Water activity and Sorption
properties of Food
Water in Food
Water in Food
Intracellular or Dispersing Medium or Dispersed Phase
Extracellular Solvent (Emulsions)
Component • Butter
• Vegetable & Animal • Margarine
Products
Water in Food
Free Water
Bound Water
Water in Food
❑Water molecules that form hydrogen
Free Water bonds only between other water
molecules
❑Is lightly entrapped & therefore easily
Bound Water
pressed from food
❑Acts as a dispersing agent & solvent
❑Can be easily removed by drying and
evaporation
Water in Food
❑Water molecules that are
electrostatically bound to the
dissolved substances
❑Remains unfrozen at temperature
Free Water below 0⁰C
❑Is unavailable as a solvent
Bound Water ❑Amount of unfreezable water vary
from one food to another (is based on
the protein content)
❑Severe conditions are needed to
remove bound water (vacuum oven,
distillation)
Water in
Food
Free Water
Bound Water
Food Deterioration & Water
Activity
Microorganisms Chemical Reactions Physical Injuries
Rate of Deterioration Water Content
Moisture Content
Wet-Weight Basis Dry-Weight Basis
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟
𝑚= × 100
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑎𝑚𝑝𝑙𝑒 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟
𝑚= × 100
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑠𝑜𝑙𝑖𝑑𝑠
𝑚= × 100
𝑚𝑎𝑠𝑠 𝑜𝑓 𝑤𝑎𝑡𝑒𝑟 + 𝑠𝑜𝑙𝑖𝑑𝑠
Moisture Content vs. Food
Deterioration
Food
Stability
Prediction
Moisture
Content
?
Moisture Content vs. Food
Deterioration
Potato Starch is stable at a relatively high
moisture content (20%)
Food
Moisture
Stability
Content
Prediction
Peanut oil deteriorates if moisture
content exceeds 0.6%
Water Activity (aw)
➢ Measure of the availability of water molecule to
enter into microbial, enzymatic or chemical reactions
➢ Determines the shelf life of food
➢ Bound water is inversely related to water activity
(As the % of bound water in a food increases the aw
decreases)
Moisture Content and aw of Different Foods
Importance of Water Activity in Foods
Water Activity (aw)
➢ Water in foods exerts a vapour pressure
➢ Amount of vapour pressure depends on,
▪ Moisture content
▪ Composition of food
▪ Temperature and humidity of air
▪ Concentration of dissolved solutes
Water Activity (aw)
➢ Ratio of the vapour pressure of water (P) in a food to the
saturated vapour pressure of water (P0) at the same temperature
𝑃
𝑎𝑤 =
𝑃0
Water Activity (aw) & Relative Humidity
(RH)
➢ aw is a measure of relative humidity (RH)
➢ Hence, the relative humidity (RH ) of the atmosphere in
equilibrium with the food is,
𝑅𝐻% = 𝑎𝑤 × 100%
Effect of Water Activity (aw)
➢ Decreased aw,
▪ Retards the growth of microorganisms
▪ Slows enzyme catalyzed reactions
▪ Retards non enzymatic browning
➢ With aw at 0.3, the product is most stable with respect to,
▪ Lipid oxidation
▪ Non enzymatic browning
▪ Enzymatic activity
▪ Various microbial parameters
Effect of aw on microbiological and in biochemical reactions
Interaction of aw , pH, and temperature in some foods
Effect of Water Activity (aw)
➢ To decrease aw thus improving the shelf life of food is by the
use of additives with high water binding capacity (humectants)
▪ Common salt
▪ Glycerol
▪ Sucrose