Gillette Foamy Aerosol Shave Foam
Procter & Gamble Australia Pty Ltd                                                                                                                        Chemwatch Hazard Alert Code: 4
Chemwatch: 4689-23                                                                                                                                                         Issue Date: 27/06/2017
Version No: 4.1.1.1                                                                                                                                                         Print Date: 21/12/2017
Safety Data Sheet according to WHS and ADG requirements                                                                                                                           S.GHS.AUS.EN
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
                     Product name         Gillette Foamy Aerosol Shave Foam
                           Synonyms       Gillette Foam Range
           Proper shipping name           AEROSOLS
    Other means of identification         Not Available
Relevant identified uses of the substance or mixture and uses advised against
                                          SDS are intended for use in the workplace. For domestic-use products, refer to consumer labels.
         Relevant identified uses
                                          Shaving foam.
Details of the supplier of the safety data sheet
       Registered company name            Procter & Gamble Australia Pty Ltd
                            Address       Level 4, 1 Innovation Rd, Macquarie Park NSW 2113 Australia
                           Telephone      1800 641 820
                                  Fax     Not Available
                            Website       Not Available
                               Email      Not Available
Emergency telephone number
       Association / Organisation         Not Available
  Emergency telephone numbers             Not Available
      Other emergency telephone
                                          Not Available
                       numbers
CHEMWATCH EMERGENCY RESPONSE
  Primary Number                          Alternative Number 1                                                          Alternative Number 2
  1800 039 008                            1800 039 008                                                                  +612 9186 1132
  Once connected and if the message is not in your prefered language then please dial 01
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
 HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
 CHEMWATCH HAZARD RATINGS
                            Min           Max
Flammability           4
Toxicity               0                            0 = Minimum
Body Contact           1                            1 = Low
                                                    2 = Moderate
Reactivity             0                            3 = High
Chronic                0                            4 = Extreme
                 Poisons Schedule         Not Applicable
                                    [1]   Aerosols Category 1
                   Classification
                            Legend:       1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
               Hazard pictogram(s)
                   SIGNAL WORD            DANGER
                                                                                                                                                                                    Continued...
Chemwatch: 4689-23                                                                            Page 2 of 8                                                                           Issue Date: 27/06/2017
Version No: 4.1.1.1                                                                                                                                                                  Print Date: 21/12/2017
                                                                        Gillette Foamy Aerosol Shave Foam
 Hazard statement(s)
                                  H222     Extremely flammable aerosol.
                               AUH044      Risk of explosion if heated under confinement.
 Supplementary statement(s)
    Not Applicable
 Precautionary statement(s) Prevention
                                  P210     Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
                                   P211    Do not spray on an open flame or other ignition source.
                                  P251     Pressurized container: Do not pierce or burn, even after use.
 Precautionary statement(s) Response
 Not Applicable
 Precautionary statement(s) Storage
                             P410+P412     Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
 Precautionary statement(s) Disposal
 Not Applicable
 SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
 Substances
   See section below for composition of Mixtures
 Mixtures
    CAS No                                 %[weight]                                     Name
    Not Available                          >60                                           ingredients nonhazardous, including
   7732-18-5                               ^                                             water
   68476-85-7.                             <10                                           hydrocarbon propellant
 SECTION 4 FIRST AID MEASURES
 Description of first aid measures
                                           If this product comes in contact with eyes:
                                                 Wash out immediately with water.
                           Eye Contact
                                                 If irritation continues, seek medical attention.
                                                 Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
                          Skin Contact           Generally not applicable.
                                           If aerosols, fumes or combustion products are inhaled:
                                                Remove to fresh air.
                                                Lay patient down. Keep warm and rested.
                             Inhalation         Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
                                                If breathing is shallow or has stopped, ensure clear airway and apply resuscitation, preferably with a demand valve resuscitator, bag-valve mask device, or
                                                pocket mask as trained. Perform CPR if necessary.
                                                Transport to hospital, or doctor.
                                           Not considered a normal route of entry.
                             Ingestion         Immediately give a glass of water.
                                               First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
 Indication of any immediate medical attention and special treatment needed
    Treat symptomatically.
 SECTION 5 FIREFIGHTING MEASURES
 Extinguishing media
        Water spray or fog.
        Foam.
        Dry chemical powder.
        BCF (where regulations permit).
        Carbon dioxide.
