P91 Article PDF
P91 Article PDF
WELDING
GLOBAL MANUFACTURING BASES
AND OFFICES
ASIA
JAPAN:
KOBE STEEL, LTD., Welding Business
Global Operations and Marketing Department
TODAY
Marketing Center
Tel. (81) 3 5739 6331 Fax. (81) 3 5739 6960
21
KOREA:
KOBE WELDING OF KOREA CO., LTD.
Tel. (82) 55 292 6886 Fax. (82) 55 292 7786
CHINA:
Vol..
KOBE WELDING OF SHANGHAI CO., LTD.
Tel. (86) 21 6191 7850 Fax. (86) 21 6191 7851
SINGAPORE:
KOBELCO WELDING ASIA PACIFIC PTE. LTD.
Tel. (65) 6268 2711 Fax. (65) 6264 1751
THAILAND:
THAI-KOBE WELDING CO., LTD.
Tel. (66) 2 636 8650 to 8652 Fax. (66) 2 636 8653
KOBE MIG WIRE (THAILAND) CO., LTD.
Tel. (66) 2 324 0588 to 0591 Fax. (66) 2 324 0797
VIETNAM:
REP. OFFICE of THAI-KOBE WELDING in DONG NAI
Tel. (84) 61 395 5218
MALAYSIA:
KOBE WELDING (MALAYSIA) SDN. BHD.
Tel. (60) 4 3905792 Fax. (60) 4 3905827
INDONESIA:
P.T. INTAN PERTIWI INDUSTRI
(Technically Collaborated Company)
Tel. (62) 21 639 2608 Fax. (62) 21 649 6081
INDIA:
KOBELCO WELDING INDIA PVT. LTD.
Tel. (91) 124 4010063 Fax. (91) 124 4010068
EUROPE
NETHERLANDS:
KOBELCO WELDING OF EUROPE B.V.
Tel. (31) 45 547 1111 Fax. (31) 45 547 1100
SWEDEN:
KOBELCO WELDING OF EUROPE AB
Tel. (46) 31 767 55 91
AMERICA
USA:
KOBELCO WELDING OF AMERICA INC.
Tel. (1) 281 240 5600 Fax. (1) 281 240 5625
Preface ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ Preface ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■
company in the world. Some of these activities were on display at the Japan desired. While we have 3D CAD Model
MES
Integration
International Welding Show held in Tokyo last April, including a proposed not yet started marketing it Production
operation PLC,
Production
information
means of manpower-saving automation that combines four robotic welding overseas, we are investi- Production Line
systems with the most suitable consumable, as well as our range of welding gating whether to start Sensor network,
Field network
PF-N5/US-609S for SAW on 9%Ni steels: consumables created specifically for the shipbuilding, energy and automobile recommending it for
Excellent solution in horizontal
and flat positions industries. (See the bulletin article on pages 9-10 in this issue for more details.) automation on large-scale Figure 1: ISHIMATSU welding robots Figure 2: Integration of product life cycle in PLM
page
During the show, we could highlight the achievements of our activities to many visitors
structures.
9 at the KOBELCO booth, while emphasizing our plans to develop welding automation
and manpower savings further by utilizing IoT and AI technologies in the future.
Secondly, I will discuss the function of robotic welding systems utilizing KOBELCO’s Information and
Communication Technology (ICT). We have already improved productivity by using ICT as discussed in last
year’s KWT. “Vertical integration of production” is a key concept of our activity, as shown in Figure 2. Product life
On the other hand, the welding solution many of our customers rely on is not
cycle management (PLM) is a holistic management system, based on ICT, of product-related information covering
related to robotic automation at all; for example, shielded metal arc welding with
covered electrodes remains one of the most convenient of welding processes.
the whole lifecycle of products, such as design, production, maintenance, disposal and recycling, with the aim of
KOBELCO-Your Best Partner maximizing profits. Although it is not easy to create operation commands that order a robot to conduct steady
is highlighted at JIWS 2018 The environment surrounding the welding business is changing day by day, and welding with three-dimensional CAD data, ICT has allowed us to achieve it. Furthermore, it will allow us to
so are most customers. By staying sensitive to the changes, we will be able not achieve better traceability and perform organic control by recording the conditions at times of spatter and fume
only to develop new products that match their needs but to enhance the generation and stops, in addition to recording overall welding conditions and system operations.
distinctiveness and added-value of our products.
