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Lanaset

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0% found this document useful (0 votes)
151 views40 pages

Lanaset

Uploaded by

Lyracism Uguumur
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 40

Textile Effects

LANASET®
Dyeing system for wool and wool blends

LANASET_poc_14-9-10.indd 1 14.09.2010 08:32:18


LANASET® Solubility (g/l) Xenon light Main
SD
90°C 1/12
90°C 60°C 1/3
90°C 30°C 1/1

80 5
Bril
1.4 % Yellow 4GN 80 5–6
with
80 6

80 5 Cos
1.4 % Yellow 2R 80 5 sha
80 5–6 Gre

65 5
65 5–6 Bas
1.7 % Orange RN
65 6

65 5
1.3 % Brown G-01 65 5–6 Red
65 6

80 5–6
80 6 Cos
1.2 % Brown B
50 6–7

80 4 Bas
1.0 % Red G 80 5 Exc
80 5–6

80 4 Thi
80 5 on
1.1 % Red 2GA-01 ble
80 5–6

—* 4
20 5 For
1.7 % Red 2B
15 5–6

65 3–4
20 4 Bas
0.9 % Bordeaux B
20 5

*LANASET® Red 2B should not be dissolved above 60°C

LANASET_poc_14-9-10.indd 2 14.09.2010 08:37:04


ght Main properties and recommendation for combination shades
TERASIL W

Brilliant lemon yellow for self-shades or brilliant greens in combinations


with LANASET® Blue 5G.

Cost effective basis for restrained yellow shades and combination


shades. Excellent compatibility especially with LANASET® Red G and
Grey G.

Basis for brilliant orange shades with very good build up.

Reddish brown as basis for light to medium beige and brown shades.

Cost effective basis for medium and dark brown shades.

Basis for restrained red shades and combination shades .


Excellent compatibility especially with LANASET® Yellow 2R and Grey G.

This dye has been especially developed to achieve best shade solidity
on wool/polyamide blends. Trichromatic red component for WO/PA
blend dyeing in combination with LANASET® Yellow 2R and Grey G.

For brilliant red shades with high light and wet fastness properties.

Basis for bordeaux shades.

LANASET_poc_14-9-10.indd 3 14.09.2010 08:37:04


TERASIL® W untreated wool
Ch Ch Ch Ch Ch

Wash. 40°C
IWS TM 250

Rubbing
Wash. 50°C
ISO 105-
C06B2

Wash. 49°C
AATCC 69
2A

Milling alk.
ISO 105-E12

Hot water
70°C
ISO 105- E08
WO WO WO WO WO
PA PA PA CO CO
CO CO CO

1SD 2SD 1SD 2SD 1SD 2SD 1SD 2SD 1SD 2SD 1SD

fabric 25x13 mm 4–5 4–5 4–5 4–5 4–5 4–5


5 4–5 5 5 5
5 5 5 5 4–5 4–5
4 3–4 4–5 4 4–
5 5 4–5 4 5 5
5 5 5 5
5 5 5 5 5 4–5
4 4 4–5 4–5 4–5 4–5
4–5 4–5 5 5 5
5 5 5 5 4–5 4–5
5 4–5 4–5 4 4–
5 4–5 4–5 4–5 4–5 4
5 5 5 4–5
5 5 5 5 5 4–5
4–5 4–5 4–5 4–5 4–5 4–5
4–5 4–5 5 5 5
5 5 4–5 4–5 4–5 4–5
4–5 4 5 4–5 4
5 5 4–5 4–5 5 4–5
5 4–5 5 4–5
5 5 5 5 5 4–5
5 4–5 4–5 4 4–5 4–5
5 4–5 5 5 5
5 5 5 5 4–5 4–5
4 3–4 5 5 4–
5 5 5 5 4–5 4–5
5 5 5 5
5 5 5 5 5 4–5
4–5 4–5 4–5 4–5 4–5 4–5
5 5 5 5 5
5 5 5 4–5 4–5 4–5
4–5 4 4–5 4 4–
5 4–5 4–5 4–5 4–5 4
5 5 5 4–5
5 5 5 5 5 4–5
4–5 4 4–5 4–5 4–5 4–5
5 5 5 5
5 5 4–5 4–5 4–5 4–5 5
4–5 4 4 3–4
5 4–5 4 3–4 4–5 4 4
4–5 4 4–5 4
5 5 3–4 3–4 5 4–5

4–5 4 4–5 4–5 4–5 4–5 4–5 4–5 4–5 4–5


4–5 5 4–5 4–5 4–5 4–5 4–
4 4 4 3–4
4–5 4–5 3–4 3–4 4 4 3–
5 5 4–5 4
5 4–5 4–5 4–5 4–5 4–5

4–5 4–5 4–5 4–5 4–5 4–5 5 5 5 5


5 5 4–5 4–5 4–5 4–5 5
3–4 3 4–5 4
4–5 4 4 3–4 4–5 3–4 4
4–5 4–5 4–5 4
5 4–5 5 5 5 4–5

4 4 4–5 4–5 4–5 4–5


5 5 5 5 5
5 5 5 5 4–5 4–5
4–5 3–4 4–5 4 4
4–5 4–5 4 4 4 4
5 4–5 4–5 4–5
5 5 5 5 4–5 4–5

LANASET_poc_14-9-10.indd 4 14.09.2010 08:37:04


untreated wool TERASIL W
Ch Dry Ch 1/12 1/12 1/12
Rubbing

Decatizing
severe

Light AATCC
20 AFU

Light AATCC
40 AFU

Light AATCC
60 AFU
WO Wet 1/3 1/3 1/3
CO 1/1 1/1 1/1

SD 1SD 2SD 1SD

5 5 5 4–5 4 3–4
4 4–5 4–5 4–5 4
4–5 4–5
5 4–5 4–5 4–5

5 5 5 4–5 4 4
4 4–5 4–5 4 4
4–5 4
4–5 4–5 4–5 4

5 5 5 4 3–4 3–4
4–5 4 4 5 4–5 4 3–4
4–5 4–5 4 4

5 5 5 4 4 3–4
5 4–5 4 5 4–5 4 3–4
5 5 4–5 4

5 5 5 4–5 4 3–4
4 4–5 4 5 4–5 4 4
4–5 4–5 4–5 4–5

5 5 4–5 4 3 3
3–4 4 3–4 5 4 3–4 3
4 4 4 3–4

4–5 4 3 2–3
4–5 4–5
3–4 4–5 4 3–4 3
3–4 3–4
4 4 4 3–4

5 5 4–5 4 3–4 2–3


4 4 3–4 5 4 3–4 3
4 4–5 4 4

5 5 5 3–4 2–3 2
4 4 3–4 5 3–4 2–3 2
4–5 4 3 2–3

LANASET_poc_14-9-10.indd 5 14.09.2010 08:37:04


TERASIL® W chlorinated wool untreated wool
Ch Ch Ch Ch Shade depth

Dry cleaning
Wash. 40°C
IWS TM 250

Perspiration
alk. TM 174

Stability to
chlorination

Stability PMS
treatment
WO WO
PA PA
CO CO

1SD 1SD 1SD 1SD 1SD

fabric 25x13 mm 4–5 4–5


5 4–5 4–5 4–5 1.4%
4–5 3–4
5 4
4–5 4–5
5 4–5 4–5 4–5 1.4%
4–5 3
4–5 4
4–5 5
5 4–5
4–5 5 1.7%
5 3–4
5 4
5 5
5 4–5
5 3–4 4–5 4–5 1.3%
5 4
4–5 4–5
5 4
4 3 4 5 1.2%
5 4
4–5 4–5
5 4–5
4–5 3 4 5 1.0%
5 4

