carpro trading ltd.

Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 1 of 10

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

ECH2O waterless wash
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
Automotive care products
Uses advised against
Any non-intended use.
1.3. Details of the supplier of the safety data sheet
Company name: carpro trading ltd.
Street: 7, Lfigeneias 4th floor strovolos
Place: 1687 Nicosia (CYPRUS)
Responsible Department: +972 546 411 911
1.4. Emergency telephone +972 546 411 911
number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008
Hazard categories:
Serious eye damage/eye irritation: Eye Irrit. 2
Hazard Statements:
Causes serious eye irritation.
2.2. Label elements
Regulation (EC) No. 1272/2008
Signal word: Warning

Pictograms:

Hazard statements
H319 Causes serious eye irritation.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
Special labelling of certain mixtures
EUH208 Contains citral, Orange, sweet, ext.. May produce an allergic reaction.
2.3. Other hazards
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.

SECTION 3: Composition/information on ingredients

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 carpro trading ltd.
Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 2 of 10

3.2. Mixtures

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
68585-34-2 Alcohols, C10-16, ethoxylated, sulfates, sodium salts 1-<5%
500-223-8
Skin Irrit. 2, Eye Dam. 1; H315 H318
68603-42-9 Amides, coco, N,N-bis(hydroxyethyl) 1-<5%
271-657-0
Skin Irrit. 2, Eye Irrit. 2, Aquatic Acute 1; H315 H319 H400
5392-40-5 citral <1 %
226-394-6 605-019-00-3
Skin Irrit. 2, Skin Sens. 1; H315 H317
8028-48-6 Orange, sweet, ext. <1 %
232-433-8
Flam. Liq. 3, Skin Irrit. 2, Skin Sens. 1, Asp. Tox. 1, Aquatic Chronic 2; H226 H315 H317 H304
H411
Full text of H and EUH statements: see section 16.
Labelling for contents according to Regulation (EC) No 648/2004
5 % - < 15 % aliphatic hydrocarbons, < 5 % anionic surfactants, < 5 % non-ionic surfactants, perfumes (Benzyl
benzoate, Limonene, Citral, Linalool).
Further Information
Product does not contain listed SVHC substances > 0,1 % according to Regulation (EC) No. 1907/2006 Article
59 (REACH).

SECTION 4: First aid measures

4.1. Description of first aid measures

General information
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data
sheet if possible).
After inhalation
In case of accident by inhalation: remove casualty to fresh air and keep at rest. In case of respiratory tract
irritation, consult a physician.
After contact with skin
Gently wash with plenty of soap and water. In case of skin irritation, seek medical treatment.
After contact with eyes
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. In case of eye irritation consult an ophthalmologist.
After ingestion
Rinse mouth thoroughly with water. Let water be drunken in little sips ( dilution effect). Do NOT induce vomiting.
In all cases of doubt, or when symptoms persist, seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

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 carpro trading ltd.
Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 3 of 10

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
Carbon dioxide (CO2). Dry extinguishing powder. alcohol resistant foam. Atomized water.
Unsuitable extinguishing media
High power water jet.
5.2. Special hazards arising from the substance or mixture
Can be released in case of fire: Carbon monoxide (CO), Carbon dioxide (CO2). Nitrogen oxides (NOx),
Sulphur oxides, Formaldehyde
5.3. Advice for firefighters
In case of fire: Wear self-contained breathing apparatus.
Additional information
Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water.
Co-ordinate fire-fighting measures to the fire surroundings.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

See protective measures under point 7 and 8.
6.2. Environmental precautions
Discharge into the environment must be avoided.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal .
Clean contaminated objects and areas thoroughly observing environmental regulations.
6.4. Reference to other sections
Safe handling: see section 7
Personal protection equipment: see section 8
Disposal: see section 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
Wear suitable protective clothing. See section 8.
Advice on protection against fire and explosion
Usual measures for fire prevention.
Further information on handling
General protection and hygiene measures: refer to chapter 8
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed in a cool, well-ventilated place.
Advice on storage compatibility
Do not store together with: Explosives. Oxidizing solids. Oxidizing liquids. Radioactive substances. Infectious
substances. Food and animal feedingstuff.
Further information on storage conditions
Keep the packing dry and well sealed to prevent contamination and absorbtion of humidity.
Recommended storage temperature: 20°C
Protect against: Light. UV-radiation/sunlight. heat. moisture.