The above-mentioned robots and PLM were exhibited
As our KOBELCO members continue to visit your countries and regions, please let at the Japan International Welding Show (JIWS) held in
them know your problem(s), trouble(s) and/or needs for your welding operations. Tokyo last April. KOBELCO representatives will visit
Lastly, our vision, aiming to be the most reliable welding solutions company in the your countries and regions directly to introduce our
world that was established and succeeded by my predecessors, Messrs. Kasuya and latest products and technologies including the above
Koshiishi, will never be changed even as I become the Head of the Welding Business. I and listen to your requests. As your requests are always
surely believe that our responsibilities are to provide you with stable, high quality changing, I believe it is important for us to deal with
KOBELCO WELDING TODAY
products and excellent services, cultivated by the high capability of Monodzukuri your needs properly. By rotating the circle of “needs→
is published by
Marketing Center (production system innovation), so as to obtain your full trust in the KOBELCO brands. Hiroyuki Shimizu dealing→improvement” and receiving feedback on
Head of the Technical Center progress, we will continue deepening our activities to
Welding Business,
As we promise to make wholehearted efforts in order to meet your Welding Business
KOBE STEEL, LTD. KOBE STEEL, LTD. achieve our business vision of “being the most reliable
expectations, your support is most appreciated.
URL: http//www.kobelco.co.jp/english welding solutions company in the world.”
1 2
Technical Highlight ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ KOBELCO
WELDING
TODAY
B91 Series welding consumables Table 2: Trend of AWS B9/B91 standard
Vol.21 No.2 2018
for Grade 91 steels Upper limit of Upper limit of PWHT Chemical compositions and Ac1
Year
Mn+Ni content temperature at
in deposited metal specified for testing
Reference
(Year of revision) *2
3 transformation point of B91 Series
(mass %) *1 (°
C) welding consumables
Up to 759 (SMAW) or B9: SMAW, GMAW, Although 9Cb Series welding consumables are not
Not regulated*3 GTAW (1996)
2004 760 SAW (1997) entirely compatible with AWS specifications because
they are designed to obtain comparatively high Mn+Ni
B9: GMAW, GTAW
(2005) content, they have been utilized successfully in domestic
2005
-2010
1.5 or 1.50 775 SMAW (2006) and overseas projects in which PWHT temperature
SAW (2007)
FCAW (2010) requirements have been relatively low. However, in
B9 deleted → B91
cases where following AWS specifications is mandatory,
From newly established particularly in overseas projects, these consumables
2010 1.40 775 B91: SAW (2011),
onwards FCAW (2012)
could not be applied.
SMAW (2014) *4
KSL originally developed and marketed the B9 Series
Note: *1) Wire or cut rod chemistry in case of GMAW and GTAW
*2) AWS Specification No.: SMAW: A5.5; SAW: A5.23; GMAW & GTAW: consumables to be compatible with AWS specifications.
they have been well-received by many domestic and A5.28; FCAW: A5.36 The B91 Series consumables were later developed to
1 Preface
overseas boiler fabricators.
*3) Sum of both Mn and Ni specified upper limit figures is 2.25
*4) Revision of GMAW and GTAW is under discussion as of May, 2018. comply with stricter AWS requirements in 2012,
especially the ever-stricter limitations on Mn+Ni content.
