Njock Et Al., 2020
Njock Et Al., 2020
A R T I C L E I N F O A B S T R A C T
Keywords:                                                 This paper presents a thermodynamic analysis of an organic Rankine cycle with a water-loop (ORC-WL) as an
Thermodynamic analysis                                    efficient means of heat regeneration and saving Water Consumption (WC). The ORC-WL was simulated with wet,
ORC with water-loop                                       dry and isentropic refrigerants such as R717, R600a and R1234yf, respectively, in order to compare its technical
Water consumption
                                                          performance to the conventional ORC (C-ORC) and ORC with internal heat exchanger (ORC-IHE). The ther
Energy efficiency
Exergy efficiency
                                                          modynamic analysis developed in the EES software was used to carry out the Energy Efficiency (EnE), Exergy
Net power output                                          Efficiency (ExE), Net Power Output (NPO), and WC as comparison performance parameters. A specific study has
                                                          shown that the ORC-IHE, due to its remarkable contribution to the degradation of available energy and with a
                                                          high WC compared to that of C-ORC, can be disqualified in favour of the ORC-WL which considerably improves
                                                          these parameters thanks to the water-loop. For the same operating conditions and with reference to R600a, When
                                                          C-ORC exhibited an EnE of 8.70 %, an ExE of 67.01 %, NPO of 8.57 kW and WC of 0.71 kg.s− 1, those of ORC-IHE
                                                          were 10.08 %; ExE of 64.87 %; NPO of 9.11 kW and WC of 5.30 kg.s.-1, respectively, whereas those of ORC-WL
                                                          were 9.95 %, 84.85 %, 9.95 kW and 0.82 kg.s− 1, respectively. The study on monitoring of evaporating tem
                                                          perature, superheating, and pinch showed that the ORC-WL can operate with evaporating temperature and
                                                          superheating above 90 ◦ C and 15 ◦ C, respectively. A pinch of no more than 3 ◦ C, on the other hand, is ideal.
                                                          Finally, wet refrigerants are not suitable for ORC-WL, and dry refrigerants offer better performance than isen
                                                          tropic refrigerants,
    * Corresponding author.
      E-mail address: julbinpaulnjock2@gmail.com (J. Paul Njock).
https://doi.org/10.1016/j.tsep.2022.101303
Received 4 August 2021; Received in revised form 3 January 2022; Accepted 12 April 2022
Available online 22 April 2022
2451-9049/© 2022 Elsevier Ltd. All rights reserved.
J. Paul Njock et al.                                                                                         Thermal Science and Engineering Progress 32 (2022) 101303
    ORC technology has demonstrated its importance as a clean tech              turbine outlet which can be achieved by using a wet condenser, a dry
nology for sustainable energy resources [6]. Originally designed for             cooling tower, or a hybrid system [14]. However, the efficiency and
waste heat recovery as cogeneration systems in industrial thermal                capacity of the power plants are observed reduced with the dry cooling
plants, this technology is nowadays oriented towards the exploitation of         system due to the presence of the fans that require electricity and which
energy from geothermal sources, biomass energy, solar energy and the             the velocity can be raised to increase the air mass flow rate in order to
waste heat recovery at low temperature [7,8]. Furthermore, these sys            ensure the condensation when the ambient air temperature increases
tems are considered as reliable technologies, due to their similarity with       [14]. Turchi et al. [15], investigated the effect of replacing a wet cooling
conventional water Rankine technologies [6,9] with the particularity of          system with a dry cooling system on a concentrating solar power plant
using a working refrigerant with a lower boiling point than the water            (CSP). According to the location of the CSP, the results indicated an
[8,10].                                                                          increase in electricity cost closely related to the presence of fans in the
    The potential for solar energy in Africa is unlimited, with sunshine         dry cooling system. Zhai and Rubin [16] investigated on the water re
levels twice as high as in Germany [11]. This solar potential is fairly          quirements of wet and dry cooling systems for pulverized coal power
distributed, with over 80 % of African land receiving more than 2 MWh.           plants with and without carbon capture systems. The results showed that
m− 2 annually [12]. In Central Africa, the amount of sunshine is com            the makeup water requirements in the wet cooling system are affected
parable to or even greater than in many other regions of the world,              by the average ambient air temperature. In contrast, the performance
which have made solar energy a significant source of their energy con           and cost of a dry cooling system are extremely sensitive to local air
sumption. The deployment of solar ORC plants in this part of Africa              temperature, respectively. According to Çengel et al. [17], more the heat
could thus contribute to solving the issue of insufficient electricity           capacity of the fluid “A” is greater than the fluid “B”, more its capacity to
supply. However, there are various challenges related to this technol           give up or store energy is better compared to the fluid “B”. This analysis
ogy’s implementation in Central Africa, including particularly the na           shows that the wet cooling is more preferred over the dry cooling due to
ture of the working refrigerants; most of them are not eco-friendly. In          the inferior thermal cooling properties of the air over the water. How
addition, the climatic conditions are characterized by high average              ever, the use of wet condensers is specifically challenged by the risk of
ambient temperatures with minimal variation [13], restricting the                disruption of local water resources [18], increased water treatment costs
working fluid’s condensation stage.                                              [19,20] and environmental restrictions [19].
    Indeed, deploying solar ORC plants in Central Africa means locating              Many investigations are proposing solutions for water saving in
them in sunny regions, while ensuring the condensation of steams at the          power plants, whether solar thermal, coal-fired or others. Indeed, water
                                                                             2
J. Paul Njock et al.                                                                                            Thermal Science and Engineering Progress 32 (2022) 101303
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J. Paul Njock et al.                                                                                                    Thermal Science and Engineering Progress 32 (2022) 101303
Table 1 (continued )
  Authors              Title                           Relevant highlights           Ref.
leaving the turbine (4) and the refrigerant leaving the pump (2) takes
place through the cooling water-loop (a-b-c) as shown in Fig. 2. The                            3. Modelling
thermodynamic evolution of the working refrigerant in the ORC
configuration with water-loop (ORC-WL) follows the thermodynamic                                3.1. Mathematical models
evolution observed in an ORC-IHE. The cooling water (a), after cooling
and condensing the working refrigerant, is conveyed to the IHE (b)                              The assumptions made about the operation of each configuration were as
where it gives up heat to the liquid refrigerant leaving the pump before                        follows:
being discharged to the main body of the cooling source or to a cooling
tower (c).                                                                                       • The operating regime is permanent;
                                                                                                 • Energy loss and pressure drops along the pipe of each cycle are
                                                                                                   neglected;
                                                                                                 • Heat is transferred only to the cooling refrigerant. This assumes that
                                                                                                   there is no heat loss to the environment from the components or
                                                                                                   pipes;
                                                                                                 • The effect of hydrostatic pressure at the pump is such that it’s rela
                                                                                                   tively small to be neglected;
                                                                                            4
J. Paul Njock et al.                                                                                                    Thermal Science and Engineering Progress 32 (2022) 101303
                                                                                                 h1 − h2
                                                                                   ηis,pump =                                                                                         (6)
                                                                                                 h1 − h2s
                                                                                       Where h is the specific enthalpy; the index 3, 4 and 4 s represent the
                                                                                   inlet, the real outlet and the isentropic outlet of the turbine, respectively;
                                                                                   and the index 1, 2 and 2 s represent the inlet, the real outlet and the
                                                                                   isentropic outlet of the pump, respectively.
