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MATERIAL SAFETY DATA SHEET
S-OIL SEVEN CLEAN
Date of the previous version: 2017-04-07 Revision Date: 2020-08-03 Version 2.1
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name S-OIL SEVEN CLEAN
Pure substance/mixture Mixture
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended Use Automotive flushing oil
1.3. Details of the supplier of the safety data sheet
Supplier S-OIL CORPORATION
192, Baekbeom-ro, Mapo-gu,
Seoul 121-805, Korea
For further information, please contact:
Contact Point HSSEQ
E-mail Address dolyoo@s-oil-total.com
1.4. Emergency telephone number
Korea + 82 2 527-6052
2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
GHS Classification
Not classified as hazardous
2.2. Label elements
GHS label elements, including precautionary statements
Symbol(s) Not Classified
Signal Words Not Classified
2.3. GHS Hazard Statements
Not Classified
2.4. GHS Precautionary Statements
Prevention Not Classified
Response Not Classified
Storage Not Classified
Disposal Not Classified
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MATERIAL SAFETY DATA SHEET
S-OIL SEVEN CLEAN
Date of the previous version: 2017-04-07 Revision Date: 2020-08-03 Version 2.1
2.5. Other hazards
Physical-Chemical Properties Contaminated surfaces will be extremely slippery.
Environmental properties Should not be released into the environment
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixture
Chemical Name CAS-No EC-No Weight %
Distillates (petroleum), hydrotreated heavy
64742-54-7 265-157-1 95.0 ~ 99.0
paraffinic
Mixed performance additive Mixture - 1.0 ∼ 4.0
Antiwear additive Mixture - < 1.0
Oil solution of acrylic copolymer Mixture - < 1.0
Polymerized dimethyl silicone fluid Mixture - < 0.1
Additional information Product containing mineral oil with less than 3% DMSO extract as measured by
IP 346
4. FIRST AID MEASURES
4.1. Description of first-aid measures
General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR
OR EMERGENCY MEDICAL CARE.
Eye contact Rinse thoroughly with plenty of water, also under the eyelids.
Skin contact Remove contaminated clothing and shoes. Wash skin with soap and water.
Wash contaminated clothing before reuse. High pressure jets may cause skin
damage. In this case, the casualty should be sent immediately to hospital.
Inhalation Move to fresh air.
Ingestion Do NOT induce vomiting. Never give anything by mouth to an unconscious
person. Call a physician or Poison Control Center immediately.
4.2. Most important symptoms and effects, both acute and delayed
Eye contact Not classified.
Not classified. High pressure injection of the products under the skin may have
Skin contact
very serious consequences even though no symptom or injury may be
apparent.
Inhalation Not classified. Inhalation of vapors in high concentration may cause irritation of
respiratory system.
Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting
and diarrhea.
4.3. Indication of immediate medical attention and special treatment needed, if necessary
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MATERIAL SAFETY DATA SHEET
S-OIL SEVEN CLEAN
Date of the previous version: 2017-04-07 Revision Date: 2020-08-03 Version 2.1
Notes to physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing media Carbon dioxide (CO2). ABC powder. Foam. Water spray or fog.
Unsuitable extinguishing media No information available
5.2. Special hazards arising from the substance or mixture
Special Hazard Incomplete combustion and thermolysis may produce gases of varying toxicity
such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes
and soot. These maybe highly dangerous if inhaled in confined spaces or at
high concentration.
5.3. Advice for fire-fighters
Special protective equipment for fire- Wear self-contained breathing apparatus and protective suit.
fighters
Other information Cool containers / tanks with water spray. Fire residues and contaminated fire
extinguishing water must be disposed of in accordance with local regulations.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
General Information Do not touch or walk through spilled material. Contaminated surfaces will be
extremely slippery. Use personal protective equipment. Ensure adequate
ventilation. Remove all sources of ignition.
6.2. Environmental precautions
General Information Do not allow material to contaminate ground water system. Try to prevent the
material from entering drains or water courses. Local authorities should be advised if significa
cannot be contained.
6.3. Methods and material for containment and cleaning up
Methods for containment Dam up. Contain spillage, and then collect with non-combustible absorbent
material, (e.g.sand, earth, diatomaceous earth, vermiculite) and place in
container for disposal according to local / national regulations (see section 13).
Keep in suitable, closed containers for disposal.
6.4. Reference to other sections
Personal Protective Equipment See Section 8 for more detail.
Waste treatment See section 13.