4–5 4–5
5 4–5
4–5 3–4 4 4–5 1.1%
5 4

4 4–5
5 4
3–4 2–3 4–5 5 1.7%
4 3–4

4–5 4–5
5 4
4 4–5 0.9%
3–4 2–3
4–5 3–4

LANASET_poc_14-9-10.indd 6 14.09.2010 08:37:04


untreated wool
epth Ch Ch Discharge- PAN A
Dry cleaning

multifiber

artificial light
MIRALAN®
HTW 120°C

Reservation

Shade change
ability PES TL 84
Decrolin CO

1SD 1SD 1SD

4–5 RR
% 5 4–5 5 4–5 R
3–4

4 RR
% 5 4 4–5 4 R
3

4
RR
% 5 4 5 4
R
2–3

3–4
3–4 R
% 5 4–5 4
2–3 R

3–4
3–4 R
% 5 4–5 4
2–3 R

3–4
3–4 YY
% 5 3–4 Du 2–3
2 Y

4
4–5 3–4 3 3–4 YY
%
3 Y

3–4
% 5 4–5 4 3–4 YY
2 Y

4
% 5 4 2–3 4 YY
2 Y

LANASET_poc_14-9-10.indd 7 14.09.2010 08:37:04


LANASET® Solubility (g/l) Xenon light Main
SD
90°C 1/12
90°C 60°C 1/3
90°C 30°C 1/1

80 4
Bril
1.6 % Violet B 60 4–5
Can
60 5

80 5
Bril
2.0 % Blue 2R 80 5 Can
80 5–6

80 4–5 Bril
80 5 Esp
1.8 % Blue 2RA com
80 5–6

80 4–5 Gre
2.2 % Blue 5G 80 5 with
80 5–6 tow

65 5
65 5–6 Bas
1.9 % Green B
65 6

80 5 Blu
1.0 % Grey G 80 5–6 Exc
80 6

80 Bril
N/L 5–6
3.9 % Navy R 80 fast
N/Dk 6–7
80

65 B/L 7 Neu
3.5 % Black B 65 B/Dk 8 fast
65

LANASET_poc_14-9-10.indd 8 14.09.2010 08:37:04


ght Main properties and recommendation for combination shades

Brilliant violet with high light and wet fastness properties.


Can be shaded with LANASET® Red 2B and Blue 2R.

Brilliant blue for royal blue self-shades with high fastness properties.
Can be shaded with LANASET® Violet B and Blue 5G.

Brilliant royal blue with higher migration than LANASET® Blue 2R.
Especially suitable as basis for blue shades on WO/PA blends in
combination with LANASET Red 2GA-01, Bordeaux B and Grey G.

Greenish blue with high fastness properties. Basis for brilliant greens
with LANASET® Yellow 4GN. To correct shade shifts in artificial light
towards green.

Basis for green and olive shades with a very high fastness level.

Bluish grey with high light fastness for greys and combination shades.
Excellent compatibility with LANASET® Yellow 2R and Red G.

–6 Brilliant navy blue. Basis for medium to dark navy shades with high
–7 fastness properties.

7 Neutral black with good build up and leveling properties at a high


8 fastness level.

LANASET_poc_14-9-10.indd 9 14.09.2010 08:37:04


untreated wool
Ch Ch Ch Ch Ch

Wash. 40°C
IWS TM 250

Rubbing
Wash. 50°C
ISO 105-
C06B2

Wash. 49°C
AATCC 69
2A

Milling alk.
ISO 105-E12

Hot water
70°C
ISO 105- E08
WO WO WO WO WO
PA PA PA CO CO
CO CO CO

1SD 2SD 1SD 2SD 1SD 2SD 1SD 2SD 1SD 2SD 1SD

4 4 4–5 4 4–5 4–5


4–5 4–5 5 5 5
5 5 5 5 4–5 4–5
4–5 4 4–5 4 4
5 5 5 5 5 5
5 5 5 4–5
5 5 5 5 5 5
4–5 4–5 4–5 4–5 4–5 4–5
5 5 5 5 4–
5 5 4–5 4–5 4–5 4–5
4–5 4 4–5 3–4 4
5 4–5 5 4–5 4–5 4–5
5 5 5 4–5
5 5 5 5 5 5
4–5 4 4 4 4–5 4–5
4–5 4–5 4–5 4–5 5
4–5 4–5 4 4 4–5 4
4 3–4 3–4 3 3–
4–5 4–5 3–4 3 3–4 3
5 5 4–5 4–5
5 4–5 5 5 4–5 4–5
4 4 4–5 4–5 4–5 4–5
5 5 5 5 4–
5 5 4–5 4–5 4–5 4–5
5 4–5 4–5 4 4
5 5 5 5 4–5 4
5 5 5 4–5
5 5 5 5 5 4–5
4 4 4 4–5 4–5 4–5
4–5 4–5 4–5 4–5 5
5 5 4–5 4–5 4–5 4–5
5 5 5 4 4–
5 5 5 5 5 4–5
5 5 5 4–5
5 5 5 5 4–5 4–5
4–5 4–5 4–5 4–5 4–5 4–5
5 5 5 5
5 5 4–5 4–5 4–5 4–5 5
4–5 3–4 5 4–5
4–5 4 3–4 3 4 3 4–
5 5 5 5
5 5 5 5 4–5 4–5

4–5 4–5 4 4–5 4–5 4–5 4–5 4–5 5 5


5 5 4–5 4–5 4–5 4–5 5
4 3–4 4–5 4
5 4–5 3–4 3–4 4–5 4 4
5 5 5 4–5
5 5 5 5 4–5 4–5

4–5 4–5 4–5 4–5 4–5 4–5 5 4–5 5 5


5 5 4–5 4–5 4–5 4–5 5
3–4 3 4 3
4–5 4 3 2–3 4 3–4 3–
4–5 4–5 4–5 3–4
5 5 5 5 4–5 4–5