Revision No: 2,0 GB - EN Print date: 04.01.2018

 carpro trading ltd.
Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 4 of 10

7.3. Specific end use(s)

refer to chapter 1.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

64-17-5 Ethanol 1000 1920 TWA (8 h) WEL

- - STEL (15 min) WEL
- Oil mist, mineral (excluding metalworking - 5 TWA (8 h) OES
fluids) (OLD)
- 10 STEL (15 min) OES

8.2. Exposure controls

Appropriate engineering controls

Provide adequate ventilation.
Protective and hygiene measures
Always close containers tightly after the removal of product. When using do not eat, drink, smoke, sniff. Wash
hands before breaks and after work.
Eye/face protection
Wear safety glasses; chemical goggles (if splashing is possible). DIN EN 166
Hand protection
Wear suitable gloves.
Suitable material:
FKM (fluororubber). - Thickness of glove material: 0,4 mm
Breakthrough time >= 8 h
Butyl rubber. - Thickness of glove material: 0,5 mm
Breakthrough time >= 8 h
CR (polychloroprenes, Chloroprene rubber). - Thickness of glove material: 0,5 mm
Breakthrough time >= 8 h
NBR (Nitrile rubber). - Thickness of glove material: 0,35 mm
Breakthrough time >= 8 h
PVC (Polyvinyl chloride). - Thickness of glove material: 0,5 mm
Breakthrough time >= 8 h
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard
EN 374 derived from it.
Check leak tightness/impermeability prior to use. In the case of wanting to use the gloves again, clean them
before taking off and air them well.
Skin protection
Suitable protective clothing: Lab apron.
Minimum standard for preventive measures while handling with working materials are specified in the TRGS
500 (D).
Respiratory protection
With correct and proper use, and under normal conditions, breathing protection is not required.
Respiratory protection necessary at: exceeding exposure limit values, generation/formation of aerosols,

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 carpro trading ltd.
Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 5 of 10

insufficient ventilation
Suitable respiratory protection apparatus: Combination filtering device (EN 14387) - Type AP2/3
The filter class must be suitable for the maximum contaminant concentration (gas/vapour/aerosol/particulates)
that may arise when handling the product. If the concentration is exceeded, self-contained breathing apparatus
must be used. Observe the wear time limits according GefStoffV in combination with the rules for using
respiratory protection apparatus (BGR 190).
Environmental exposure controls
No special precautionary measures are necessary.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: liquid
Colour: light blue
Odour: characteristic
pH-Value: 7,5
Changes in the physical state
Melting point: not determined
Initial boiling point and boiling range: 90 °C
Sublimation point: not determined
Softening point: not determined
Pour point: not determined
Flash point: 70 °C
Sustaining combustion: Not sustaining combustion
Explosive properties
none
Lower explosion limits: not determined
Upper explosion limits: not determined
Ignition temperature: not determined
Auto-ignition temperature
Gas: not determined
Decomposition temperature: not determined
Oxidizing properties
none
Vapour pressure: not determined
Density: not determined
Water solubility: not determined
Solubility in other solvents
not determined
Partition coefficient: not determined
Viscosity / dynamic: not determined
Viscosity / kinematic: not determined
Flow time: not determined
Vapour density: not determined
Evaporation rate: not determined
Solvent separation test: not determined
Solvent content: not determined
Revision No: 2,0 GB - EN Print date: 04.01.2018
 carpro trading ltd.
Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 6 of 10

