Revision date: 12/12/2019 Revision: 5 Supersedes date: 17/08/2017

SAFETY DATA SHEET

NITOCOTE EPS BASE

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name NITOCOTE EPS BASE

Product number A1760010AE1, A1760012AE1, A1760000AE1

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Base component of Epoxy polysulphide protective coating

1.3. Details of the supplier of the safety data sheet

Supplier Al Gurg Fosroc LLC
PO Box 657
Dubai
United Arab Emirates
+ 971 4 2858606

1.4. Emergency telephone number

Emergency telephone +97142039699 (08:00 to 16:30) // +971506258232 (16:30 to 08:00)GMT+4

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Repr. 1B - H360 STOT SE 3 - H335

Environmental hazards Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H315 Causes skin irritation.

H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H360 May damage fertility or the unborn child.
H410 Very toxic to aquatic life with long lasting effects.

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Precautionary statements P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.

Contains SILICA FLOUR, EPOXY RESIN (Type A) (Number average MW <= 700 ),
EPICHLOROHYDRIN, POLYMER W/BISPHENOL A

Supplementary precautionary P201 Obtain special instructions before use.

statements P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing vapour/ spray.
P264 Wash contaminated skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P312 Call a POISON CENTRE/doctor if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

SILICA FLOUR 30-60%

CAS number: 14808-60-7

Classification
Eye Irrit. 2 - H319
STOT SE 3 - H335

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin 10-30%

(number average molecular weight ≤ 700)
CAS number: 25068-38-6 EC number: 500-033-5 REACH registration number: 01-
2119456619-26-XXXX

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

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EPICHLOROHYDRIN, POLYMER W/BISPHENOL A 10-30%

CAS number: 25036-25-3 EC number: 682-390-8

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317

XYLENE 5-10%
CAS number: 1330-20-7 EC number: 215-535-7 REACH registration number: 01-
2119488216-32-0000

Classification
Flam. Liq. 3 - H226
Acute Tox. 4 - H312
Acute Tox. 4 - H332
Skin Irrit. 2 - H315

DIBUTYL PHTHALATE 5-10%

CAS number: 84-74-2 EC number: 201-557-4
M factor (Acute) = 1
Substance of very high concern (SVHC).

Classification
Repr. 1B - H360Df
Aquatic Acute 1 - H400

ETHYLBENZENE <1%
CAS number: 100-41-4 EC number: 202-849-4

Classification
Flam. Liq. 2 - H225
Acute Tox. 4 - H332
STOT RE 2 - H373
Asp. Tox. 1 - H304

IRON OXIDE BLACK PIGMENT <1%

CAS number: 1317-61-9

Classification
Not Classified

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ISO-BUTANOL <1%
CAS number: 78-83-1 EC number: 201-148-0

Classification
Flam. Liq. 3 - H226
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
STOT SE 3 - H335, H336

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Move affected person to fresh air at once. Move affected person to fresh air and keep warm
and at rest in a position comfortable for breathing. Get medical attention if any discomfort
continues.

Ingestion Rinse mouth thoroughly with water. Move affected person to fresh air and keep warm and at
rest in a position comfortable for breathing. Never give anything by mouth to an unconscious
person. Do not induce vomiting. Get medical attention.

Skin contact Remove affected person from source of contamination. Wash skin thoroughly with soap and
water. Get medical attention promptly if symptoms occur after washing.

Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information Get medical attention promptly if symptoms occur after washing.

Inhalation May cause respiratory irritation.

Ingestion Toxic if swallowed.

Skin contact May cause an allergic skin reaction. May cause irritation.

Eye contact Causes serious eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with the following media: Foam. Carbon dioxide (CO2). Dry chemicals, sand,
dolomite etc.

5.2. Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.

Hazardous combustion Thermal decomposition or combustion products may include the following substances: Oxides
products of carbon. Toxic gases or vapours.

5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

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6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear personal protective clothing and equipment, see Section 8.

6.2. Environmental precautions

Environmental precautions Prevent from entering into ditches, sewers, waterways and groundwater.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Containers with collected
spillage must be properly labelled with correct contents and hazard symbol. Dispose of
contents/container in accordance with local regulations.

