SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : ACTI-BROM® 1318
APPLICATION : BIOCIDE
COMPANY IDENTIFICATION : Nalco Company
1601 W. Diehl Road
Naperville, Illinois
60563-1198
EMERGENCY TELEPHONE NUMBER(S) : (800) 424-9300 (24 Hours) CHEMTREC
NFPA 704M/HMIS RATING
HEALTH : 1/1 FLAMMABILITY : 0/0 INSTABILITY : 0/0 OTHER :
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme * = Chronic Health Hazard
2. COMPOSITION/INFORMATION ON INGREDIENTS
Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the
nature of the hazard(s).
Hazardous Substance(s) CAS NO % (w/w)
Sodium Bromide 7647-15-6 30.0 - 60.0
3. HAZARDS IDENTIFICATION
**EMERGENCY OVERVIEW**
CAUTION
Causes moderate eye irritation.
Avoid contact with eyes, skin and clothing. Wash with soap and water after handling. Remove contaminated clothing
and wash before reuse.
May evolve hydrogen bromide and bromine under fire conditions.
PRIMARY ROUTES OF EXPOSURE :
Eye, Skin
HUMAN HEALTH HAZARDS - ACUTE :
EYE CONTACT :
Can cause mild to moderate irritation.
SKIN CONTACT :
May cause irritation with prolonged contact.
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
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SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
INGESTION :
Not a likely route of exposure. No adverse effects expected.
INHALATION :
Not a likely route of exposure. Aerosols or product mist may irritate the upper respiratory tract.
SYMPTOMS OF EXPOSURE :
Acute :
A review of available data does not identify any symptoms from exposure not previously mentioned.
Chronic :
A review of available data does not identify any symptoms from exposure not previously mentioned.
AGGRAVATION OF EXISTING CONDITIONS :
A review of available data does not identify any worsening of existing conditions.
HUMAN HEALTH HAZARDS - CHRONIC :
No adverse effects expected other than those mentioned above.
4. FIRST AID MEASURES
SKIN CONTACT :
Flush affected area with water. If symptoms develop, seek medical advice.
IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20
minutes. Call a poison control center or doctor for treatment advice.
IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if
present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
IF SWALLOWED: Call poison control center or doctor immediately for treatment advice. Have person sip a glass of
water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give
anything by mouth to an unconscious person.
IF INHALED: Remove victim to fresh air. If not breathing, give artificial respiration, preferably, mouth-to-mouth. Get
medical attention.^
5. FIRE FIGHTING MEASURES
FLASH POINT : None
EXTINGUISHING MEDIA :
Not expected to burn. Keep containers cool by spraying with water. Use extinguishing media appropriate for
surrounding fire.
FIRE AND EXPLOSION HAZARD :
May evolve hydrogen bromide and bromine under fire conditions.
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
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SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :
In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS :
Restrict access to area as appropriate until clean-up operations are complete. Ensure clean-up is conducted by
trained personnel only. Ventilate spill area if possible. Do not touch spilled material. Stop or reduce any leaks if it is
safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal
Protection). Notify appropriate government, occupational health and safety and environmental authorities.
METHODS FOR CLEANING UP :
SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by
diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with
water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in
compliance with regulations indicated in Section 13 (Disposal Considerations).
ENVIRONMENTAL PRECAUTIONS :
This pesticide is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into lakes,
streams, ponds, estuaries, oceans or other waters, unless in accordance with the requirements of a National Pollutant
Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to
discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local
sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA.
7. HANDLING AND STORAGE
HANDLING :
Avoid eye and skin contact. Do not take internally. Do not get in eyes, on skin, on clothing. Have emergency
equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Keep the containers closed
when not in use. Use with adequate ventilation.
STORAGE CONDITIONS :
Store the containers tightly closed. Store in suitable labeled containers.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMITS :
This product does not contain any substance that has an established exposure limit.
ENGINEERING MEASURES :
General ventilation is recommended.
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
3 / 11
SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
RESPIRATORY PROTECTION :
Respiratory protection is not normally needed. Respiratory protection is not normally needed. If significant mists,
vapors or aerosols are generated an approved respirator is recommended. HALF FACE SPECIAL
MULTICONTAMINANT with a Particulate pre-filter.
HAND PROTECTION :
Neoprene gloves Nitrile gloves Butyl gloves PVC gloves
SKIN PROTECTION :
Wear standard protective clothing.
EYE PROTECTION :
Wear chemical splash goggles.
HYGIENE RECOMMENDATIONS :
If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing
before reuse. Keep an eye wash fountain available. Keep a safety shower available.
HUMAN EXPOSURE CHARACTERIZATION :
Based on our recommended product application and personal protective equipment, the potential human exposure is:
Moderate
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Liquid
APPEARANCE Colorless
ODOR None
SPECIFIC GRAVITY 1.45 @ 77 °F / 25 °C
DENSITY 12.1 lb/gal
SOLUBILITY IN WATER Complete
pH (100 %) 7.9
VISCOSITY 5 cps
FREEZING POINT 7 °F / -14 °C
BOILING POINT 218 °F / 103.5 °C
VAPOR PRESSURE 5.6 mm Hg @ 68 °F / 20 °C
VOC CONTENT 0.00 %
Note: These physical properties are typical values for this product and are subject to change.