                                                                                       The thermal effectiveness of the IHE was defined as follows:
                       Fig. 2. ORC-WL configuration.                                                      Max{(T23 − T2 ), (T4 − T41 ) }
                                                                                   ηIHE,ORC−    IHE   =                                                                               (7)
                                                                                                                    T4 − T2
 • All heat exchangers used are counter-current and insulated, and their
   thermal efficiencies are assumed constant during the operating.                                        Max{(T23 − T2 ), (Tb − Ta ) }
                                                                                   ηIHE,ORC−    WL    =                                                                               (8)
                                                                                                                   Tb − T2
    The total mass balance is written as:                                             Finally, the performance of each configuration is measured by en
∑         ∑
    min =     mout                                                       (1)       ergy efficiency, exergy efficiency, and net power output as follows:
                                                                                   Pnet,i = P ́ l, i − Wpump,i − Wpumpwater ,i                                                        (9)
    The energy balance is written as follows:                                                   e
          ∑            ∑
Qk − Wk +     (mh)in =    (mh)out                                        (2)                 Pnet,i
                                                                                   ηth,i =                                                                                          (10)
                                                                                              Qg
  The exergy balance is written as follows:
 (        )                                                                                              Wturb,i
∑      T0                                                                          ηII,i =                                                                                          (11)
   1−      Qk − W + m(ψ in − ψ out ) = Xdest                             (3)                 Wturb,i + Wpumpwater ,i + Idest,total,i
       Tk
    The mass flow rate is represented by m. Qk is the amount of heat                   Where in the ith ORC configuration,i ∈{C-ORC, ORC-IHE, ORC-
transmitted across the boundary to point k at the temperature Tk ; h is the        WL},Pnet,i , ηth,i and ηII,i are the net power output, energy efficiency and
specific enthalpy, W is the work exchanged between the component and               exergy efficiency of a configuration, respectively; Wpump,i and Wpumpwater ,i
the external environment, ψ is the exergy related to the flow of a unit of         are the mechanical power of the ORC pump and water pump respec
mass, T0 is the temperature of the environment in which the ORC con               tively; and P ́ l, i is the electrical power at the output of electrical
                                                                                                          e
figurations are immersed, and Xdest is the exergy destroyed at a compo            generator. Idest,total,i , is the total exergy destroyed calculated as follows:
nent. The subscripts in and out indicate the input and output limits of the
control volume, respectively.
Table 2
Mass, energy and exergy balance for each ORC configuration.
  Configuration          Component                       Mass balance                     Energy balance                               Exergy balance
                                                                               5
J. Paul Njock et al.                                                                                                      Thermal Science and Engineering Progress 32 (2022) 101303
                  ∑
                  n                                                                            configuration.
Idest,total,i =         Xdest,j                                                  (12)
                  j=1
                                                                                               5. Results and discussions
   j, is the index corresponding to the component of an ORC
configuration.                                                                                 5.1. Specific case study
   The water consumption is evaluated from the heat released at the
condenser as follows:                                                                              For the same 100 kW heat source and the same operating parameters
                                                                                               considered, Table 5 shows that the dry refrigerant R600a is well suited
          Qcond,i
ma,i =                                                                           (13)          for the operation of the configurations studied. Based on the thermo
         hb − ha
                                                                                               dynamic properties at different states of R600a, the improvements in the
    The mass flow rate of the cooling water is represented by ma,i . Qcond,i ,                 C-ORC provided by the ORC-IHE are superior to those of the ORC-WL.
is the heat released at the condenser; and ha and hb are the specific en                      For example, with R600a refrigerant in the C-ORC, the temperature at
thalpies at the inlet and outlet of the condenser, respectively.                               the thermal generator inlet is 35.83 ◦ C. This temperature is 57.43 ◦ C in
                                                                                               the ORC-IHE and 55.73 ◦ C in the ORC-WL, a difference of 1.7 ◦ C
                                                                                               compared to the ORC-IHE. Furthermore, in the C-ORC, the temperature
3.2. Refrigerants selected and properties
                                                                                               of the cooling water discharged was initially observed at 59.24 ◦ C is
                                                                                               33 ◦ C in the ORC-IHE and 55.02 ◦ C in the ORC-WL. With a temperature
    In addition to the strict energy performance requirements for ORC
                                                                                               drop of 26.24 ◦ C of the cooling water between the ORC-IHE and the C-
operation, there are practical and safety environmental constraints to
                                                                                               ORC compared to 4.22 ◦ C between the ORC-WL and the C-ORC, with the
consider when selecting the working refrigerants. Many researches have
                                                                                               low temperature difference observed previously, positive effects can a
been conducted to select appropriate ORC working refrigerants. Quoilin
                                                                                               priori be envisaged in the ORC-WL with dry refrigerants.
et al. [27], established a list of 13 general criteria for refrigerant selec
                                                                                                   Table 6 shows that the refrigerant R717 by its nature as a wet
tion. Wang et al. [28], investigated the energy performance of an ORC
                                                                                               refrigerant does not guarantee the operation of the ORC-IHE and ORC-
cycle according to the temperature of the heat source. A synthesis shows
                                                                                               WL for the defined operating conditions. On closer inspection, in these
that at low temperatures, low latent heat and high density of the
                                                                                               two configurations the refrigerant temperature at the turbine outlet is
working refrigerant are preferable to increase the turbine inlet mass flow
                                                                                               35 ◦ C (ORC-IHE) and the water temperature at the condenser outlet is
rate and improve ORC performance [29]. At high temperatures, the
                                                                                               33 ◦ C (ORC-WL), while the temperature at the pump outlet is 36.31 ◦ C.
thermostability of the working refrigerant is the main limiting factor for
                                                                                               This situation is such that it is the refrigerant at the pump outlet that
ORC applications [30]. Also, the environmental impact (ODP, GWP) has
                                                                                               transfers heat, which does not satisfy the IHE operating constraints in
to be taken into account as well as cost, safety (flammability and
                                                                                               both cases as indicated by Jannot [33]. During the simulations with the
toxicity) and compatibility with the ORC components (corrosion, vis
                                                                                               same operating conditions, other wet refrigerants such as R22, R152a
cosity, and thermal conductivity or condensate formation during steam
                                                                                               and SO2 [32] were used. No compatibility of these wet refrigerants was
expansion) [31].
