Handbook Molecular
Handbook Molecular
Edited by
Róisín M. Burke, Alan L. Kelly, Christophe Lavelle
and Hervé This vo Kientza
First edition published 2021
by CRC Press
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and by CRC Press
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Library of Congress Cataloging‑in‑Publication Data
Names: Burke, Róisín, editor.
Title: Handbook of molecular gastronomy: scientific foundations and culinary
applications / edited by Róisín Burke, Alan Kelly, Christophe Lavelle,
and Hervé This vo Kientza.
Description: First edition. | Boca Raton: CRC Press, 2021. |
Includes bibliographical references and index.
Identifiers: LCCN 2020053893 (print) | LCCN 2020053894 (ebook) |
ISBN 9781466594784 (hardback) | ISBN 9780429168703 (ebook)
Subjects: LCSH: Molecular gastronomy–Handbooks, manuals, etc.
Classification: LCC TX651 .H335 2021 (print) |
LCC TX651 (ebook) | DDC 641.01/3--dc23
LC record available at https://lccn.loc.gov/2020053893
LC ebook record available at https://lccn.loc.gov/2020053894
ISBN: 978-1-4665-9478-4 (hbk)
ISBN: 978-0-367-74161-7 (pbk)
ISBN: 978-0-429-16870-3 (ebk)
Typeset in Times
by Newgen Publishing UK
Contents
Anthocyanins in Food...........................................................................................................................................................................13
Véronique Cheynier
Browning: The Glycation and Maillard Reactions –Major Non-Enzymatic Browning Reactions in Food................................81
Frédéric J. Tessier
Capillarity in Action.............................................................................................................................................................................91
Hervé This vo Kientza
v
vi Contents
Chocolate: Chocolates from around the World, Simple Physics, Complex Flavour....................................................................121
Bhagyashri L. Joshi, Sarah Gindra and Thomas A. Vilgis
Chocolate: Oral Processing of Chocolate – Successive Interplay of Sensory and Physicochemical Parameters.......................131
Thomas A. Vilgis
Cooking................................................................................................................................................................................................157
Hervé This vo Kientza
Dehydration.........................................................................................................................................................................................203
José M. Aguilera
Distillation: The Behaviour of Volatile Compounds during Distillation of Hydro-Alcoholic Solutions and
during Hydro-Distillation...................................................................................................................................................................213
Martine Esteban-Decloux
Emulsions: Lecithin............................................................................................................................................................................249
Elzbieta Kozakiewicz and Daniel Cossuta
Contents vii
Essential Oils.......................................................................................................................................................................................265
Eric Angelini and Laure Dziuba
Evaporation.........................................................................................................................................................................................281
Hervé This vo Kientza
Expansion............................................................................................................................................................................................291
Hervé This vo Kientza
Fats and Oils: From Fat Droplets in Plant Seeds to Novel Foods...................................................................................................299
Juan C. Zambrano, Behic Mert and Thomas A. Vilgis
Fats and Oils: Extra Virgin Olive Oil in Cooking –Molecular Keys for Traditional and
Modern Mediterranean Gastronomy................................................................................................................................................311
Raffaele Sacchi
Fermentation: Kimchi........................................................................................................................................................................321
Weon-Sun Shin
Freeze-Drying......................................................................................................................................................................................349
Yrjö H. Roos
Frying...................................................................................................................................................................................................365
Franco Pedreschi
Gels.......................................................................................................................................................................................................375
Hervé This vo Kientza
viii Contents
Hydrocolloid Usages as Gelling and Emulsifying Agents for Culinary and Industrial Applications..........................................385
Rachel Edwards-Stuart and Reine Barbar
Meat: Reduction of Nitrate and Nitrite Salts in Meat Products –What Are the Consequences
and Possible Solutions?.......................................................................................................................................................................423
Régine Talon and Sabine Leroy
Roasting...............................................................................................................................................................................................473
Laura Febvay and Hervé This vo Kientza
Sauces...................................................................................................................................................................................................495
Hervé This vo Kientza
