Date : 02.02.
2015
MATERIAL SAFETY DATA SHEET MSDS : S 1000-01
Page : 1/ 5
SECTION I . PRODUCT AND COMPANY IDENTIFICATION Product
Name : ENTOX INSECTICIDE(AEROSOL)
Variants : 400 ml
Manufactorer’s Name : PRIVATE LABEL AEROSOL DOLUM SAN. TİC. A.Ş.
Adres : İstasyon Mah. Baraj Yolu 93. Sok. No:100
City : Ergene/ TEKİRDAĞ
Telephone : 282 674 53 88
Fax : 282 674 53 89
E-mail : info@privatelabel.com.tr
SECTION II . HAZARD IDENTIFICATION
Classification according to Regulation (EC) No 1272/2008 as amended
Flammable gas Category 1 H220: Extremely flammable gas.
H280: Contains gas under pressure; may
explode if
heated.
Classification according to Directive 67/548/EEC or 1999/45/EC as amended
F+; R12
The full text for all R-phrases is displayed in section 16.
Label elements
Labeling according to Regulation (EC) No 1272/2008 (CLP)
Signal Words : Danger
Hazard statements : H 220 : Extremely flammable gas
: H 229 : Pressurized container, may burst if heated
: H225 : Highly flammable liquid and vapour
Precautionary statements:
- General : P 102: Keep out of the reach for children
- Prevention : P 210: Keep away from heat/sparks/open flames/hot surfaces –
No smoking
: P 251 : Pressurized container. Do not pierce or burn, even after
use.
- Storage : P 410+ P 412 : Protect from sunlight. Do not expose to
temperatures
exceeding 50 ºC / 122 F
Labeling according to Directive 67/548 ECC or EC 1999/45
R-Phrases : R 12 Extremely Flammable
S-Phrases : S 2 Keep out of the reach of children
: S 16 Keep away from sources of ignition - No smoking
: S 17 Keep away from combustible material
: S 26 In case of contact with eyes, rinse immediately with
plenty of water
and seek medical advice.
: S 47 Keep at temperature not exceeding 50 ºC
Other Hazards
According to Regulation (ec) No 1272/2008 (CLP)
See section 12 – Results of PBT and vPvB assessment
If applicable information is provided in this section on other hazards which do not result in
classification but which may contribute to the overall hazards of the substance or mixture
SECTION III . COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous raw CAS % Classification (pure form) according to regulations
materials Number Range
European Directive (EC)1272/2008 (CLP)
67/548/EEC
Classificatio Concantration Hazard Hazard
n Limits Classification Statement
Butane 106-97-8 < 40 F+; R12 Flammable gases, H220 GHS02
Isobutane Propane 75-28-5 Category 1,)
74-98-6
Cypermethrin 52315-07-8 0,1-0,5 Xn; R20/22 Acute Tox. 4 * H332 GHS07
R43 Acute Tox. 4 * H302 GHS09
N; R50-53 STOT SE 3 H335 Wng
Aquatic Acute 1 H400
Aquatic Chronic 1 H410
Tetramethrin 7696-12-0 0,1-0,5 Not Not classified
classified
PBO(Piperonyl 51-03-6 0,3-0,7 Not Not classified
butoxide) classified
SECTION IV . FIRST AID MEASURES
Eye Contact : Immediately flush with plenty of water at least 15 minutes. Remove contact
lenses, if present and easy to do. Get medical attention if iritation develops or persists.
Skin Contact : Immediately flush skin with plenty of water. Remove and isolate
contaminated clothinand shoes. Get medical attention if iritation develops or persists. For
minör skin contact,
avoid spreading material on unaffected skin. Wash clothing separately before reuse.
Ingestion : If swallowed, DO NOT induce vomiting unless directed to do so by medical
personnel.
Never give anything by mouth to an unconscious person. Get medical attention
immediately.