The biggest concern in the field of thermal power On the other hand, an issue concerning high Cr ferritic Both tables show that the upper limits for Mn+Ni content
generation is the reduction of CO2 emissions. However, steel is the combined amount of Mn+Ni, which has have been repeatedly reduced in both sets of standards. In Table 3 shows the typical chemical compositions of
the most effective way of achieving that is to improve gradually come to be a subject of regulation. For example, welding Gr. 91 steels, this has allowed the upper limits on deposited metals and Ac1 transformation points, and Table
the efficiency of power generation, which requires such international standards bodies as ASME and AWS the temperature for PWHT, which is essential for reducing 4, the typical mechanical properties after PWHT, of the
steam at high temperature and pressure to be fed into have started to review the issue accordingly. residual stress after welding, to be eased higher. Following 9Cb and B91 Series consumables, respectively. It can be
power generating turbines. In Figure 1, it can be seen optimum PWHT, Gr. 91 weld metal exhibits a tempered seen that the B91 Series consumables are designed to
The B91 Series consumables, developed in accordance
that steam conditions (temperature and pressure) at martensite structure that provides excellent high provide the designated mechanical properties after PWHT
with these concerns, will be discussed as products
thermal power generation plants in Japan have trended temperature strength and toughness. However, it is while Mn+Ni content is controlled to be equal to or less
corresponding to the AWS standards.
up over the decades. well-understood that once the PWHT temperature exceeds than 1.0%, lower than that of the 9Cb Series consumables.
the Ac1 transformation point, fresh martensite transforms Figure 2 shows the relationship between Mn+Ni content
650
2 International standards
back into austenite, and, during cooling, returns to become and actually measured Ac1 transformation points. It can be
fresh martensite again, leading to deterioration of creep and seen that typical Ac1 transformation points actually
steam temperature at turbine inlet (℃)
50 620
610
toughness properties. Therefore, the content of Mn and Ni measured with the B91 Series consumables show 800 °C
steam pressure at turbine inlet (MPa)
3 4
Technical Highlight ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ KOBELCO
WELDING
TODAY
840 250 Vol.21 No.2 2018
740℃x10h
5 Usability of the B91 Series
740℃x2h
760℃x2h
780℃x2h
760℃x8h
780℃x8h
820
200 consumables
800
The usability of B91 Series consumables has also been
780 150
improved. As for covered electrodes for SMAW, alloy
vE+20℃ (J)
Ac1 (℃)
760
core rods are generally used to stabilize the alloying
100 element quality in welds of high-Cr ferritic steels;
740 Co:0.40%
User spec.
however, electrode burn frequently happens during
Co:0.80%
50
≧27J
CM-95B91 welding especially with DC (Direct Current).
Co:0.40-0.42%(B91Series)
720 TG-S90B91 CM-95B91 is designed to reduce electrode burn and can
Co:Not contained
PF-200S/US-90B91 achieve welding even in a higher range of welding
700
0.5 1 1.5 2 2.5
0
20.0 20.5 21.0 21.5 22.0 22.5
current than the conventional TRUSTARCTM CM-9Cb.
PWHT Parameter (x103) A problem peculiar to SAW consumables on high-Cr
Mn+Ni Content of Weld metal (mass%) ferritic steels, namely, the burnt-slag that sticks on weld
(L.M.P.: (T+273)×(C+logt), T:℃, t:h, C=20)
bead surface, has also been reduced. Figure 7 shows a
Figure 2: Relationship between Mn+Ni content and Ac1 Figure 3: Microstructure of CM-95B91 Figure 5: Relationship between L.M.P. and vE+20C° comparison of bead appearances by SAW with the
combination of B91 wire and the newly improved flux,
Another feature of B91 Series consumables is the Figure 5 shows the relationship between L.M.P. and and the conventional flux, respectively. It can be seen
4 Mechanical properties of that the adhesive slag on bead surface is greatly reduced
addition of cobalt (Co). As Figure 2 suggests, the Ac1 notch toughness at +20°C.
transformation point tends to fall in relation to the increase
B91 Series consumables with the improved SAW flux.