LANASET_poc_14-9-10.indd 10 14.09.2010 08:37:04


untreated wool
Ch Dry Ch 1/12 1/12 1/12
Rubbing

Decatizing
severe

Light AATCC
20 AFU

Light AATCC
40 AFU

Light AATCC
60 AFU
WO Wet 1/3 1/3 1/3
CO 1/1 1/1 1/1

SD 1SD 2SD 1SD

5 5 4–5 3–4 3 2–3


4 5 4 3 3
4 3–4
4–5 4 3–4 3

5 4–5 4 4–5 3–4 3


3–4 5 4–5 3–4 3
4 4
4–5 4–5 3–4 3–4

4–5 5 4–5 4 3–4 3


3 3–4 3–4 4–5 4 3–4 3
4–5 4–5 3–4 3–4

5 4–5 4 4 3–4 3
4 4 3–4 5 4 3–4 3
4–5 4 4 3–4

4–5 5 5 4 3–4 3
4 4–5 4–5 5 4–5 4 3–4
4–5 4–5 4 4

5 5 5 4–5 4 3
4–5 4–5 4 5 4–5 3–4 3–4
5 4–5 4–5 4

5 1/2 N/L 4 1/2 N/L 3–4 1/2 N/L 3


5 5
4 5 NL 4–5 NL 4 NL 4
4 4
4–5 N/Dk 4–5 N/Dk 4–5 N/Dk 4–5

5 5 5 1/2 B/L 4–5 1/2 B/L 4–5 1/2 B/L 4


3 3–4 3 5 B/L 5 B/L 4–5 B/L 4–5
3–4 B/Dk 5 B/Dk 5 B/Dk 5

LANASET_poc_14-9-10.indd 11 14.09.2010 08:37:04


chlorinated wool untreated wool
Ch Ch Ch Ch Shade depth

Dry cleaning
Wash. 40°C
IWS TM 250

Perspiration
alk. TM 174

Stability to
chlorination

Stability PMS
treatment
WO WO
PA PA
CO CO

1SD 1SD 1SD 1SD 1SD

4 4
5 4–5 2–3 Y 5 1.6%
4–5 3
5 4
4–5 4–5
5 4–5 2–3 Y 4–5 2.0%
5 3
5 4–5
4–5 4–5
5 4–5
2–3 YD 4–5 1.8%
4–5 3
5 4–5
3–4 Y 3–4
5 4
5 3 3Y 5 2.2%
5 4
3–4 Y 3–4 Y
5 4–5
5 3–4 4 4–5 1.9%
5 4–5
4–5 4–5
4–5 4–5
3 3–4 4 4–5 1.0%
5 4–5

4–5 5
4–5 3–4
4 3 4–5 4–5 N/L 2.6%
5 3–4

5 5
4–5 4
3–4 2–3 4–5 5 B/L 2.3%
5 3–4

LANASET_poc_14-9-10.indd 12 14.09.2010 08:37:04


untreated wool
epth Ch Ch Discharge- PAN A
Dry cleaning

artificial light
MIRALAN®
HTW 120°C

Reservation
multifiber

Shade change
ability PES TL 84
Decrolin CO

1SD 1SD 1SD

3–4 RR
% 5 4 2 2–3 R
3

4 RD
% 5 4–5 2 4 R
2–3

4–5
RD
% 4–5 4–5 2 3
R
3

3
3 YY
% 5 4 2
3 Y

5
4–5 Y
% 5 4 2
3–4 D

3–4
3–4 YY
% 5 4–5 4–5
3 Br

3–4
2–3 RR
6% 5 4–5 4–5
2–3 R

3–4
2 RR
3% 5 4–5 2
2–3 Y

LANASET_poc_14-9-10.indd 13 14.09.2010 08:37:04


LANASET®
Pretreatment / bleaching / fluorescent whitening
Scouring
FW
If the goods are soiled with grease, oil, spinning lubricants or dirt, it is advisable to wash them before
UVI
dyeing. This can be done in the dyeing machine, using soft water.
UVI
Suggested recipe: UVI
0.5–3.0 gl/l ULTRAVON® PRE or INVADINE® DA UVI
0.5–2.0 g/l INVATEX® CS
y g/l ammonia or soda ash Gen
neutral washing: pH 6.5 – 7.7 treat 20–40 min at 50–65°C/122–149°F
rinse warm and cold The L
alk washing: pH 8 – 9.5 treat 20–40 min at 40–50°C/104–122°F blend
rinse warm and cold react
Almo
In some cases the addition of electrolyte, e.g. up to 5 g/l sodium sulfate, can assist the removal of Near
mineral oil lubricants. For a
the fi
Bleaching/fluorescent whitening range
Wool can be bleached at all stages of processing using conventional dyeing equipment. cially
of wo
Oxidation bleaching
The most commonly used bleaching agent, hydrogen peroxide, is applied under alkaline conditions. Reco
A phosphate-free alkaline bleaching method using stabilizer CLARITE® BAC gives whites that are
LANA
superior to those obtained by stabilizing with phosphate: Addition of INVATEX® CS complexing and
It is r
dispersing agent improves the hand of the bleached wool.
The f
allow
4 g/l CLARITE® BAC
LANA
0–2 g/l INVATEX® CS
15–30 ml/l hydrogen peroxide 35%
60 min at 45°C/113°F
LAN
drain, rinse and sour off to pH 5.5 SET
Reduction bleaching Yello
Reduction bleaching using stabilized hydrosulfite can be performed as a single process where a full Yello
bleach is not required, or as a treatment to follow hydrogen peroxide bleaching. In the latter case, Oran
reduction bleaching will give an improved, neutral white, generally with better light fastness than that Brow
attained with peroxide bleaching alone. Brow
Red
0.5–1 g/l ULTRAVON® PRE or INVADINE® DA Red
2–5 g/l stabilized sodium dithionite Bord
x % fluorescent whitening agent Viole
1–2 h at 50–60°C/122–140°F Blue
Rinse and add 0.5 ml/l hydrogen peroxide 35% to the final rinsing bath to remove residual sulfurous Blue
compounds. Gree
Grey
If required, a fluorescent whitening agent (FWA) can be added to the reduction bleaching bath. Navy
The following FWAs can be used, depending on required shade. Blac

LANASET_poc_14-9-10.indd 14 14.09.2010 08:37:05


LANASET®

FWA amount pH shade


e
UVITEX® NFW LIQ 0.5–2.0% 5–6 violet
UVITEX® NFW-V LIQ 0.5–2.0% 5 distinctly violet
UVITEX® BHR 200% 0.50–2.0% 6–7 red
UVITEX® BHT LIQ 115% 0.75–3.0% 7 neutral blue

General
The LANASET® dyeing system is a versatile and comprehensive system for dyeing wool and wool
blends. The LANASET® range comprises modified, tinctorially strong 1:2 metal complex, acid and
reactive dyes with high wet and light fastness. The dyes cover the shade spectrum systematically.
Almost all fashion shades can be produced economically using simple combinations of these dyes.
Nearly identical dyeing properties and high exhaustion result in excellent compatibility and reproducibility.
For all depths of shade LANASET® dyes are applied at pH 4.5 –the isoelectric region of wool–, leaving
the fiber in excellent physical condition. The auxiliary ALBEGAL® SET, designed especially for the dye
range, ensures safe and level dyeings. LANASET® dyes are suitable for dyeing wool in all forms,
especially loose stock, slubbing and yarn. In addition the LANASET® range is highly suitable for blends
of wool with numerous other fibers, including polyester, polyamide, silk, acrylics and cellulose.

. Recommendations for combination shades


LANASET® dyes possess similar dyeing properties and therefore have excellent compatibility.
It is recommended to use the dye closest in color to that required and to shade as appropriate.

The following LANASET® dyes are highly suitable for combinations in the more muted shade area,
allowing a wide range to be covered: LANASET® Yellow 2R, Red G, Brown B and Grey G.

Shade Yellow Orange Scarlet/ Bor- Violet Blue Blue- Green/ Brown/ Navy Black
aera Red deaux green/ olive beige/
LANA-
SET® turquoise grey
Yellow 4GN
Yellow 2R
Orange RN
t Brown G-01
Brown B
Red G
Red 2B
Bordeaux B
Violet B
Blue 2R
s Blue 5G
Green B
Grey G
Navy R
Black B
Basic Shading component trichromatic element

LANASET_poc_14-9-10.indd 15 14.09.2010 08:37:05


LANASET®
Dyeing Pro
Dyeing chemicals Conv
Penetration accelerants
ALBAFLOW® CIR or ALBAFLOW® UNI-01 is added to the dyebath to de-aerate and rapidly wet out the
goods. These products also have a foam-suppressing effect.

Leveling agent
ALBEGAL® SET is amphoteric and has affinity for both dye and fiber. For all shade depths
1% ALBEGAL® SET is used at liquor ratios from 8:1 to 25:1. Below 8:1 the amount should be reduced
to 0.5%, above 25:1 it should be increased.

