Safety data sheet

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015

SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier

Protectol® PE
Chemical name: 2-phenoxyethanol
CAS Number: 122-99-6

REACH registration number: 01-2119488943-21-0000, 01-2119488943-21-0006

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: biocide

For the detailed identified uses of the product see appendix of the safety data sheet.

1.3. Details of the supplier of the safety data sheet

Company:
BASF SE
67056 Ludwigshafen
GERMANY
Operating Division Care Chemicals

Telephone: +49 621 60-44676

E-mail address: emd-ems-ehs-masterdata@basf.com

1.4. Emergency telephone number

International emergency number:

Telephone: +49 180 2273-112

SECTION 2: Hazards Identification

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
2.1. Classification of the substance or mixture

According to Regulation (EC) No 1272/2008 [CLP]

Acute Tox. 4 (oral)

Eye Dam./Irrit. 2

For the classifications not written out in full in this section the full text can be found in section 16.

2.2. Label elements

Globally Harmonized System, EU (GHS)

Pictogram:

Signal Word:
Warning

Hazard Statement:
H319 Causes serious eye irritation.
H302 Harmful if swallowed.

Precautionary Statements (Prevention):

P280 Wear eye/face protection.
P270 Do not eat, drink or smoke when using this product.
P264 Wash with plenty of water and soap thoroughly after handling.

Precautionary Statements (Response):

P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P301 + P330 IF SWALLOWED: rinse mouth.
P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.

Precautionary Statements (Disposal):

P501 Dispose of contents/container to hazardous or special waste collection
point.

According to Regulation (EC) No 1272/2008 [CLP]

Hazard determining component(s) for labelling: 2-PHENOXYETHANOL

2.3. Other hazards

According to Regulation (EC) No 1272/2008 [CLP]

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015

No specific dangers known, if the regulations/notes for storage and handling are considered.

SECTION 3: Composition/Information on Ingredients

3.1. Substances

Chemical nature

2-phenoxyethanol
CAS Number: 122-99-6
EC-Number: 204-589-7
INDEX-Number: 603-098-00-9

For the classifications not written out in full in this section, including the indication of danger, the
hazard symbols, the R phrases, and the hazard statements, the full text is listed in section 16.

3.2. Mixtures

Not applicable

SECTION 4: First-Aid Measures

4.1. Description of first aid measures
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:

Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an
eye specialist.

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

SECTION 5: Fire-Fighting Measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam

5.2. Special hazards arising from the substance or mixture

harmful vapours, carbon oxides
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire. Vapours may form explosive mixture with air.

5.3. Advice for fire-fighters

Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.

SECTION 6: Accidental Release Measures

High risk of slipping due to leakage/spillage of product.

6.1. Personal precautions, protective equipment and emergency procedures

Use personal protective clothing. Information regarding personal protective measures see, section 8.

6.2. Environmental precautions

Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.

6.3. Methods and material for containment and cleaning up

For large amounts: Dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material.
Dispose of absorbed material in accordance with regulations.

6.4. Reference to other sections

Information regarding exposure controls/personal protection and disposal considerations can be
found in section 8 and 13.

SECTION 7: Handling and Storage

7.1. Precautions for safe handling
Prevent contact with air/oxygen (formation of peroxide).
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015

Protection against fire and explosion:

Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should
be kept handy.

7.2. Conditions for safe storage, including any incompatibilities

Suitable materials for containers: Stove-lacquer RDL 50, glass, High density polyethylene (HDPE),
Low density polyethylene (LDPE), tinned carbon steel (Tinplate)
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated
place. Keep under nitrogen. Protect from atmospheric humidity.

The product is not damaged by low temperatures or by frost.

Protect from temperatures above: 100 °C

7.3. Specific end use(s)

See exposure scenario(s) in the attachment to this safety data sheet.

SECTION 8: Exposure Controls/Personal Protection

8.1. Control parameters

Components with occupational exposure limits

122-99-6: 2-phenoxyethanol

Components with PNEC

122-99-6: 2-phenoxyethanol
freshwater: 0.943 mg/l
marine water: 0.0943 mg/l
intermittent release: 3.44 mg/l
sediment (freshwater): 7.2366 mg/kg
sediment (marine water): 0.7237 mg/kg
soil: 1.26 mg/kg
STP: 24.8 mg/l

Components with DNEL

122-99-6: 2-phenoxyethanol
worker: Long-term exposure - systemic and local effects, Inhalation: 8.07
mg/m3
worker: Long-term exposure- systemic effects, dermal: 34.72 mg/kg
consumer: Long- and short-term exposure - local effects, Inhalation: 2.5 mg/m3
consumer: Long-term exposure- systemic effects, dermal: 20.83 mg/kg
consumer: Long- and short-term exposure - systemic effects, oral: 17.43 mg/kg

8.2. Exposure controls

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. (Particle filter EN 143 P2 or FFP2)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
fluoroelastomer (FKM) - 0.7 mm coating thickness
Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding >
30 minutes of permeation time according to EN 374)
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).