6.4. Reference to other sections

Reference to other sections See Section 12 for additional information on ecological hazards.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid spilling. Provide adequate ventilation. Avoid inhalation of vapours. Use approved
respirator if air contamination is above an acceptable level. Avoid contact with skin and eyes.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Chemical storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
TITANIUM DIOXIDE
Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ inhalable dust
Long-term exposure limit (8-hour TWA): WEL 4 mg/m³ respirable dust
XYLENE
Long-term exposure limit (8-hour TWA): WEL 50 ppm 220 mg/m³
Short-term exposure limit (15-minute): WEL 100 ppm 441 mg/m³
Sk
DIBUTYL PHTHALATE
Long-term exposure limit (8-hour TWA): WEL 5 mg/m³
Short-term exposure limit (15-minute): WEL 10 mg/m³
ETHYLBENZENE
Long-term exposure limit (8-hour TWA): WEL 100 ppm 441 mg/m³
Short-term exposure limit (15-minute): WEL 125 ppm 552 mg/m³
Sk
CLAY
Long-term exposure limit (8-hour TWA): WEL 10 mg/m3 total dust
IRON OXIDE BLACK PIGMENT
Long-term exposure limit (8-hour TWA): 5 mg/m³ fume
Short-term exposure limit (15-minute): 10 mg/m³ fume
ISO-BUTANOL

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Long-term exposure limit (8-hour TWA): WEL 50 ppm 154 mg/m³

Short-term exposure limit (15-minute): WEL 75 ppm 231 mg/m³
WEL = Workplace Exposure Limit.
Sk = Can be absorbed through the skin.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS:
25068-38-6)

DNEL Workers - Inhalation; Short term systemic effects: 12.25 mg/m³

Workers - Inhalation; Long term systemic effects: 12.25 mg/m³

PNEC - Fresh water; 0.006 mg/l

TITANIUM DIOXIDE (CAS: 13463-67-7)

DNEL Industry - Inhalation; Long term local effects: 10 mg/m³

Consumer - Oral; Long term systemic effects: 700 mg/kg/day

PNEC - Fresh water; 0.127 mg/l

- Sediment (Freshwater); >=1000 mg/kg
- marine water; 1 mg/l
- Sediment (Marinewater); >= 100 mg/kg
- Soil; 100 mg/kg
- STP; 100 mg/l

XYLENE (CAS: 1330-20-7)

DNEL Workers - Inhalation; Long term systemic effects: 77 mg/m³

Workers - Inhalation; Short term systemic effects: 289 mg/m³
Workers - Dermal; Long term systemic effects: 180 mg/kg/day

PNEC - Fresh water; 0.327 mg/l

- marine water; 0.327 mg/l
- STP; 6.58 mg/l

DIBUTYL PHTHALATE (CAS: 84-74-2)

DNEL Workers - Inhalation; Long term systemic effects: 0.13 mg/m³

Workers - Dermal; Long term systemic effects: 0.19 mg/kg bw/day

PNEC - Fresh water; 10 µg/l

- marine water; 1 µg/l

ETHYLBENZENE (CAS: 100-41-4)

DNEL Workers - Inhalation; Long term systemic effects: 77 mg/m³

Workers - Dermal; Long term systemic effects: 180 mg/kg bw/day

PNEC - Fresh water; 0.1 mg/l

- marine water; 0.01 mg/l

ISO-BUTANOL (CAS: 78-83-1)

DNEL Workers - Inhalation; Long term local effects: 310 mg/m³

PNEC - Fresh water; 0.4 mg/l

- marine water; 0.04 mg/l

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8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours. Observe any occupational
controls exposure limits for the product or ingredients.

Eye/face protection Wear tight-fitting, chemical splash goggles or face shield.

Hand protection Wear protective gloves made of the following material: Rubber (natural, latex). Neoprene.
Polyvinyl chloride (PVC).

Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact.

Hygiene measures Wash at the end of each work shift and before eating, smoking and using the toilet. Wash
promptly with soap and water if skin becomes contaminated. Promptly remove any clothing
that becomes contaminated. Do not smoke in work area. Do not eat, drink or smoke when
using this product.