                                                                                               observed except that of R152a with the ORC-IHE. This result motivated
    According to the above selection principles, three common organic
                                                                                               us to set aside the wet refrigerants including the R717; the aim being to
working refrigerants, R1234yf, R717, and R600a, are selected for
                                                                                               have refrigerants which are necessarily compatible with the three ORC
simulation even though for most of them the thermal efficiency of the
                                                                                               configurations.
ORC machine is lower than that offered by the non-eco-friendly fluids.
                                                                                                   Table 7 shows that the isentropic refrigerant R1234yf is also suited
Therefore, they are more eco-friendly refrigerants with a low GWP and
                                                                                               for the operation of the configurations studied. Similar observations to
zero ODP and also have good acceptable performance for ORC, as pre
                                                                                               those for R600a are made for R1234yf. A cooling water temperature
sented by Dijoux et al. [32]. The type of refrigerant was also varied to
                                                                                               drop of 15.7 ◦ C between the ORC-IHE and the C-ORC, and 1.9 ◦ C be
take into account the influence of the wet, dry and isentropic nature of
                                                                                               tween the ORC-WL and the C-ORC were observed. The temperature of
the refrigerant on the performance of each configuration. The basic
                                                                                               35.83 ◦ C at the generator inlet of C-ORC is 57.43 ◦ C in the ORC-IHE and
physical parameters of these working refrigerants are shown in Table 3.
                                                                                               55.73 ◦ C in the ORC-WL, a difference of 1.7 ◦ C compared to the ORC-
                                                                                               IHE. In fact, positive effects can a priori also be envisaged in the ORC-
4. Operating parameters and methodology used                                                   WL with isentropic refrigerants.
                                                                                                   Fig. 4 shows the temperature scale in the T-s diagram for each
    The thermal source is assumed to be 100 kW and the rest of the                             configuration and as a function of R600a and R1234yf. As shown in
operating parameters used in this work are reported in Table 4. Note that                      Fig. 4, the slope of heat recovery by water is greater in the C-ORC (Fig. 4.
T3′′ is the temperature of the working fluid at steam saturation and is                        a and 4.d corresponding to R600a and R1234yf, respectively) and ORC-
equal to the evaporation temperature. The methodology used as illus                           WL (Fig. 4c and 4.f corresponding to R600a and R1234yf, respectively)
trated in Fig. 3 is such that a specific case has been studied in order to                     configurations compared to that observed in the ORC-IHE configuration
present the different thermodynamic states of the refrigerant at each                          (Fig. 4.b and 4.e corresponding to R600a and R1234yf, respectively).
inlet and outlet level of the different components of an ORC configura                        This is necessarily due to the fact that in the ORC-IHE configuration, the
tion, as well as the performance of each of these components and of the                        working fluid at the turbine outlet before being cooled first gives up
ORC configurations. Subsequently, the ORC configurations are simu                             some of its calories to the fluid leaving the ORC pump.
lated showing how the evaporating temperature, superheating and                                    It should also be noted that since the water evolves at a constant
pinch influence the performance and water consumption in each ORC
Table 3
Properties of the fluids selected for this work according to Santos et al. [27] and Dijoux et al. [28].
  Rfrigerant            Name                  Molecular weight (g.      Tc (K)      Pc (MPa)       Latent heat (kJ.       Type of fluid   ASHRAE Safety            GWP      ODP
                                              mol− 1)                                              kg− 1)                                 Group
                                                                                         6
J. Paul Njock et al.                                                                                                  Thermal Science and Engineering Progress 32 (2022) 101303
Table 4
Operating parameters used in this work.
  Tam (◦ C)            Ta (◦ C)   Pa (bar)   T3 (◦ C)      T1 (◦ C)      T3 − T3˝ (◦ C)    T4 − Tb = T41 − Tb (◦ C)          ηis,pump        ηis,turb      ηIHE         ηal
                                                                                    7
J. Paul Njock et al.                                                                                               Thermal Science and Engineering Progress 32 (2022) 101303
Table 5
Thermodynamic properties at different states of the dry refrigerant R600a in each ORC configuration.
  Configuration         Point           T(◦ C)           P(bar)          h(kJ.kg− 1)            s(kJ.kg− 1.K− 1)           v(dm3.kg− 1)            State of the refrigerant
Table 6
Thermodynamic properties at different states of the wet refrigerant R717 in each ORC configuration.
  Configuration         Point           T(◦ C)           P(bar)          h(kJ.kg− 1)            s(kJ.kg− 1.K− 1)           v(dm3.kg− 1)            State of the refrigerant
pressure of 3 bars, the evaporation temperature at this pressure is about              justified by an exergy efficiency of the ORC-WL of 84.85 % with R600a
134 ◦ C. This temperature level gives the certainty that in the process of             and 66.29 % with R1234yf, compared to 64.87 % with R600a and 58.52
cooling the working fluid, the water will remain in the state of com                  % with R1234yf for the ORC-IHE, respectively. Another negative point
pressed liquid and the law of its boiling point. Thus, the representation              of the ORC-IHE is its excessive consumption of cooling water. It is 5.30
of its evolution in the T-s diagrams of R600a and R1234yf can only                     kg/s with R600a and 5.11 kg/s with R1234yf. The ORC-WL consumes
highlight the quantities of heat involved.                                             0.82 kg/s with R600a and 1.20 kg/s with R1234yf. Under the same
    Table 8 shows the energy flow for each component and the perfor                   operating conditions, the C-ORC consumes 0.71 kg/s with R600a and
mance of each ORC configuration corresponding to the considered                        1.09 kg/s with R1234yf. These results show that for the case of a solar
operational conditions. For the reasons of non-compatibility of R717                   ORC project, the ORC-WL is the most appropriate configuration in terms
previously indicated (Table 7), the energy flow for each component and                 of water savings and which the net power output is not far from that of
the performance of each ORC configuration related to the effect of this                the ORC-IHE.