Size Reduction.....................................................................................................................................................................................523
José M. Aguilera
Smoked Foods......................................................................................................................................................................................527
Jane K. Parker and Alice Pontin
Spherification......................................................................................................................................................................................537
Linda A. Luck
Sugars: Soft Caramel and Sucre à la Crème –an Undergraduate Experiment about Sugar Crystallization...........................545
Irem Altan, Patrick Charbonneau and Justine de Valicourt
Temporal Domination of Sensation: When Building Dishes, Let’s Take Temporality into Account...........................................575
Pascal Schlich
3D Printing of Food............................................................................................................................................................................605
Megan M. Ross, Róisín M. Burke and Alan L. Kelly
Cooking and Science Workshops: The “Soft of the World”, Gelling Agents.................................................................................651
Pere Castells
An Educational Satellite Project around the Scientific Elucidation of Culinary Precisions in Lebanon and
in the Middle East...............................................................................................................................................................................665
Reine Barbar, Jean-Marie Malbec, Christophe Lavelle and Hervé This vo Kientza
Bon Appétit, Marie Curie! A Stanford University Introductory Science of Cooking Course.....................................................673
Markus W. Covert and Imanol Arrieta-Ibarra
Molecular Gastronomy in Science Education and Science Communication at the National University of Singapore.............679
Linda Sellou and Lau Shi Yun
Decantation..........................................................................................................................................................................................751
Hervé This vo Kientza
Note by Note Recipes for a Press Conference and Tasting Organized at ITHQ, 2012.................................................................755
Erik Ayala-Bribiesca and Ismael Osorio
Greek Diracs........................................................................................................................................................................................771
Makis Kalossakas and Nicolas Nikolakopoulos
An Eclipse Dish...................................................................................................................................................................................775
Hervé This vo Kientza
Vegetable Salad...................................................................................................................................................................................785
Jean Chauvel
Filtration..............................................................................................................................................................................................789
Hervé This vo Kientza
Molecular Cooking..............................................................................................................................................................................801
Róisín M. Burke and Pauline Danaher
Spherification......................................................................................................................................................................................819
Sasa Hasic
Slowly Cooked Lamb Neck with Fermented Flour Pancakes, Sunchoke Puree and Beer Glaze................................................849
Alex Tsionitis
Index.....................................................................................................................................................................................................851
About the Editors
Róisín M. Burke is a senior lecturer in the School of Culinary Christophe Lavelle is a research scientist at the French National
Arts and Food Technology, College of Arts and Tourism, Centre for Scientific Research, working at the National Museum
Technological University Dublin, City Campus, Ireland. She of Natural History and Sorbonne University in Paris. He is an
obtained her PhD from University College Dublin and subse- expert in biophysics, epigenetics and food science and teaches in
quently carried out postdoctoral research at the Agricultural many universities and professional schools (including Sorbonne
University in Wageningen, The Netherlands. Róisín lectures and University, Le Cordon Bleu and Basque Culinary Center). He is
conducts research, specializing in Culinary Science and Food frequently invited to conferences for general public or profes-
Product Development. In the last 14 years, she has developed sional audiences, and is also responsible for the scientific training
Molecular Gastronomy as a subject discipline in The School of cookery teachers at the national level. He is the author of more
of Culinary Arts and Food Technology, TU Dublin. She has than 60 research papers and 12 books on food, including Toute
published widely in international peer-reviewed journals and has la chimie qu’il faut savoir pour devenir un chef! (Flammarion,
joined a number of editorial teams. For many years, Róisín has 2017) and Je mange donc je suis. Petit dictionnaire curieux de
lectured to international students, and she is the TU Dublin co- l’alimentation (Museum National d’Histoire Naturelle, 2019).
ordinator of the Erasmus+ MSc programme in Food Innovation He is a member of several scientific and food societies (including
and Product Design (FIPDes). She has given guest lectures in the French Biophysical Society, the American Biophysical
Ireland and abroad. Society, the Disciples d’Escoffier Society and the Association for
the Study of Food and Society).
