Safety Data Sheet
Druckdatum: 03.09.2012 überarbeitet am: 24.07.2012
1. IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY /UNDERTAKING
Product identifier
Productname: VA-013 (Art.-Nr. V60-0164 1,5l, V60-0165 5l)
Details oft he supplier oft he safety data sheet:
9,(52/$*
.DUOVWUDH
2OGHQEXUJ
Tel : 0049 (0)
Fax : 0049 (0)
Product Information:
Tel: 0049 (0)
Health Emergency:
Notrufnummer: 0049 (0)551/ 19240 – Gift-Informationszentrum Nord (Göttingen)
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
DSD/DPD CLASSIFICATION: Xn; R22 |
2.2 Label elements
Under the criteria of Directive 1999/45/EC (dangerous preparations):
- contains: Ethylene glycol
Symbols:
Xn - Harmful
R22; Harmful if swallowed.
S2; Keep out of the reach of children.
S46; If swallowed, seek medical advice immediately and show this container or label.
3. COMPOSITION / INFORMATION ON INGREDIENTS
3.1 Mixtures
This material is a mixture.
COMPONENTS EC NUMBER SYMBOL / RISK AMOUNT
PHRASES
Ethylene glycol 203-473-3 Xn/R22 60-100 % weight
Glycerol 200-289-5 None 10-30 % weight
Sodium 2- 243-283-8 Xn/Repro. Cat. 3/R63 1-4.99 % weight
ethylhexanoate
The full text of all R-phrases is shown in Section 16. This product contains a bittering agent.
COMPONENTS CAS NUMBER EC NUMBER REGISTRATION CLP AMOUNT
NUMBER CLASSIFICATION
Ethylene 107-21-1 203-473-3 01-2119456816- Acute Tox. 60-100 %
glycol 2 4/H302; STOT RE weight
2/H373
Glycerol 56-81-5 200-289-5 ** None 10-30 %
weight
Sodium 2- 19766-89-3 243-283-8 ** Repr. 2/H361d 1-4.99
ethylhexanoate %weight
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The full text of all CLP H-statements is shown in Section 16.
** Not available or substance is not currently required for registration under REACH.
4. FIRST AID MEASURES
4.1 Description of first aid measures
Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and
flush eyes with water.
Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if
contaminated. To remove the material from skin, use soap and water. Discard contaminated clothing and
shoes or thoroughly clean before reuse.
Ingestion: If swallowed, get medical attention. Do not induce vomiting. Never give anything by mouth to
an unconscious person.
Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air,
move the exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs.
4.2 Most important symptoms and effects, both acute and delayed
IMMEDIATE SYMPTOMS AND HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin is not expected to be harmful.
Ingestion: May be harmful if swallowed.
Inhalation: Not expected to be harmful if inhaled. Breathing this material at concentrations above the
recommended exposure limits may cause central nervous system effects. Central nervous system effects may
include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision, drowsiness,
confusion, or disorientation. At extreme exposures, central nervous system effects may include respiratory
depression, tremors or convulsions, loss of consciousness, coma or death.
DELAYED OR OTHER SYMPTOMS AND HEALTH EFFECTS: Not classified.
4.3 Indication of any immediate medical attention and special treatment needed
Not applicable.
5. FIRE FIGHTING MEASURES
5.1 Extinguishing media
Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames. Dry Chemical, CO2,
AFFF Foam or alcohol resistant foam.
5.2 Special hazards arising from the substance or mixture
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne
solids, liquids, and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds
will be evolved when this material undergoes combustion.
5.3 Advice for firefighters
This material will burn although it is not easily ignited. For fires involving this material, do not enter any
enclosed or confined fire space without proper protective equipment, including self-contained breathing
apparatus.
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Eliminate all sources of ignition in vicinity of spilled material. Refer to Sections 5 and 8 for more information.
6.2 Environmental precautions
Stop the source of the release if you can do it without risk. Contain release to prevent further
contamination of soil, surface water or groundwater.
6.3 Methods and material for containment and cleaning up
Clean up spill as soon as possible, observing precautions in Exposure Controls/Personal Protection. Use
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appropriate techniques such as applying non-combustible absorbent materials or pumping. Where feasible and
appropriate, remove contaminated soil and dispose of in a manner consistent with applicable requirements. Place
other contaminated materials in disposable containers and dispose of in a manner consistent with applicable
requirements. Report spills to local authorities as appropriate or required.
6.4 Reference to other sections
See sections 8 and 13.
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Do not taste or swallow. Keep out of the reach of children.
7.2 Conditions for safe storage, including any incompatibilities
General Handling Information: Avoid contaminating soil or releasing this material into sewage and
drainage systems and bodies of water.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty
container or it may rupture with explosive force. Empty containers retain product residue (solid, liquid,
and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
such containers to heat, flame, sparks, static electricity, or other sources of ignition. They may explode and cause
injury or death. Empty containers should be completely drained, properly closed, and promptly returned to a drum
reconditioner or disposed of properly.