7. HANDLING AND STORAGE
7.1. Precautions for safe handling
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MATERIAL SAFETY DATA SHEET
S-OIL SEVEN CLEAN
Date of the previous version: 2017-04-07 Revision Date: 2020-08-03 Version 2.1
Advice on safe handling When using, do not eat, drink or smoke. For personal protection see section 8.
Use only in well-ventilated areas. Do not breathe vapors or spray mist. Avoid
contact with skin, eyes and clothing.
Prevention of fire and explosion Take precautionary measures against static discharges. Ground/bond
containers, tanks and transfer/receiving equipment.
Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the
risk of contact with the product. Regular cleaning of equipment, work area and
clothing is recommended. Wash hands before breaks and immediately after
handling the product. Do not use abrasives, solvents or fuels. Do not dry hands
with rags that have been contaminated with product. Do not put product
contaminated rags into workwear pockets.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures/Storage Keep away from food, drink and animal feeding stuffs. Keep in a bunded area.
conditions Keep container tightly closed. Keep preferably in the original container.
Otherwise reproduce all indication of the regulation label on the new container.
Do not remove the hazard labels of the containers (even if they are empty).
Design the installations in order to avoid accidental emissions of product (due to
seal breakage, for example) onto hot casings or electrical contacts. Protect from
frost, heat and sunlight. Protect from moisture.
Materials to Avoid Strong oxidizing agents.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Exposure limits Mineral oil mist:
USA: OSAH (PEL) TWA 5 mg/m3, NIOSH (REL) TWA 5 mg/m3,
STEL 10 mg/m3, ACGIH (TLV) TWA 5 mg/m3 (highly refined)
Legend See section 16.
8.2. Exposure controls
Occupational Exposure Controls
Engineering Measures Apply technical measures to comply with the occupational exposure limits.
When working in confined spaces (tanks, containers, etc.), ensure that there is
a supply of air suitable for breathing and wear the recommended equipment.
Personal Protective Equipment
General Information If the product is used in mixtures, it is recommended that you contact the appropriate
protective equipment suppliers. These recommendations apply to the product as
supplied.
Respiratory protection None under normal use conditions. When workers are facing concentrations above the
exposure limit they must use appropriate certified respirators. Respirator with
combination filter for vapour/particulate (EN 14387). Type A/P1. The use of breathing
apparatus must comply strictly with the manufacturer’s instructions and the regulations
governing their choices and uses.
Eye Protection If splashes are likely to occur, wear:. Safety glasses with side-shields.
Skin and body protection Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing.
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MATERIAL SAFETY DATA SHEET
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Date of the previous version: 2017-04-07 Revision Date: 2020-08-03 Version 2.1
Hand Protection Hydrocarbon-proof gloves. Fluorinated rubber. Nitrile rubber. Please observe the
instructions regarding permeability and breakthrough time which are provided by the
supplier of the gloves. Also take into consideration the specific local conditions under
which the product is used, such as the danger of cuts, abrasion. If used in solution, or
mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the EC approved gloves.
Environmental exposure controls
General Information The product should not be allowed to enter drains, water courses or the soil.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Color Yellow To amber
Physical State @20°C liquid
Odor Characteristic
Property Values Remarks Method
pH Not applicable
Boiling point/boiling range Not applicable
Flash point 248 °C Cleveland Open Cup (COC)
478.4 ℉ Cleveland Open Cup (COC)
Evaporation rate No information available
Flammability Limits in Air No information available
Vapor Pressure No information available
Vapor density No information available
Density 853.3 kg/m3 @ 15 °C
Water solubility Negligible Insoluble
Solubility in other solvents No information available
logPow No information available
Autoignition temperature Not applicable
Viscosity, kinematic 33.45 mm2/s @ 40 °C
Explosive properties Not explosive
Oxidizing Properties Not applicable
Possibility of hazardous reactions Not applicable
9.2. Other information
10. STABILITY AND REACTIVITY
10.1. Reactivity
General Information None under normal processing.
10.2. Chemical stability
Stability. Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous Reactions None under normal processing.
10.4. Conditions to Avoid
Conditions to Avoid Heat (temperatures above flash point), sparks, ignition points, flames, static electricity.
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MATERIAL SAFETY DATA SHEET
S-OIL SEVEN CLEAN
Date of the previous version: 2017-04-07 Revision Date: 2020-08-03 Version 2.1
10.5. Incompatible Materials
Materials to Avoid Strong oxidizing agents.
10.6. Hazardous Decomposition Products
Hazardous Decomposition Product Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon
Monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot.
11. TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity Local effects Product Information
Skin contact . Not classified. High pressure injection of the products under the skin may have very
Serious consequences even though no symptom or injury may be apparent.
