AS TG3 Working Thermometers
AS TG3 Working Thermometers
Working Thermometers
                   Calibration
                   Procedures
Published by:
International Accreditation New Zealand
626 Great South Road, Greenlane, Auckland 1005
Private Bag 28 908, Remuera, Auckland 1136, New Zealand
Telephone 64 9 525 6655
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Email: info@ianz.govt.nz
www.ianz.govt.nz
ISBN: 0908611 58 7
Contents Page
1 Introduction ............................................................... 3
7 Uncertainty of Measurement..................................... 6
    Tables
    1        Thermometers complying with BS 593:1989 ...............                         4
    2        Calibration at 36.5oC ....................................................      8
    3        Calibration at 37.5oC ....................................................      9
    4        Calibration at 36.9oC ....................................................      11
    5        Calibration at 37.1oC ....................................................      12
2
Working Thermometers – Calibration Requirements
break the bulb. If the broken thread sticks, tap the           5     Selection of a Reference
thermometer gently. Separation of the column of a                    Thermometer
reference thermometer can occur in transit and
requires the same treatment for repair. Spirit left in
the expansion chamber or near the top of the                   The selection of an appropriate reference
thermometer can be gently heated to distil it off.             thermometer will be influenced by the range of
                                                               temperature measurements that are to be made and
                                                               the uncertainty of measurement that it is required to
                                                               achieve.
Note: This table is not complete and BS 593 should be consulted for the full range of thermometers
specified.
4
Working Thermometers – Calibration Requirements
BS 1900:1976 provides similar information about             in a clean cloth with a mallet or a hammer and put
secondary reference thermometers whilst ASTM E1             into a thermos flask deep enough to immerse the
provides details of ASTM and IP thermometers. If an         thermometer to the correct level. Distilled water is
uncertainty of calibration of less than 0.02°C is           then added until the whitish ice colour disappears
required then a BS 1900 thermometer must be used.           and clear ice remains. Excess water should then be
                                                            drained off but the whitish colour should not return
Let us suppose that a laboratory intends to purchase        The ice point reading can now be taken providing
a reference thermometer with which to calibrate a           test thermometers are inserted to the 0°C mark or
group of its own working thermometers.           The        partial immersion mark, whichever is appropriate.
reference thermometers must first be submitted to an        Read the thermometer with a magnifying eyepiece
appropriate calibration agency to be calibrated.            and record the reading. Repeat that measurement at
                                                            least twice (preferably with another observer). An ice
The working thermometers in question will be used           point used for extended periods should have the
to measure the temperature of a water bath set at           excess water drained off occasionally.
44.5°C. They must be calibrated with an uncertainty
of ± 0.2°C.                                                 Any change in the temperature correction at the ice
                                                            point, which has occurred between the current
In general, the uncertainty of calibration of the           calibration and the initial calibration of the
reference thermometer should be a factor of five            thermometer made by the external calibration
smaller than the uncertainty of calibration that is         agency, should be applied at all other calibrated
required for the working thermometer. In this case,         points.
as an uncertainty of calibration of ± 0.2°C is required
for the working thermometer, the uncertainty of the         For example, a laboratory may perform an ice point
reference thermometer’s calibration must be ±               check on a reference thermometer which was
0.04°C (0.2x1/5).                                           subjected to a complete calibration at the time it was
                                                            purchased.
A good quality reference thermometer can generally
be calibrated with an uncertainty of one fifth of a         The initial calibration report may have indicated the
                                                            following results:
scale division so if an uncertainty of ± 0.04°C is
required this implies that the reference thermometer
must have scale divisions of 0.2°C (0.04x5).
                                                            Thermometer Reading (°C)        Correction (°C)
For the application under consideration, therefore, a
reference thermometer covering the region of
44.5°C, with graduations of at least 0.2°C is required.                -0.04                    +0.04
The BS 593 thermometer A70C/TOTAL listed above                          5.00                    +0.04
meets this specification.                                              10.00                    +0.06
                                                                       15.00                    +0.02
In summary, a reference thermometer must have                          20.00                    +0.06
scale divisions equal to, or less than, the uncertainty                25.00                    +0.08
of measurement required in the calibration of the                      30.00                    +0.06
working thermometer with which it is to be compared.                   35.00                    +0.04
                                                                       40.00                    +0.04
6      Ice Point Checks
Checks on the relaxation changes in both a                  To obtain the correct temperature the correction
reference and working thermometer should be made            must be added to (or subtracted from if negative) the
every six months on the ice point (0°C mark) of the         thermometer reading.
thermometer.      The ice point check need not,
however, be made on a working thermometer used              The laboratory might obtain three ice point readings
continually at one temperature (say 37°C). Such a           as follows:
thermometer would be more appropriately checked                      -0.02°C; -0.02°C; -0.02°C
at this temperature every six months against a single
reference thermometer (which itself would still             The new ice point reading is the average of the
require the ice point check).                               above, i.e. –0.02°C. The thermometer is, therefore,
                                                            reading low by 0.02°C and so the correction to be
An ice point is made with distilled water frozen in         applied is +0.02°C. This compares with the earlier
clean trays in a freezer. It is preferable for the ice to   calibration which gave a correction at 0°C of
be shaved in a food processor or purpose built              +0.04°C.     Corrections at all other temperature
shaver (low cost ice shavers are available from some        reported by the calibration agency must now be
department stores). Alternatively the ice is crushed        altered by (0.02 – 0.04) i.e. –0.02°C, thus:
                                                                                                                5
                                                                         Working Thermometers – Calibration requirements
6
Working Thermometers – Calibration Requirements
Ref 1 2 3 4 4 3 2 1 Ref
                                                          7
                                                                            Working Thermometers – Calibration requirements
Reference T1 T2 T3 T4
Correction to reference
from calibration
certificate +0.02°C                   +0.02
Therefore                average
temperature                           36.70
in bath at calibration =
Repeat this procedure for the results of the second test carried out at 37.5oC.