Respiratory protection Respiratory protection may be required if excessive airborne contamination occurs.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Viscous liquid.

Colour
Various colours.

Odour Mild.

Odour threshold Not determined.

pH Not applicable.

Melting point Not determined.

Initial boiling point and range >200°C @

Flash point >150°C

Evaporation rate Not determined.

Evaporation factor Not determined.

Flammability (solid, gas) Not determined.

Upper/lower flammability or Not determined.

explosive limits

Other flammability Not available.

Vapour pressure Not determined.

Vapour density Not determined.

Relative density 1.5 @ 20°C

Bulk density Not determined.

Solubility(ies) Insoluble in water.

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Partition coefficient Not determined.

Auto-ignition temperature Not determined.

Decomposition Temperature Not determined.

Viscosity 800 P @ 23°C

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Stable at normal ambient temperatures and when used as recommended.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

Materials to avoid Avoid contact with strong oxidising agents.

10.6. Hazardous decomposition products

Hazardous decomposition Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or
products vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - dermal
ATE dermal (mg/kg) 21,120.59

Acute toxicity - inhalation

ATE inhalation (gases ppm) 86,402.41

ATE inhalation (vapours mg/l) 211.21

ATE inhalation (dusts/mists 28.8

mg/l)

Inhalation Irritating to respiratory system.

Ingestion Toxic if swallowed.

Skin contact May cause an allergic skin reaction. Irritating to skin.

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Eye contact Irritating to eyes. Symptoms following overexposure may include the following: Redness.
Pain.

Route of exposure Ingestion. Skin and/or eye contact

Toxicological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 5,000.0

mg/kg)

Species Rat

Notes (oral LD₅₀) NOAEL 750 mg/kg, Oral, Rat

ATE oral (mg/kg) 5,000.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 20,000.0

mg/kg)

Species Rabbit

Notes (dermal LD₅₀) LD₅₀ >1600 mg/kg, Dermal, Rat

ATE dermal (mg/kg) 20,000.0

Skin corrosion/irritation

Animal data Rabbit Moderately irritating.

Skin sensitisation

Skin sensitisation May cause sensitisation by skin contact.

XYLENE

Acute toxicity - dermal

ATE dermal (mg/kg) 1,100.0

Carcinogenicity

IARC carcinogenicity IARC Group 3 Not classifiable as to its carcinogenicity to humans.

DIBUTYL PHTHALATE

Acute toxicity - inhalation

Acute toxicity inhalation 4.25

(LC₅₀ vapours mg/l)

ATE inhalation (vapours 4.25

mg/l)

Acute and chronic health INGESTION. May cause stomach pain or vomiting. Inhalation May cause
hazards respiratory system irritation. SKIN CONTACT. May cause skin irritation/eczema.
May cause sensitisation by skin contact. EYE CONTACT. Irritating to eyes.

ETHYLBENZENE

Carcinogenicity

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IARC carcinogenicity IARC Group 2B Possibly carcinogenic to humans.

SECTION 12: Ecological information

Ecotoxicity Harmful to aquatic organisms, may cause long term adverse effects in the aquatic
environment

12.1. Toxicity
Toxicity The product contains a substance which is harmful to aquatic organisms.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Toxicity Ecotoxic to fish / daphnia / algae

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 3.6 mg/l, Leuciscus idus (Golden orfe)
LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss (Rainbow trout)

Acute toxicity - aquatic EC₅₀, 48 hours: 1.8 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic EC50, 72 hours: 11 mg/l, Scenedesmus capricornutum (fresh water algae)
plants

XYLENE

Toxicity Not considered toxic to fish.

DIBUTYL PHTHALATE

Acute aquatic toxicity

LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1

Acute toxicity - fish LC₅₀, 96 hours: 0.85 mg/l, Pimephales promelas (Fat-head Minnow)
LC₅₀, 96 hours: 1.6 mg/l, Salmo gairdneri

Acute toxicity - aquatic LC₅₀, 48 hours: 3.7 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic EC₅₀, 96 hours: 0.75 mg/l, Selenastrum capricornutum

plants

12.2. Persistence and degradability

Persistence and degradability There are no data on the degradability of this product.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Persistence and The product is not readily biodegradable.

degradability

XYLENE

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Persistence and Expected to be not readily biodegradable.

degradability

12.3. Bioaccumulative potential

Partition coefficient Not determined.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Partition coefficient log Pow: 3.242

12.4. Mobility in soil

Mobility The product is insoluble in water and will sediment in water systems.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Mobility The product has poor water-solubility.

