Solid State Electronic Devices
● Ben Streetman, Sanjay Banerjee - Solid State
Electronic Devices
Crystal Properties and Growth of
Semiconductors
electrical behavior of solids
transport of charge through a metal or a semiconductor depends not only on the properties of the electron but also on the arrangement of atoms in the solid
Semiconductors have electrical conductivities intermediate between metals and insulators
Conductivity of these materials can be varied over orders of magnitude by changes in temperature, optical excitation, and impurity content
One of the most important characteristics of a semiconductor, which distinguishes it from metals and insulators, is its energy band gap
● Lattice
periodicity in a crystal is defined in terms of a symmetric array of points in space called the lattice
add atoms at each lattice point in an arrangement called a basis
one atom or a group of atoms having the same spatial arrangement, to get a crystal
the lattice contains a volume or cell that represents the entire lattice
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the total electronic configuration for Si (Z = 14) in the ground state is
Ls22s22p63s23p2
electrons in an outer n = 3 orbit
Si has a closed Ne configuration (see Table 2-2) plus four
(3s23p2).These are the four valence electrons
of Si; two valence electrons are in an 5 state and two are in ap state.
Energy Bands