While notch toughness differs depending on the
in Mn+Ni content. While the B91 Series consumables Figure 4 shows the relationship between tensile welding consumables, all consumables exhibit better
contain Co, the element is not likely to affect the Ac1 strength (TS), 0.2% offset yield strength (0.2%OS) or Improved SAW flux
notch toughness when the L.M.P. is larger. In cases where
transformation point; after all, the consumables without 0.2% proof stress (0.2%PS) and the heat treatment the L.M.P. exceeds 21.0 x 10 3 , the obtained notch
Co also show a Ac1 transformation point that decreases in parameter, referred to as the Larson-Miller Parameter toughness values are sufficient enough for practical use.
relation to increases in Mn+Ni content. In fact, Co is (L.M.P.), in relation to CM-95B91, TRUSTARC TM
added for a different reason – restraining delta (δ) ferrite TG-S90B91 (AWS A5.28 ER90S-B9) and Figure 6 shows the creep rupture properties of
formation. Besides the Ac1 transformation point, another TRUSTARC T M PF-200S/US-90B91 (AWS A5.23 CM-95B91 and TG-S90B91.
influential factor on the Gr. 91 steels is the formation of δ F9PZ-EB91-B91).
ferrite structure. Because it is desirable that a weld 1000
contains no δ ferrite structure but 100% martensite It is clear that these welding consumables fully
structure, the Electric Power Research Institute (EPRI) satisfy the mechanical property requirements of Gr. 91 CM-95B91
TG-S90B91
proposed an index called Cr-Ni balance (CNB) less than steels (0.2%PS equal to or more than 415MPa and TS
10% in its report No. 1023199 “Guidelines and equal to or more than 585MPa) even at L.M.P.=22.0 x P91 steel (NIMS DATA SHEET NO.43A)
760℃x2h
740℃x6h
760℃x8h
780℃x8h
CM-95B91
Although Mn and Ni are known as the austenite 800 10
27.0 28.0 29.0 30.0 31.0 32.0
forming elements and the CNB equation also shows they TG-S90B91
Creep Parameter (x103)
0.2%PS, TS
can prevent δ ferrite formation, excessive amounts of Mn 700 PF-200S/ (L.M.P. : (T+273)×(C+logt), T: ℃, t:h, C=30)
and Ni are not allowed from the view point of AWS US-90B91
Open:0.2%PS
specification as well as Ac1 transformation point. For this 600 TS≧585MPa Figure 6: Creep rupture test results of CM-95B91 and TG-S90B91
Figure 7: Bead appearance comparison by SAW between
Solid:TS improved fluxes and conventional fluxes with B91 wire
reason, Co, another austenite forming element, is added
in order to restrain δ ferrite formation without changing 500
It confirms that these consumables provide more
Ac1 transformation point. sufficient creep rupture properties than those of the butt
0.2%PS≧415MPa joint welds (dotted line) even at PWHT temperature as
Figure 3 shows the microstructure of TRUSTARCTM 400
high as 780°C. Testing of the creep rupture properties of
20.0 20.5 21.0 21.5 22.0 22.5
CM-95B91 (AWS A5.5 E9015-B91), one of the B91 these consumables under an extended time creep condition
PWHT Parameter (x103)
Series consumables. The full tempered martensite (L.M.P.: (T+273)×(C+logt), T:℃, t:h, C=20) of 600°C x 100MPa is being carried out. For example, the
structure is easily recognized. tests of CM-95B91 and TG-S90B91 have passed 26,000
Figure 4: Relationship between L.M.P. and 0.2%P.S., T.S. and 21,000 hours respectively and are still in progress.
5 6
Technical Highlight ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■
Products Spotlight ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ ■ KOBELCO
WELDING
TODAY
PF-N5/US-609S for SAW on 9%Ni steels: Vol.21 No.2 2018
6 Notes on usage
Excellent solution in horizontal
As B91 Series consumables provide high Cr-ferritic [References]
and flat positions
weld metals with a high degree of self-hardening, in (1) Heat-Resistant High-Cr Ferritic Steel Filler Metals for
comparison with those for 1.25Cr-0.5Mo and Thermal Electric Power Boiler: KOBELCO WELDING TODAY
PREMIARC TM US-609S wire with PREMIARC TM The welded bead appearances of the first side and
2.25Cr-1Mo steels, their weld metals also have high Vol. 12 No. 1 (2009)
PF-N5 bonded type flux provides an excellent cross-sectional macrostructures of both the 12 and 30
delayed-crack susceptibility. It is, therefore, essential to (2) ASME B31.1: POST WELD HEAT TREATMENT, 132.1 (2014)
solution for submerged arc welding (SAW) of 9% mm plates are shown in Figures 1 and 2, respectively.
