Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 1
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
1. Identification of the Substance/Mixture and of the Company/Undertaking
1. 1. Product Identifier
Product Name: Cadmium Yellow No. 4, light
Article No.: 21030
1. 2. Relevant identified Uses of the Substance or Mixture and Uses advised against
Identified uses:
To dye plastics, varnishes and cement.
Production of ceramic coating suited for firing and decor
preparation for glass and ceramic.
Uses advised against:
Not for cosmetics, medicine, tattoo inks
1. 3. Details of the Supplier of the Safety Data Sheet (Producer/Importer)
Company: Kremer Pigmente GmbH & Co. KG
Address: Hauptstr. 41-47, 88317 Aichstetten, Germany
Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606
Internet: www.kremer-pigmente.de
EMail: info@kremer-pigmente.de
Importer: --
1. 4. Emergency No.
Emergency No.: +49 7565 914480 (Mon-Fri 8:00 - 17:00)
2. Hazards Identification
2. 1. Classification of the Substance or Mixture
Classification according to Regulation
(EC) No. 1272/2008 (CLP/GHS)
This product does not require classification and labelling as
hazardous according to CLP/GHS.
Classification according to Directive No.
67/548/EC or No. 1999/45/EC
The material is not subject to classification according to EC lists.
Safety Phrases:
Possible Environmental Effects:
2. 2. Label Elements
Classification according to Regulation
(EC) No. 1272/2008 (CLP/GHS)
This product does not require classification and labelling as
hazardous according to CLP/GHS.
Hazard designation:
Signal word:
Hazard designation:
Safety designation:
Keep out of reach of children.
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Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 2
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
P102
P270 Do not eat, drink or smoke when using this product.
Hazardous components for labelling:
2. 3. Other Hazards
No information available.
3. Composition/Information on Ingredients
3. 1. Substance
3. 2. Mixture
Chemical Characterization: Inorganic pigment, inorganic salt.
Cadmium zinc sulphide yellow
Information on Components / Hazardous
Ingredients:
Cadmium zinc sulfide yellow, Pigment Yellow 35, 50 - 100 % CAS-Nr: 8048-07-5
C.I. 77205 EINECS-Nr: 232-466-8
EC-Nr:
Additional information:
4. First Aid Measures
4. 1. Description of the First Aid Measures
General information:
Do not leave affected persons unattended.
After inhalation:
Get medical help.
In case of unconsciousness place patient stable in side position for
transportation.
Consult physician if symptoms persist.
After skin contact:
Wash with soap and rinse with plenty of water.
Remove contaminated clothing.
After eye contact:
Rinse open eye for several minutes under running water. Should
irritation continue, seek medical advice.
Remove contact lens.
Protect unharmed eye.
After ingestion:
Rinse mouth thoroughly with plenty of water and drink plenty of
water. Consult a physician.
Never give anything by mouth to an unconscious person.
Do not give milk or alcohol to drink.
4. 2. Most important Symptoms and Effects, both Acute and Delayed
Symptoms:
No further information available.
Effects:
No further information available.
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Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 3
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
4. 3. Indication of any Immediate Medical Attention and special Treatment needed
Treatment:
First-aid measures must be specified together with the responsible
physician for industrial medicine.
5. Fire-Fighting Measures
5. 1. Extinguishing Media
Suitable extinguishing media:
Use extinguishing media for surrounding fire.
Unsuitable extinguishing media:
None known.
5. 2. Special Hazards arising from the Substance or Mixture
Special hazards:
Do not let extinguishing water enter the sewerage system or water
courses.
5. 3. Advice for Firefighters
Protective equipment:
Wear self-contained respiratory protective device.
Further information:
Collect contaminated extinguishing water and debris separately;
avoid contamination of sewage system.
Contaminated extinguishing water and debris should be disposed
of according to local regulations.
6. Accidential Release Measures
6. 1. Personal Precautions, Protective Equipment and Emergency Procedures
Personal precautions:
Wear appropriate protective equipment. Keep spectators away.