Eye contact . Not classified.
Inhalation . Not classified. Inhalation of vapors in high concentration may cause irritation of
respiratory system.
Ingestion . Not classified. Ingestion may cause gastrointestinal irriation, nausea, vomiting and
diarrhea.
Acute toxicity - Component Information
Chemical name Oral Dermal Inhalation
Distillates (petroleum), LC50 5 mg/L
LD50 > 5000 mg/kg LD50 > 5000 mg/kg
hydrotreated heavy (4hr, aerosol, rat – OECD
(rat – OECD 420) (rabbit – OECD 402)
paraffinic 403)
LD50 > 5000 mg/kg LD50 > 4000 mg/kg
Mixed performance additive -
(rat – OECD 401) (rabbit – OECD 402)
Antiwear additive ATEmix > 10,000 mg/kg - -
Oil solution of acrylic LD50 > 2000 mg/kg LD50 > 2000 mg/kg
-
polymer (rat) (rabbit)
Sensitization
Sensitization Not classified as a sensitizer.
Specific effects
Carcinogenicity This product is not classified carcinogenic.
Mutagenicity This product is not classified as mutagenic.
Reproductive toxicity This product does not present any known or suspected reproductive hazards.
Repeated Dose Toxicity
Subchronic toxicity No information available.
Target Organ Effects (STOT)
Target Organ Effects (STOT) No information available.
Other information
Other adverse effects Characteristic skin lesions (pimples) may develop following prolonged and repeated
exposures (contact with contaminated clothing).
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MATERIAL SAFETY DATA SHEET
S-OIL SEVEN CLEAN
Date of the previous version: 2017-04-07 Revision Date: 2020-08-03 Version 2.1
12. ECOLOGICAL INFORMATION
12.1. Toxicity
1) Acute toxicity
Toxicity to daphnia and other
Chemical name Toxicity to algae Toxicity to fish
aquatic invertebrates
EL50 > 100 mg/l EL50 > 10000 mg/l LL50 > 100 mg/l
Distillates (petroleum),
(48hr, Pseudokirchnerella (48hr, Daphnia magna – (96hr, Oncorhynchus mykiss
hydrotreated heavy paraffinic
subcapitata – OECD 201) OECD 202) – OECD 203)
2) Chronic toxicity
Toxicity to daphnia and other
Chemical name Toxicity to algae Toxicity to fish
aquatic invertebrates
NOEL 10 mg/l NOEL > 1000 mg/l
Distillates (petroleum),
- (21day, Daphnia magna – (14/28 day, Oncorhynchus
hydrotreated heavy paraffinic
QSAR Petrotox) mykiss – QSAR Petrotox)
Effects on terrestrial organisms No information available.
12.2. Persistence and degradability
General Information No information available
12.3. Bioaccumulative potential
Product Information No information available.
logPow No information available
Component Information No information available
12.4. Mobility in soil
Soil Given its physical and chemical characteristics, the product generally shows low soil
mobility.
Air Loss by evaporation is limited.
Water Insoluble. The product spreads on the surface of the water.
12.5. Results of PBT and vPvB assessment
PBT and vPvB assessment No information available.
12.6. Other adverse effects
General Information No information available
13. DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste from Residues / Unused Should not be released into the environment. Do not empty into drains. Dispose of in
Products accordance with all applicable national environment laws and regulations. Where
possible recycling is preferred to disposal or incineration
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or
disposal.
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MATERIAL SAFETY DATA SHEET
S-OIL SEVEN CLEAN
Date of the previous version: 2017-04-07 Revision Date: 2020-08-03 Version 2.1
14. TRANSPORT INFORMATION
ADR/RID Not regulated
IMDG/IMO Not regulated
ICAO/IATA Not regulated
ADN Not regulated
15. REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture
International Inventories
TSCA
KECL
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
KECL - Korean Existing and Evaluated Chemical Substances
Further information
15.2. Chemical Safety Assessment
Chemical Safety Assessment No information available
16. OTHER INFORMATION
Abbreviations, acronyms
Legend Section 8
+ Sensitizer * Skin designation
** Hazard Designation C: Carcinogen
M: Mutagen R: Toxic to reproduction
Revision Date: 2020-08-03
Revision Note *** Indicates updated section.
This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above. It is understood by
theuser that any use of the product for purposes other than those for which it was designed entails potential risk. The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his
activity. The user bears sole liability for the precautions required when using the product. The regulatory texts
indicated herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and
exhaustive. It is the user's responsibility to ensure that he is subject to no other obligations than those mentioned.
End of the safety data sheet
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