10. STABILITY AND REACTIVITY
STABILITY :
Stable under normal conditions.
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
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SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
HAZARDOUS POLYMERIZATION :
Hazardous polymerization will not occur.
CONDITIONS TO AVOID :
Freezing temperatures.
MATERIALS TO AVOID :
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen,
permanganate) may generate heat, fires, explosions and/or toxic vapors.
HAZARDOUS DECOMPOSITION PRODUCTS :
Under fire conditions: None known
11. TOXICOLOGICAL INFORMATION
ACUTE ORAL TOXICITY :
Species: Rat
LD50: > 5,000 mg/kg
Test Descriptor: Similar Product
ACUTE DERMAL TOXICITY :
Species: Rabbit
LD50: > 2,000 mg/kg
Test Descriptor: Similar Product
PRIMARY SKIN IRRITATION :
Species: Rabbit
Draize Score: 0.0 /8.0
Test Descriptor: Similar Product
PRIMARY EYE IRRITATION :
Species: Rabbit
Draize Score: 16.0 /110.0
Test Descriptor: Similar Product
SENSITIZATION :
This product is not expected to be a sensitizer.
CARCINOGENICITY :
None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer
(IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists
(ACGIH).
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
5 / 11
SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
HUMAN HAZARD CHARACTERIZATION :
Based on our hazard characterization, the potential human hazard is: Low
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL EFFECTS :
The following results are for the product and a similar product. The following results are for the active components.
The following results are for the hypobromous acid (as Br2) generated from sodium bromide and hypochlorite.
ACUTE FISH RESULTS :
Species Exposure LC50 Test Descriptor
Fathead Minnow 96 hrs > 5,000 mg/l Product
Rainbow Trout 96 hrs > 1,000 mg/l Similar Product
Bluegill Sunfish 96 hrs > 1,000 mg/l Similar Product
Fathead Minnow 96 hrs 0.097 mg/l HOBr (Generated from NaBr)
Rainbow Trout 96 hrs 0.23 mg/l HOBr (Generated from NaBr)
Bluegill Sunfish 96 hrs 0.52 mg/l HOBr (Generated from NaBr)
Sheepshead Minnow 96 hrs 0.19 mg/l HOBr (Generated from NaBr)
ACUTE INVERTEBRATE RESULTS :
Species Exposure LC50 EC50 Test Descriptor
Daphnia magna 48 hrs 7,900 mg/l Active Substance ( Sodium
Bromide )
Ceriodaphnia dubia 48 hrs > 5,000 mg/l Product
Daphnia magna 48 hrs 0.038 mg/l HOBr (Generated from NaBr)
American Oyster 96 hrs 0.54 mg/l HOBr (Generated from NaBr)
Mysid Shrimp (Mysidopsis 96 hrs 0.17 mg/l HOBr (Generated from NaBr)
bahia)
ADDITIONAL ECOLOGICAL DATA
AOX information: Product contains no organic halogens.
PERSISTENCY AND DEGRADATION :
Biological Oxygen Demand (BOD) : This material is an oxidizing biocide and is not expected to persist in the
environment.
Greater than 95% of this product consists of inorganic substances for which a biodegradation value is not applicable.
MOBILITY :
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and
output. The level III model does not require equilibrium between the defined media. The information provided is
intended to give the user a general estimate of the environmental fate of this product under the defined conditions of
the models.
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
6 / 11
SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;
Air Water Soil/Sediment
<5% 30 - 50% 50 - 70%
The portion in water is expected to be soluble or dispersible.
BIOACCUMULATION POTENTIAL
This preparation or material is not expected to bioaccumulate.
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION
Based on our hazard characterization, the potential environmental hazard is: Low
Based on our recommended product application and the product's characteristics, the potential environmental
exposure is: Moderate
If released into the environment, see CERCLA/SUPERFUND in Section 15.
13. DISPOSAL CONSIDERATIONS
If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery
Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D.
As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional
handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage,
disposal or recycling facility.
DO NOT REUSE EMPTY CONTAINER. Triple rinse the container (or equivalent). Then offer for recycling or
reconditioning, or puncture and dispose of in a sanitary landfill, or incinerate. Burn only if allowed by state and local
authorities. If burned, stay out of smoke.
14. TRANSPORT INFORMATION
The information in this section is for reference only and should not take the place of a shipping paper (bill of lading)
specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging, properties,
and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT :
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
AIR TRANSPORT (ICAO/IATA) :
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
7 / 11
SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
MARINE TRANSPORT (IMDG/IMO) :
Proper Shipping Name : PRODUCT IS NOT REGULATED DURING
TRANSPORTATION
15. REGULATORY INFORMATION
This section contains additional information that may have relevance to regulatory compliance. The information in this
section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized
compliance or hazard assessment. Nalco accepts no liability for the use of this information.
NATIONAL REGULATIONS, USA :
OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 :
Based on our hazard evaluation, the following substance(s) in this product is/are hazardous and the reason(s) is/are
shown below.
