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SAFETY DATA SHEET- Extra Neutral Alcohol Ethanol 96,5%

SUKI SPIRITS PVT LTD

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SECTION 1: Identification of the substance/mixture and of the
company/undertaking
Date issued 26.11.2013
1.1. Product identifier
Product name Ethanol 96,5%
Chemical name Ethyl alcohol
Synonyms methyl carbinol
REACH Reg No. 01-2119457610-43-0000
CAS no. 64-17-5
EC no. 200-578-6
Index no. 603-002-00-5
Article no. 12110000
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/preparation For the preparation of paints and as a solvent. Disinfectant. Antiseptic.
Antifreeze liquid. General purpose cleaner.
1.3. Details of the supplier of the safety data sheet
Company name Suki Spirits Pvt Ltd
Office address 1/22 Asaf Ali Road, 2nd Floor, New Delhi 110002 India
Postal address 1/22 Asaf Ali Road, 2nd Floor
Postcode 110002
City New Delhii
Country INDIA
Tel +919873173503
Fax/Mob +919873173503
E-mail karan@sukispirits.com
Website www.sukispirits.com
1.4. Emergency telephone number
Emergency telephone +919873173503

SECTION 2: Hazards identification

2.1. Classification of substance or mixture
Classification according to F; R11
67/548/EEC or 1999/45/EC
Classification according to Flam. Liq. 2; H225;
Regulation (EC) No 1272/2008
[CLP/GHS]
2.2. Label elements
Hazard Pictograms (CLP)

Signal word Danger

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Precautionary statements P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting//equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all
Contaminated clothing. Rinse skin with water/shower.
P370 + P378 In case of fire: Use for extinction.
P403 + P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to
2.3. Other hazards
Other hazards Not known.

SECTION 3: Composition/information on
ingredients 3.1. Substances
Substance Identification Classification Contents
Ethanol CAS no.: 64-17-5 F; R11 96,5%
EC no.: 200-578-6 Flam. Liq. 2; H225
Index no.: 603-002-00-5
Synonyms: Ethanol
Column headings CAS no. = Chemical Abstracts Service; EU (Einecs or Elincs number) =
European inventory of Existing Commercial Chemical Substances; Ingredient
name = Name as specified in the substance list (substances that are not
included in the substance list must be translated, if possible). Contents given
in; %, %wt/wt, %vol/wt, %vol/vol, mg/m3, ppb, ppm, weight%, vol%
HH/HF/HE T+ = Very toxic, T = Toxic, C = Corrosive, Xn = Harmful, Xi = Irritating, E
= Explosive, O = Oxidizing, F+ = Extremly flammable, F = Very
flammable, N = Environmental hazard

SECTION 4: First aid measures

4.1. Description of first aid measures
Inhalation Move the exposed person to fresh air at once. Get medical attention if any
discomfort continues.
Skin contact Remove contaminated clothes and rinse skin thoroughly with water.
Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any
contact lenses and open eyes wide apart. Get medical attention if any
discomfort continues.
Ingestion NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Do
not induce vomiting. Rinse mouth with water. Get medical attention if any
discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
Information for health personnel Treat Symptomatically. Do not give victim anything to drink if he is
Unconscious.
4.3. Indication of any immediate medical attention and special treatment needed
Specific details on antidotes No recommendation given.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water
fog.
5.2. Special hazards arising from the substance or mixture
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Fire and explosion hazards HIGHLY FLAMMABLE! Solvent vapours may form explosive mixtures with air.
Hazardous combustion products Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).
5.3. Advice for firefighters
Fire fighting procedures No specific fire fighting procedure given.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Personal protection measures Ensure suitable personal protection (including respiratory protection) during
removal of spillages in a confined area. Ventilate well. Stop leak if possible
without risk. Avoid contact with skin and eyes. Do not breathe vapour.
6.2. Environmental precautions
Environmental precautionary Avoid discharge into drains, water courses or onto the ground.
measures
6.3. Methods and material for containment and cleaning up
Cleaning method Dam and absorb spillages with sand, earth or other non-combustible material.
6.4. Reference to other sections
Other instructions No recommendation given.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Handling Keep away from heat, sparks and open flame. Take precautionary measures
against static discharges. Mechanical ventilation may be required.
Protective Safety Measures
Advice on general Provide easy access to water supply and eye wash facilities.
occupational hygiene
7.2. Conditions for safe storage, including any incompatibilities
Storage Keep away from heat, sparks and open flame. Ground container and transfer
equipment to eliminate static electric sparks. Store in a cool and well-
ventilated place.
7.3. Specific end use(s)
Specific use(s) Not entered.