ALBEGAL® SET improves the compatibility of the LANASET® dyes, promotes their migration and
exhaustion, and greatly helps to ensure fiber and surface levelness. These effects can be improved
still further by an addition of 5–10% Glauber’s salt (particular recommended for dyeing yarn and
piece goods).

Dyeing accelerant
MIRALAN® TOP is a special dyeing accelerant for the LANASET® TOP process to accelerate diffusion
of LANASET® dyes inside the wool fiber and shorten the dyeing time. The LANASET® TOP process is
recommended only for dyeing loose wool and tops.

MIRALAN® TOP works also as low temperature auxiliary and allows dyeing temperatures of 85 – 90°C
(depending from shade depth).
A
Wool care product
MIRALAN® Q-01 improves the quality of the wool at all stages of processing. It reduces felting and
setting during dyeing and has a lubricating effect. Carding and spinning properties of loose material are
improved. In package dyeing, flattening on crossover points is reduced and bulk increased. In piece
dyeing, running marks and felting are prevented.

Dissolving the dyes


B
Paste the dye cold with soft water, add hot water (60–90°C) and boil up briefly with live steam if
necessary. Stir thoroughly (with rapid stirrer if necessary).

Auxiliaries and chemicals should not be added during dissolving. For further details on solubility of the
individual dyes, please see tables in the pattern section.

The temperature of dye solutions containing LANASET® Red 2B should not exceed 60°C/140°F.

Dyebath pH
LANASET® dyes are applied at pH 4.5, the ideal pH for wool as it minimizes fiber damage during
dyeing. The pH is best set with a buffer of sodium acetate and acetic acid or with ALBATEX® AB-45,
a pH controlling agent, which sets the pH at 4.5.

LANASET_poc_14-9-10.indd 16 14.09.2010 08:37:05


LANASET®
Procedure for loose stock and tops
Conventional LANASET® dyeing process

the
103°C
15–40 min
98°C

ced
1–2°C/min

on 50°C
is

0°C 5 5 20–60 min


A B

A 0.5 g/l ALBAFLOW® UNI-01 or CIR


are 1.0 % ALBEGAL® SET
e 1–2 g/l MIRALAN® Q-01
x % ALBATEX® AB-45
or formic acid or acetic acid
pH 4.5

B y % LANASET® dyes
he

ye-

LANASET_poc_14-9-10.indd 17 14.09.2010 08:37:05


LANASET®
LANASET® TOP dyeing process Pro
The LANASET TOP process for loose wool and tops shortens the dyeing process by means of the
®

dyeing accelerant MIRALAN® TOP. The benefits of the process are as follows:
• reduces dyeing time at the boil to half, improving productivity
• improves exhaustion to almost 100%
- reduced effluent load
- shorter rinsing cycles
- dyeings can be performed in standing baths
• saves time, water and energy

98°C

1–2°C/min

50°C

5 5 10–30 min
A B
B
A 0.5 g/l ALBAFLOW® UNI-01 or CIR
1.5 % MIRALAN® TOP The
1–2 g/l MIRALAN® Q-01 sodi
x % formic acid
pH 4.5
Alter
B y % LANASET® dyes Inste
With
the e
Note: 0.5–
For pale shades a combination of 1.0% MIRALAN® TOP with 0.5% ALBEGAL® SET is recommended This
to improve levelness. shad

MIRALAN® TOP can also be used as low temperature dyeing auxiliary and improves exhaustion at
85°C – 90°C.

LANASET_poc_14-9-10.indd 18 14.09.2010 08:37:05


LANASET®
Procedure for yarn and piece dyeing
e
103°C
15–40 min
98°C

1°C/min

75°C

1°C/min

50°C

10 10 15–20 20–60 min


A B

A 0.5 g/l ALBAFLOW® UNI-01 or CIR


1–1.5 % ALBEGAL® SET
1–2 g/l MIRALAN® Q-01
5–10 % Glauber’s salt anhyd.
1 g/l sodium acetate cryst.
x % acetic acid
ph 4.5–5.5

B y % LANASET® dyes

The pH of the dye bath can be set with 3–5 g/l ALBATEX® AB-45 instead of using acetic acid and
sodium acetate.

Alternative method with ALBATEX® PS-35 pH slider


Instead of setting the pH at a constant value at 4.5–5.5 the dyeing is started under neutral condition.
With the help of ALBATEX® PS-35 the pH slides down to the final pH during the heating phase and until
the end of the dyeing process, reducing a to quick uptake at the begin.0.5–1.5 g/l ALBATEX® PS-35 are
required for an end pH of 4.5 to 5.
ed
This method is particularly recommended whenever leveling problems can be expected (e.g. pale
shades, inside/outside differences in package dyeing).

LANASET_poc_14-9-10.indd 19 14.09.2010 08:37:05


LANASET®
Procedure for chlorinated and shrink resist treated wool Pro
A slightly alkaline pre-wash is recommended prior to dyeing in order to neutralize the chlorinated wool. Shad
Since the dye affinity to the fiber is generally increased by a shrink-resist process, the dyeing is started LANA
at lower temperature and higher pH (see table below) to get best leveling. is no
Note: Wetfastness is reduced due to the chlorination process. 75–8
For medium and dark shades LANASOL® reactive dyes are recommended.
Corr
103°C Dyein
15–40 min
98°C treati

1°C/min

70°C Befor
Shad

1°C/min

30°C

To re
treate
10 10 15–20 20–60 min
Re-d
A B
Note
A 0.5 g/l ALBAFLOW® UNI-01 or CIR LANA
1–1.5 % ALBEGAL® SET
1–2 g/l MIRALAN® Q-01
5–10 % Glauber’s salt anhyd Softe
1 g/l sodium acetate cryst. After
x % acetic acid Differ
ph 7–5.5 elega
SAPA
B y % LANASET® dyes More
Proc
pH
Amount of dye pH Tim
0–0.5 % 7.5–7 Tem
0.5–1 % 7–6.5 Liqu
1–2 % 6.5–6
>4 % 5 The a
The g
Alternative method with ALBATEX® PS-35 pH slider (230–
Recommendations see previous page.

LANASET_poc_14-9-10.indd 20 14.09.2010 08:37:05


LANASET®
Process parameters
ool. Shading
ted LANASET® dyeings are highly reproducible. All LANASET® dyes can be used for shading. As a rule there
is no need to top up with chemicals. Before the shading dye is added, the dyebath should be cooled to
75–80°C. For loose wool and tops, the additions can be made with steam off.

Correction of faulty dyeings


Dyeings that have turned out too deep or slightly unlevel can be weakened by 10–15% or leveled by
treating in a fresh bath for 30 min at the boil with
2 % ALBEGAL® SET
10 % Glauber’s salt anhyd.
x % acetic acid 80%
pH 6–7
Before re-dyeing cool dyebath to 60°C/140°F and adjust with acetic acid to pH 4.5.
Shade weakening by 30–40% can be achieved by treating in a fresh bath for 30 min at the boil with
4 % TINEGAL® W
10 % Glauber’s salt anhyd.
x % acetic acid 80%
pH 6–7

To remove TINEGAL® W residues and improve rubbing fastness before re-dyeing, the goods should be
treated (after rinsing) with 2% INVALON® DAM for 10 min at 40°C/104°F and rinsed again.

Re-dye in a fresh bath.

Note:
LANASET® Violet B, Blue 2R and Blue 5G can only be weakened marginally.