 Special hazards arising from the substrate or mixture
                    Fire Incompatibility   None known
 Advice for firefighters
                                                 Alert Fire Brigade and tell them location and nature of hazard.
                                                 May be violently or explosively reactive.
                          Fire Fighting          Wear breathing apparatus plus protective gloves.
                                                 Prevent, by any means available, spillage from entering drains or water courses.
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Chemwatch: 4689-23                                                                           Page 3 of 8                                                                            Issue Date: 27/06/2017
Version No: 4.1.1.1                                                                                                                                                                 Print Date: 21/12/2017
                                                                       Gillette Foamy Aerosol Shave Foam
                                               Use fire fighting procedures suitable for surrounding area.
                                               Liquid and vapour are flammable.
                                               Moderate fire hazard when exposed to heat or flame.
                                               Vapour forms an explosive mixture with air.
                                               Moderate explosion hazard when exposed to heat or flame.
                                               Vapour may travel a considerable distance to source of ignition.
                                          Other decomposition products include:
              Fire/Explosion Hazard
                                          ,
                                          carbon dioxide (CO2)
                                          ,
                                          sulfur oxides (SOx)
                                          ,
                                          nitrogen oxides (NOx)
                            HAZCHEM       2Y
 SECTION 6 ACCIDENTAL RELEASE MEASURES
 Personal precautions, protective equipment and emergency procedures
   See section 8
 Environmental precautions
   See section 12
 Methods and material for containment and cleaning up
                                          Slippery when spilt.
                          Minor Spills
                                          amp;66t3
                                              Alert Fire Brigade and tell them location and nature of hazard.
                                              May be violently or explosively reactive.
                                              Wear breathing apparatus plus protective gloves.
                          Major Spills        Prevent, by any means available, spillage from entering drains or water course.
                                              If safe, leaking/damaged cans should be placed in a container outdoors, away from all the ignition sources, until pressure has dissipated.
                                              Undamaged cans should be gathered and stowed safely.
                                          Collect, using a spark-free shovel, and seal in labelled drums for disposal
   Personal Protective Equipment advice is contained in Section 8 of the SDS.
 SECTION 7 HANDLING AND STORAGE
 Precautions for safe handling
                                          No special handling procedures required.
                        Safe handling
                                          No protective clothing required due to physical form of product.
                    Other information          Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can
 Conditions for safe storage, including any incompatibilities
                                               Aerosol dispenser.
                    Suitable container
                                               Check that containers are clearly labelled.
            Storage incompatibility       None known
 SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
 Control parameters
   OCCUPATIONAL EXPOSURE LIMITS (OEL)
   INGREDIENT DATA
   Source                                 Ingredient                     Material name                            TWA                          STEL                Peak                 Notes
   Australia Exposure Standards           hydrocarbon propellant         LPG (liquified petroleum gas)            1800 mg/m3 / 1000 ppm        Not Available       Not Available        Not Available
   EMERGENCY LIMITS
    Ingredient                            Material name                                                      TEEL-1                       TEEL-2                          TEEL-3
   hydrocarbon propellant                 Liquified petroleum gas; (L.P.G.)                                  65,000 ppm                   2.30E+05 ppm                    4.00E+05 ppm
    Ingredient                            Original IDLH                                                                      Revised IDLH
    ingredients nonhazardous,
                                          Not Available                                                                      Not Available
    including
   water                                  Not Available                                                                      Not Available
   hydrocarbon propellant                 2,000 [LEL] ppm                                                                    Not Available
 Exposure controls
           Appropriate engineering
                                          None under normal operating conditions.
                          controls
                                                                                                                                                                                            Continued...
Chemwatch: 4689-23                                                                           Page 4 of 8                                                                             Issue Date: 27/06/2017
Version No: 4.1.1.1                                                                                                                                                                  Print Date: 21/12/2017
                                                                        Gillette Foamy Aerosol Shave Foam
                  Personal protection
             Eye and face protection       None under normal operating conditions.
                       Skin protection     See Hand protection below
                Hands/feet protection      None under normal operating conditions.