Adsorption/desorption Water - Koc: 445 @ °C

coefficient

XYLENE

Mobility The product is insoluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information This material and its container must be disposed of as hazardous waste.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (ADN) 3082

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14.2. UN proper shipping name

Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
(ADR/RID) PHTHALATE: DBP, EPOXY RESIN (Type A) (Number average MW <= 700 ))

Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
PHTHALATE: DBP, EPOXY RESIN (Type A) (Number average MW <= 700 ))

Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
PHTHALATE: DBP, EPOXY RESIN (Type A) (Number average MW <= 700 ))

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS DIBUTYL
PHTHALATE: DBP, EPOXY RESIN (Type A) (Number average MW <= 700 ))

14.3. Transport hazard class(es)

ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ICAO packing group III

ADN packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number 90

(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code

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Transport in bulk according to Not applicable.

Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

Guidance Workplace Exposure Limits EH40.

Respiratory protective equipment at work (HSG53).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

General information Only trained personnel should use this material.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 12/12/2019

Revision 5

Supersedes date 17/08/2017

SDS number 11496

Hazard statements in full H225 Highly flammable liquid and vapour.

H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H360 May damage fertility or the unborn child.
H373 May cause damage to organs (Hearing organs) through prolonged or repeated
exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.

The information on this data sheet represents our current data and is reliable, provided that the product is used under the
prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance
literature. Any other use of the product which involves using the product in combination with any other product or any other
process is the responsibility of the user.

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SAFETY DATA SHEET

NITOCOTE EPS HARDENER

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name NITOCOTE EPS HARDENER

Product number A1760002AE1

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Hardener Component of Epoxy Polysulphide Protective Coating

1.3. Details of the supplier of the safety data sheet

Supplier Al Gurg Fosroc LLC
PO Box 657
Dubai
United Arab Emirates
+ 971 4 2858606

1.4. Emergency telephone number

Emergency telephone +97142039699 (08:00 to 16:30) // +971506258232 (16:30 to 08:00)GMT+4

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Flam. Liq. 3 - H226

Health hazards Acute Tox. 4 - H302 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Repr. 2 -
H361fd STOT RE 2 - H373

Environmental hazards Aquatic Chronic 2 - H411

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H226 Flammable liquid and vapour.

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

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Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.

Contains O,O'-Bis(2-aminopropyl)polypropyleneglycol, NONYLPHENOL, 1-METHOXY-2-PROPANOL,

LIQUID POLYSULPHIDE POLYMER

Supplementary precautionary P201 Obtain special instructions before use.

statements P202 Do not handle until all safety precautions have been read and understood.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P260 Do not breathe vapour/ spray.
P261 Avoid breathing vapour/ spray.
P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P310 Immediately call a POISON CENTER/ doctor.
P314 Get medical advice/ attention if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P391 Collect spillage.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

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O,O'-Bis(2-aminopropyl)polypropyleneglycol 10-30%
CAS number: 9046-10-0

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Aquatic Chronic 3 - H412

NONYLPHENOL 10-30%
CAS number: 84852-15-3 EC number: 284-325-5
M factor (Acute) = 1 M factor (Chronic) = 1
Substance of very high concern (SVHC).