wet refrigerant were not listed. Table 8 shows that the electrical output                  Another observation made is that when the pumping power is not
with the ORC-WL configuration, in the case of dry and isentropic re                   taken into account, the net power output of the ORC-IHE configuration
frigerants, is approximately equal to that of the ORC-IHE within a few                 without the pumping power is 10.08 kW higher than that of the ORC-WL
watts. For the operating conditions considered, when the net power                     configuration observed at 9.95 kW. When the pumping power is taken
output of the ORC-IHE is 10.08 kW and 8.79 kW for R600a and R1234yf                    into account, the net power output of the ORC-IHE configuration
respectively, that of the ORC-WL is 9.95 kW and 8.65 kW, respectively, a               observed at 9.11 kW becomes lower than that of the ORC-WL configu
difference of 130 W and 140 W respectively. The available energy                       ration observed at 9.81 kW.
quality of the ORC-WL is higher than that of the ORC-IHE. This is
                                                                                  8
J. Paul Njock et al.                                                                                                 Thermal Science and Engineering Progress 32 (2022) 101303
Table 7
Thermodynamic properties at different states of the isentropic refrigerant R1234yf in each ORC configuration.
  Configuration         Point           T(◦ C)           P(bar)           h(kJ.kg− 1)             s(kJ.kg− 1.K− 1)           v(dm3.kg− 1)            State of the refrigerant
5.2. Effect of the evaporating temperature, superheating and pinch,                     increase of about 15.49 % compared to the C-ORC, and a saving of 4.48
respectively                                                                            kg/s at the ORC-IHE.
5.2.1. Effect of the evaporating temperature T3′′                                       5.2.2. Effect of the superheating T3 - T3′′
    Fig. 5 shows the variation of energy and exergy efficiencies of the                     Fig. 8 shows the influence of superheating (T3 - T3′′ ) on the energy
three studied ORC configurations according to the evaporating tem                      and exergy performance of each configuration. As shown in this figure,
perature, for R600a and R1234yf respectively. Firstly, the dry refrig                  the dry refrigerant R600a offers significantly better energy and exergy
erant R600a has higher energy and exergy efficiencies than the                          performance than R1234yf for each configuration. As also shown in
isentropic refrigerant R1234yf. Thus, compared to R600a, an improve                    Fig. 8, R600a is suitable for each configuration in the superheating
ment in the energy efficiency of C-ORC is observed when an IHE is                       range, whereas the isentropic nature of R1234yf makes it not suitable for
associated with it (ORC-IHE). But with ORC-IHE, the exergy efficiency                   ORC-IHE and ORC-WL for superheating below 3 ◦ C. Indeed, for a su
becomes lower than that of C-ORC. This shows that due to the IHE, the                   perheat below 3 ◦ C, the temperature of the fluid at the turbine outlet
irreversibilities are higher than those observed in the C-ORC. By                       remains lower than that of the fluid at the pump outlet. This condition,
changing the location of the IHE and implementing a water-loop be                      as mentioned above, does not allow for the preheating of the fluid at the
tween the condenser and the IHE (ORC-WL), an improvement in the                         pump outlet. In this temperature range the T23 temperature in the ORC-
energy efficiency of the C-ORC, slightly less than 0.13 % of that obtained              IHE is higher than the T4 temperature, and the Tb temperature in the
with the ORC-IHE was observed at T3′′ = 90 ◦ C. Although this result is                 ORC-WL is lower than the T2 temperature. As the case of R717, this
rather low, it demonstrates the positive aspect of the water loop in heat               situation does not satisfy the IHE operating constraints in both cases.
recovery. From an exergy point of view, ORC-WL significantly decreases                  From a superheating of 3 ◦ C, the ORC-IHE offers a higher energy per
the irreversibilities of C-ORC as shown in Fig. 5. This result shows that               formance than C-ORC, but slightly higher than ORC-WL, still with an
the use of water as a heat recovery medium improves the energy quality                  absolute difference of 0.13 % is observed. From an exergy point of view,
compared to C-ORC and ORC-IHE.                                                          the energy quality of ORC-IHE remains roughly equal to that of C-ORC,
    Fig. 6 shows the variation of the net power output of each configu                 while it is significantly higher with ORC-WL over the entire superheat
ration with evaporating temperature. This net power output for each                     range. Fig. 8 also shows that with increasing superheating, the energy
configuration increases with increasing evaporating temperature. Once                   quality of ORC-IHE and C-ORC degrades further, while it increases
again, the net power output obtained with R600a is higher than that                     considerably in ORC-WL.
obtained with R1234yf. However, with both refrigerants, as shown in                         Fig. 9 shows the variations of the net power output according to the
Fig. 6, when the pumping power is taken into account the net power                      superheating (T3 - T3′′ ). As shown in this figure, the net power output
output obtained with ORC-IHE is slightly lower than that obtained with                  obtained with R600a is higher than that obtained with R1234yf.
ORC-WL in the considered evaporating temperature range. An absolute                     Increasing superheating has no significant effect on the C-ORC with
difference of 693 W was observed at T3′′ = 90 ◦ C between the two                       R600a, whereas with R1234yf the net power output of the C-ORC in
challenged configurations.                                                              creases with increasing superheating. On the other hand, a considerable
    Fig. 7 shows how the evaporating temperature affects the cooling                    increase in net power output in the ORC-IHE and ORC-WL with super
water consumption in each configuration. R600a shows lower water                        heat is observed. At 90 ◦ C, the difference of net power output between
consumption than R1234yf. For each configuration the cooling water                      the ORC-IHE and the ORC-WL is 140 W, as previously observed.