strictly control welding procedures. If the pre-heating (3) ASME Sec. II Part C, SFA-5.5 (2015)
Ni steels in horizontal and flat positions. The
and interpass temperatures are properly controlled, (4) ASME Sec. II Part C, SFA-5.23 (2015) US-609S wire is made of Hastelloy*1 C276 and is
delayed cracks are prevented and sound weld metals (5) ASME Sec. II Part C, SFA-5.28 (2015) classified in AWS A5.14/A5.14M as ERNiCrMo-4. Its
can be obtained. Pre-heating as well as interpass 12 mm thick
(6) ASME Sec. II Part C, SFA-5.36 (2015) typical chemical composition is shown in Table 1.
temperatures of 250-350°C are generally recommended.
(7) EPRI 1023199: Guidelines and Specifications for The mechanical properties of all weld metal by
Impurities like P and S in the B91 Series consumables High-Reliability Fossil Power Plants (2011) PF-N5/US-609S are shown in Table 2.
should be kept as low as possible in order to prevent hot (Note:*1 Hastelloy is a trademark of Haynes International.)
cracks from occurring during welding.
Table 1: Typical chemical composition of US-609S (wire mass%)
Because the weld metals by the B91 Series C Si Mn P S Cu Ni
30 mm thick
consumables are more susceptible to hot crack and have US-609S wire 0.01 0.03 0.5 <0.001 0.003 <0.01 58.3
a higher solid-liquid coexistent region than those of AWS
A5.14/A5.14M ≤0.02 ≤0.08 ≤1.0 ≤0.04 ≤0.03 ≤0.50 Rem
1.25Cr-0.5Mo and 2.25Cr-1Mo steel weld metals, ERNiCrMo-4 Figure 1: Bead appearances of the first side
welding should not be performed with excessively high Cr Mo Fe W Co V Other
welding current and speed from the view point of US-609S wire 15.9 15.9 5.6 3.5 <0.01 <0.005 <0.1
welding procedure. As for PWHT condition, it should be AWS
A5.14/A5.14M
14.5
to
15.0
to
4.0 3.0
to ≤2.5 ≤0.35 ≤0.50
to
carefully selected, taking required tensile strength and ERNiCrMo-4 16.5 17.0 7.0 4.5
notch toughness properties into consideration, even Table 2: Typical mechanical properties of all weld metal
though B91 Series consumables can be utilized at a high Tensile test Charpy impact test
temperature such as 760-780°C. 0.2% PS TS EL vE-196°C 12 mm 30 mm
(MPa) (MPa) (%) (J)
thick thick
PF-N5/US-609S 459 729 46 88, 102, 99: Ave 96
7 Postscript
Butt joint welding was performed on plates with
Figure 2: Cross-sectional macrostructures
thicknesses of 12 and 30 mm according to the The results of radiographic tests, butt joint tensile
There are three characteristics of the B91 Series welding parameters in Table 3. tests and Charpy impact tests as low as -196° C
welding consumables. The first is that they correspond (shown in Tables 4, 5, and 6 respectively) indicate that
Table 3: Welding parameters
to international standards such as ASME and AWS. the combination of PF-N5/US-609S can be applied for
Plate Welding condition
The second is that high PWHT temperatures can be thickness Pass sequence Pass Current Voltage Speed Speed
welding 9%Ni steels with satisfactory performances.
applied due to their high Ac1 transformation point. And mm (in.) (A) (V) (cm/min.) (in./min.)
Table 4: Radiographic test results
third, they are designed to obtain excellent creep 1 300 30 12
Plate thickness Indication size <0.8mm Indication size ≥0.8mm
rupture properties even in high PWHT conditions. 35° 2 340 40 16
(mm) in 600mm length in 600mm length
Table 5 compares the features of the B91 and 9Cb 12
3 4 3 360 40 16
12 0 6
1 4 360 26 50 20
Series consumables. (15/32) 6
2 30 20 8
60°7 5
5 360 40 16
9 10