Softening of wool by exhaust process


After dyeing, softening agents are applied, usually in a separate bath, to achieve a soft and pleasant hand.
Different softeners can be used, depending on the hand required of the specific end product, e. g. soft,
elegant, surface smooth, cool, warm, luxurious, drapy, bulky etc.

SAPAMINE® CA NEW and ULTRATEX® EMJ achieve two of the most commonly requested effects.
More options are available.

Process:
pH 4.5–5.5 (adjusted with acetic acid)
Time 15–20 min
Temperature 30–40°C
Liquor ratio 3:1–20:1

The amount of softener ranges from 1 to 5%, depending on requirements.

The goods are hydro-extracted without subsequent rinsing and the fabric is dried at 110–130°C
(230–266°F).

LANASET_poc_14-9-10.indd 21 14.09.2010 08:37:05


LANASET®
Vigoureux printing and continuous dyeing Woo
Processing Outle
Vigoureux printing is a special technique in which slivers of raw, bleached or dyed wool are printed with PES/
stripes, steamed, run through a backwasher, and then dried. fabric
The m
Continuous dyeing is done in a single, non-stop pass, slivers of raw wool being padded with liquor, be fo
steamed, run through a backwasher, and then dried. (for p

Printing / dyeing recipes Dyei


x g LANASET® dyes All LA
y g cold water optim
z g boiling water dyes
they
100–300 g thickener (2% solution)
very
10–20 g acetic acid 80% Exce
2 g LYOPRINT® AP the id
10–30 g THERMACOL® PN •
5–10 g ALBEGAL® SET •

1000 g


Steaming time •
The steaming times tabulated below are for guidance only. In each specific case the precise length of
the treatment will depend on depth of shade, steaming temperature, density of material and type of Impo
steamer used.
Dyein
The m
semi-continuous continuous
show
Pale shades 30–60 min 15–30 min MIRA
Deep shades 60 min 20–40 min Altern
UNIV
dyes
Saturated (not superheated) steam should be used. If dry steam is used, it is good practice to add the
acce
necessary moisture by injecting water, to interrupt steaming after half the time has elapsed, and to allow
recom
the slubbing to cool down. The steaming temperature is 100-102°C (212-216°F), depending on the
type of steamer.
Woo
Thickening MIRA
The amount of dye applied can largely be controlled by the viscosity of the print paste or padding liquor. prop
The b
The right thickening is the key to good printing. In principle, only thickeners should be used which are
easy to wash off and resistant to acid, e.g. guar based thickener. When present in the print paste or
padding liquor, the thickener should be well dissolved, otherwise problems can arise,e.g.
agglomeration of dye and thickener, sticking on the backwasher, wrapping round rollers, dusting
during gilling or spinning. To be on the safe side, therefore, many mills prefer to use stock thickenings.

LANASET_poc_14-9-10.indd 22 14.09.2010 08:37:05


LANASET®
Wool / polyester blends
Outlets
with PES/wool blended fabrics are mainly used for apparel, i.e. suits. Blending wool with PES makes the
fabric cheaper and increases durability and wrinkle-resistance. Main outlets are worsted fabrics.

The most common blend ratio for PES/WO is 55:45 but a large variety of other blend ratios can also
be found in the market. PES/WO blends are dyed in piece form (solid shades) or as yarn on packages
(for pattern wovens).

Dyeing system
All LANASET® dyes are ideal for PES/WO blends. They are applied at pH 4.5, which guarantees
optimum wool preservation, and perfect conditions for the dispersion stability of TERASIL® disperse
dyes. LANASET® dyes are stable at 120°C and have excellent migration at this temperature, therefore
they can also be recommended for piece dyeing of PES/WO blends. All LANASET® dyes are noted for
very good reservation of PES. The selection of dyes follows the same rules as for pure wool.

Excellent technical behavior during dyeing and good fastness properties make the LANASET® dyes
the ideal range for dyeing PES/WO blends:
• coverage of a wide range of colors, including brilliant shades
• pale to deep shades attainable, including navy and black
• one-bath dyeing method
• shade stability at 120°C/248°F, no interference with wool protecting agents
of
• optimal wool protection
• good overall light and wet fastness

Important parameters for dyeing polyester and wool blends


Dyeing temperature and time
The most common dyeing temperature is 120°C. At this temperature the selected TERASIL® dyes
show good build-up on PES and the wool quality is largely preserved if the wool-protecting agent
MIRALAN® HTW is used. The normal dyeing time is 45 min, the maximum time limit at 120°C is 60 min.
the
allow Alternatively PES/WO blends can be dyed at 106°C. But in this case the diffusion accelerant
e UNIVADINE® ent build up on PES and only low-energy
disperse dyes can be used. For very fine weaving yarns, where even a small reduction of tensile
strength is not acceptable, a maximum dyeing temperature of 115°C in presence of a wool protecting
agent is recommended.
quor.
Wool protecting agent
are MIRALAN® HTW improves the heat resistance and preserves the mechanical and technological
r properties of the wool fiber at 120*C/248°F.
ra-
or The best effects are achieved by using 4% MIRALAN® HTW.

LANASET_poc_14-9-10.indd 23 14.09.2010 08:37:05


LANASET®

TERASIL® dye selection for WO/PES blends


The right selection of TERASIL® disperse dyes is essential for good results. The main criteria for the
selection of TERASIL® dyes are stability to reduction and low staining on wool. The recommended
TERASIL® dyes are shown in the following table:

Shade Tri- Yellow/ Brill. Red Bor- Violet Blue Green Brown Navy Black
aera chromy Orange Scarlet deaux
TERASIL® Red
Yellow W-6GS
Golden Yellow W-3R
Brown 2RFL 200%
Red FBN CONC
Red 3BL-01 150%
Rubine 2GFL
Violet BL-01 150%
Blue 3RL-02 150%
Blue BGE-01 200%
Navy NFR
Black BFE
A
Basic Shading component

Trichromatic recommendation
TERASIL® Brown 2RFL or Yellow W-6GS
TERASIL® Rubine 2GFL
TERASIL® Blue 3RL-02 150%
TERASIL® Yellow W-6GS is the basis for brilliant green shades together with TERASIL® Blue BGE-01 200%
TERASIL® Red FBN CONC, Rubine 2GFL and Red 3BL-01 150%
TERASIL® Black BFE and Navy NFR: need 60 min dyeing time at 120º C and UNIVADINE® DFM or B
E3-DAP to achieve adequate build up and reproducibility

Dyeing at 106°C A hy
The build-up of most disperse dyes is insufficient at this temperature. Only low-energy dyes in presence this
of a diffusion accelerant like UNIVADINE® DFM or E3-DAP are suitable for d
In ce
Recommendation for trichromatic dyeings: but p
TERASIL® Yellow 4G
TERASIL® Red FBN CONC
TERASIL® Blue 3RL-02 150%

LANASET_poc_14-9-10.indd 24 14.09.2010 08:37:05


LANASET®

Dyeing procedure for WO/PES blends

120°C

60–90 min
106°C
lack

1°C/min

40°C

5 5 20–45 min
A B

A 0.5 g/l ALBAFLOW® UNI-01 or CIR


1 g/l MIRALAN® Q-01
0.5 g/l ALBEGAL® SET
5 % MIRALAN® HTW
0–1 g/l UNIVADINE® DFM or E3-DAP
3–4 % ALBATEX® AB-45
ph 4.5

00%. B x % LANASET® dyes


y % TERASIL® dyes

A hydrosulfite reduction clear after dyeing is not recommended owing to the sensitivity of wool to
e. this process. A wash off with 2 g/l ERIOPON® OS or E3-SOP at pH 4–5 at 70°C°C for 20 min is
recommended for deep shades to remove disperse dye stains from the wool.