Avoid formation of dust.
Ensure adequate ventilation.
6. 2. Environmental Precautions
Environmental precautions:
Prevent contamination of soils, drains and surface water.
Contact local authorities if product pollutes soil or vegetation.
6. 3. Methods and Material for Containment and Cleaning Up
Methods and material:
Take up mechanically and collect in suitable containers for
disposal. Avoid formation of dust and static discharges. Prevent
from getting into sewage system. Wear protective gear and self-
contained breathing apparatus.
6. 4. Reference to other Sections
Protective clothing, see Section 8.
7. Handling and Storage
7. 1. Precautions for Safe Handling
Instructions on safe handling:
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Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 4
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
Avoid formation of dust. Do not inhale dust.
Wear adequate protective clothing (see para. 8).
Hygienic measures:
Do not eat or drink during work. Do not smoke.
7. 2. Conditions for Safe Storage, including any Incompatibilities
Storage conditions:
Store in tightly sealed containers in a dry and well ventilated
location.
Do not store together with strong acids and oxidants.
Requirements for storage areas and
containers:
Electrical installation/working materials must comply with the
technological safety standards.
Information on fire and explosion
protection:
Avoid dust formation.
Provide adequate exhaust ventilation at places where dust is
formed.
Storage class (VCI):
13; Non combustible solids
Further Information:
Store in a dry place.
No decomposition if used and stored according to specifications.
7. 3. Specific End Use(s)
Further information:
The technical guidelines for the application of this product/mixture
should be followed.
8. Exposure Controls/Personal Protection
8. 1. Parameters to be Controlled
Does not contain substances with occupational exposure limits.
Parameters to be controlled (DE):
Parameters to be controlled:
Derived No-Effect Level (DNEL):
Predicted No-Effect Concentration
(PNEC):
Additional Information:
8. 2. Exposure Controls
Technical protective measures:
Technical protective measures have priority to personal protective
measures.
Personal Protection
General protective measures:
Wear adequate protective clothing.
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Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 5
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
Wash hands and face at the end of work. Carry out work under a
fume hood. Do inhale product.
Respiratory protection:
None required under normal operating conditions.
Hand protection:
In case of prolonged contact:
Recommended
Protective glove material:
Eye protection:
Safety glasses (EN 166)
Body protection:
Protective clothing.
Environmental precautions:
Avoid contamination of sewage system, open water ways and
ground water.
9. Physical and Chemical Properties
9. 1. Information on Basic Physical and Chemical Properties
Form: powder
Color: bright yellow
Odor: odorless
Odor threshold:
No information available.
pH-Value: 7 (5% suspension)
Melting temperature:
not available
Boiling temperature:
not available
Flash point:
not applicable
Evaporation rate:
not applicable
Flammability (solid, gas):
not applicable
Upper explosion limit:
no information available
Lower explosion limit:
no information available
Vapor pressure:
not determined
Vapor density:
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Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 6
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
No information available.
Density: 3.5 - 5.5 g/cm3
Solubility in water: insoluble
Coefficient of variation (n-
Octanol/Water):
not applicable
Auto-ignition temperature:
No information available.
Decomposition temperature: > 300°C
Viscosity, dynamic:
not applicable
Explosive properties:
not available
Oxidizing properties:
no information available
Bulk density:
not determined
9. 2. Further Information
Solubility in solvents:
Viscosity, kinematic
Burning class:
Solvent content:
Solid content:
Particle size:
No data available.
Other information:
10. Stability and Reactivity
10.1. Reactivity
Stable if used according to specifications.
10.2. Chemical Stability
No decomposition if used according to specifications.
10.3. Possibility of Hazardous Reactions
Reacts with acids: development of hydrogen sulfide.
Reacts with strong oxidants.
10.4. Conditions to Avoid
Conditions to avoid:
No information available.
Thermal decomposition:
No data available.
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Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 7
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
10.5. Imcompatible Materials
Strong acids and strong oxidizing agents.
10.6. Hazardous Decomposition Products
None if handled according to specifications.