Inhalation : Remove the fresh air. Oxygen or artificial respiration if needed. Do not use
mouth – to mouth method if victim inhaled the substance. Induce artificial respiration with the
aid of a pocket mask equipped with a one way valve or other proper respiratory medical
device. Call a physican if symptoms develop or persist.
Note : If you feel unwell, seek medical advice (show the label where possible)
Intentional misuse by delibaretely concentrating and inhaling aerosol products
may be harmful or fatal. Help stop inhalation abuse; for information visit
www.inhalant.org
SECTION V . FIRE FIGHTING MEASURES
Hazard Classification : Flammable.See Section XIV for Shipping
Classifications
: Containers may explode when heated. Vapor org as
may spread to
distant ignition sources and flash back.
Flash Point : Aerosol Level 1 per NFPA
Extinguishing Media : CO2, foams or dry chemicals.
Special Firefighting Procedures : Since pressurized aerosols cans may explode when
exposed to
excessive heat, protect from excessive heat with water
spray
Hazardous Combustion Products : Oxides of carbon, nitrogen, hydrocarbons & derivates
Content Under Pressure : Yes. Exposure to temparature > 120 ºF/50 °C
Explosive : Yes
Specific Hazards : Fire may produce irritating, corrosive and / or toxic
gases.
SECTION VI . ACCIDENTAL RELEASE MEASURES
SPILLS, LEAKS : Small or household quantities may be cleaned up and disposed
of in household trash. For large (industrial ) releases, prevent spill from entering a waterway.
Material may be slippery if spilled.
Methods for cleaning up : Wearing appropriate personal protective equipment. Soak up
with inert absorbent material. keep in suitable and closed containers for disposal. After
cleaning, flush away traces with water.
Personel precautions : Ensure adequate ventilation. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces
before entering. Keep unnecessary personnel away.
Methods for containment : Eliminate all ignition sources (no smoking, flares, sparks or
flames in immediate area) Stop leak if you can do so without risk . Move the cylinder to a
safe and open area if the leak is irreparable.
SECTION VII . HANDLING & STORAGE
Handling Precautions : Pressurized container. Do not pierce burn, even after use. Do
not handle or store near an open flame,, heat or other sources of ignition. Use only in
area provided with appropriate exhaust ventilation. Do not use if spray button is missing or
defective. Avoid prolenged exposure.
Storage Requirements : Level 1 Aerosol
Contents under pressure. Do not puncture, incinerate or crush.
The pressure in sealed containers can increase under the
influence of heat. Keep away from heat, sparks, and flame.
Avoid exposure to long periods of sunlight. Store in cool place.
Keep the container dry. Keep in an area equipped with
sprinklers. Keep out of the reach of children.
Note To Parents :Intentional misuse by delibaretely concentrating and inhaling
aerosol products may be harmful or fatal. Read label instructions carefully.
SECTION VIII . EXPOSURE CONTROLS/ PERSONAL PROTECTION
Chemical Name Cas No ACGIH TLV OSHA PEL
Butane 106-97-8 TWA= 1000 ppm NA
Isobutane 75-28-5 TWA= 1000 ppm
Propane 74-98-6 TWA= 1000 ppm TWA=1000 ppm
TWA=1800 mg/m³
Personal Protection
Engineering controls : Ensure adequate ventilation, especially in confined areas.
Eye/ Face Protection : Wear chemical goggles
Skin Protection : Protective gloves. Wear chemical protective equipment that is
specifically recommended by the manufacturer.
Respiratory Protection : When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.
For Routine Consumer Use : Special precautions are not necessary.
General Hygiene Considerations: When using do not smoke. Handle in accordance with good
industrial hygiene and safety practice
SECTION IX . PHYSICAL & CHEMICAL PROPERTIES
Form Liquid in Colour Opaque
pressurized metal
can
Odour Characteristic Solubility Soluble in water
Melting Point Not available pH (Liquid) 5-8
Density (25 °C) 0,95 g/ml
(Liquid)
SECTION X . STABILITY & REACTIVITY
Stable : Stable under recommended storage conditions.