Classification
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Repr. 2 - H361
Aquatic Acute 1 - H400
Aquatic Chronic 1 - H410

1-METHOXY-2-PROPANOL 10-30%
CAS number: 107-98-2 EC number: 203-539-1

Classification
Flam. Liq. 3 - H226
STOT SE 3 - H336

LIQUID POLYSULPHIDE POLYMER 10-30%

CAS number: 68611-50-7

Classification
Aquatic Chronic 2 - H411

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2-piperazin-1-ylethylamine 1-5%
CAS number: 140-31-8 EC number: 205-411-0 REACH registration number: 01-
2119471486-30-XXXX

Classification
Acute Tox. 4 - H302
Acute Tox. 3 - H311
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Repr. 2 - H361fd
STOT RE 1 - H372
Aquatic Chronic 3 - H412

TRIETHYLENETETRAMINE 1-5%
CAS number: 112-24-3 EC number: 203-950-6

Classification
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Chronic 3 - H412

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Remove affected person from source of contamination. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Get medical attention if any
discomfort continues.

Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Never give anything by mouth to
an unconscious person. Get medical attention immediately.

Skin contact Remove affected person from source of contamination. Take off immediately all contaminated
clothing. Rinse immediately with plenty of water. Get medical attention promptly if symptoms
occur after washing.

Eye contact Remove affected person from source of contamination. Rinse with water. Remove contact
lenses, if present and easy to do. Continue rinsing. Continue to rinse for at least 15 minutes
and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information Get medical attention promptly if symptoms occur after washing.

Inhalation May cause respiratory irritation.

Ingestion May cause chemical burns in mouth and throat. May cause stomach pain or vomiting.

Skin contact Causes severe burns. May cause an allergic skin reaction. May cause skin irritation.

Eye contact May cause serious eye damage.

4.3. Indication of any immediate medical attention and special treatment needed

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Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide or dry powder.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion Thermal decomposition or combustion products may include the following substances: Toxic
products gases or vapours. Ammonia or amines. Oxides of carbon.

5.3. Advice for firefighters

Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions

Environmental precautions Prevent entry into confined spaces such as waterways, sewers, basements.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Stop leak if safe to do so. Absorb in vermiculite, dry sand or earth and place into containers.
Containers with collected spillage must be properly labelled with correct contents and hazard
symbol. Dispose of contents/container in accordance with local regulations.

6.4. Reference to other sections

Reference to other sections For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid contact with skin and eyes. Use only outdoors or in a well-ventilated area. Keep away
from heat, sparks and open flame.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Flammable liquid storage.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
1-METHOXY-2-PROPANOL
Sk
Long-term exposure limit (8-hour TWA): WEL 100 ppm 375 mg/m³
Short-term exposure limit (15-minute): WEL 150 ppm 560 mg/m³
Sk = Can be absorbed through the skin.
WEL = Workplace Exposure Limit.

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O,O'-Bis(2-aminopropyl)polypropyleneglycol (CAS: 9046-10-0)

DNEL Industry/Professional, Workers - ; Long term systemic effects: 2.5 mg/kg bw/day

PNEC - Fresh water; 0.015 mg/l

1-METHOXY-2-PROPANOL (CAS: 107-98-2)

DNEL Industry - Inhalation; Short term local effects: 553.5 mg/m³

Industry - Dermal; Long term systemic effects: 50.6 mg/kg/day
Industry - Inhalation; Long term systemic effects: 369 mg/m³

PNEC - Fresh water; 10 mg/l

- marine water; 1 mg/l
- Intermittent release; 100 mg/l

2-piperazin-1-ylethylamine (CAS: 140-31-8)

DNEL Workers - Inhalation; Long term systemic effects: 3.6 mg/m³

Workers - Inhalation; Short term systemic effects: 21.4 mg/m³
Workers - Dermal; Long term systemic effects: 3.3 mg/kg/day
Workers - Dermal; Short term systemic effects: 20 mg/kg/day

PNEC - Fresh water; 0.0058 mg/l

- marine water; 0.58 mg/l

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.

controls

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles.

Hand protection Wear protective gloves made of the following material: Nitrile rubber. Polyvinylidene
chloride/polyethylene (PVDC/PE). Neoprene.

Other skin and body Wear appropriate clothing to prevent skin contamination.
protection

Hygiene measures Wash at the end of each work shift and before eating, smoking and using the toilet. Wash
promptly with soap and water if skin becomes contaminated. Promptly remove any clothing
that becomes wet or contaminated.

Respiratory protection Use an approved air purifying respirator with replaceable filter cartage comply with EN 140and
filter EN 141: Organic Vapour cartridge type A1

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Viscous liquid.

