Karim 2020
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Abstract
This paper presents a comprehensive study of the metallurgical challenges of welding dissimilar metals.
It also describes the important factors in dissimilar welding which need to be considered for automotive
applications. It further investigates effective approaches to overcome these present challenges. Steels,
aluminum alloys, and magnesium alloys are widely used metals in car bodies. However, it is difficult to
weld these dissimilar metals and achieve good joint quality, due to their inherent disparate properties. The
formation of brittle, crack sensitive and corrosion susceptible intermetallic phases is the main obstacle to
dissimilar weld quality. Various approaches have been attempted by many researchers to enhance the
performance of dissimilar welds. The most notable efforts include the application of interlayers, cover plate,
least heat input, a combination of welding and mechanical joining, and alloying elements of filler metals.
Based on considerations of joint performance, production cost and time, present industry infrastructure, and
so on, the most effective and feasible approaches were identified which required the least amount of heat
input, and the appropriate filler metal alloying elements.
Key Words : Review, Dissimilar metals, Welding, Car body, Steels, Aluminum, Magnesium, Intermetallics
highly susceptible to cracks and corrosion10). The ther- Weight SLC BIW : 180kg Materials Weight distribution
Aluminium 96kg (53%)
mal cycle of the welding process changes the properties Aluminium sheet
Aluminium die-casting Steel 66kg (36%)
Magnesium 11kg (7%)
of the weld zone and adjacent base metals. The differ- Aluminium extrusion
Steel Plastic 7kg (4%)
Hot-formed steel
ence in thermal properties of dissimilar metals induces Magnesium sheet
Magnesium die-casting
the thermal stresses and forms cavities and cracks. Fiberglass themoplastic
Fusion welding
facturing process. Research on laser welding has been
Solid state welding
Resistance spot welding Diffusion welding grown gradually in the past years. Laser welding sets
Shielded metal arc welding Explosive welding
Gas metal arc welding Impact welding low heat input by localized fusion that reduces HAZ and
Gas tungsten arc welding Friction welding
Cold metal transfer Magnetic pulse welding IMC layer thickness38). But, laser welding also needs
Ultrasonic welding
Dissimilar metals huge investment for a change or modification of the
welding
present infrastructures. Recently, hybrid welding has also
Low dilution welding
Laser welding Welding+mechanical joining drawn great attention from researchers and manufacturers.
Electron beam welding Resistance element welding
Laser pulse welding Friction element welding
Hybrid welding is a joining method that combines two
Pulsed arc welding
different welding processes simultaneously to form the
same weld pool39). Furthermore, the hybridization of
Fig. 2 Various processes for dissimilar metals welding
welding and mechanical joining is being investigated.
Resistance element welding and friction element weld-
er metal are melted to form the weld. On the other hand,
ing are the combinations of fusion welding and me-
when base metals are heated to an elevated temperature
chanical joining technologies which produce a fusion
less than the melting point and pressure is applied to
bond between an auxiliary element and the bottom
form the weld, it is termed as solid-state welding. Low
sheet, and a mechanical locking between the element
dilution welding is also one kind of fusion welding. It
and the top sheet. From industrial point of view, the fur-
can be classified as the relatively less melting of base
ther development of resistance spot welding and electric
metals during welding19). The widely studied dissimilar
arc welding for dissimilar metal joining can be the most
metal welding processes are resistance spot welding20),
convenient to avoid extra investment and higher manu-
friction welding21), friction stir welding22), friction stir spot
facturing cost.
welding23,24), laser brazing25), diffusion welding26), explosive
Achieving a good weld quality of dissimilar metal
welding27-29), impact welding30), ultrasonic welding31-33)
welding is not easy due to the formation of cracks and
and magnetic pressure seam welding34). Fig. 2. shows
corrosion sensitive intermetallics. Various approaches
the various welding processes for dissimilar metals.