9.2. Other information

Solid content: not determined

SECTION 10: Stability and reactivity

10.1. Reactivity
No information available.
10.2. Chemical stability
The product is chemically stable under recommended conditions of storage, use and temperature.
10.3. Possibility of hazardous reactions
No information available.
10.4. Conditions to avoid
Protect against: UV-radiation/sunlight. heat.
10.5. Incompatible materials
Materials to avoid: Oxidizing agents, strong. Reducing agents, strong.
10.6. Hazardous decomposition products
Can be released in case of fire: Carbon monoxide (CO), Carbon dioxide (CO2). Nitrogen oxides (NOx),
Sulphur oxides, Formaldehyde

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicocinetics, metabolism and distribution
No data available.
Acute toxicity
Based on available data, the classification criteria are not met.
CAS No Chemical name
Exposure route Dose Species Source Method
68603-42-9 Amides, coco, N,N-bis(hydroxyethyl)
oral LD50 (>5000) Rat. MSDS extern.
mg/kg
5392-40-5 citral
oral LD50 6800 Rat. ECHA Dossier
mg/kg
dermal LD50 >2000 Rat. ECHA Dossier
mg/kg

Irritation and corrosivity

Causes serious eye irritation.
Skin corrosion/irritation: Based on available data, the classification criteria are not met.
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
citral:
In-vitro mutagenicity OECD Guideline 471 (Bacterial Reverse Mutation Assay) = negative. Literature
information: ECHA Dossier; In-vivo mutagenicity OECD Guideline 474 (Mammalian Erythrocyte Micronucleus
Test) = negative. Literature information: ECHA Dossier; Carcinogenicity: Method: -; Species: Rat. Result:
negative. Literature information: RESS,NB HAILEY,JR MARONPOT,RR BUCHER,JR TRAVLOS,GS,
HASEMAN,JK ORZECH,DP JOHNSON,JD AND HEJTMANCIK,MR; TOXICOLOGY AND CARCINOGENESIS
Revision No: 2,0 GB - EN Print date: 04.01.2018
 carpro trading ltd.
Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 7 of 10

STUDIES OF MICROENCAPSULATED CITRAL IN RATS AND MICE; TOXICOL. SCI. 71(2):198-206, 2003
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Specific effects in experiment on an animal
No data available.

SECTION 12: Ecological information

12.1. Toxicity
CAS No Chemical name
Aquatic toxicity Dose [h] | [d] Species Source Method
68603-42-9 Amides, coco, N,N-bis(hydroxyethyl)
Acute fish toxicity LC50 (4) mg/l 96 h MSDS extern.
Acute algae toxicity ErC50 (2,3) 96 h MSDS extern.
mg/l
Acute crustacea toxicity EC50 (2,39) 48 h MSDS extern.
mg/l
5392-40-5 citral
Acute fish toxicity LC50 4,6 mg/l 96 h Leuciscus idus ECHA Dossier
Acute algae toxicity ErC50 103,8 72 h Desmodesmus ECHA Dossier
mg/l subspicatus
Acute crustacea toxicity EC50 6,8 mg/l 48 h Daphnia magna ECHA Dossier

12.2. Persistence and degradability

CAS No Chemical name
Method Value d Source
Evaluation
68603-42-9 Amides, coco, N,N-bis(hydroxyethyl)
74% 30 MSDS extern.
Easily biodegradable (concerning to the criteria of the OECD)
5392-40-5 citral
EU Method C.4-D 90% 28 ECHA Dossier
Product is biodegradable.