                       Body protection     See Other protection below
                      Other protection     No special equipment needed when handling small quantities
                      Thermal hazards      Not Available
 Recommended material(s)                                                                              Respiratory protection
   GLOVE SELECTION INDEX                                                                               Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI
    Glove selection is based on a modified presentation of the:                                        Z88 or national equivalent)
    "Forsberg Clothing Performance Index".                                                             Where the concentration of gas/particulates in the breathing zone, approaches or exceeds the
    The effect(s) of the following substance(s) are taken into account in the computer-                "Exposure Standard" (or ES), respiratory protection is required.
    generated selection:                                                                               Degree of protection varies with both face-piece and Class of filter; the nature of protection
    Gillette Foamy Aerosol Shave Foam                                                                  varies with Type of filter.
     Material                                                                   CPI                     Required Minimum               Half-Face               Full-Face         Powered Air
     BUTYL                                                                      C                       Protection Factor              Respirator              Respirator        Respirator
     NATURAL RUBBER                                                             C                       up to 5 x ES                   Air-line*             AX-2                AX-PAPR-2 ^
     NEOPRENE                                                                   C                       up to 10 x ES                  -                     AX-3                -
     PVA                                                                        C                       10+ x ES                       -                     Air-line**          -
     VITON                                                                      C                      * - Continuous Flow; ** - Continuous-flow or positive pressure demand
                                                                                                       ^ - Full-face
   * CPI - Chemwatch Performance Index                                                                 A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen
   A: Best Selection                                                                                   cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur dioxide(SO2), G =
   B: Satisfactory; may degrade after 4 hours continuous immersion                                     Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB =
   C: Poor to Dangerous Choice for other than short term immersion                                     Methyl bromide, AX = Low boiling point organic compounds(below 65 degC)
   NOTE: As a series of factors will influence the actual performance of the glove, a final
   selection must be based on detailed observation. -
   * Where the glove is to be used on a short term, casual or infrequent basis, factors such as
   "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise
   be unsuitable following long-term or frequent use. A qualified practitioner should be consulted.
 SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
 Information on basic physical and chemical properties
                                           Supplied as an aerosol pack. Contents under PRESSURE. Contains highly flammable hydrocarbon propellant.
                           Appearance
                                           |Fragrant foam; mixes with water.
                          Physical state   Liquid                                                          Relative density (Water = 1)        1.0 approx.
                                                                                                       Partition coefficient n-octanol /
                                 Odour     Not Available                                                                                       Not Available
                                                                                                                                  water
                      Odour threshold      Not Available                                                Auto-ignition temperature (°C)         Not Available
                      pH (as supplied)     Not Available                                                   Decomposition temperature           Not Available
      Melting point / freezing point
                                           Not available.                                                                 Viscosity (cSt)      Not Available
                                (°C)
    Initial boiling point and boiling
                                           Not available.                                                     Molecular weight (g/mol)         Not Applicable
                           range (°C)
                       Flash point (°C)    Not Applicable                                                                           Taste      Not Available
                      Evaporation rate     Not Available                                                           Explosive properties        Not Available
                          Flammability     Not Applicable                                                           Oxidising properties       Not Available
                                                                                                           Surface Tension (dyn/cm or
         Upper Explosive Limit (%)         Not Applicable                                                                                      Not Available
                                                                                                                               mN/m)
           Lower Explosive Limit (%)       Not Applicable                                                  Volatile Component (%vol)           >80
                Vapour pressure (kPa)      Not Available                                                                      Gas group        Not Available
              Solubility in water (g/L)    Miscible                                                                pH as a solution (1%)       Not available.
             Vapour density (Air = 1)      Not Available                                                                        VOC g/L        Not Available
 SECTION 10 STABILITY AND REACTIVITY
                             Reactivity    See section 7
                                                Elevated temperatures.
                                                Presence of open flame.
                      Chemical stability
                                                Product is considered stable.
                                                Hazardous polymerisation will not occur.
                                                                                                                                                                                             Continued...
Chemwatch: 4689-23                                                                                Page 5 of 8                                                                             Issue Date: 27/06/2017
Version No: 4.1.1.1                                                                                                                                                                        Print Date: 21/12/2017
                                                                      Gillette Foamy Aerosol Shave Foam
            Possibility of hazardous
                                         See section 7
                            reactions
               Conditions to avoid       See section 7
             Incompatible materials      See section 7
         Hazardous decomposition
                                         See section 5
                        products
 SECTION 11 TOXICOLOGICAL INFORMATION
 Information on toxicological effects
                                         Not considered an irritant through normal use.