consumption decreases slightly with increasing evaporating tempera                         Fig. 10 shows how the superheating (T3 - T3′′ ) influences the cooling
ture. Maintaining a constant pinch of 2 ◦ C between the turbine outlet (4)              water consumption. Overall, the water consumption is very high in the
and the water outlet (b), the ORC-IHE shows with R600a at T3′′ = 90 ◦ C,                ORC-IHE with R600a or R1234yf. With R1234yf, increasing the super
a significant cooling water consumption of about 5.30 kg/s compared to                  heating from 3 ◦ C to 11 ◦ C leads to an increase in water consumption in
that of the C-ORC of 0.71 kg/s; i.e. a drastic increase of about 645.48%.               the ORC-IHE. Over the superheating of 11 ◦ C, this water consumption
Using a heat regeneration water-loop, the specific cooling water con                   becomes more or less constant, indicated by a constant limit tempera
sumption under the same operating conditions is about 0.82 kg/s; i.e. an                ture T41 of 35 ◦ C. However, R600a has lower water consumption than
                                                                                  9
J. Paul Njock et al.                                                                                                                                                 Thermal Science and Engineering Progress 32 (2022) 101303
                                                                                                                   R1234yf
                                                 150
                                                                  ORC-IHE with R1234yf
                                                 125
                                                                                                                                                                 1
                                                                                                                                                              09
                                                                  Water cooling with R1234yf
0, 0
                                                                                                                                                          19
                                                                                                                              01
                                                                                                                                                                           g
                                                                                                                                                                        3/k
                                                                                                                                                       42
                                                                                                                                                      0, 0
                                                                                                                                        3
                                                                                                                          0, 0
                                                 100
0, 0
                                                                                                                                                                    9m
                                                                                                                                                                      9
                                                                                                                                                                  0, 0
                                                                                                                                                                0, 1
                              Temperature [°C]
                                                                                                                    30,8 bar
                                                  75
                                                  50                                       23                                                4
                                                                                       2                                                41
                                                                                   1            8,95 bar
                                                                                                                                             b
                                                  25                               a
                                                 -50
                                                   0,75     1,00                                1,25                1,50                         1,75                    2,00              2,25
                                                                                                                              -1        -1
                                                                                                Entropy [kJ.kg .K ]
                                                                                                                    (e)
                                                                                                             R1234yf
                                          150
                                                            ORC-WL with R1234yf
                                          125
                                                                                                                                                           1
                                                                                                                                                        09
0, 0
                                                                                                                                                    19
                                                                                                                        01
                                                                                                                                                                     g
                                                                                                                                                                  3/k
                                                                                                                                                 42
                                                                                                                               3
                                                                                                                                                0, 0
                                                                                                                    0, 0
                                          100
                                                                                                                                             0, 0
                                                                                                                                                              9m
                                                                                                                                                                9
                                                                                                                                                            0, 0
                                                                                                                                                          0, 1
                       Temperature [°C]
                                                                                                              30,8 bar
                                             75
                                                                                   b
                                             50                        c       2
                                                                                   23                                               4
                                                                                                   8,95 bar
                                                                           1                                                        b
                                             25
                                                                           a
                                                 0
                                          -50
                                            0,75          1,00                          1,25                  1,50                      1,75                    2,00                 2,25
                                                                                                                         -1    -1
                                                                                        Entropy [kJ.kg .K ]
                                                                                                                   (f)
Fig. 4. T-s diagrams with R600a and R1234yf and cooling water temperature evolution. (a): C-ORC with R600a; (b): ORC-IHE with R600a; (c): ORC-WL with R600a;
(d): C-ORC with R1234yf; (e): ORC-IHE with R1234yf; and (f): ORC-WL with R1234yf.
R1234yf. As shown in Fig. 10, the water consumption in the ORC-WL                                                         the fluid load of the ORC and thus a decrease in the water mass for
remains considerably lower than that observed in the ORC-IHE.                                                             cooling the fluid at the condenser.
   As also shown in Fig. 10 the increase in superheat leads to a decrease
in water consumption in the ORC-WL configuration. Indeed, with                                                            5.2.3. Effect of the pinch T4 – Tb
increasing in superheat, the enthalpy difference between the superheat                                                       Fig. 11 shows the influence of pinch (T4 - Tb) on the energy and
point and the generator inlet becomes large, which leads to a decrease in                                                 exergy performance of the three configurations studied. Keeping the
                                                                                                                    10
J. Paul Njock et al.                                                                                                                                                                                                                                                                   Thermal Science and Engineering Progress 32 (2022) 101303
                                                                                                                  R600a
                                    250                                                                                                                                                                                                                                               R600a
                                                                                                                                                                                                         250
                                                                      C-ORC with R600a
                                                                                                                                                 2
                                                                                                                                                                                                                                          ORC-IHE with R600a
06
                                                                                                                                                                                                                                                                                                                     2
                                                                                                                                                                                                                                                                                                                    06
                                                                                                                                             0,0
                                    200
                                                                                                                                                                                                                                                                                                                 0,0
                                                                                                                                                                                                         200
                                                                                                                                                               66
                                                                      Water cooling with R600a
                                                                                                                                                                                                                                                                                                                                   66
                                                                                                                                                                                                                                          Water cooling with R600a
0, 0
3/k
                                                                                                                                                                                                                                                                                                                                                g
                                                                                                                                                           1
0, 0
                                                                                                                                                                                                                                                                                                                                            3/k
                                                                                                                                                       0, 2
8m
                                                                                                                                                                                                                                                                                                                               1
                                                                                                                                                                   0, 7
                                                                                                                                                                                                                                                                                                                           0, 2
                                                                                                                                                                    2
                                                                                                                                                                                                                                                                                                                                       8m
                                                                                                                                                                2, 3
0, 7
                                                                                                                                                                                                                                                                                                                                        2
                                                                                                                                                               7, 5
                                    150
                                                                                                                                                                                                                                                                                                                                    2, 3
                                                                                                                                                                                                                                                                                                                                   7, 5
                 Temperature [°C]
                                                                                                                                                                                                         150
                                                                                                                                                                                      Temperature [°C]
                                                                                                                                     3
                                    100                                                                                16,4 bar
                                                                                                                                                                                                         100                                                                           16,4 bar
                                                                                                                                                                                                                                                                                                         3
                                                                                                                                                                                                                                                                     23
                                                                                                                                         4
                                          50                                         1        2         4,65 bar                                                                                          50                                                                                                 4
                                                                                                                                                                                                                                                        1            2    4,65 bar
                                                                                                                                         b                                                                                                                                                          41
                                                                                                                                                                                                                                                                                                             b
                                                                                     a                                                                                                                                                                   a
                                                0                                                                                                                                                              0
                                      -50                                                                                                                                                                 -50
                                                                       0,2          0,4               0,6              0,8
                                                                                                                                                                                                                                           0,2         0,4                0,6          0,8
                                    -100                                                                                                                                                                 -100
                                       0,0                      0,5          1,0              1,5                      2,0           2,5             3,0            3,5         4,0                         0,0                     0,5          1,0                 1,5              2,0             2,5                 3,0           3,5         4,0