10.7. Further Information
11. Toxicological Information
11. 1. Information on Toxicological Effects
Acute Toxicity
LD50, oral: > 5000 mg/kg
LD50, dermal:
No information available.
LC50, inhalation:
No information available.
Primary effects
Irritant effect on skin:
Non irritating
Irritant effect on eyes:
Non-irritating to eyes
Inhalation:
Ingestion:
Sensitization:
No relevant data found.
Mutagenicity:
No relevant data found.
Reproductive toxicity:
No relevant data found.
Carcinogenicity:
No relevant data found.
Teratogenicity:
No information available.
Specific target organ toxicity (STOT):
No relevant data found.
Additional toxicological information:
No information available.
12. Ecological Information
12. 1. Aquatic Toxicity
Fish toxicity:
No negative effects.
Daphnia toxicity:
No negative effects. next page: 8
Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 8
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
Bacteria toxicity:
No negative effects.
Algae toxicity:
No negative effects.
12. 2. Persistency and Degradability
Inorganic substance. Biological degradability is not affected.
12. 3. Bioaccumulation
No bioaccumulation expected.
12. 4. Mobility
No information available.
12. 5. Results of PBT- und vPvP Assessment
This product is neither a PBT or vPvB substance nor does it
contain a PBT or vPvB substance.
12. 6. Other Adverse Effects
Water hazard class:
Behaviour in sewage systems:
Further ecological effects:
No ecological data available.
AOX Value:
13. Disposal Considerations
13. 1. Waste Treatment Methods
Product:
Dispose of according to official national and local regulations.
European Waste Code (EWC):
Uncleaned packaging:
Empty containers can be landfilled after cleaning, when in
compliance with the Environmental Protection (Duty of Care)
Regulations 1991.
Waste Code No.:
14. Transport Information
14. 1. UN Number
ADR, IMDG, IATA
14. 2. UN Proper Shipping Name
ADR/RID:
No hazardous goods according to ADR (land transportation).
IMDG/IATA:
No hazardous goods according to IMDG.
14. 3. Transport Hazard Classes
ADR Class:
not applicable
Hazard no.:
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Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 9
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
Classification code:
Tunnel restriction code:
IMDG Class (sea):
Hazard no.:
EmS No.:
IATA Class:
Hazard no.:
14. 4. Packaging Group
ADR/RID:
not applicable
IMDG:
IATA:
14. 5. Environmental Hazards
None
14. 6. Special Precautions for User
Not classified as a dangerous good under transport regulations.
14. 7. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code
not applicable
14. 8. Further Information
15. Regulatory Information
15. 1. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture
Water hazard class:
1, slightly hazardous for water (German Regulation)
Local regulations on chemical accidents:
EC-Regulation 96/82 does not apply (2003).
Employment restrictions:
Restriction and prohibition of application:
EC. REACH, Section XVII, Restrictions on the Manufacture,
Placing on the Market and Use of Certain Dangerous Substances,
Preparations and Articles, Registered no. 23
The use of cadmium in pigments in certain polymers, as well as in
aqueous- and non-aqueous based paints is restricted.
Technical instructions on air quality:
15. 2. Chemical Safety Assessment
EC SVHC-List: This product does not contain a substance in the
candidate list for substances of very high concern (REACH
Regulation (EC) 1907/2006, Article 57)
15. 3. Further Information
This product is not a ozone-depleting substance (EC Reg.
2037/2000) and not a persistent organic pollutant (POP) (EC Reg.
850/2004).
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Safety Data Sheet
According to regulation (EC) No. 1907/2006 (REACH)
21030 Cadmium Yellow No. 4, light
Page 10
Revised edition: 04.10.2017 Version: 2 Printed: 04.10.2017
16. Other Information
This product should be stored, handled and used in accordance
with good hygiene practices and in conformity with any legal
regulations. This information contained herein is based on the
present state of knowledge and is intended to describe our product
from the point of view of safety requirements. It should be
therefore not be construed as guaranteeing specific properties.