were attempted by the many researchers to achieve
The fusion welding, solid-state welding, and mechan-
good weld quality. The notable approaches are the ap-
ical joining processes are being extensively investigated
plication of interlayer, cover plate, low heat input, com-
for dissimilar metal joining. But, there are some key
bination of welding and mechanical joining, and appro-
factors including the present infrastructures of automo-
priate alloying of filler metals. Table 2 presents some of
tive industries, joint performance, speed of the joining
process, and manufacturing cost need to be considered the attempts taken by different researchers to enhance
for the selection of the joining process. The require- the performance of dissimilar metal welds of steel-alu-
ments of costly investment for complex equipment and minum40-62), aluminum-magnesium63-69), and steel-mag-
the new layout of the plant, and longer processing time nesium70-79). In terms of present infrastructures in auto-
can intervene in the wide application of the solid-state motive industries, manufacturing cost, and weld quality
welding and mechanical joining processes. In the pres- the application of the least amount of heat input and ap-
ent infrastructures of the industries, the application of propriate filler metal alloys were identified as the most
fusion welding processes can be most convenient and significant approaches. Though the application of cover
economic. Resistance spot welding (RSW) is the most plate, and interlayer or transition material can reduce
used welding process in automotive sectors35,36). RSW the IMC layer thickness, but the addition of extra weight
is cheap and high-speed joining process that also pro- and cost can limit their applications. The resistance ele-
vides dimensional accuracy10). Electric arc welding is ment welding facilitates welding between the element
also very popular. Shielded metal arc welding (SMAW), and the bottom sheet of similar materials, and can be a
gas metal arc welding (GMAW) and gas tungsten arc promising joining process in future automotive industries
welding (GTAW) are the three common types of elec- with the least modification of present infrastructures.
tric arc welding processes. Formation of the large heat-
affected zone (HAZ) and brittle IMCs are the main 4. Steel-Aluminum Welding
challenges of electric arc welding37). Friction welding is
one broadly investigated solid-state welding process in Steels and aluminum alloys are the extensively used
multi-material structures. Friction welding can reduce metals for automotive body manufacturing. Because of
thermal and metallurgical mismatch and brittle IMC the unique combination of high strength and toughness
phases. But the longer processing time of friction weld- of steels, and lightweight and formability of aluminum
ing makes it costly and difficult to adapt in the manu- alloys, they are the most investigated dissimilar combi-
Table 2 Various research approaches to enhance the performance of dissimilar metal welds
Welding Steel - Aluminum - Steel –
Aluminum Magnesium Magnesium Approaches
Metal inert gas (MIG) Nguyen et al.40) Shah et al.41) Zhang et al.63) Wang et Liu et
welding al.70) al.71) Minimizing
Tungsten inert gas Borrisutthekul et Song et al.43) Liu et al.64) Wang et al.72) heat input
(TIG) welding al.42) Alloying of
Resistance spot Pouranvari Qui et Winnicki et al.47) Zhang et al.65) Min et Feng et Filler metal
welding (RSW) et al.44) al.45) Baskoro et al.48) Sun et al.66) al.73) al.74) Applying
Satonaka Su et al.49) cover plate
et al.46) Ibrahim et al.50) Applying
Oikawa et al.51) interlayer
Sun et al.52)
53)
Resistance
Laser welding Torkamany et al. Dharmendra et al.54) Chang et Liu et Li et al.75) element
al.67) al.64) welding
Cold metal transfer Jácome et al.55) Shang et al. 68)
Ren et al.76) Friction
(CMT) Kang et al.56) element
Friction stir welding Watanabe et al.57) Morishige Chang et Czerwinski et al. 77)
welding
(FSW) et al.69) al.67)
Element welding Meschut et al.58) Meschut et al.58) Manladan et al.78) Not
Qui et al.59) Absar et al.62) Manladan et al.79) investigated
Ling et al.60)
Ling et al.61)
nations38). But the welding between steel and aluminum Temperature C Atomic percent aluminum
0 10 20 30 40 50 60 70 80 90 100
offers several metallurgical challenges due to their in- 1600
1538℃
herent incompatibility in mechanical, thermal and elec- 1400
trical properties80,81). There are large differences in their 1394℃
1200
melting temperatures, thermal and electrical conductivities,
expansion coefficients, heat capacities, specific heats,
1000
and lattice transformation. Consequently, the weld qual- 912℃
ity is extremely influenced by this properties82). Aluminum 800
770℃
has nearly six times the thermal conductivity, three 660 452
600
times the modulus of elasticity, twice the specific heat
and thermal expansion than those of steel. Steel-alumi- 400
0 10 20 30 40 50 60 70 80 90 100
num alloy forms a weld-brazing joint as the welding Fe
Weight percent aluminum Al
(a) (b) mation mechanism of the IMC layer. The faster cooling
Fe(S) AI(L) Fe(S) Al(L) of molten Al forms FeAl3 which interrupts the diffusion
Grain of of Al atom to steel and changes the morphology and
IMC Fe2Al5
Fe2Al5
Initial interface layer
crystal orientation of Fe2Al5. When the temperature is
below 450℃, the diffusion coefficient of DFe-Al (Fe in
Al) and DAl-Fe (Al in Fe) are negligible, and when the
(c) (d) Al(S) temperature reaches at 450℃, the diffusion coefficient
Fe(S) Al(L) Fe(S)
Fe2Al5 of DFe-Al (8.95*10-11 cm2/s) is 106 times higher than
IMC IMC
layer Fe2Al5 layer DAl-Fe (1.21*10-16 cm2/s)92).