                                                                                    Entropy [kJ.kg-1.K-1]                                                                                                                                              Entropy [kJ.kg-1.K-1]
                                                                                                                (a)                                                                                                                                                             (b)
                                                                                                                             R600a
                                                       250                                                                                                                                                                                                                                   R1234yf
                                                                                                                                                                                                                              150
                                                                             ORC-WL with R600a
                                                                                                                                                       2
                                                                                                                                                     0,0
                                                                                                                                                        06
                                                                                                                                                                                                                                                  C-ORC with R1234yf
                                                       200                                                                                                                                                                    125
                                                                                                                                                                              66
                                                                                                                                                                                                                                                                                                                                          1
                                                                             Water cooling with R600a
                                                                                                                                                                                                                                                                                                                                       09
                                                                                                                                                                              g
                                                                                                                                                                                                                                                  Water cooling with R1234yf
                                                                                                                                                                          0, 0
3/k
                                                                                                                                                                                                                                                                                                      9
                                                                                                                                                                          1
0,0
                                                                                                                                                                                                                                                                                                                                    19
                                                                                                                                                                      0, 2
01
                                                                                                                                                                                                                                                                                                                                     g
                                                                                                                                                                       1
8m
                                                                                                                                                                                                                                                                                                                                 3/k
                                                                                                                                                                                                                                                                                                                                 42
                                                                                                                                                                                                                                                                                                                 3
                                                                                                                                                                                                                                                                                                                                0,0
                                                                                                                                                                   0, 7
                                                                                                                                                                                                                                                                                                   0, 0
                                                                                                                                                                2, 3
                                                                                                                                                                                                                              100
                                                                                                                                                                                                                                                                                                                              0,0
                                                                                                                                                               7, 5
                                                                                                                                                                                                                                                                                                                            9m
                                                       150
                                                                                                                                                                                                                                                                                                                              9
                                    Temperature [°C]
                                                                                                                                                                                                                                                                                                                           0,0
                                                                                                                                                                                                                                                                                                                         0,1
                                                                                                                                                                                                           Temperature [°C]
                                                                                                                                                                                                                                                                                              30,8 bar
                                                                                                                                             3                                                                                 75
                                                       100                                                  b
                                                                                                                              16,4 bar
                                                                                              c        23                                                                                                                      50                                2                                                   4
                                                                                                                                                 4
                                                        50                                                  2         4,65 bar                                                                                                                               1
                                                                                                                                                                                                                                                                                  8,95 bar
                                                                                                  1                                                                                                                                                                                                                  b
                                                                                                                                                 b
                                                                                                                                                                                                                               25
                                                                                                                                                                                                                                                             a
                                                          0
                                                                                          a                                                                                                                                     0
                                                        -50
                                                                              0,2             0,4                0,6          0,8                                                                                             -25                0,2         0,4                0,6          0,8
                                                       -100                                                                                                                                                                   -50
                                                          0,0         0,5           1,0                     1,5               2,0            2,5             3,0          3,5             4,0                                   0,75         1,00                         1,25                1,50                       1,75            2,00             2,25
                                                                                          Entropy [kJ.kg-1.K-1]                                                                                                                                                           Entropy [kJ.kg-1.K-1]
                                                                                                                        (c)                                                                                                                                                                   (d)
Fig. 4. (continued).
Table 8
Energy flow for each component and performance of the C-ORC, ORC-IHE and ORC-WL configurations in the specific case study.
  Refrigerant                                                                                                                       R600a                                                                                                                                                     R1234yf
                                                                                                                                    C-ORC                                   ORC-IHE                                                       ORC-WL                                              C-ORC                                      ORC-IHE                 ORC-WL
evaporating temperature and superheating constant, Fig. 11 shows that                                                                                                                                               it is more observed in ORC-IHE than in ORC-WL. As shown in Fig. 11, the
the energy and exergy performance of R600a is higher than that of                                                                                                                                                   increase in pinch leads in each configuration to an increase in irre
R1234yf. From the energy point of view, with R600a or R1234yf, the                                                                                                                                                  versibilities, which are manifested at the condenser in the case of the C-
sensitivity of the pinch on the energy performance of C-ORC and ORC-                                                                                                                                                ORC and ORC-IHE configurations, and at the condenser and the IHE
IHE is observed to be negligible, while its increase leads to a decrease                                                                                                                                            exchanger in the case of ORC-WL.
in the energy performance of ORC-WL. Indeed, in the case of the C-ORC                                                                                                                                                    Fig. 12 shows the variations of the net power output of the studied
and the ORC-IHE, the state (2) of the refrigerant at the thermal generator                                                                                                                                          ORC configurations according to the pinch (T4 - Tb). The net power
inlet remains independent of the pinch, while in the case of the ORC-WL,                                                                                                                                            output is much better with the R600a than with the R1234yf. For both
this state remains closely linked to it. As a result, the definition of a low                                                                                                                                       refrigerants used, the increase in pinch is observed to be negligible on
pinch appears to be required for improved ORC-WL performance.                                                                                                                                                       the net power outputs of C-ORC and ORC-IHE. While this increase leads
    From the exergy point of view, although the state (2) of refrigerant is                                                                                                                                         the decrease of the net power output of ORC-WL, but remains compa
not dependent on the pinch in the case of C-ORC and ORC-IHE, the                                                                                                                                                    rable to that of ORC-IHE. When the pinch is low, less than 3 ◦ C, the
quality of the energy in each of the three configurations is degraded and                                                                                                                                           difference between the ORC-IHE and the ORC-WL is even more
                                                                                                                                                                                                    11
J. Paul Njock et al.                                                                                                                             Thermal Science and Engineering Progress 32 (2022) 101303
                                                     18                                                                                                                 90
                                                                           = 0.80
                                                                     is,turb            T4 - Tb = T41 - Tb = 2 °C
                                                     16              is,pump = 0.85     T3 - T3" = 10 °C
                                                                     IHE = 0.85         Ta = 29 °C                                                                      80
                                                                                                                                                                             [%]
                        [%]
                                                     14
                                                                     al = 0.90
                                                                                                                                                                                  II
                               th
                                                                T1 = 35 °C
                                                     12
                                                                                                                                                                        70
                                                                                                                                                                             Exergy efficiency
                        Energy efficiency
10
                                                                                                                                                                        60
                                                      8
                                                      6
                                                                                                                                                                        50
                                                      4
                                                                                                         Carnot   /C-ORC/ORC-IHE/ORC-WL
                                                      2                                                                                                               40
                                                      48               52        56     60     64        68            72         76    80       84        88        92
                                                                                      Evaporating temperature T3" [°C]
                                                               th, C-ORC/R1234yf                     th, ORC-IHE/R1234yf                            th, ORC-WL/R1234yf
                                                               th, C-ORC/R600a                       th, ORC-IHE/R600a                              th, ORC-WL/R600a
                                                               II, C-ORC/R1234yf                     II, ORC-IHE/R1234yf                            II, ORC-WL/R1234yf
                                                               II, C-ORC/R600a                       II, ORC-IHE/R600a                              II, ORC-WL/R600a
Fig. 5. Energy and exergy efficiency of ORC configurations according to the evaporating temperature for R1234yf and R600a refrigerants.
