                      Voltage Engineering and EMC. In 1998 he joined KEMA (now DNV GL) as a
                                                      senior consultant, in the field of condition assessment, asset management and
Bibliography                                          EMC. From 2001 to 2006 he held a management position, and from 2006 on
[1] N. Robinson, Transformer oil ana-                 he has been active as a (senior) principal consultant, and has served numerous
lysis: a basic introduction, in: Transfor-            clients in Europe, North America, the Middle East and Asia Pacific on asset
mer and substation handbook 2014,                     management issues. From 2004 to 2007 he also held a position as a part-time
Electricity &Control Spot On, Crown                   professor at the Eindhoven University of Technology in the Netherlands,
Publications                                          engaged in Asset Management of Electrical Infrastructures. His expertise
                                                      includes asset and maintenance management, condition assessment and
[2] CIGRÉ, Thermal performance of                     diagnostics, dielectrics and electrical insulation, electromagnetic fields and
transformers, CIGRÉ brochure 393,                     EMC. He has published over 150 scientific and professional publications.
WG A2.24, 2009
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