In certain cases 1–2 g/l ERIOPON® RC in the wash bath can bring a significant improvement,
but preliminary lab trials are recommended to check influence on shade.

ence

LANASET_poc_14-9-10.indd 25 14.09.2010 08:37:05


LANASET®
Wool / polyamide blends
Outlets Dye
Polyamide fibers are often blended with wool to strengthen its mechanical properties without losing the The d
typical wool character. Main outlets for this blend are woolen fabrics for coats, knitting yarns for socks At pa
and carpet yarns. The main WO/PA blend ratio is 80/20. than
In me
shad
Dyeing system
dyes
Polyamide is chemically related to wool because amino groups are integral components of both fibers.
Therefore polyamide can be dyed with the same dyes as wool. The LANASET® dyeing system offers Dye
the following advantages: Besid
• coverage of a wide range of colors, including brilliant shades each
• one-bath dyeing method darke
• excellent tone-in-tone dyeing of both fibers dyes
• good light fastness for carpet yarn dyeing same
• ideal for deep shades due to high wet fastness Dyes
For c
in ord
Parameters influencing partition between wool and polyamide
Polyamide fiber type LANA
The most common polyamide types are PA 6 and PA 66. PA 6 has higher dye affinity than PA 66 and The f
therefore needs more blocking agent to achieve solid shades on its blends with wool. Beside this allow
difference based on chemical composition, the fiber fineness (dtex), fiber surface/cross section LANA
(round, trilobal, etc.), degree of delustering, texturing, and pretreatment (heat setting) influence the LANA
color depth on polyamide. LANS
LANA
Wool fiber LANA
Quality and type, fiber diameter and pretreatment, all influence the uptake and shade depth on wool.
Class
If the wool has been treated by a shrink-resist-process its dye affinity is increased appreciably. In most block
of these cases wool then dyes to a darker shade than the polyamide blended with it.

Blocking agent
Blocking agents like ERIONAL® FRN consist of colorless anionic compounds having high affinity for
polyamide. They partially saturate the polyamide fiber and allow the dye to move onto the wool portion
of the blend. The amount of blocking agent has to be adjusted so that an even distribution can be
achieved between the fibers.

The required amount of blocking agent depends on the dyes used, dye concentration, fiber type and
blend ratio, and has to be determined in preliminary lab trials simulating bulk conditions as closely as
possible.

LANASET_poc_14-9-10.indd 26 14.09.2010 08:37:05


LANASET®

Dye concentration
the The distribution of dyes between the two fibers depends strongly on the applied dye concentration. At
cks pale to medium depths below the saturation limit of polyamide, this fiber is generally colored deeper
than wool. Therefore dye uptake by polyamide must be retarded by ERIONAL® FRN.In medium to deep
shades an even distribution between the fibers is often encountered. In deep shades many dye classes
dye the wool darker. In such cases the polyamide has to be covered with dyes having high affinity for
polyamide.
ers.
s
Dye selection
Besides the dye selection based on end-use requirements such as wet and light fastness properties,
each individual dye has different affinity for wool and polyamide. This means that some dyes dye wool
darker and some dye polyamide darker. For dye combinations it is very important that the individual
dyes distribute more or less evenly between wool and polyamide and that they react similarly to the
same amount of blocking agent to give good solidity.

Dyes with low affinity for polyamide need less blocking agent than dyes with medium or high affinity.
For combination shades dyes should be selected if possible only from the group with the same affinity
in order to achieve best solidity.

LANASET® dye selection


The following LANASET® dyes are highly suitable for combinations in the more muted shade area,
nd allowing a wide range to be covered:
LANASET® Yellow 2R
LANASET® Red 2GA-01
LANASET® Brown B
LANASET® Grey G
LANASET® Blue 2RA

ol. Classification of LANASET® dyes according to their affinity for polyamide and the necessary amount of
ost blocking agent for good solid shades:

Low amount Medium amount High amount


ERIONAL® FRN ERIONAL® FRN ERIONAL® FRN
LANASET® dyes with LANASET® dyes with LANASET® dyes with
tion low affinity to PA medium affinity to PA high affinity to PA
Yellow 4GN Red G Yellow 2R
d Orange RN Red 2B Red 2GA-01
s Violet B Blue 5G Bordeaux B
Blue 2R Brown B
Green B Blue 2RA
Navy R
Grey G
Black B

LANASET_poc_14-9-10.indd 27 14.09.2010 08:37:05


LANASET®

Recommendations for combination shades on WO/PA blends Dyei

Shade Trichro- Brill. Yellow Orange Scarlet Red Bor- Violet Blue Green Brown Navy Black
aera matic Yellow Olive Brill. deaux
LANA-
SET® sytem Red
Yellow 4GN
Yellow 2R •
Orange RN •
Brown B
Red 2GA-01
Red G
Red 2B
Bordeaux B
Violet B
Blue 2R
Blue 2RA •
Blue 5G • • • •
Green B
Grey G
Navy R
Black B
Amount of medium medium A
blocking high low high low medium high high low high low high
-high -high
agent
Basic Shading component • shading dye if neccessary

*The
used

LANASET_poc_14-9-10.indd 28 14.09.2010 08:37:05


LANASET®

Dyeing procedure for WO/PA blends

Black
103°C
15–40 min
98°C

1°C/min

75°C

1°C/min

40°C


10 10 15–20 20–60 min
A B C

edium A 0.5 g/l ALBAFLOW® UNI-01 or CIR


-high 1 g/l MIRALAN® Q-01
0–4 % ERIONAL® FRN*
5 % Glauber’s salt
1 g/l sodium acetate
x % acetic acid
pH 4.5–5.5

B 1 % ALBEGAL® SET

C y % LANASET® dyes

*The necessary amount of blocking agent depends on the type of polyamide and the dye concentration
used. It has to be determined in preliminary lab trial on the specific material and shade.

LANASET_poc_14-9-10.indd 29 14.09.2010 08:37:05


LANASET®
Wool / acrylic blends
Outlets Dyei
The most important outlets for acrylic/wool blends are knitted textiles for sportswear, leisurewear and
fashionable men’s and women’s outerwear, plus hand knitting yarns.

These blends are dyed primarily in yarn form as packages or muffs. Hand knitting yarns and high-quality
machine knitting yarns are also hank-dyed for the best results.

Dyeing system
A suitable dyeing system comprises LANASET®/MAXILON® dyes, the main benefits of which are:
• coverage of a wide range of colors, including brilliant shades
• trichromatic systems available
• pale to deep shades attainable, including navy and black
• good overall light and wet fastness
• one-bath, two-stage dyeing method except for black
• good stability of the dyebath containing LANASET® and MAXILON® dyes

MAXILON® dye selection


The most important criteria for selecting cationic dyes are sensitivity to reduction and reservation
of the wool. A

The trichromatic system for acrylic/wool comprises:

• MAXILON® Golden Yellow GL


• MAXILON® Red GRL
• MAXILON® Blue SL
B
For further details and suitability of other MAXILON® dyes see also pocket card 512003.
C

The
for 2

Blac
Blac
the w

LANASET_poc_14-9-10.indd 30 14.09.2010 08:37:05


LANASET®

Dyeing procedure for WO/PAN blends


nd

uality 100–103°C

0.5°C/min

75–80°C

1°C/min

40°C

10 10 20 45–60 min
A B C

A 0.5 g/l ALBAFLOW® UNI-01 or CIR


1 % ALBEGAL® SET
0–3 % Glauber’s salt
3–4 % ALBATEX® AB-45
pH 4.5

B x % LANASET® dyes

C y % MAXILON® dyes
0–1.5 % retarder

The wet fastness of deep shades can be improved by washing off with 1–2 g/l INVALON® DAM (pH 4)
for 20 min at 60–65°C/140–149°F followed by thorough rinsing.