General safety and hygiene measures

Wearing of closed work clothing is recommended. No eating, drinking, smoking or tobacco use at the
place of work. Handle in accordance with good industrial hygiene and safety practice.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Form: liquid
Colour: colourless
Odour: faint specific odour
Odour threshold:
not determined
pH value: 7
(10 g/l, 20 °C)
Melting point: 9.1 °C (Directive 92/69/EEC, A.1)
(1,013 hPa)
Boiling point: 244.3 °C (Directive 92/69/EEC, A.2)
decomposition point: > 350 °C (OECD Guideline 103)
Flash point: 126 °C (Directive 92/69/EEC, A.9,
closed cup)
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
Evaporation rate:
not determined
Flammability: not flammable
Lower explosion limit: 1.4 %(V)
Upper explosion limit: 9.0 %(V)
Ignition temperature: 475 °C (DIN 51794)
Vapour pressure: 0.01 hPa
(20 °C)
Density: 1.11 g/cm3
(20 °C)
Relative density:
No data available.
Relative vapour density (air):
Heavier than air.
Solubility in water:
24 g/l
(20 °C)
Partitioning coefficient n-octanol/water (log Kow): 1.2 (OECD Guideline 107)
(23 °C; pH value: 7)
Self ignition: Based on its structural properties the
product is not classified as self-
igniting.

Thermal decomposition: not determined

Viscosity, dynamic: 41 mPa.s (OECD 114)
(19.8 °C)
19 mPa.s (OECD 114)
(40.5 °C)
Explosion hazard: Based on the chemical structure
there is no indicating of explosive
properties.
Fire promoting properties: Based on its structural properties
the product is not classified as
oxidizing.

9.2. Other information

Self heating ability: It is not a substance capable of

spontaneous heating.

Surface tension: 70.7 mN/m (Directive 79/831/EEC, A.5)

(19.9 °C; 1 g/l)
Grain size distribution: The substance / product is marketed or used in a non solid or
granular form.
Other Information:
If necessary, information on other physical and chemical parameters is indicated in this section.

SECTION 10: Stability and Reactivity

10.1. Reactivity
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
No hazardous reactions if stored and handled as prescribed/indicated.

Corrosion to metals: Corrosive effects to metal are not anticipated.

Formation of Remarks: Forms no flammable gases in the
flammable gases: presence of water.

10.2. Chemical stability

The product is stable if stored and handled as prescribed/indicated.

Peroxides: The product/the substance has a tendency towards the formation of

peroxide.

10.3. Possibility of hazardous reactions

May form explosive peroxides when exposed to air. Substance/product can form explosive mixture
with air.
The product is stable if stored and handled as prescribed/indicated.

10.4. Conditions to avoid

Avoid heat. Avoid contact with air. Avoid humidity.

10.5. Incompatible materials

Substances to avoid:
strong oxidizing agents

10.6. Hazardous decomposition products

Hazardous decomposition products:

No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information

11.1. Information on toxicological effects

Acute toxicity

Assessment of acute toxicity:

Of moderate toxicity after single ingestion. Virtually nontoxic after a single skin contact. Inhalation-
risk test (IRT): No mortality within 8 hours as shown in animal studies. The inhalation of a highly
saturated vapor-air mixture represents no acute hazard.

Experimental/calculated data:
LD50 rat (oral): > 300 - 2,000 mg/kg

rat (by inhalation): 8 h (IRT)

No mortality within the stated exposition time as shown in animal studies.

LD50 rabbit (dermal): > 5,000 mg/kg

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015

Information on: 2-phenoxyethanol

Experimental/calculated data:
LD50 rat (oral): 2,740 mg/kg (BASF-Test)
The European Union (EU) has classified this substance as 'harmful'.
----------------------------------

Irritation

Assessment of irritating effects:

Not irritating to the skin. Eye contact causes irritation.

Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404)

Serious eye damage/irritation rabbit: Irritant. (OECD Guideline 405)

Respiratory/Skin sensitization

Assessment of sensitization:
Skin sensitizing effects were not observed in animal studies.

Experimental/calculated data:
Guinea pig maximization test guinea pig: Non-sensitizing. (OECD Guideline 406)

Germ cell mutagenicity

Assessment of mutagenicity:
The substance was not mutagenic in bacteria. No mutagenic effect was found in various tests with
mammalian cell culture and mammals.

Carcinogenicity

Assessment of carcinogenicity:
No data available concerning carcinogenic effects.

Reproductive toxicity

Assessment of reproduction toxicity:

The results of animal studies gave no indication of a fertility impairing effect.

Developmental toxicity

Assessment of teratogenicity:
Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the
parental animals.

Specific target organ toxicity (single exposure)

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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
Remarks: No data available.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure)

Assessment of repeated dose toxicity:

No data available.

No reliable data was available concerning repeated dose toxicity.

Aspiration hazard

Study scientifically not justified.