FeAl3
The intermetallic compounds significantly contribute
to the mechanical properties of the welds. It is evident
from most of the previous studies that the fractures mainly
Fig. 4 Formation and growth of the IMC layer83) occurred through the IMC layers during the tensile test.
The micro-cracks in the Fe2Al5 and FeAl3 layer domi-
stages for formation and growth sequences of FeAl3 and nated the location of the fractures. Internal micro-cracks
Fe2Al5 IMC layer. As soon as welding begins the tem- may form in the IMC layers due to the mismatch of the
perature reaches the liquidus line of Al while the steel thermal expansion coefficients between the materials89).
remains in solid-state. At first, Al atoms start to diffuse Furthermore, the hardness of the interfacial region in-
to the steel and plate-like Fe2Al5 IMCs start to nucleate creases because of the work hardening effect during the
in the interface between steel and Al. It forms an IMC recrystallization of deformed plasticized zone93). Table
layer sandwich between steel and Al which creates two 3 presents the hardness values of Fe-Al intermetallic
new interfaces, one interface between Fe2Al5 IMC layer phases at room temperature94), and it was found that the
and steel, and another interface between Fe2Al5 IMC hardness of Fe-Al intermetallics was much higher than
layer and Al. The growth of the Fe2Al5 IMCs is aniso- that of base metals. Fig. 6 shows a schematic diagram
tropic, and preferably along the c-axis of the Fe2Al5 unit of a typical hardness profile for steel-Al welding. The
cell as Fe2Al5 crystalline lattice has 30% vacancies along hardness decreases from the fusion zone (FZ) to base
metal (BM). The FZ exhibits the maximum hardness,
the c-axis91). Then, Fe and Al atoms migrate through the
and in the heat-affected zone (HAZ), there is a gradual
IMC layer associated with solid-state diffusion. The
decrease in hardness from FZ to BM. In a previous
higher diffusivity of Al atoms in the Fe2Al5 IMC layer
along this c-axis direction makes faster growth rates of
Fe2Al5. The growth of the Fe2Al5 IMC layer functions Table 3 Hardness of Fe-Al intermetallic phases94)
as a barrier in the middle of solid steel and liquid Al. Phases Vickers Hardness (9.8 N)
Gradually Fe2Al5 IMC layer becomes enough thicker Fe (Steel) 180 – 480
that it almost entirely stops the coalescence between FeAl 491 – 667
solid steel and liquid Al. As the Fe atoms are bigger FeAl2 1058 – 1070
than Al atoms, the diffusion of Fe atoms decreases FeAl3 772 – 1017
through the Fe2Al5 IMC layer. It forms needle-like Fe2Al5 1000 – 1158
FeAl3 IMCs in the interface between Al and Fe2Al5 Fe3Al 344 – 368
IMC layer. Fig. 5 shows the energy-dispersive X-ray Al(5xxx, 6xxx) 35 – 150
spectroscopy (EDS) analysis of the steel-Al IMC layer.
Here, the atomic ratio of Al and Fe explicates the pres-
ence of FeAl3 and Fe2Al5 in accordance with the for- Fusion zone HAZ BM
Microhardness
5.0
4.5
Atomic ratio(Al:Fe)
4.0 Tl
3.5
3.0
2.5
2.0 A3
1.5 FeAl3 Fe2Al5
1.0 A1
0.5
0.0
1 2 3 4 5 6
EDS spot number
Distance from FZ center
Fig. 5 Energy-dispersive X-ray spectroscopy of steel– Fig. 6 Typical hardness profile schematic of steel-Al
Al IMC layer91) fusion weld11)
Table 4 Filler metal, IMCs, IMC layer thickness and fracture location of steel and aluminum welding
Welding Materials (aluminum Filler metal IMC layer IMC Fracture zone/type Ref.