Sodium Bromide : Non-Hazardous
CERCLA/SUPERFUND, 40 CFR 117, 302 :
Notification of spills of this product is not required.
SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311,
312, AND 313 :
SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) :
This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance.
SECTIONS 311 AND 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370) :
Our hazard evaluation has found this product to be hazardous. The product should be reported under the following
indicated EPA hazard categories:
X Immediate (Acute) Health Hazard
- Delayed (Chronic) Health Hazard
- Fire Hazard
- Sudden Release of Pressure Hazard
- Reactive Hazard
Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals.
The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely
hazardous substances and 10,000 pounds for all other hazardous chemicals.
SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372) :
This product does not contain substances on the List of Toxic Chemicals.
TOXIC SUBSTANCES CONTROL ACT (TSCA) :
This product is exempted under TSCA and regulated under FIFRA. The inerts are on the Inventory List.
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
8 / 11
SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
FOOD AND DRUG ADMINISTRATION (FDA) Federal Food, Drug and Cosmetic Act :
When use situations necessitate compliance with FDA regulations, this product is acceptable under : 21 CFR 173.315
chemicals used in washing or to assist in the lye peeling of fruits and vegetables, 21 CFR 176.170 Components of
paper and paperboard in contact with aqueous and fatty foods and 21 CFR 176.180 Components of paper and
paperboard in contact with dry foods., 21 CFR 176.300 Slimicides, The following limitations apply:
This product may be used to treat pulp and papermill water systems in situations requiring FDA sanction provided the
bromide concentration in the water is kept below 22 ppm. The product must be used in conjunction with an oxidant
such as bleach or gaseous chlorine. Follow instructions for use in pulp and papermill on the product label.
FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT (FIFRA) :
EPA Reg. No. 5185-467-1706
In all cases follow instructions on the product label.
This product has been certified as KOSHER/PAREVE for year-round use INCLUDING THE PASSOVER SEASON by
the CHICAGO RABBINICAL COUNCIL.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15 / formerly Sec. 307, 40 CFR
116.4 / formerly Sec. 311 :
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed
components may be present at trace levels.
CLEAN AIR ACT, Sec. 112 (Hazardous Air Pollutants, as amended by 40 CFR 63), Sec. 602 (40 CFR 82, Class I and
II Ozone Depleting Substances) :
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed
components may be present at trace levels.
CALIFORNIA PROPOSITION 65 :
Substances listed under California Proposition 65 are not intentionally added or expected to be present in this product.
MICHIGAN CRITICAL MATERIALS :
Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed
components may be present at trace levels.
STATE RIGHT TO KNOW LAWS :
This product is a registered biocide and is exempt from State Right to Know Labelling Laws.
NATIONAL REGULATIONS, CANADA :
WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) :
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR)
and the MSDS contains all the information required by the CPR.
WHMIS CLASSIFICATION :
Pesticide controlled products are not regulated under WHMIS.
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
9 / 11
SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) :
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL).
AUSTRALIA
All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme
(NICNAS).
CHINA
All substances in this product comply with the Provisions on the Environmental Administration of New Chemical
Substances and are listed on the Inventory of Existing Chemical Substances China (IECSC).
EUROPE
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Existing and New Chemical Substances list (ENCS).
KOREA
All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing
Chemicals List (ECL)
PHILIPPINES
All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory
of Chemicals & Chemical Substances (PICCS).
16. OTHER INFORMATION
Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and
exposures of this product. Based on our recommended use of this product, we have characterized the product's
general risk. This information should provide assistance for your own risk management practices. We have evaluated
our product's risk as follows:
* The human risk is: Low
* The environmental risk is: Low
Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will
assist you to determine if your product application is consistent with our recommendations. Together we can
implement an appropriate risk management process.
This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures should
be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace
operations. Please consult your local sales representative for any further information.
REFERENCES
Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000
For additional copies of an MSDS visit www.nalco.com and request access
10 / 11
SAFETY DATA SHEET
PRODUCT
ACTI-BROM® 1318
EMERGENCY TELEPHONE NUMBER(S)
(800) 424-9300 (24 Hours) CHEMTREC
Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, American
Conference of Governmental Industrial Hygienists, OH., (Ariel Insight CD-ROM Version), Ariel Research Corp.,
Bethesda, MD.
Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS CD-ROM
Version), Micromedex, Inc., Englewood, CO.
IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health
Organization, International Agency for Research on Cancer.
Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS
CD-ROM Version), Micromedex, Inc., Englewood, CO.
Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public
Health Service.
Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety
and Health Administration (OSHA), (Ariel Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD.
Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati,
OH, (TOMES CPS CD-ROM Version), Micromedex, Inc., Englewood, CO.
Ariel Insight (An integrated guide to industrial chemicals covered under major regulatory and advisory programs),
North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel
Insight CD-ROM Version), Ariel Research Corp., Bethesda, MD.
The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS CD-ROM Version),
Micromedex, Inc., Englewood, CO.
Prepared By : Product Safety Department
Date issued : 09/11/2009
Version Number : 1.19
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