Black shades
Blacks are dyed in a two-bath process, dyeing first the acrylic fiber and subsequently in a fresh bath
the wool portion.

LANASET_poc_14-9-10.indd 31 14.09.2010 08:37:05


LANASET®
Wool / silk blends
Outlets LANA
Wool/silk blends are mainly used for apparel in woven or knitted form to give them a luxury character. With
A large variety of blend ratios can be found ranging from 5 to 50% of silk. WO/S blends are dyed in recom
piece form or as yarn on packages and hanks. follow
LANA
Dyeing system Dyein
Blue
Silk is chemically related to wool because amino groups are integral components of both fibers.
Navi
Therefore silk can be dyed with the same dyes as wool. The LANASET® dyeing system offers the
following advantages:
Blac
• coverage of a wide range of colors, including brilliant shades
• one-bath dyeing method
• excellent solid shades
Dyei
• trichromatic systems available
• pure silk, pure wool and blended goods can be dyed with the same dyes

Parameters influencing partition between wool and silk


Silk fiber type
The quality and type of silk fibers e.g. mulberry silk, tussah silk, weighted silk, influence the distribution
of dyes between silk and wool. The silk used in blends should be degummed before fiber blending to
avoid negative influence of the silk gum on dyeing performance and fastness.

Wool fiber
Quality and type of wool, fiber diameter and pretreatment all influence uptake and shade depth on the
fiber. If the wool has been treated by a shrink-resist process the dye affinity is increased appreciably.
In most of these cases wool then dyes darker than the silk blended with it.

Amount of salt
Glauber’s salt is the major reagent to control the distribution of dyes between wool and silk. Salt retards
the dye uptake on wool in favor of silk.

Dyeing temperature A
Dyeing at a low temperature favors a deeper dyeing on silk. However too low a dyeing temperature
has a negative influence on the wet fastness on wool. The best temperature for LANASET® dyes for
this blend is 90°C.

Dyeing pH
The distribution of dyes between the two fibers depends on the pH used. A lower pH favors a
deeper dyeing of silk. In order to obtain reproducible results, the use of a buffer like sodium acetate is B
recommended.

Note
In or
reco
fresh

LANASET_poc_14-9-10.indd 32 14.09.2010 08:37:05


LANASET®

LANASET® dye selection


er. With most LANASET® dyes solid shades can be achieved on wool/silk blends. Therefore the normal
recommendations including the trichromatic system LANASET® Yellow 2R, Red G and Grey G can be
followed with the following exceptions:
LANASET® Red 2B, Blue 2R, Blue 2RA and Navy R dye silk lighter than the other LANASET® dyes.

Dyeing at pH 4.5 and using higher amounts of salt can improve the depth on silk.

Blue shades: Good partition is obtained by a combination of LANASET® Blue 5G and Violet B.
Navies: Solid shades can be achieved by a combination of LANASET® Navy R and Black B.
Alternatively navies could be based on LANACRON® Navy S-G 150%.
Blacks: Dyeings with LANASET® Black B need less salt and only 0.5% ALBEGAL® SET.

Dyeing procedure for WO/silk blends

90°C

1°C/min
ion
to
75°C

he 1°C/min
y.

40°C

10 10 20 45–60 min
A B

A 0.5 g/l ALBAFLOW® UNI-01 or CIR


r 1 g/l MIRALAN® Q-01
1 % ALBEGAL® SET
10–40 g/l Glauber’s salt
x % ALBATEX® AB-45
pH 4.5–5.5
is
B y % LANASET® dyes

Notes:
In order to establish the best dyeing conditions for solid shades, lab trials under identical conditions are
recommended. Wet fastness on silk is generally lower than on wool. If necessary an aftertreatment in a
fresh bath with 2% ERIONAL® ECS at pH 5–6 for 20 min at 40°C can be given to improve wet fastness.

LANASET_poc_14-9-10.indd 33 14.09.2010 08:37:05


LANASET®
Wool / cellulose blends
Outlets Dyei
Wool/cellulose blends are mainly used for apparel in woven or knitted form. A large variety of blend
ratios can be found ranging from 80/20 to 20/80. WO/CEL blends are dyed in piece form or as yarn
on packages and hanks.

Dyeing system
LANASET® dyes have excellent reservation of cellulosic fibers. Therefore they are ideal for this blend.
There are no restrictions on LANASET® dye selection therefore the same rules as for pure wool can be
followed. The two major methods to dye WO/CEL blends are a one-bath dyeing method using
SOLOPHENYL® direct dyes and a two-bath method using NOVACRON® EC or AVITERA® SE reactive
dyes for the cellulose portion.

LANASET®/SOLOPHENYL® dyeing method


This economical one-bath dyeing method is recommended for pale to medium shade depths because
of the typical wet fastness level of direct dyes. A dyeing pH of 5.5 is used to ensure good exhaustion of
the LANASET® dyes on wool and minimize staining of the wool by the SOLOPHENYL® dyes. Blocking
agent ERIONAL® FRN is mandatory, otherwise SOLOPHENYL® dyes will mainly dye the wool portion.

SOLOPHENYL® dye selection


A
The selection of SOLOPHENYL® dyes is governed by minimum staining of wool under dyeing
conditions and stability to reduction in presence of wool.

The following SOLOPHENYL® dyes are recommended:

SOLOPHENYL Use
Yellow ARLE 154% B
Orange TGL 182% •
Brown AGL-01 •
Scarlet BNLE 200% C
Red 4GE •
Bordeaux 3BLE D
Blue GL 250% •
Blue FGLE 220%
Turquoise BRLE 400% •
Note
Trichromatic dye • shading element
If nec
be g

LANASET_poc_14-9-10.indd 34 14.09.2010 08:37:05


LANASET®

Dyeing procedure for WO / CEL with LANASET® and SOLOPHENYL®

n
98°C

80°C

d.
be
1°C/min

use 50°C
n of
ng
n. 10 10 30 20 min
A B C D

A 0.5 g/l ALBAFLOW® UNI-01 or CIR


2–4 % ERIONAL® FRN
0.5–1 % ALBEGAL® SET
1 g/l sodium acetate
x % acetic acid
pH –5.5

B y % LANASET® dyes
z % SOLOPHENYL® dyes

C 1/5 part Glauber’s salt (amount see SOLOPHENYL® pattern card)

D 4/5 parts Glauber’s salt

Notes:
If necessary an aftertreatment in a fresh bath with 2 % ERIONAL® ECS at pH 5–6 for 20 min at 40°C can
be given to improve wet fastness.be given to improve wet fastness.

LANASET_poc_14-9-10.indd 35 14.09.2010 08:37:05


LANASET®
Hig
LANASET /NOVACRON EC dyeing method
® ®
Prop
For higher fastness requirements in medium to deep shades the cellulose portion of the blend is
preferably dyed with NOVACRON® EC reactive dyes. The dyeing has to be done by a two-bath- Broa
procedure, dyeing first the cellulose and, after soaping and rinsing, the wool portion in a fresh bath.