process alloy/steel) & Thickness thickness(µm)
95)
Metal Inert Al 2B50 1.0mm/ 4043 Al-Si 10 (with Al86Fe14 Between fusion
Gas (MIG) 1Cr18Ni9Ti 1.0 mm micro-cracks) Al0.7Fe3Si0.3 zone and steel
Welding (aluminized with 50µm base metal
coating)
96)
Al 1060 1.0 mm/ Hot-dip Al-Si 10 (sample A) Fe2Al5 HAZ of Al
galvanized steel 1.0 mm 40–50 (sample B) FeAl2, FeAl3
97)
6K21 Al 1.6 mm/ 4043 3.2 (maximum) FeAl3 HAZ of Al
SPRC440 1.4 mm Al-Si Fe2Al5
85)
Tungsten Inert Al 5A06 3.0 mm/ 4047 Al-Si 20–35(top) Al7.2Fe2Si Welded
Gas (TIG) SUS321 austenite stainless 12(corner) Fe2Al5 seam and steel
Welding 3.0 mm <5(middle) FeSi2 interface
98)
Resistance A5052 1.5 mm/ 3.3 (Fe2Al5) Fe4Al13 Elongated dimple
Spot Welding DP 600 1.2 mm — 0.67-15.8 (Fe4Al13) Fe2Al5 and cleavage
(RSW) EN AW 6008-T66 Al 1.5 mm/ 5 (lathlike) Fe2Al5 Interfacial layer 99)
study, it was found that the higher tensile strength can siderably depends on the welding current. Fig. 7 dis-
be obtained by reducing the amount of IMCs53), and plays the relation between the welding current and IMC
particularly Al-rich IMCs. The Al-rich intermetallics layer thickness. The IMC layer thickness gradually in-
are more brittle in nature. When the amount of Al-rich creases with the rising of welding current. The micro-
IMCs increases, the IMC layer becomes thicker and the structure in HAZ of Al alloy becomes coarser when
weld zone becomes more brittle52). As a result, the strength heat input increases. Thus, it can be said that the lower
of the weld reduces significantly. Therefore, the IMC heat input obtains finer grain in HAZ of Al alloys. Fig.
layer thickness is one of the important factors to de- 8 presents the change of microstructure in HAZ of Al
termine the bond strength of weld91). A thinner IMC alloy when welding current rises from 100 A to 130 A.
layer can improve the strength of the weld38). Table 4 It is found that the microstructure in HAZ of Al alloy is
shows filler metal, intermetallic compounds, IMC layer coarser for 130 A welding current. Heat input also increases
thickness and fracture location of different steel and with an increase in welding time or cycle. Therefore, the
aluminum welding81,85,95-102). The brittle intermetallics welding time can also influence IMC layer thickness. A
are formed in the weld zone. The weld zone becomes
weaker than the base metals and leads to fracture
through the interfacial layer of the fusion zone or the
heat-affected zone. The IMC layer thickness varies for
different material grades, sheet thickness, and surface
coatings, alloying elements of filler metal, and welding
processes. Moreover, IMC layer thickness also varies
with different welding conditions. The IMC is thick at
the center and gradually decreases in its thickness from
the center to the periphery because of high temperature
at the central region and low temperature at the periph-
eral region. Heat is one of the most important input pa-
rameters of welding, and the thickness of the IMC layer 50㎛
significantly increases with increasing heat input20,45).
Heat input increases with an increase of welding Fig. 7 IMC layer thickness at different welding current
(a) 90 A (b) 110 A (c) 130 A and (d) 150 A42)
current. Therefore, the thickness of the IMC layer con-
(c)
(a) (b) 100㎛
Table 5 IMC and mechanical property of steel–Al welds using Al-12Si and Al-6Cu filler metals43)
L+(γFe)
800 sion properties of the weld and the heat-affected zone
700 L+(α Fe) vary considerably. The thermal cycle of the welding
650℃ 649℃
0.008
process affects the microstructure and surface composi-
600
0.00043
(Mg)+ +(α Fe)
tion of welds and the adjacent base metals. The dissim-
500 ilar metal welds of steel-Al, Al-Mg, and steel-Mg in car
(Mg)
400 bodies often experience humid environments which
0
Mg
0.02 0.04 0.06 0.08 0.1
Fe
may lead to corrosion damages. The dissimilar metal
ATOMIC percent iron welds are vulnerable to galvanic corrosion, pitting cor-
Fig. 13 Mg–Fe binary phase diagram108) rosion, intergranular corrosion, hydrogen cracking and
stress corrosion. In particular, the welds are highly
formation of brittle IMCs can be detrimental for the prone to galvanic corrosion in several corrosive envi-
weld quality of steel-Mg. ronments such as seawater, CO2 or moist air. The im-
The alloying elements, particularly Al in Mg alloy can pact of galvanic corrosion is higher in a salt environ-
significantly increase the weldability of Mg to steel. ment111). Galvanic corrosion happens when two or more
The Fe-Al system can form several intermetallic dissimilar materials are electrically connected in the
compounds. Consequently, the joint strength increases same electrolyte112). Several previous studies reported
that the corrosion commenced from the weld zone be-
with the increase of Al content in the Mg alloy. It hap-
cause of its higher negative corrosion potential value
pens due to the depletion of Al at the Mg side of the
over the base metals. There are several factors greatly
IMC layer. The joint strength also increases with the de-
affect the corrosion resistance of dissimilar metal welds.
creasing of IMC layer thickness109). Therefore, magne-
The number of intermetallic compounds and filler met-
sium welding needs low and controlled heat input. The
als are the key factors of corrosion resistance for dis-
lower heat input can restrain the growth of the IMC
similar metal weld.
layer.