SECTION 12: Ecological Information

12.1. Toxicity

Assessment of aquatic toxicity:

There is a high probability that the product is not acutely harmful to aquatic organisms. The inhibition
of the degradation activity of activated sludge is not anticipated when introduced to biological
treatment plants in appropriate low concentrations.

Toxicity to fish:
LC50 (96 h) > 100 mg/l, Pimephales promelas (Flow through.)

Aquatic invertebrates:
EC50 (48 h) > 100 mg/l, Daphnia magna (Directive 79/831/EEC, static)

Aquatic plants:
EC50 (72 h) > 100 mg/l (biomass), Scenedesmus subspicatus (DIN 38412 Part 9, static)

Microorganisms/Effect on activated sludge:

EC10 (17 h) > 100 mg/l, Pseudomonas putida (DIN 38412 Part 8)

Chronic toxicity to fish:

No observed effect concentration (34 d) > 1 mg/l, Pimephales promelas (OECD Guideline draft, Flow
through.)

Chronic toxicity to aquatic invertebrates:

No observed effect concentration (21 d) > 1 mg/l, Daphnia magna (OECD Guideline 211, semistatic)

Assessment of terrestrial toxicity:

No data available concerning terrestrial toxicity.

12.2. Persistence and degradability

Assessment biodegradation and elimination (H2O):

Readily biodegradable (according to OECD criteria).
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
Elimination information:
> 70 % DOC reduction (15 d) (OECD 301 A (new version)) (aerobic, activated sludge, domestic)

Assessment of stability in water:

In contact with water the substance will hydrolyse slowly.
12.3. Bioaccumulative potential

Assessment bioaccumulation potential:

No significant accumulation in organisms is expected as a result of the distribution coefficient of n-
octanol/water (log Pow).

12.4. Mobility in soil

Assessment transport between environmental compartments:

Volatility: The substance will not evaporate into the atmosphere from the water surface.
Adsorption in soil: Adsorption to solid soil phase is not expected.

12.5. Results of PBT and vPvB assessment

The product does not fulfill the criteria for PBT (Persistent/bioaccumulative/toxic) and vPvB (very
persistent/very bioaccumulative).

12.6. Other adverse effects

The product does not contain substances that are listed in Regulation (EC) 1005/2009 on
substances that deplete the ozone layer.

12.7. Additional information

Add. remarks environm. fate & pathway:

Treatment in biological waste water treatment plants has to be performed according to local and
administrative regulations.

Other ecotoxicological advice:

Do not release untreated into natural waters.

SECTION 13: Disposal Considerations

13.1. Waste treatment methods

Must be disposed of or incinerated in accordance with local regulations.

Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
SECTION 14: Transport Information

Land transport

ADR
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

RID
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

Inland waterway transport

ADN
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user
Transport in inland Not evaluated
waterway vessel:

Sea transport

IMDG
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
Environmental hazards: Not applicable
Special precautions for None known
user

Air transport

IATA/ICAO
Not classified as a dangerous good under transport regulations
UN number: Not applicable
UN proper shipping name: Not applicable
Transport hazard class(es): Not applicable
Packing group: Not applicable
Environmental hazards: Not applicable
Special precautions for None known
user

14.1. UN number
See corresponding entries for “UN number” for the respective regulations in the tables above.

14.2. UN proper shipping name

See corresponding entries for “UN proper shipping name” for the respective regulations in the tables
above.

14.3. Transport hazard class(es)

See corresponding entries for “Transport hazard class(es)” for the respective regulations in the
tables above.

14.4. Packing group

See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards

See corresponding entries for “Environmental hazards” for the respective regulations in the tables
above.

14.6. Special precautions for user

See corresponding entries for “Special precautions for user” for the respective regulations in the
tables above.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Regulation: Not evaluated
Shipment approved: Not evaluated
Pollution name: Not evaluated
Pollution category: Not evaluated
Ship Type: Not evaluated
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BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 23.06.2015 Version: 2.2
Product: Protectol® PE
(ID no. 30063180/SDS_GEN_EU/EN)
Date of print 17.09.2015
SECTION 15: Regulatory Information
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture

If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

15.2. Chemical Safety Assessment

Chemical Safety Assessment performed

SECTION 16: Other Information

Information on intended use: This product is of industrial quality and unless otherwise specified or
agreed intended exclusively for industrial use. This includes the mentioned and recommended
usage. Any other intended applications should be discussed with the manufacturer. In particular this
concerns the application for products that are the object of special standards and regulations.

Full text of the classifications, including the indication of danger, the hazard symbols, the R phrases,
and the hazard statements, if mentioned in section 2 or 3:
Acute Tox. Acute toxicity
Eye Dam./Irrit. Serious eye damage/eye irritation

The data contained in this safety data sheet are based on our current knowledge and experience and
describe the product only with regard to safety requirements. The data do not describe the product's
properties (product specification). Neither should any agreed property nor the suitability of the product for
any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility
of the recipient of the product to ensure any proprietary rights and existing laws and legislation are
observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.