Alan L. Kelly is a professor in the School of Food and Nutritional
Sciences at University College Cork in Ireland. His teaching Hervé This vo Kientza is a physical chemist, one of the two
interests include food processing and preservation, dairy creators of Molecular and Physical Gastronomy and a promoter
product technology and new food product development, as of “molecular cooking” (he devised the name in 1999). He is
well as regularly giving courses on effective scientific commu- currently working for the French National Research Institute
nication. He leads an active research group on the chemistry for Agriculture, Food and the Environment, is a professor at
and processing of milk and dairy products, has published over AgroParisTech, and is the director of the AgroParisTech-INRAE
250 research papers, review articles and book chapters, and International Centre for Molecular and Physical Gastronomy. As
has supervised over 40 MSc and PhD students to completion. such, he organizes the International Workshops on Molecular
He has been an editor of the International Dairy Journal since and Physical Gastronomy. He is also the head of the Educational
2005 and has acted as an external examiner in universities and Committee of the Institute for Advanced Studies in Gastronomy
reviewed for journals and funding agencies around the world. and a member of several academies: the French Academy of
In July 2009, he received the Danisco International Dairy Agriculture, the Belgian Academy of Sciences, the Academy of
Science award from the American Dairy Science Association Alsace and the Academy Stanislas. He is doing scientific research
for his contributions to research in dairy science and tech- (molecular and physical gastronomy) in the Inrae-AgroParisTech
nology. In recent years, he has become very interested in the Group of Molecular Gastronomy. At the same time, he is lec-
interface between the worlds of food and culinary sciences, and turing extensively worldwide for the promotion of molecular
has organized several workshops and seminars on this topic and gastronomy, stimulating the creation of groups for research and
molecular gastronomy. In 2019, he published a book entitled education in universities and research centres, but also of “note
Molecules, Microbes and Meals: The Surprising Science of by note cooking”, an application of molecular gastronomy that
Food (Oxford University Press), and in 2020, he published he proposed as early as 1994. He has published many books and
How Scientists Communicate: Dispatches from the Frontiers of chapters of books, made TV programmes and radio shows, and
Knowledge (Oxford University Press), both of which are aimed has several blogs, but he is also the author of more than 150 sci-
at a general audience. entific articles.
xiii
Contributors
Thomas Séon Régine Talon
Institut Jean Le Rond d’Alembert, Université Clermont Auvergne,
UMR CNRS 7190, INRAE,
Sorbonne Universités, MEDIS,
Paris, Clermont-Ferrand,
France France
David S. Waldron
School of Food and Nutritional Sciences,
University College,
Cork,
T12 YN60,
Ireland
Foreword
One of the most exciting areas of research and experimentation in by note cuisine. Indeed, many books already exist for a general
the food and culinary areas in recent years is the emerging discip- audience, either addressing food science in a “light” way and/
line of molecular and physical gastronomy (in short, “molecular or dealing with modern cooking techniques and recipes, but
gastronomy”), the scientific discipline dedicated to the study no book exists yet that encompasses the whole molecular gas-
of phenomena that occur during the preparation and consump- tronomy field, providing a strong interdisciplinary background in
tion of dishes. Molecular gastronomy considers the chemistry, the physics, biology and chemistry of food and food preparation,
biology and physics of food, along with the physiology of food along with discussions on creativity and the art of cooking.
consumption. We hope that such a new resource will be very useful for food
The objective of this book is to provide a comprehensive over- scientists and chefs, as well as students studying food science or
view of this field, based on contributions from some of the main food technology and all lay people interested in gastronomy. It
scientists in their areas, but also with contributions by chefs for should be noted that the chapters in each part are organized in
the application part. In this last part, the book also addresses some what appeared to be the most logical structure, and are hence
of the most popular techniques of molecular cooking, a cooking alphabetical in Part I and in a logical sequence in Parts II and III.
style associated with molecular gastronomy and characterized The book is not intended to be read in sequence but to be used as
mainly by the use of new tools and methods, often imported from a reference work, which can be consulted under specific headings
chemistry laboratories, as well as cultural and artistic aspects of or dipped into at will.
food preparation. The newer cooking trend called “note by note Finally, we as editors wish to thank all the authors, coming
cuisine” is also explored. from so many different fields, for their enthusiasm for the pro-
Considering that “gastronomy is the knowledge and ject and their patience with the process of editing and producing
understanding of all that relates to man, as he eats” (JA Brillat- this very significant end product, and to thank Stephen Zollo and
Savarin, Physiology of taste, 1825), it may be proposed that colleagues at CRC Press/Taylor and Francis for their support
molecular gastronomy is the chemical, physical and biological for this project, guidance through the publication process, and
part of this knowledge, i.e., the scientific activity that relates great patience in awaiting the end result. We also thank Nicola
to culinary phenomena. As natural sciences have technical Howcroft at Newgen Publishing UK for support during the pro-
applications, molecular gastronomy can lead to better and/or new duction stages. We would also like to thank Ciara Tobin of the
ways of cooking. School of Food and Nutritional Sciences at University College
This book aims to fulfil the need for a comprehensive refer- Cork for significant and invaluable assistance in the preparation
ence in molecular gastronomy along with a practical guide to of this final manuscript, and Dylan Kelly for his assistance with
molecular cooking and more recent applications such as note editorial work in the process.