NOVACRON® EC dyes always stain the wool somewhat. This staining is fast and the wool recipe has
to be adjusted accordingly. In order to minimize damage to the wool only soda ash should be used for
fixation (see table below) and the temperature should not exceed 60°C. The amount of soda ash and Com
salt should be calculated for the amount of NOVACRON® EC dye based on pure cellulose. For
selection of NOVACRON® EC dyes, see corresponding pattern card.

High
First bath: NOVACRON® EC dyeing procedure

95°C Dye

80°C

70°C Sam
High
60°C

50°C

20°C Suit

45 45 10 10 15 10 10 10 min
A B C D

A ALBAFLOW® FFC g/l 0.5 0.5 0.5 0.5 0.5 0.5 0.5
LYOPRINT® RG g/l 1.0 1.0 1.0 1.0 1.0 1.0 1.0
NOVACRON® % 0–0.5 0.5–1 1–2 2–3 3–4 4–5 >5
(based on pure CEL)
Glauber’s salt g/l 20–30 30–40 40–50 50–60 60–70 70–80 90
B Soda ash g/l 2 3 4 5 5 6 7
C acetic acid 80% pH7 x x x x x x x
D ERIOPON® R LIQ g/l 1 1 1 1.5 1.5 2 2

Second bath: LANASET® dyeing procedure


For the wool component the normal dyeing procedure with LANASET® dyes can be followed.

LANASET_poc_14-9-10.indd 36 25.10.2010 08:36:52


LANASET®

LANASET®/AVITERA® SE dyeing method


AVITERA® SE dyes are predestinated to dye WO/CEL blends, offering additional benefits in terms of
sustainability compared to classical reactive dyestuffs.
Key benefits :
has • saving 50% of water consumption
for • saving 50 % of energy consumption
nd • reducing CO2 emmissions by 50%
elec- • Increasing productivity by 25%

The wash-off takes place at 60°C and with 3 wash baths only, preserving the precious wool quality
while reducing significantly process time, leading to enhanced productivity.
The high speed low temperature wash-off takes place in a slightly alkaline medium, ensuring a good
wool reservation. Slight staining on wool is fast and therefore no problem. The final shade on wool is
achieved in the second bath.

First bath: AVITERA® SE dyeing procedure

60°C

45 45 10 10 10 min
A B C D
5
A ALBAFLOW® FFC g/l 0.5 0.5 0.5 0.5 0.5 0.5 0.5
0
LYOPRINT® RG g/l 1.0 1.0 1.0 1.0 1.0 1.0 1.0
5
AVITERA® % 0–0.5 0.5–1 1–2 2–3 3–4 4–5 >5
(based on pure CEL)
0
Glauber’s salt g/l 20–30 30–40 40–50 50–60 60–70 70–80 90
7
B Soda ash g/l 2 3 4 5 5 6 7
x
C ERIOPON® E3-WOC g/l 1 1 1 1.5 1.5 2 2
2
D acetic acid 80% pH7 x x x x x x x

Second bath: LANASET® dyeing procedure


For the wool component the normal dyeing procedure with LANASET® dyes can be followed.

LANASET_poc_14-9-10.indd 37 14.09.2010 08:37:05


LANASET®
Highlights Not
Properties Customer benefits

Broad shade range Brilliant and restrained combination shades


at all depths
Brilliant shades with high wet and light
fastness

Compact range with similar dyeing behavior Reduced inventory costs


Excellent compatibility
Easy dye selection

High fastness properties High fastness to processing


Suitable for all end products
Suitable for carpets and upholstery
Suitable for Oeko-Tex Standard 100

Dyeing at pH 4.5 Minimum damage to the fiber


Quality of the wool retained
Higher spinning yields

Same dyeing method for all shade depths Simple procedure


High exhaustion More dependable results in production
Good laboratory-to-bulk transfer
Excellent reproducibility
Minimal effluent pollution

Suitable for many blends Flexibility for meeting changing market needs
Only one dye range for the wool portion of
different blends
Key for fastness tables

Ch – shade change N/L – standard depth “light navy”


CO – staining of cotton N/Dk – standard depth “dark navy”
CV – staining of viscose B/L – standard depth “light black”
PA – staining of polyamide 66 textured tricot B/Dk – standard depth “dark black”
PAN – staining of acrylics
PES – staining of polyester Br – brighter
WO – staining of wool De – deeper
Du – duller
B – bluer W – weaker
Bn – browner
G – greener BB – appreciably bluer
R – redder GG – appreciably greener
V – more violet RR – appreciably redder
Y – yellower YY – appreciably yellower

LANASET_poc_14-9-10.indd 38 14.09.2010 08:37:06


LANASET®
Notes

LANASET_poc_14-9-10.indd 39 14.09.2010 08:37:06


Copyright © 2017 Huntsman Textile Effects All rights reserved.
All trademarks mentioned are registered trademarks of Huntsman Corporation or an affiliate thereof in one or more, but not
all countries.

IMPORTANT: The following supersedes Buyer’s documents. Sales of the product described herein (“Product”) are subject to the
general terms and conditions of sale of either Huntsman Advanced Materials LLC, or its appropriate affiliate. Huntsman warrants
that at the time and place of delivery all Products sold to Buyer shall conform to the specifications provided to Buyer by
Huntsman.

While the information and recommendations included in this publication are, to the best of Huntsman’s knowledge, accurate as of
the date of publication, NOTHING CONTAINED HEREIN (EXCEPT AS SET FORTH ABOVE REGARDING CONFORMANCE WITH
SPECIFICATIONS PROVIDED TO BUYER BY HUNTSMAN) IS TO BE CONSTRUED AS A REPRESENTATION OR WARRANTY
OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO ANY WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE, NONINFRINGEMENT OF ANY INTELLECTUAL PROPERTY RIGHTS, OR
WARRANTIES AS TO QUALITY OR CORRESPONDENCE WITH PRIOR DESCRIPTION OR SAMPLE, AND THE BUYER
ASSUMES ALL RISK AND LIABILITY WHATSOEVER RESULTING FROM THE USE OF SUCH PRODUCT, WHETHER USED
SINGLY OR IN COMBINATION WITH OTHER SUBSTANCES.

No statements or recommendations made herein are to be construed as a representation about the suitability of any Product for
the particular application of Buyer or user or as an inducement to infringe any patent or other intellectual property right. Buyer is
responsible to determine the applicability of such information and recommendations and the suitability of any Product for its own
particular purpose, and to ensure that its intended use of the Product does not infringe any intellectual property rights.

The Product may be or become hazardous. The Buyer should obtain Material Safety Data Sheets and Technical Data Sheets from
Huntsman containing detailed information on Product hazards and toxicity, together with proper shipping, handling and storage
procedures for the Product, and should comply with all applicable governmental laws, regulations and standards relating to the
handling, use, storage, distribution and disposal of, and exposure to the Product. Buyer shall also take all steps necessary to
adequately inform, warn and familiarize its employees, agents, direct and indirect customers and contractors who may handle or be
exposed to the Product of all hazards pertaining to and proper procedures for safe handling, use, storage, transportation and
disposal of and exposure to the Product, and the containers or equipment in which the Product may be handled, shipped or stored.

Please note that products may differ from country to country. If you have any queries, kindly contact your local Huntsman
representative.
Huntsman is a member of :
(Ecological Toxicological Association of
Dyes and Organic Pigments Manufacturers)

322004e—March 2017, Printed in China.

LANASET_poc_14-9-10.indd 40 14.09.2010 09:12:32

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