A study investigated the corrosion properties of steel-
The application of thin interlayers has been attempted
Al weld-brazing (pulsed double-electrode gas metal arc
to bond Mg to steel in some previous studies. HSLA
welding) lap joint with Al-5%Mg filler metal112). The
steel and AZ31B-H24 Mg alloy were welded using an
IMCs formed at the interface of the weld led to the dis-
interlayer of Sn by ultrasonic spot welding110). Fig. 14 solution of the adjacent weld seam metals and accel-
(a) shows the weld without application of any interlayer erated the galvanic corrosion. The corrosion resistance
where only some hydroxides are present. After the ap- of the weld decreased with an increase in IMC layer
plication of the Sn interlayer, the interlayer forms the thickness. The heat input increased with the decrease of
Sn-Mg2Sn eutectic structure. Fig. 14 (b) exhibits the eu- bypass current and resulted in a higher corrosion current
tectic Sn-Mg2Sn layer between steel and Mg base density. Fig. 15 shows potentiodynamic polarization
metals. Fe was not observed in the IMC layer because curves under various bypass current with the same total
of higher solubility of Sn in Mg than Sn in Fe. The lap
shear strength of the Mg-steel joint with Sn interlayer
0.0 Bypass 40A
was found higher than that of a similar joint without Bypass 30A
Bypass 24A
Potential(V vs,SCE)
-0.4
-0.8
-1.0
-1.2
-8 -7 -6 -5 -4 -3 -2 -1
Log(current density/A·cm-2)
Fig. 14 Mg–steel weld (a) without Sn interlayer, and (b) Fig. 15 Polarization curves of steel–Al weld under dif-
with Sn interlayer110) ferent bypass current112)
Potential(V vs,SCE)
-0.4
-0.8
-1.0
-1.2
8. Conclusion
Recent developments of various lightweight materials
have rejuvenated the automotive industry. But the join-
ing of these dissimilar materials is still challenging for
(c) (d)
the manufacturers. The most promising steel-Al alloy,
Al alloy-Mg alloy, and steel-Mg alloy dissimilar combi-
nations and their metallurgical challenges to welding
have been discussed throughout the paper. In the in-
dustrial point of view, the improvement of resistance
spot welding and electric arc welding for multi-materi-
Fig. 17 (a) & (b) before and after corrosion test of weld
joint by AlMg6Mn filler metal, and (c) & (d) be- als integration was realized as the most convenient and
fore and after corrosion test of the weld joint by economical because of their established infrastructures.
ZnAl2 filler metal113) Minimizing intermetallic compounds were identified as
a significant factor to enhance the weld quality of dis- to Weld Dissimilar Metals in Two Industries, The Upstream
similar metal welds. The control of heat input and the Oil & Gas and the Automotive, Mater. Sci. Forum
selection of alloying elements for filler metal can effec- 580-582 (2008) 155-158.
tively reduce the amount of intermetallic compounds as https://doi.org/10.4028/www.scientific.net/MSF.580-582.155
well as the growth of IMC layer thickness. As a con- 10. F. Shahid, A. A. Khan and M. Saqib Hameed, Mechanical
sequence, the brittle IMCs formation and the corrosion and Microstuctural Analysis of Dissimilar Metal
susceptibility of the weld zone can be considerably mi- Welds, IJRRAS, 25(1) (2015) 6-14
11. M. Pouranvari and S. P. H. Marashi, Critical review of
tigated that can enhance the weld quality. The opti-
automotive steels spot welding, process, structure and
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361-403.
filler metals, base metals, and base metal coatings re-
https://doi.org/10.1179/1362171813Y.0000000120
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yazakki, H. Oikawa and T. Nose, Dissimilar Metal
ORCID: Md. Abdul Karim: https://orcid.org/0000-0003-0954-3653 Joining Technologies for Steel Sheet and Aluminum
ORCID: Yeong-Do Park: https://orcid.org/0000-0002-0165-4749
Alloy Sheet in Auto Body, Nippon Steel Tech. Rep.
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