7.3 Specific end use(s):Antifreeze/Coolant
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 2), applicable exposure limits, job activities, and other
substances in the work place when designing engineering controls and selecting personal protective equipment. If
engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the
personal protective equipment listed below is recommended. The user should read and understand all instructions
and limitations supplied with the equipment since protection is usually provided for a limited time or under certain
circumstances. Refer to appropriate CEN standards.
8.1 Control parameters
Occupational Exposure Limits:
Component Country/Agency TWA STEL Ceiling Notation
Ethylene EU-Indicative 52 mg/m3 104 mg/m3 -- Skin
glycol
Ethylene United Kingdom 52 mg/m3 104 mg/m3 -- Skin
glycol
Glycerol United Kingdom 10 mg/m3 -- -- --
8.2 Exposure controls
ENGINEERING CONTROLS:
Use in a well-ventilated area.
PERSONAL PROTECTIVE EQUIPMENT
Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear
safety glasses with side shields as a good safety practice.
Skin Protection: No special protective clothing is normally required. Where splashing is possible, select
protective clothing depending on operations conducted, physical requirements and other substances in
the workplace. Suggested materials for protective gloves include: Natural rubber, Neoprene, Nitrile
Rubber, Polyvinyl Chloride (PVC or Vinyl).
Respiratory Protection: No respiratory protection is normally required.
ENVIRONMENTAL EXPOSURE CONTROLS:
See relevant Community environmental protection legislation or the Annex, as applicable.
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9. PHYSICAL AND CHEMICAL PROBERTIES
Attention: the data below are typical values and do not constitute a specification.
9.1 Information on basic physical and chemical properties
Appearance
Color: Red
Physical State: Liquid
Odor: Faint or Mild
Odor Threshold: No data available
pH: 8.6
Melting Point: No data available
Freezing Point: No data available
Initial Boiling Point: 178°C (352.4°F) (Typical)
Flashpoint: Not Applicable
Flammability (solid, gas): No Data Available
Flammability (Explosive) Limits (% by volume in air):
Lower: No Data Available Upper: No Data Available
Vapor Pressure: No data available
Vapor Density (Air = 1): >1
Relative Density: 1.1 (Estimated) @ 20°C (68°F) / 20°C (68°F)
Density: 1.1 kg/l @ 20°C (68°F) (Typical)
Solubility: Miscible
Partition coefficient:
n-octanol/water: No data available
Auto-ignition temperature: Not Applicable
Decomposition temperature: No Data Available
Viscosity: No data available
Explosive Properties: No Data Available
Oxidising properties: No Data Available
9.2 Other Information: No Data Available
10. STABILITY AND REACTIVITY
10.1 Reactivity: This material is not expected to react.
10.2 Chemical Stability: This material is considered stable under normal ambient and anticipated storage
and handling conditions of temperature and pressure.
10.3 Possibility of hazardous reactions: Hazardous polymerization will not occur.
10.4 Conditions to Avoid: Not applicable
10.5 Incompatible materials to avoid: May react with strong oxidizing agents, such as chlorates, nitrates,
peroxides, etc. May react with strong acids or strong oxidizing agents, such as chlorates, nitrates,
peroxides, etc.
10.6 Hazardous decomposition products: Aldehydes (Elevated temperatures), Ketones (Elevated
temperatures)
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Serious Eye Damage/Irritation: The eye irritation hazard is based on evaluation of data for product
components.
Skin Corrosion/Irritation: The skin irritation hazard is based on evaluation of data for product
components.
Skin Sensitization: The skin sensitization hazard is based on evaluation of data for product components.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for product
components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for product components.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for product
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components.
Germ Cell Mutagenicity: The hazard evaluation is based on data for components or a similar material.
Carcinogenicity: The hazard evaluation is based on data for components or a similar material.
Reproductive Toxicity: The hazard evaluation is based on data for components or a similar material.
Specific Target Organ Toxicity- Single Exposure: The hazard evaluation is based on data for components or a
similar material.
Specific Target Organ Toxicity - Repeated Exposure: The hazard evaluation is based on data for
components or a similar material.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains ethylene glycol (EG). The toxicity of EG via inhalation or skin contact is expected to be
slight at room temperature. The estimated oral lethal dose is about 100 cc (3.3 oz.) for an adult human. Ethylene
glycol is oxidized to oxalic acid which results in the deposition of calcium oxalate crystals mainly in the brain
and kidneys. Early signs and symptoms of EG poisoning may resemble those of alcohol intoxication. Later,
the victim may experience nausea, vomiting, weakness, abdominal and muscle pain, difficulty in breathing and
decreased urine output. When EG was heated above the boiling point of water, vapors formed which reportedly
caused unconsciousness, increased lymphocyte count, and a rapid, jerky movement of the eyes in persons
chronically exposed. When EG was administered orally to pregnant rats and mice, there was an increase in fetal
deaths and birth defects. Some of these effects occurred at doses that had no toxic effects on the mothers.
We are not aware of any reports that EG causes reproductive toxicity in human beings.