Colour Brown to black

Odour Amine.

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Odour threshold Not determined.

pH Not applicable.

Melting point Not determined.

Initial boiling point and range >180°C @

Flash point 48°C Closed cup.

Evaporation rate Not determined.

Evaporation factor Not determined.

Flammability (solid, gas) Not determined.

Upper/lower flammability or Not determined.

explosive limits

Other flammability Not determined.

Vapour pressure Not determined.

Vapour density Not determined.

Relative density 1.0 @ 20°C

Bulk density Not determined.

Solubility(ies) Insoluble in water.

Partition coefficient Not determined.

Auto-ignition temperature Not determined.

Decomposition Temperature Not determined.

Viscosity ~2 P @ 25°C

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.

of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The following materials may react with the product: Acids. Alkalis. Strong oxidising agents.

10.2. Chemical stability

Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Possibility of hazardous Under normal conditions of storage and use, no hazardous reactions will occur.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials

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Materials to avoid Avoid contact with strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Hazardous decomposition Thermal decomposition or combustion products may include the following substances: Oxides
products of carbon. Ammonia or amines.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 1,479.25

Acute toxicity - dermal

ATE dermal (mg/kg) 3,501.43

Inhalation May cause respiratory system irritation. May cause respiratory allergy.

Ingestion Causes burns. May cause chemical burns in mouth and throat. May cause stomach pain or
vomiting.

Skin contact Causes burns. May cause an allergic skin reaction.

Eye contact May cause serious eye damage. Causes burns.

Toxicological information on ingredients.

O,O'-Bis(2-aminopropyl)polypropyleneglycol

Acute toxicity - oral

ATE oral (mg/kg) 500.0

Acute toxicity - dermal

ATE dermal (mg/kg) 1,100.0

NONYLPHENOL

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 1,620.0

mg/kg)

Species Rat

ATE oral (mg/kg) 1,620.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 2,031.0

mg/kg)

Species Rat

1-METHOXY-2-PROPANOL

Acute toxicity - oral

Notes (oral LD₅₀) LD₅₀ 11700 mg/kg, Oral, Rat

Acute toxicity - dermal

Notes (dermal LD₅₀) LD₅₀ 13000 mg/kg, Dermal, Rabbit

Acute toxicity - inhalation

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Notes (inhalation LC₅₀) LC50 10000 ppm, Inhalation, Rat

LIQUID POLYSULPHIDE POLYMER

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 5,000.0

mg/kg)

Species Rat

ATE oral (mg/kg) 5,000.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 7,800.0

mg/kg)

Species Rat

ATE dermal (mg/kg) 7,800.0

2-piperazin-1-ylethylamine

Acute toxicity - oral

ATE oral (mg/kg) 500.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 866.0

mg/kg)

Species Rabbit

ATE dermal (mg/kg) 866.0

Germ cell mutagenicity

Genotoxicity - in vivo Ames test: Negative.

Reproductive toxicity

Reproductive toxicity - Fertility - NOAEL 150 mg/kg/day, Oral, Rabbit

fertility

Specific target organ toxicity - repeated exposure

STOT - repeated exposure NOAEL 53.5 mg/m³, Inhalation, Rat

Target organs Respiratory system, lungs

TRIETHYLENETETRAMINE

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 2,500.0

mg/kg)

Species Rat

ATE oral (mg/kg) 2,500.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 550.0

mg/kg)

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Species Rabbit

ATE dermal (mg/kg) 1,100.0

SECTION 12: Ecological information

Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

12.1. Toxicity
Toxicity The product contains a substance which is toxic to aquatic organisms.

Ecological information on ingredients.