                              Inhaled
                                         WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
                                         Not normally a hazard due to physical form of product.
                            Ingestion
                                         Considered to be non toxic
                        Skin Contact     Not considered an irritant through normal use.
                                  Eye    The liquid may produce eye discomfort causing temporary smarting and blinking.
                             Chronic         Generally not applicable.
      Gillette Foamy Aerosol Shave         TOXICITY                                                                           IRRITATION
                             Foam          Not Available                                                                      Not Available
                                           TOXICITY                                                                           IRRITATION
                                water
                                           Not Available                                                                      Not Available
                                           TOXICITY                                                                           IRRITATION
                                                                                      [1]                                     Not Available
            hydrocarbon propellant         Inhalation (rat) LC50: 84.684 mg/l15 min
                                                                                            [1]
                                           Inhalation (rat) LC50: 90.171125 mg/l15 min
                             Legend:     1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified
                                         data extracted from RTECS - Register of Toxic Effect of chemical Substances
                      HYDROCARBON
                                         inhalation of the gas
                        PROPELLANT
        WATER & HYDROCARBON
                                         No significant acute toxicological data identified in literature search.
                  PROPELLANT
                        Acute Toxicity                                                                                      Carcinogenicity
           Skin Irritation/Corrosion                                                                                        Reproductivity
      Serious Eye Damage/Irritation                                                                                 STOT - Single Exposure
                 Respiratory or Skin
                                                                                                                STOT - Repeated Exposure
                       sensitisation
                         Mutagenicity                                                                                    Aspiration Hazard
                                                                                                                           Legend:            – Data available but does not fill the criteria for classification
                                                                                                                                              – Data available to make classification
                                                                                                                                              – Data Not Available to make classification
 SECTION 12 ECOLOGICAL INFORMATION
 Toxicity
                                           ENDPOINT          TEST DURATION (HR)                                          SPECIES                                                   VALUE          SOURCE
      Gillette Foamy Aerosol Shave
                             Foam          Not                                                                                                                                     Not            Not
                                                             Not Available                                               Not Available
                                           Available                                                                                                                               Available      Available
                                           ENDPOINT          TEST DURATION (HR)                                          SPECIES                                                   VALUE          SOURCE
                                water      Not                                                                                                                                     Not            Not
                                                             Not Available                                               Not Available
                                           Available                                                                                                                               Available      Available
                                           ENDPOINT          TEST DURATION (HR)                                          SPECIES                                                   VALUE          SOURCE
            hydrocarbon propellant         Not                                                                                                                                     Not            Not
                                                             Not Available                                               Not Available
                                           Available                                                                                                                               Available      Available
                             Legend:     Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12
                                         (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE
                                         (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
 Persistence and degradability
                                                                                                                                                                                                    Continued...
Chemwatch: 4689-23                                                                        Page 6 of 8                                                Issue Date: 27/06/2017
Version No: 4.1.1.1                                                                                                                                  Print Date: 21/12/2017
                                                                    Gillette Foamy Aerosol Shave Foam
    Ingredient                           Persistence: Water/Soil                                                                  Persistence: Air
   water                                 LOW                                                                                      LOW
 Bioaccumulative potential
    Ingredient                           Bioaccumulation
   water                                 LOW (LogKOW = -1.38)
 Mobility in soil
    Ingredient                           Mobility
   water                                 LOW (KOC = 14.3)
 SECTION 13 DISPOSAL CONSIDERATIONS
 Waste treatment methods
                                              Consult State Land Waste Management Authority for disposal.
                                              Discharge contents of damaged aerosol cans at an approved site.
      Product / Packaging disposal            Allow small quantities to evaporate.
                                              DO NOT incinerate or puncture aerosol cans.
                                              Bury residues and emptied aerosol cans at an approved site.