Hazardous Decomposition Products : oxides of carbon and unknown organic compounds
Incompatible With : Strong oxidizers, acids or bases. Do not expose to heat
or in enclosed places that could overheat
Special Conditions To Avoid : Avoid freezing. Keep away from open flames, hot
surfaces, sunlight or impact, sources of ignition Avoid temparatures above 50 °C / 120 ° F
SECTION XI . TOXICOLOGICAL INFORMATION
COMPENENT TOXICITY
Chemical Name Cas No LD 50 Oral- LD 50 Dermal- LC 50
With Units – With Units – Inhalation –
Rat - mg/kg Rat -Rabbit - With units- Rat/
mg/kg Rabbit
Tetramethrin 7696-12-0 > 5000 mg/kg Rat > 2000
mg/kg
ACUTE EFFECTS
Eye Contact : May cause redness or iritation. Causes burns.
Skin Contact : Overexposure may cause a skin reaction such as redness. Causes burns.
Ingestion : May cause nausea, vomiting and diarhea. Harmful if swallowed.
Respiratory : Intentional misuse by deliberately concentrating and inhaling the contents can
cause serious injury or death.
CARCINOGEN EFFECTS No data available
SECTION XII . ECOLOGICAL INFORMATION
Ecotoxicity effects : No data available
SECTION XIII . DISPOSAL CONSIDERATION
Disposal by Consumer :
PESTICIDAL WASTE: Observe all applicable ederal, Provincial and State regulations and
Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or
recycle where facilities exist.
Contents under pressure. Do not puncture or incinerate.
Waste Codes : DOO1 Waste Flammable material with flash point< 130° F
SECTION XIV . TRANSPORT INFORMATION
FOR SHIPMENT DOMESTIC - INTERNATIONAL- INTERNATIONAL –
IN CONSUMER ALL MODES AIR WATER
PACKACING (US DOT) (IATA /ICAO) (IMO / IMDG)
Proper Shipping Aerosols Aerosols Aerosols
Name
Hazard Class 2.1 2.1 2.1
UN / ID UN 1950 UN 1950 UN 1950
Packing Group Not Applicable Not Applicable Not Applicable
EMERGENCY GUIDE NUMBER : UN 1950 Aerosol =126/171
DOT HAZARDOUS SUBSTANCE RQ : Insecticides or insect repellents
DOT MARINE POLLUTANTS : None / no reportable quantities
IATA FORBIDDEN SUBSTANCES : None / no reportable quantities
SECTION XV . REGULATORY INFORMATION
Regulatory Information : Cosmetic product regulated is 76/768 EEC “Cosmetics
Directive”
RCRA : See section XIII . Disposal Considerations
CAA HAPS or ozone Depletors : None /no reportable quantities
CERCLA/SARA 302 Hazardous Substances : None /no reportable quantities
CERCLA/SARA 311/312 Hazardous Categories : None /no reportable quantities
CERCLA / SARA 313 Emission Reporting : Butane, Propane, Isobutane , Permethrin,
Tetramethrin, Piperonyl butoxide
CERCLA RQ : None /no reportable quantities
CA Proposition 65 listed Chemicals : None /no reportable quantities
CA 22 CCR Hazardous Wastes : None /no reportable quantities
Safety phrases:
S 2 Keep out of the reach of children
S 16 Keep away from sources of ignition - No smoking
S 17 Keep away from combustible material
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S 61 Avoid release to the environment. Refer to special instructions/safety data sheet
SECTION XVI . OTHER INFORMATIONS
Notice to Reader
The information provided in this MSDS is correct to the best of our knowledge, information and belief at
the date of its
publication and is in our opinion consistent with the state of general scientific and technical knowledge at
that date,
but we can not accept liability for loss,injury or damage which may result froam its use. It does not
constituate
a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions
of use and handling are beyond sellers's control. Use is responsible to evaluate all available information
when using product for any particular use and to comply with all Federal, State, Provincial and Local laws
and regulations.