xxv
Introduction to Molecular Gastronomy and Its Applications
Molecular Gastronomy was originally defined as the scientific dis- Of course, it could be imagined that molecular gastronomy
cipline that has the goal of “looking for mechanisms of phenomena would disappear when its duty was done, i.e., promoting the sci-
occurring during culinary processes” (Announcement poster for the entific study of dishes, but at the same time, there is a strong argu-
International Workshop on Molecular and Physical Gastronomy, ment for keeping it in the field of food science and technology,
Ettore Majorana Centre for Scientific Culture, Erice, Italy, 1992). because this is not the same as the science of food ingredients or
The initial name “molecular and physical gastronomy” was later the sciences of processes. The work is not finished, and the field
shortened to “molecular gastronomy”, but the scientific programme remains a source of discoveries and technical innovation through
did not change, except that it was progressively made clearer when technological work, particularly because the newly created inter-
it was increasingly recognized that technology and education were face lies between so many disciplines.
not scientific activities but rather, applications of science. Molecular Gastronomy was first proposed as a scientific
In spite of this quite clear definition by its creators, “molecular activity, but it is true that at the time when it was introduced, there
gastronomy” has been widely referred to in the media and in was also a side goal of modernizing culinary processes, in par-
culinary circles using different definitions and terminology. These ticular with tools from labs (with a basis in chemistry and physics).
include, for example, “Molecular Cooking/Cuisine”, “Modernist The expression “molecular cooking” was introduced to describe
Cuisine” and “Scientific Cooking”, to name but a few. the new culinary techniques using these tools. This led progres-
Thus, some confusion has remained, because “gastronomy” sively to the introduction of a new culinary style, called “molecular
is often confused with “haute cuisine” or “fine dining”, and cuisine”, based on these new tools. Two examples of this are dishes
also because innovative chefs were interested in the possible made using siphons and meat cooked at a low temperature; these
applications of molecular gastronomy and hence, indeed, doing are the obvious hallmark of chefs practising molecular cooking or
molecular cooking! molecular cuisine, which was, in fact, the original intention. Let us
insist on the slight difference: molecular cooking is the name for
cooking with “modern” culinary tools, especially tools that were
not found in kitchens in the 1970s; in particular, these include tools
Clarification of What Molecular Gastronomy Is
coming from laboratories, such as siphons, thermal circulators,
Even after years of efforts to explain the differences, two main liquid nitrogen, ultrasonic probes and rotary evaporators. On the
sources of confusion remain: other hand, molecular cuisine is the style of cooking based on
using such new tools, in particular for new applications. All this is
1. between molecular gastronomy, on the one hand, and well illustrated in Part III of this Handbook.
food science and technology, on the other; Let us finish by observing that the “modern tools” of the 1980s
2. between molecular gastronomy, molecular cooking and are no longer modern today, and young chefs cannot even imagine
molecular cuisine. a world without low-temperature cooking or sous-vide, just as chefs
at the end of the 20th century could hardly have imagined how to
In terms of the first of these, it should be observed that cook when gas wasn’t widely available. It has even been said that
“molecular gastronomy” is certainly not intended to include all molecular cooking and molecular cuisine are already no longer
food sciences, but only part of this field. Indeed, the emergence current concepts (because “note by note cooking” is a drastic mod-
of molecular gastronomy was due in part to the fact that, in the ernization), but the technical transformation of culinary activity is
1980s, food scientists did not study real culinary processes and certainly not complete. Only today have companies begun to sell
dishes prepared daily in homes or restaurants or other culinary ultrasonic probes for making emulsions, for example.
enterprises, but mainly industrial processes and food ingredients.
There were no scientific investigations into the physical and
chemical transformations that occurred during the preparation of
coq au vin, Irish stew or in fact, most dishes. For example, it Science and Cooking
should be noted that cooking using wine was never considered by For “science”, one should first observe that this word has various
science, in spite of the fact that wine is used in about half of all meanings, such as knowledge in general, or “natural sciences”.
the recipes for French traditional sauces! However, when someone discusses the issue of precision and
1
2 Introduction to Molecular Gastronomy and Its Applications
rigour, the general meaning of knowledge is not specified, and techniques have been introduced after research in molecular gas-
instead, the natural sciences are emphasized. The goal of science tronomy, examples of which will also be given.