SECTION 8: Exposure controls/personal protection 8.1.

Control parameters
Other Information about threshold Norske grenseverdier; FOR-2011-12-06-1358 vedlegg 1.
limit values Etanol: 8 t.: 500ppm, 950 mg/m3 (2003)
DNEL / PNEC
Exposure guidelines Country of origin: Sverige
Limit value type: KTV
Other Information OEL Short Term Value: 1900 mg/m3
Source: Nationella hygieniska gränsvärden, AFS 2005:17
NGV, 1000 mg/m3
8.2. Exposure controls
Occupational exposure limits Provide adequate ventilation. Observe Occupational Exposure Limits and
minimise the risk of inhalation of vapours. Protective gloves and goggles are
recommended. Provide eyewash, quick drench.
Safety signs
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Respiratory protection
Respiratory protection Respiratory protection must be used if air contamination exceeds acceptable
level. Use respiratory equipment with gas filter, type A2.
Hand protection
Hand protection Use protective gloves. Chemical resistant gloves required for prolonged or
repeated contact. Gloves of nitrile rubber, PVA or Viton are recommended.
Eye / face protection
Eye protection Use safety goggles or face shield in case of splash risk.
Skin protection
Skin protection (except hands) Wear appropriate clothing to prevent any possibility of skin contact.
Hygiene / Environmental
Specific hygiene measures Wash hands after contact.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Colour Colourless.
Odour Odour of alcohol.
Comments, pH (as supplied) Not applicable.
Melting point/melting range Value: -115 °C
Boiling point / boiling range Value: 78 °C
Flash point Value: 12 °C
Explosion limit Value: 3,5-15 %
Vapour pressure Value: 5,9 kPa
Test temperature: 20 °C
Vapour density Value: 1,6
Specific gravity Value: 789 kg/m3
Test temperature: 20 °C
Solubility description Completely soluble in water. Soluble in: Organic solvents.
Partition coefficient: n-octanol/water Value: -0,32
Spontaneous combustability Value: 425 °C
Viscosity Value: 1,2 mPas
Test temperature: 20 °C
9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Heating may cause a fire.
10.2. Chemical stability
Stability Stable under the prescribed storage conditions.
10.3. Possibility of hazardous reactions
Possibility of hazardous reactions Not known.
10.4. Conditions to avoid
Conditions to avoid Avoid heat, flames and other sources of ignition.
10.5. Incompatible materials
Materials to avoid Avoid contact with oxidising agents (e.g. nitric acid, peroxides and
chromates). Strong acids.
10.6. Hazardous decomposition products
Hazardous decomposition products Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).

SECTION 11: Toxicological information

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11.1. Information on toxicological effects
Toxicological Information:
Other toxicological data Acute Toxicity (Oral LD50): mg/kg (oral rat) 7060
Acute Toxicity (Inhalation LC50): mg/l (vapours) (4h) 124,7
Acute Toxicity (Dermal LD50): mg/kg (ipr-rat) > 20 000
Potential acute effects
Inhalation In high concentrations, vapours are narcotic and may cause headache,
fatigue, dizziness and nausea. Icke klassificerad som aspirationstoxisk
(Not classified as asp. tox.)
Skin contact Prolonged or frequent contact may cause redness, itching, eczema and skin
cracking. Defats the skin.
Eye contact Causes serious eye irritation.
Ingestion Ingestion of large amounts may cause unconsciousness. However, ingestion
may cause nausea, headache, dizziness and intoxication. Ingestion may
cause irritation of the gastrointestinal tract, vomiting and diarrhoea. May
cause irritation to the mouth and throat.
Delayed effects / repeated exposure
Sensitisation Not known.
Chronic effects None known.
Carcinogenic, Mutagenic or Reprotoxic
Carcinogenicity None.
Mutagenicity Not known.
Teratogenic properties Not known.
Reproductive toxicity Not known.