 SECTION 14 TRANSPORT INFORMATION
 Labels Required
                      Marine Pollutant   NO
                           HAZCHEM       2Y
 Land transport (ADG)
                          UN number      1950
           UN proper shipping name       AEROSOLS
                                           Class       2.1
           Transport hazard class(es)
                                           Subrisk     Not Applicable
                       Packing group     Not Applicable
               Environmental hazard      Not Applicable
                                           Special provisions     63 190 277 327 344
       Special precautions for user
                                           Limited quantity       1000ml
 Air transport (ICAO-IATA / DGR)
                          UN number      1950
           UN proper shipping name       Aerosols, flammable; Aerosols, flammable (engine starting fluid)
                                           ICAO/IATA Class          2.1
           Transport hazard class(es)      ICAO / IATA Subrisk      Not Applicable
                                           ERG Code                 10L
                       Packing group     Not Applicable
               Environmental hazard      Not Applicable
                                           Special provisions                                               A145 A167 A802; A1 A145 A167 A802
                                           Cargo Only Packing Instructions                                  203
                                           Cargo Only Maximum Qty / Pack                                    150 kg
       Special precautions for user        Passenger and Cargo Packing Instructions                         203; Forbidden
                                           Passenger and Cargo Maximum Qty / Pack                           75 kg; Forbidden
                                           Passenger and Cargo Limited Quantity Packing Instructions        Y203; Forbidden
                                           Passenger and Cargo Limited Maximum Qty / Pack                   30 kg G; Forbidden
 Sea transport (IMDG-Code / GGVSee)
                          UN number      1950
           UN proper shipping name       AEROSOLS
                                                                                                                                                             Continued...
Chemwatch: 4689-23                                                                              Page 7 of 8                                                                          Issue Date: 27/06/2017
Version No: 4.1.1.1                                                                                                                                                                   Print Date: 21/12/2017
                                                                            Gillette Foamy Aerosol Shave Foam
                                               IMDG Class           2.1
         Transport hazard class(es)
                                               IMDG Subrisk         Not Applicable
                      Packing group        Not Applicable
              Environmental hazard         Not Applicable
                                               EMS Number                 F-D, S-U
       Special precautions for user            Special provisions         63 190 277 327 344 381 959
                                               Limited Quantities         1000ml
 Transport in bulk according to Annex II of MARPOL and the IBC code
    Not Applicable
 SECTION 15 REGULATORY INFORMATION
 Safety, health and environmental regulations / legislation specific for the substance or mixture
   WATER(7732-18-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS
   Australia Inventory of Chemical Substances (AICS)
   HYDROCARBON PROPELLANT(68476-85-7.) IS FOUND ON THE FOLLOWING REGULATORY LISTS
   Australia Exposure Standards                                                                           Australia Inventory of Chemical Substances (AICS)
   Australia Hazardous Substances Information System - Consolidated Lists                                 International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List
                                                                                                          Passenger and Cargo Aircraft
    National Inventory                     Status
   Australia - AICS                        Y
    Canada - DSL                           Y
    Canada - NDSL                          N (water; hydrocarbon propellant)
    China - IECSC                          Y
   Europe - EINEC / ELINCS / NLP           Y
    Japan - ENCS                           N (hydrocarbon propellant)
   Korea - KECI                            Y
    New Zealand - NZIoC                    Y
   Philippines - PICCS                     Y
    USA - TSCA                             Y
                                           Y = All ingredients are on the inventory
    Legend:
                                           N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
 SECTION 16 OTHER INFORMATION
 Other information
 Ingredients with multiple cas numbers
    Name                                   CAS No
   hydrocarbon propellant                  68476-85-7., 68476-86-8.
   Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
   available literature references.
    The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other
    settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
 Definitions and abbreviations
   PC-TWA: Permissible Concentration-Time Weighted Average
   PC-STEL: Permissible Concentration-Short Term Exposure Limit
   IARC: International Agency for Research on Cancer
   ACGIH: American Conference of Governmental Industrial Hygienists
   STEL: Short Term Exposure Limit
   TEEL: Temporary Emergency Exposure Limit。
   IDLH: Immediately Dangerous to Life or Health Concentrations
   OSF: Odour Safety Factor
   NOAEL :No Observed Adverse Effect Level
   LOAEL: Lowest Observed Adverse Effect Level
   TLV: Threshold Limit Value
   LOD: Limit Of Detection
   OTV: Odour Threshold Value
   BCF: BioConcentration Factors
   BEI: Biological Exposure Index
   This document is copyright.
   Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
   permission from CHEMWATCH.
                                                                                                                                                                                              Continued...
Chemwatch: 4689-23                       Page 8 of 8             Issue Date: 27/06/2017
Version No: 4.1.1.1                                              Print Date: 21/12/2017
                             Gillette Foamy Aerosol Shave Foam
    TEL (+61 3) 9572 4700.
                                                                          end of SDS