is to discover mechanisms and phenomena, using a method that
classically goes through (1) identification of a phenomenon;
(2) quantitative characterization of the phenomenon; (3) grouping
Applications in Schools, Colleges and Universities
the data in equations (“laws”); (4) producing theories or models
by grouping these laws and introducing new notions or concepts; We have said that molecular gastronomy is a scientific activity,
(5) drawing testable theoretical conclusions from the theory; and and this is true. As for any scientific field, there are applications
(6) experimentally testing these theoretical conclusions. This has in both directions: educational and technical. These applications
nothing to do with making food per se, and it is clear as well that are developing simultaneously, and even more since cooking has
cooking has nothing to do with the natural sciences; the goals become more popular, with TV shows in all countries. Indeed,
and methods are both completely different, and they will always cooking, which was traditionally an activity for women, is now
remain separate. routinely done by men. One can observe that in developed coun-
In another point about the relationship between science and tries such as France (and probably also elsewhere), in the 1950s,
cooking, there has been some discussion about “science in the culinary lessons were given only to girls at school. For this
kitchen”, in particular in relation to a quotation by the French country in particular, so called “Ateliers expérimentaux du goût”,
chefs Auguste Escoffier, Phileas Gilbert and Emile Fetu, who i.e., activities mixing natural sciences and cooking (plus art),
predicted in their famous Guide Culinaire (1907) that cooking were introduced in all primary schools in 2001. Today, “science
would become “scientific”. Let’s first observe that cooking and cooking” activities are performed in colleges, high schools
is an activity mixing a social component, a technical compo- and even universities focusing on the sciences.
nent and art (see Hervé This and Pierre Gagnaire’s discussion In specialized colleges, such as culinary schools, more and
in Cooking, a quintessential art, University of California Press, more molecular gastronomy activities are being performed, and
2010). Indeed, there is also an element of human relationships today the new French teachers for culinary schools are all being
and sociology in the act of producing food for others or of eating educated in molecular gastronomy with a view to experimenting
food that was prepared by others. In terms of technique, it is clear in their classes, conducting science and cooking activities, or
that cutting, heating and mixing are all technical activities, but activities in which the culinary teacher is working alongside
one important component is “art”, i.e., the activity of producing science teachers.
“beautiful” objects. Here, the beauty is in the food to be eaten, not For chefs, there are many initiatives for continuous education;
only to be looked at, which leads to the conclusion that “good” for example, in France, every month for 18 years, seminars of
means “beautiful to eat”. molecular gastronomy have been run in Paris. Such seminars also
The fact is that there will never be any sciences “in” the kit- exist in many other places, with various names.
chen. On the other hand, one can have applications of natural The general public has through organized workshops and
sciences in the kitchen (e.g., molecular cooking or note by note other activities and through the media, many opportunities to
cooking), and also, one can use culinary phenomena for scien- enjoy the delights that applying science in the kitchen can bring.
tific objects, which is indeed the main principle of molecular However, this is not new; as early as the very beginning of the
gastronomy. As shown in the description of the cycle of the nat- 20th century, the microbiologist Edouard de Pomiane was a star,
ural scientific method, there is no end to the process, as theories in particular with Radio-Cuisine, the first French programme on
are always insufficient and can always be improved. In contrast cooking, writing best-sellers about what was not called molecular
to molecular cooking, which will end when all the “new” hard- gastronomy.
ware has become old, molecular gastronomy will continue to For all these educational applications, in spite of their great
evolve. success, one could make the same criticism as for science popu-
Today, as molecular cooking is less trendy than it used to be larization in general, i.e., that a discourse is given, avoiding
(low-temperature cooking and making foam with siphons are calculations, and this is a difficulty, because in this way, the
“classical” techniques nowadays), molecular gastronomy, in con- receiver of the popularized discourse cannot evaluate the validity
trast, is developing regularly in universities around the world, of this information but has to trust the source. Indeed, the receiver
with new laboratories, new research groups and new educational remains at the surface, and probably the only way to circumvent
curricula. In this way, new aspects of molecular gastronomy are this difficulty is through experimenting. This is what is proposed in
generated, and the discipline continues to evolve. many educational activities mentioned here, and, for sure, testing
It is a very exciting time … which is also why this Handbook “culinary precisions” is a good way to invite everybody to share
is timely! This book is divided into three parts. The first one the excitement of science by taking the very first step and making it
includes scientific information about phenomena that occur useful. It is no use trying to investigate phenomena that do not exist!
during culinary activities, and this is, as already said, exactly what
molecular gastronomy is. The second and third parts then show
educational and technical and culinary applications, respectively.
In the case of “education”, groups all over the world have been
Applications to the Culinary Arts
using results from molecular gastronomy in order to promote We have explained that the applications of science are not science
scientific studies. Regarding technical applications, many new itself, and it is true that the fruit is not the tree. However, it is
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