12.3. Bioaccumulative potential

Partition coefficient n-octanol/water
CAS No Chemical name Log Pow
5392-40-5 citral 2,76

12.4. Mobility in soil

No data available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
No data available.
Further information
Do not allow to enter into surface water or drains.
Revision No: 2,0 GB - EN Print date: 04.01.2018
 carpro trading ltd.
Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 8 of 10

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal
Observe in addition any national regulations! Consult the local waste disposal expert about waste disposal.
Non-contaminated packages may be recycled.
According to EAKV, allocation of waste identity numbers/waste descriptions must be carried out in a specific
way for every industry and process.
Control report for waste code/ waste marking according to EAKV:
Waste disposal number of waste from residues/unused products
200129 MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND
INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately
collected fractions (except 15 01); detergents containing hazardous substances; hazardous waste
Waste disposal number of used product
200129 MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND
INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately
collected fractions (except 15 01); detergents containing hazardous substances; hazardous waste
Waste disposal number of contaminated packaging
150110 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately
collected municipal packaging waste); packaging containing residues of or contaminated by
hazardous substances; hazardous waste
Contaminated packaging
Handle contaminated packages in the same way as the substance itself.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
Inland waterways transport (ADN)
14.1. UN number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
Marine transport (IMDG)
14.1. UN number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: No dangerous good in sense of this transport regulation.
14.2. UN proper shipping name: No dangerous good in sense of this transport regulation.
14.3. Transport hazard class(es): No dangerous good in sense of this transport regulation.
14.4. Packing group: No dangerous good in sense of this transport regulation.
14.5. Environmental hazards

Revision No: 2,0 GB - EN Print date: 04.01.2018

 carpro trading ltd.
Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 9 of 10

ENVIRONMENTALLY HAZARDOUS: no
14.6. Special precautions for user
refer to chapter 6-8
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not relevant

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
2010/75/EU (VOC): No information available.
2004/42/EC (VOC): No information available.
Information according to 2012/18/EU Not subject to 2012/18/EU (SEVESO III)
(SEVESO III):
Additional information
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].
REACH 1907/2006 Appendix XVII, No. (mixture): 3
National regulatory information
Water contaminating class (D): 2 - clearly water contaminating
15.2. Chemical safety assessment
For the following substances of this mixture a chemical safety assessment has been carried out:

SECTION 16: Other information

Changes
Rev. 1.0; 22.09.2016, Initial release
Rev. 2,00; 27.12.2017, Changes in chapter: 2-16.
Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route
CAS Chemical Abstracts Service
DNEL: Derived No Effect Level
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
LOAEL: Lowest observed adverse effect level
LOAEC: Lowest observed adverse effect concentration
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
NOAEL: No observed adverse effect level
NOAEC: No observed adverse effect level
NTP: National Toxicology Program
N/A: not applicable
OSHA: Occupational Safety and Health Administration
PNEC: predicted no effect concentration
PBT: Persistent bioaccumulative toxic
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de
fer (Regulations Concerning the International Transport of Dangerous Goods by Rail )

Revision No: 2,0 GB - EN Print date: 04.01.2018

 carpro trading ltd.
Safety Data Sheet

according to Regulation (EC) No 1907/2006

ECH2O waterless wash

Revision date: 27.12.2017 Product code: Page 10 of 10

SARA: Superfund Amendments and Reauthorization Act

SVHC: substance of very high concern
TRGS Technische Regeln fuerGefahrstoffe
TSCA: Toxic Substances Control Act
VOC: Volatile Organic Compounds
VwVwS: Verwaltungsvorschrift wassergefaehrdender Stoffe
WGK: Wassergefaehrdungsklasse
Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]
Classification Classification procedure
Eye Irrit. 2; H319 Calculation method

Relevant H and EUH statements (number and full text)

H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
EUH208 Contains citral, Orange, sweet, ext.. May produce an allergic reaction.
Further Information
Classification according EC regulation 1272/2008 (CLP): - Classification procedure:
Health hazards: Calculation method.
Environmental hazards: Calculation method.
Physical hazards: On basis of test data and / or calculated and / or estimated.

The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product
named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of
processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety
data sheet.)

Revision No: 2,0 GB - EN Print date: 04.01.2018