SECTION 12: Ecological information

12.1. Toxicity
Acute aquatic, fish Value: 13500 mg/l
Method of testing: LC50
Fish, species: Pimephales promelas
Duration: 96h
Acute aquatic, algae Value: 5000 mg/l
Method of testing: IC50
Algae, species: Scenedesmus subspicatus
Duration: 7d
Acute aquatic, Daphnia Value: 5400 mg/l
Method of testing: EC50
Daphnia, species: D. magna
Duration: 72h
12.2. Persistence and degradability
Degradation half life Lättnedbrytbart. 85% bryts ned på 28 dygn OECD 301D
Chemical oxygen demand (COD) Value: 0,4-0,8
Method of testing: COD
Biological oxygen demand (BOD) Value: 0,4-0,8
Method of testing: BOD
12.3. Bioaccumulative potential
Bioaccumulative potential Will not bio-accumulate.
Bioconcentration factor (BCF) Value: 0,66
Method of testing: BCF
12.4. Mobility in soil
Mobility The product is water soluble and may spread in water systems.
12.5. Results of PBT and vPvB assessment
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PBT assessment results This substance is not classified as PBT or vPvB.
12.6. Other adverse effects
Other adverse effects / Remarks None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Specify the appropriate methods of Confirm disposal procedures with environmental engineer and local regulations.
disposal Absorb in vermiculite or dry sand and dispose of at a licenced hazardous waste
collection point. Liquid components can be disposed of by incineration. Yes
Product classified as hazardous
waste
Packaging classified as hazardous No
waste

SECTION 14: Transport information

14.1. UN number
ADR 1170
RID 1170
IMDG 1170
ICAO/IATA 1170
14.2. UN proper shipping name
ADR ETHANOL
RID ETHANOL
IMDG ETHANOL
ICAO/IATA ETHANOL
14.3. Transport hazard class(es)
ADR 3
Hazard no. 33
RID 3
ADN 33
IMDG 3
ICAO/IATA 3
14.4. Packing group
ADR II
RID II
IMDG II
ICAO/IATA II
14.5. Environmental hazards
Comment Not relevant.
14.6. Special precautions for user
EmS F-E, S-D
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC
Code SECTION 15: Regulatory information
EC no. 200-578-6
15.1. Safety, health and environmental regulations/legislation specific for
the substance or mixture
Other Label Information Regulation (EC) No 1272/2008 of the European Parliament and of the Council
of 16 December 2008 on classification, labelling and packaging of substances
and mixtures, amending and repealing Directives 67/548/EEC and

1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments.

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Legislation and regulations Dangerous Substance Directive 67/548/EEC.
The Chemicals (Hazard Information and Packaging for Supply) Regulations
2009 (S.I 2009 No. 716).
The List of Wastes (England) (Amendment) Regulations 2005. (SI 2005 No.
895). Avfallsförordningen (2011:927).
15.2. Chemical safety assessment

SECTION 16: Other information

Hazard symbol

R-phrases R11 Highly flammable.

S-phrases S2 Keep out of the reach of children.
S7 Keep container tightly closed.
S16 Keep away from sources of ignition - No smoking.
Classification according to Flam. Liq. 2; H225;
Regulation (EC) No 1272/2008
[CLP/GHS]
List of relevant R-phrases (under R11 Highly flammable.
headings 2 and 3).
List of relevant H-phrases (Section H225 Highly flammable liquid and vapour.
2 and 3).
Responsible for safety data sheet