                                                     11
                                                                               Pnet /C-ORC/R1234yf
                                                     10
                                                                               Pnet /ORC-IHE/R1234yf
                                                      9                        Pnet /ORC-WL/R1234yf
                        Net power output Pnet [kW]
                                                                               Pnet /C-ORC/R600a
                                                      8
                                                                               Pnet /ORC-IHE/R600a
                                                      7                        Pnet /ORC-WL/R600a
                                                      5                                                                       = 0.80
                                                                                                                        is,turb              T4 - Tb = T41 - Tb = 2 °C
                                                                                                                        is,pump = 0.85       T3 - T3" = 10 °C
                                                      4
                                                                                                                        IHE   = 0.85         Ta = 29 °C
                                                      3                                                                 al   = 0.90
                                                                                                                       T1 = 35 °C
                                                      2
                                                          48             52       56      60        64        68             72        76      80         84       88           92
                                                                                       Evaporating temperature T3" [°C]
                       Fig. 6. Net power output of ORC configurations according to the evaporating temperature for R1234yf and R600a refrigerants.
                                                                                                                  12
J. Paul Njock et al.                                                                                                                              Thermal Science and Engineering Progress 32 (2022) 101303
                                                         6
                                                       5,5
                                                                                                                                            IHE   = 0.85
                                                         2
                                                                                                                                            al   = 0.90
                                                       1,5
                                                         1
                                                       0,5
                                                         48          52         56     60       64           68          72           76         80        84        88            92
                                                                                     Evaporating temperature T3" [°C]
                   Fig. 7. Water consumption of ORC configurations according to the evaporating temperature for R1234yf and R600a refrigerants.
                                                       11                                                                                                               92
                                                                   T4 - Tb = T41 - Tb = 2 °C          T1 = 35 °C
                                                10,5                                                                                                                    86,5
                                                                   T3" = 90 °C                        Ta = 29 °C
                       [%]
                                                                                                                                                                              [%]
                                                       10
                                                                                                                                                                        81
                               th
                                                                                                                                                                                   II
                                                       9,5                                            = 0.80            IHE   = 0.85
                       Energy efficiency
                                                                                                                                                                              Exergy efficiency
                                                                                            is,turb
                                                                                                                                                                        75,5
                                                                                            is,pump    = 0.85           al   = 0.90
                                                        9
                                                                                                                                                                        70
                                                       8,5
                                                                                                                                                                        64,5
                                                        8
7,5 59
                                                        7                                                                                                             53,5
                                                         0         1,5      3        4,5    6          7,5          9        10,5      12        13,5      15       16,5
                                                                                       Superheating T3 - T3" [°C]
                                                             th, C-ORC/R1234yf                  th, ORC-IHE/R1234yf                              th, ORC-WL/R1234yf
                                                             th, C-ORC/R600a                    th, ORC-IHE/R600a                                th, ORC-WL/R600a
                                                             II, C-ORC/R1234yf                  II, ORC-IHE/R1234yf                              II, ORC-WL/R1234yf
                                                             II, C-ORC/R600a                    II, ORC-IHE/R600a                                II, ORC-WL/R600a
Fig. 8. Energy and exergy of ORC configurations according to the superheating for R1234yf and R600a refrigerants.
                                                                                                               13
J. Paul Njock et al.                                                                                                                                         Thermal Science and Engineering Progress 32 (2022) 101303
                                                                            11
                                                                                          Pnet /C-ORC/R1234yf                          Pnet /C-ORC/R600a
                                                                        10,5              Pnet /ORC-WL/R1234yf                         Pnet /ORC-WL/R600a
                                                                            8,5                                                                  T3" = 90 °C
                                                                                                                                                 T1 = 35 °C
                                                                             8
                                                                             7
                                                                              0     1,5       3       4,5       6     7,5          9        10,5        12      13,5         15      16,5
                                                                                                       Superheating T3 - T3" [°C]
                                          Fig. 9. Net power output of ORC configurations according to the superheating for R1234yf and R600a refrigerants.
                                                                        6
                       Water consumption WC [kg.s-1]
                                                                                                                                                      WC,C-ORC/R1234yf
                                                                                                                                                      WC,ORC-IHE/R1234yf
                                                                        4                         Ta = 29 °C        T1 = 35 °C                        WC,ORC-WL/R1234yf
                                                                                                  T4 - Tb = T41 - Tb = 2 °C                           WC,C-ORC/R600a
                                                                                                                                                      WC,ORC-IHE/R600a
                                                                                                  T3" = 90 °C
                                                                                                                                                      WC,ORC-WL/R600a
                                                                        0
                                                                         0        1,5     3         4,5        6      7,5          9         10,5        12        13,5        15       16,5
                                                                                                      Superheating T3 - T3" [°C]
                                   Fig. 10. Water consumption of ORC configurations according to the superheating for R1234yf and R600a refrigerants.
noticeable.                                                                                                                 IHE.
    Fig. 13 shows the variation in the cooling water consumption of the
studied configurations according to the pinch (T4 - Tb). As shown in this                                                   6. Conclusions
figure, the water consumption in ORC-IHE increases drastically with the
pinch. While water consumption, in the ORC-WL and C-ORC is nearly                                                               The performance of the ORC machine with a water-loop as a means
insensitive to pinch. However, the water consumption of R1234yf re                                                         of heat regeneration for solar power projects in climatic conditions
mains higher than that of R600a in ORC-WL and C-ORC, while in ORC-                                                          similar to Central Africa was studied in comparison with the ORC with
IHE the water consumption of R600a remains slightly higher than that of                                                     internal heat exchanger and with reference to the conventional ORC.