O,O'-Bis(2-aminopropyl)polypropyleneglycol

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: >100 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 15 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic IC₅₀, 72 hours: 135 mg/l, Algae

plants

NONYLPHENOL

Acute aquatic toxicity

LE(C)₅₀ 0.1 < L(E)C50 ≤ 1

M factor (Acute) 1

Acute toxicity - fish LC₅₀, 96 hours: 0.128 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 0.0848 mg/l, Daphnia magna

invertebrates

Chronic aquatic toxicity

M factor (Chronic) 1

1-METHOXY-2-PROPANOL

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 6812 mg/l, Leuciscus idus (Golden orfe)

Acute toxicity - aquatic EC₅₀, 48 hours: >21000 mg/l, Daphnia magna

invertebrates

LIQUID POLYSULPHIDE POLYMER

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 1000 mg/l, Cyprinodon variegatus (Sheepshead minnow)

Acute toxicity - aquatic EC₅₀, 24 hours: 20 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic EC₅₀, 72 hours: 100 mg/l, Selenastrum capricornutum

plants

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2-piperazin-1-ylethylamine

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: >100 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 58 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic EC₅₀, 72 hours: > 300 mg/l, Freshwater algae
plants

TRIETHYLENETETRAMINE

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 330 mg/l, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquatic EC₅₀, 48 hours: 31.1 mg/L, Daphnia magna

invertebrates

Acute toxicity - aquatic EC₅₀, 72 hours: 20 mg/l, Pseudokirchneriella subcapitata

plants

Acute toxicity - EC₅₀, 16 hour: 680 mg/l, Bacteria

microorganisms

12.2. Persistence and degradability

Persistence and degradability The product is not readily biodegradable.

Ecological information on ingredients.

1-METHOXY-2-PROPANOL

Persistence and The product is biodegradable.

degradability

2-piperazin-1-ylethylamine

Persistence and The product is not readily biodegradable.

degradability

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation. Not determined.

Partition coefficient Not determined.

Ecological information on ingredients.

1-METHOXY-2-PROPANOL

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

2-piperazin-1-ylethylamine

Partition coefficient log Pow: -1.48

12.4. Mobility in soil

Mobility The product is insoluble in water.

12.5. Results of PBT and vPvB assessment

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Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

Ecological information on ingredients.

O,O'-Bis(2-aminopropyl)polypropyleneglycol

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

TRIETHYLENETETRAMINE

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Waste is classified as hazardous waste.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 2734

UN No. (IMDG) 2734

UN No. (ICAO) 2734

UN No. (ADN) 2734

14.2. UN proper shipping name

Proper shipping name POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (CONTAINS O,O'-Bis(2-
(ADR/RID) aminopropyl)polypropyleneglycol, 1-METHOXY-2-PROPANOL)

Proper shipping name (IMDG) POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (CONTAINS O,O'-Bis(2-
aminopropyl)polypropyleneglycol, 1-METHOXY-2-PROPANOL, NONYLPHENOL, LIQUID
POLYSULPHIDE POLYMER )

Proper shipping name (ICAO) POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (CONTAINS O,O'-Bis(2-
aminopropyl)polypropyleneglycol, 1-METHOXY-2-PROPANOL)

Proper shipping name (ADN) POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (CONTAINS O,O'-Bis(2-
aminopropyl)polypropyleneglycol, 1-METHOXY-2-PROPANOL)

14.3. Transport hazard class(es)

ADR/RID class 8

ADR/RID subsidiary risk 3

ADR/RID classification code FC

ADR/RID label 8

IMDG class 8

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IMDG subsidiary risk 3

ICAO class/division 8

ICAO subsidiary risk 3

ADN class 8

ADN subsidiary risk 3

Transport labels

14.4. Packing group

ADR/RID packing group II

IMDG packing group II

ICAO packing group II

ADN packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

IMDG Code segregation 18. Alkalis
group

EmS F-E, S-C

ADR transport category 2

Emergency Action Code •2W

Hazard Identification Number 83

(ADR/RID)

Tunnel restriction code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

Guidance Workplace Exposure Limits EH40.

Respiratory protective equipment at work (HSG53).

15.2. Chemical safety assessment

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No chemical safety assessment has been carried out.

SECTION 16: Other information

General information The user must be instructed in the proper work procedure and be familiar with the contents of
these instructions.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 24/12/2019

Revision 3a

Supersedes date 17/08/2019

SDS number 11159

Hazard statements in full H226 Flammable liquid and vapour.

H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H336 May cause drowsiness or dizziness.
H361 Suspected of damaging fertility or the unborn child.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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