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Vivekananda Academy: Online Test Batch Poly TRB Chemistry Portion

The document outlines the content of an online test for the VIVEKANANDA ACADEMY's PG Test 10 focused on thermodynamics and statistical thermodynamics. Key topics include the laws of thermodynamics, Maxwell relations, chemical potential, fugacity, and various distribution functions. It also covers non-equilibrium thermodynamics and applications related to diffusion potential and entropy production.

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Emayavaramban Mani
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34 views1 page

Vivekananda Academy: Online Test Batch Poly TRB Chemistry Portion

The document outlines the content of an online test for the VIVEKANANDA ACADEMY's PG Test 10 focused on thermodynamics and statistical thermodynamics. Key topics include the laws of thermodynamics, Maxwell relations, chemical potential, fugacity, and various distribution functions. It also covers non-equilibrium thermodynamics and applications related to diffusion potential and entropy production.

Uploaded by

Emayavaramban Mani
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
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VIVEKANANDA ACADEMY

ONLINE TEST BATCH


POLY TRB CHEMISTRY PORTION

PG TEST 10 (15.08.21)

Thermodynamics: First and second Laws of thermodynamics – relation


between Cp and Cv in terms of coefficients of expansion and compressibility.
Maxwell relations - partial molar properties - Glibbs' Duhem equation –
variation of chemical potential with temperature and pressure – fugacity – Third
law and calculation of entropy. Statistical thermodynamics: Maxwell
Boltzmann, Bose-Einstein and Fermi-Dirac distribution- Partition function,
translational, rotational and vibrational partition function, calculation of
thermodynamic functions, equilibrium constant and heat
capacity from partition functions. Einstein and Debye theories of heat capacity
of solids, concept of negative absolute temperature.
Non equilibrium, thermodynamics: Phenomenological laws - Onsagers'
reciprocity relation - application to Diffusion potential, electrokinetic
phenomena – entropy production.

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