R1234yf. In terms of water consumption, ORC-WL is better than ORC-                                                          The comparison parameters under the same operating conditions were
                                                                                                                       14
J. Paul Njock et al.                                                                                                                        Thermal Science and Engineering Progress 32 (2022) 101303
10,5 88
                                                                                                                                                                84
                                                       10
                                                                                                                                                                      [%]
                         [%]
                                                                                                                                                                80
                                                                     Ta = 29 °C    T1 = 35 °C
                                                       9,5
                                                                                                                                                                           II
                               th
                                                                     T4 - Tb = T41 - Tb = 2 °C                  = 0.80         IHE   = 0.85
                                                                                                      is,turb                                                   76
                                                                                                                                                                      Exergy efficiency
                         Energy efficiency
                                                                                                                                                                68
                                                       8,5
                                                                                                                                                                64
                                                           8
                                                                                                                                                                60
                                                       7,5                                                                                                       56
                                                         0,5         1     1,5       2         2,5     3             3,5       4          4,5          5       5,5
                                                                                               Pinch T4 - Tb [°C]
                                                               th, C-ORC/R1234yf                th, ORC-IHE/R1234yf                        th, ORC-WL/R1234yf
                                                               th, C-ORC/R600a                  th, ORC-IHE/R600a                          th, ORC-WL/R600a
                                                               II, C-ORC/R1234yf                II, ORC-IHE/R1234yf                        II, ORC-WL/R1234yf
                                                               II, C-ORC/R600a                  II, ORC-IHE/R600a                          II, ORC-WL/R600a
Fig. 11. Energy and exergy efficiency of ORC configurations according to the pinch for R1234yf and R600a refrigerants.
                                                      12
                                                                           Pnet /C-ORC/R1234yf                                 Pnet /C-ORC/R600a
                                                      11                   Pnet /ORC-IHE/R1234yf                               Pnet /ORC-IHE/R600a
                         Net power output Pnet [kW]
10
                                                       8
                                                                     T4 - Tb = T41 - Tb = 2 °C                       = 0.80                 = 0.85
                                                                                                           is,turb                   IHE
                                                                     Ta = 29 °C
                                                       7
                                                                     T3 - T3" = 10 °C                      is,pump    = 0.85         al   = 0.90
                                                                     T1 = 35 °C
                                                       6
                                                       0,5           1     1,5          2       2,5         3          3,5           4           4,5       5           5,5
                                                                                            Pinch T4 - Tb [°C]
                                      Fig. 12. Net power output of ORC configurations according to the pinch for R1234yf and R600a refrigerants.
energy efficiency, exergy efficiency, net power and cooling water con                                      fluids were R600a, R717 and R1234yf. The simulation results showed
sumption. These configurations were simulated in an environment                                             that:
where the average ambient temperature is 32 ◦ C, the initial cooling
water temperature is 29 ◦ C and the heat source is constant at 100 kW.                                       • Wet fluids such as R717 present unsuitable operating conditions for
The condensing temperature was assumed to be 35 ◦ C relative to the                                            the ORC-IHE and ORC-WL configurations. Indeed, for these two
cooling water temperature. The refrigerants used as working candidate                                          configurations and for the operating conditions considered, the gas
                                                                                                      15
J. Paul Njock et al.                                                                                                     Thermal Science and Engineering Progress 32 (2022) 101303
                                                    22
                                                    20
                                               ]
                                                    18        WC,ORC-IHE/R1234yf
                                             -1     16        WC,ORC-WL/R1234yf
                                                              WC,C-ORC/R600a
                                                    14
                                                              WC,ORC-IHE/R600a
                                                    12        WC,ORC-WL/R600a                                                       Ta = 29 °C
                                                    10                                                                      T3 - T3" = 10 °C
                                                    8                                                                       T1 = 35 °C
                                                    6                                                                               = 0.85
                                                                                                      is,turb =   0.80        IHE
                                                    4
                                                                    T4 - Tb = T41 - Tb = 2 °C         is,pump =   0.85        al   = 0.90
                                                    2
                                                    0
                                                    0,5   1   1,5       2      2,5          3       3,5           4         4,5          5        5,5
                                                                            Pinch T
                                                                                  4 - Tb [°C]
Fig. 13. Water consumption of ORC configurations according to the pinch for R1234yf and R600a refrigerants.
     temperature at the turbine outlet is observed at 35 ◦ C, which does not              CRediT authorship contribution statement
     allow the preheating of the working fluid at the pump outlet, whose
     temperature is observed at 36.31 ◦ C.                                                    Julbin Paul Njock: Conceptualization, Methodology, Validation,
 •   The internal heat exchanger in the ORC-IHE improves the efficiency                   Formal analysis, Investigation, Writing – review & editing, Writing –
     of the C-ORC. However, this technique contributes considerably to                    original draft. Max Ndame Ngangue: Conceptualization, Methodology,
     the degradation of the available energy, and we observe a drastic                    Supervision, Writing – review & editing, Validation, Writing – original
     increase in cooling water consumption almost 7 times that of the C-                  draft. Alain Christian Biboum: Conceptualization, Methodology, Su
     ORC;                                                                                 pervision, Writing – review & editing, Validation, Writing – original
 •   The ORC-WL improves the energy efficiency of the C-ORC in a way                      draft. Olivier Thierry Sosso: Conceptualization, Methodology, Valida
     that is close to the improvement of the ORC-IHE. But the presence of                 tion, Formal analysis, Investigation, Writing – review & editing, Writing
     the water loop in the ORC-WL significantly increases the quality of                  – original draft. Robert Nzengwa: Conceptualization, Methodology,
     the available energy. The water consumption of the ORC-WL is                         Supervision, Writing – review & editing, Writing – original draft.
     slightly higher than that of the C-ORC. Its net power output is only a
     few watts (130 to 140 W) less than that of the ORC-IHE;                              Declaration of Competing Interest
 •   Dry refrigerants are the most suitable for the operation of the ORC-
     WL. Their influence on the performance of the three configurations                       The authors declare that they have no known competing financial
     studied is greater than that of isentropic refrigerants.                             interests or personal relationships that could have appeared to influence
 •   In the evaporating temperature range of 50–90 ◦ C, for each config                  the work reported in this paper.
     uration studied and for the different working refrigerants selected,
     the increase in evaporating temperature contributes to the increase                  References
     in thermal efficiency and net power output, but leads to a decrease in
     the cooling water.                                                                   [1] UNFPA, “UNFPA (2015). Annual Report. For people, Planet & Prosperity,” 2015.
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reported in this paper.
                                                                                     16
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