classiral theoy

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Neuton Laus electromognHc

classical
to
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rodtatiem is just
Coneiet

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emY
Accovdn9 fotAiS thevg

Coled Photon
o hafides

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hhoton dehends uh orn

Energy
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o repn y
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atiing away oi
deterioration or
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en 11Onment. a
metak
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boergy of o hhoton of a elrctromogneffr Yodi akToy TOn
iay-i
rcdiation : De ones
tVea
clechromognetic
Ttnsity Set to
nawing )Wavelergth djoo nm
cloesicad Reony otunsity
1own as an ore,
Ail th
etals ltPIesen tihei-
peopotion ad to
55en diectly tiom tinese ores tt
1l an instabl: state
state by 1ecombini
mor OTOSi0n
Ttasity of em
ii wane(engtb So0 m
it, dctility ad
+ Eom quatum heorgH iotnsity cmr
Cnit aMea
hotons htesent
Covers Vi i b l e
suoliaHOn Shecrum
Electromagoetic
Of dijart
e array
e shectru Odu
Momertum of Photon
no mags
Todiations
=
d elecomognctic
momntem I Photan
As hur classical Reory
wawe num
b ar reaen
of
Heon - d u a natw
AS uantum
Wawe nwmban
Eeinstein Relatvity E
650-4Doo 25000
00,D00
Plank Pa E hY 2500
(osrnic
yisible Photo mos
mtcro
Tnfraued
-Pm = O E =
Pc E h: rodio wowe
roliatio
Vra o
eJecdrorir
cerop
elet hre bay
freayen rotcima
PX c h
(DreR)
n ol&d
elerron 9r
1 e o n on esY
Photon ho mOmustum intusity ( y Vs
P h momentum dehende is also a
hlof of
C m k o u n d .
Shectru h a u t t a w o
e srno
w a v e ruum a u ( J r
momoum
Con Calub Uig Phofon
Beers Rauo k d
Relatjooshih
betur en
tronsition
ght tion o
destru 1tot
ofnmeta
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and
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known s an
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r cudroi Hed odtoli 2
1 111 t O t
d'a
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T o i oicosiey o j inciclent redre. asul
gn Lo: x tYk
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da
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n a hcutrulr 2id
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r
amonochroRhic rCdiahom hesd molo
then
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homognous OuHon thod decreadr
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intesity
o rodicion Rcknes tR mtooum A oc
a
SamHr
ron
tsrty Thudnd
d i s diuetty suohorfional to
enamitttd
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0 h raodiakon
2olve:
Re Som
rodliadfon and Ccnc. &oluuion Calculak fRe
ahsorbonce o
ln a slide dos not obSeb h e Sam rdiahHon
A o91.(
+ au slides ahsorb San US Suma on
ahsoyb diforns USe totegraho
au 8lides
(ichangk is changing)
dT IC
da
dL K xIx
 Miouve 3hechoscofhy (ov)hur fRutational
Datomic moleeur AssUme as
rigid e
o. N
The Dtatrion al energy a
rigid diotumic
Siti
molecule
hnown as
at or Al
(joule) Tietais 1epreSrilt tii
rototion pourr -Do , ,'
t ton
Aut
h T t t t tilt auti
Fn ) wor n.
8T hc
J2
h: 6. 636 xto
C3xto ms
TT 3.14
d echronic
AS
t
aettron ic
moment
rigid uoton Assurnption
Und
is Gsrutant
inerta )
T(T+1) Cr
F T)
 Seleien Rur
R i g i d h r e t o n
3n destru
moletuJe tion oi a
metai
The molecud Must hoase
roonent
a t o m i e
joule for nono diadtomic (A2) molecude
(T41
moleaudes d a s not Chou
InGcte he ej *dti
tomod i ctonic gnal it
n CSor b MiCTUOVe odiaton known as an T. Sl
do nat t
fr t
Fo Herodiotomi c moleade
T:O
o,
1o, flo Adve 113-1531
t
Nev ent btre
Selection Rue
+Re Valu
Sheite
6e Gn
AT
O,
AT AtM:
T:O
(
ijote ra tnd +1iS for absopotion
Selection md T: 3
Fo -1 is fo
emission
T3 T:2
Selection Kule AJ
aheifi Sdechorn Rule J:0 T +2X
l be alitwed
Troraition uobahility (P)
only
Rotad ionod degen r a u T+I
uld cheo te
P 1 the Zignal
fUr rasiton Ul b cdsouwccd nof
i teroty
ie CoM Cded ade
2
Tor. ' r o r f n ora)
Trara itianru bobility (P) 1I i n fegvnl
F () M4
TMI
fin
fitrnesi
rofion 2 of Jlourd
(o)
Po rotaitton 9 ollOued
 F r a n a i t h a n
Rrquismd
r
Energy
T: J 66
FTe T(Tu)
F(T+)
ie traaition
AF
FG
Requiste cd for
Energy
B(TH1)(T12)- r (T+)
line
B(T) (T2 T) heetrol
Lntensi o
26(T+1) Ttercit o hecrol dthende
1
iNo-d molecuds hatiipeig
Csa
to esd
AF26 Tefaionol ratant
(rorue Degeroxoo
oSSocia
2 rly ousr cner
T: T:3 AF 8(41) I xehulaim a
= 6B TLevd
FREGUENCY OF SPECTRUM KT
hc
eyency Specrrn 1 a u a
e ma noia
where
Meqie d fo frastios feve
Lneg
AF Short Cu Jmar
enegy gah ob
ensity ofToliation and
htehrun F)mus be qual
absen tron
akesece
 ton or
. destruction of a metal
R o t a i o n a d M o l e e u l e
D i ' a d o m e m o l e d e
o n a t a n t c
(cvma A)
2 1 e m a u n
bond
Ingts
Rigid Tto
16.2646 known d an ore.
il h
T(T+1 o.1
(T)
p o l e r n o n e n t o ' h
T
fn+fz2
NTE icroO hetrur
in
ora
turen fur
he
r(n) 02340
nct
-
n o y rotesr
urrites Problern nrd
ioigid diatornic ttne
odjurst
The Go betuu
ren 2 n
Aitr Inse
2) in
1 i T U a u e

ndrun,
ston)
Pypody igid
urning
totererust)
dito
oftesA i Colo
itait
16.2546 p7
o
I 2 1 C armu
() 6
2
1+16
6.364
 AND ITS CONTROL
10.70
A) Degnateg of 3 Des ts
6-RST owailabie at 4s en egy
Nbn- Rigid rotor Real molrtade
(Diatornie
molti)
TR bond etuween +R atorna
ehowu
pring bond lengt chang
dutiny
a IY o c d o to intey G 1nCoporat
fox Co
molccule e
Tmox
3 Caludat bond leng duwing ottion a
ne trm
qiven(6= 1.64 Gn Centrfugal diSfortion turm ored , enegy
mo
mu
n fofua .
ukr
kevd
rotaiona!
3
ono
-36D
I290
F) 20
9.12
i* 290
FTo)
56 25 Non Rief
Rigd
Selecion Rule
etum