2-Ethylhexanoic acid (2-EXA) caused an increase in liver size and enzyme levels when repeatedly
administered to rats via the diet. When administered to pregnant rats by gavage or in drinking water, 2-EXA
caused teratogenicity (birth defects) and delayed postnatal development of the pups. Additionally, 2-EXA
impaired female fertility in rats. Birth defects were seen in the offspring of mice who were administered
sodium 2-ethylhexanoate via intraperitoneal injection during pregnancy.
12. ECOLOGICAL INFORMATION
12.1 Toxicity
This material is not expected to be harmful to aquatic organisms. The product has not been tested. The
statement has been derived from the properties of the individual components.
12.2 Persistence and degradability
This material is expected to be readily biodegradable. The product has not been tested. The statement
has been derived from the properties of the individual components.
12.3 Bioaccumulative potential
Bioconcentration Factor: No Data Available
Octanol/Water Partition Coefficient: No data available
12.4 Mobility in soil
No data available.
12.5 Results of PBT and vPvB assessment
This product is not, or does not contain, a substance that is a potential PBT or a vPvB.
12.6 Other adverse effects
No other adverse effects identified.
13. DISPOSAL CONSIDERATIOINS
13.1 Waste treatment methods
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet
the criteria of a hazardous waste as defined by international, country, or local laws and regulations. In
accordance with European Waste Catalogue (E.W.C.) the codification is the following: 16 01 14
14. TRANSPORT INFORMATION
The description shown may not apply to all shipping situations. Consult appropriate Dangerous Goods
Regulations for additional description requirements (e.g., technical name) and mode-specific or
quantity-specific shipping requirements.
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ADR/RID
NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT
14.1 UN number: Not applicable
14.2 UN proper shipping name: Not applicable
14.3 Transport hazard class(es): Not applicable
14.4 Packing group: Not applicable
14.5 Environmental hazards: Not applicable
14.6 Special precautions for user: Not applicable
ICAO
NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT
14.1 UN number: Not applicable
14.2 UN proper shipping name: Not applicable
14.3 Transport hazard class(es): Not applicable
14.4 Packing group: Not applicable
14.5 Environmental hazards: Not applicable
14.6 Special precautions for user: Not applicable
IMO
NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORT
14.1 UN number: Not applicable
14.2 UN proper shipping name: Not applicable
14.3 Transport hazard class(es): Not applicable
14.4 Packing group: Not applicable
14.5 Environmental hazards: Not applicable
14.6 Special precautions for user: Not applicable
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code: Not applicable
15. REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
REGULATORY LISTS SEARCHED:
01=EU. Directive 76/769/EEC: Restrictions on the marketing and use of certain dangerous substances.
02=EU Directive 90/394/EEC: Carcinogens at work.
03=EU Directive 92/85/EEC: Pregnant or breastfeeding workers.
04=EU Directive 96/82/EC (Seveso II): Article 9.
05=EU Directive 96/82/EC (Seveso II): Articles 6 and 7.
06=EU Directive 98/24/EC: Chemical agents at work.
07=EU Directive 2004/37/EC: On the protection of workers.
08=EU Regulation EC No. 689/2008: Annex 1, Part 1.
09=EU Regulation EC No. 689/2008: Annex 1, Part 2.
10=EU Regulation EC No. 689/2008: Annex 1, Part 3.
11=EU Regulation EC No. 850/2004: Prohibiting and restricting persistant organic pollutants (POPs).
12=EU REACH, Annex XVII: Restrictions on manufacture, placing on the market and use of certain dangerous
substances, mixture & article.
13=EU REACH, Annex XIV: Candidate List of Substances of Very High Concern for Authorization (SVHC).
The following components of this material are found on the regulatory lists indicated.
Ethylene glycol 06
CHEMICAL INVENTORIES:
All components comply with the following chemical inventory requirements: AICS (Australia), EINECS
(European Union), IECSC (China), PICCS (Philippines), TSCA (United States).
One or more components does not comply with the following chemical inventory requirements: DSL
(Canada), ENCS (Japan), KECI (Korea).
15.2 Chemical safety assessment
No chemical safety assessment.
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16. OTHER INFORMATION
REVISION STATEMENT: This revision updates the following sections of this Material Safety Data Sheet:
3, 16.
Revision Date: FEBRUARY 02, 2012
Full text of R-phrases:
R22; Harmful if swallowed.
R63; Possible risk of harm to the unborn child.
Full text of CLP H-statements:
H302; Harmful if swallowed
H361d; Suspected of damaging the unborn child
H373; May cause damage to organs through prolonged or repeated exposure
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA – Time Weighted Average
STEL – Short-term Exposure Limit PEL – Permissible Exposure Limit
CVX CAS – Chemical Abstract Service Number
NQ – Not Quantifiable
Prepared according to the criteria of EU Regulation 1907/2006 by the Chevron Energy Technology
Company, 100 Chevron Way, Richmond, California 94802.
The above information is based on the data of which we are aware and is believed to be correct as of the
date hereof. Since this information may be applied under conditions beyond our control and with which
we may be unfamiliar and since data made available subsequent to the date hereof may suggest
modifications of the information, we do not assume any responsibility for the results of its use. This
information is furnished upon condition that the person receiving it shall make his own determination of
the suitability of the material for his particular purpose.
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