8
Working Thermometers – Calibration Requirements
Reference T1 T2 T3 T4
Correction to reference
thermometer                             +0.02
The procedure outlined above should be carried out at each point on the working thermometer’s scale that is to be
calibrated.
The corrections to a thermometer being used over a wide range of temperatures can be plotted against
temperature to produce a calibration curve. This procedure facilitates interpolation of corrections at intermediate
temperatures.
                                                                                                                  9
                                                                     Working Thermometers – Calibration requirements
8.3   Uncertainty of Calibration between ± 0.5°C         When the bath temperature is stable or slowly
      and ± 0.1°C                                        increasing begin reading from left to right and back
8.3.1 Equipment                                          recording the readings as you go. Tap each
(i)   A well stirred temperature-controlled water        thermometer gently before reading. The readings
      bath which is stable to at least half the          should be made in the following order:
      uncertainty of the calibration required. A very
      slowly rising temperature is desirable but in no         Ref 1, Test 1, 2, 3, 4, Ref 2, Ref 2, Test
      case should the temperature be falling during            4, 3, 2, 1, Ref 1
      calibration as sticking of the mercury will lead
      to calibration errors. Spatial gradients within    Repeat the measurements at approximately 37.1°C.
      the area of the bath being used for
      comparison should be checked before                If the working thermometer is to be calibrated over a
      calibration begins and must be less than half      wide range such as 0°C to 50°C, tests should be
      the uncertainty of test required.                  carried out at the ice point, 9.9°C and 10.1°C,
(ii)  Two calibrated reference thermometers, the         19.9°C and 20.1°C etc, up to 50°C.
      uncertainty of calibration of which should be at
      most ¼ of that of the uncertainty of calibration   8.3.3 Calculation of Corrections
      required for the thermometer under test.           Average the two sets of readings for each of the six
      These should be partial immersion if the           thermometers        and   correct  the    reference
      working thermometers are partial immersion         thermometer readings using data from their
      and/or if depth of immersion in the comparison     calibration certificates. Presume that at 37°C the
      bath is limited. Note that in Table 1 the          corrections required are +0.02°C for Reference 1
      calibration uncertainty of partial immersion       and +0.05°C for Reference 2. (These figures will
      thermometers is generally greater than that for    probably have been interpolated from corrections
      total immersion thermometers covering the          given by the reference thermometers’ calibration
      same range. The reference thermometers             certificates at 35°C and 40°C.)
      must be calibrated by an appropriate agency
      (see Appendix I).                                  The average of the two corrected reference
(iii) A magnifying eyepiece to reduce parallax           thermometers’ readings are now subtracted
      errors and improve readability.                    algebraically from the average for each test
(iv)  A flat plate, drilled to take both reference and   thermometer to give the error as shown in Tables 4
      working thermometers, which can be clamped         and 5.
      over the bath. O-rings or rubber grommets
      can be used to hold the thermometers in the
      plate at the correct height.
8.3.2 Procedure
Let us assume that a working thermometer is to be
compared with a reference thermometer at a
particular temperature (37°C say). Insert the
reference thermometers into the support plate with
no more than four working thermometers in the
order:
10
Working Thermometers – Calibration Requirements
Ref 1 T1 T2 T3 T4 Ref 2
Reference correction
from calibration
certificate =                       +0.02                                                       +0.05
Reference
Temperature (1)                     36.92                               Reference Temperature   36.91
                                                                                 (2)
Average of
references                          36.92
(Temperature in bath)
Correction (1) to
test thermometers
(change sign)                                      +0.02      +0.07      +0.17        -0.08
                                                                                                        11
                                                                            Working Thermometers – Calibration requirements
Ref 1 T1 T2 T3 T4 Ref 2
Correction to references
from calibration
certificates                   +0.02                                                                            +0.05
Reference
Temperature (1)                37.14                               Reference Temperature (2)                    37.10
Average of
References                     37.12
(Temperature in bath)
Correction (2) to
test thermometers
(Change sign)                                -0.03          +0.02            -0.18             -0.08
Average of corrections
(1) and (2) to test
thermometers at 37.0°C                        0.00          +0.04            0.00              -0.08
Round        to     0.1°C
(readability            of
thermometer)                                  0.0             0.0             0.0              -0.1
12
Working Thermometers – Calibration Requirements
The corrections to a thermometer being used over a                2)      A total immersion mercury in glass
wide range of temperatures can be plotted against                         thermometer (0-300°C divided to
temperature to produce a calibration curve. This                          0.5°C) in an oil bath at 105°C but
facilitates interpolation of corrections at intermediate                  immersed at the 30°C mark.
temperatures.
                                                                  k = 0.00016
8.4 Correction of Total Immersion
     Thermometers used at Partial Immersion                       N = 105°C - 30°C = 75°C
If it is not possible to fill the comparison bath
sufficiently to immerse a total immersion reference               Tc = 105°C
thermometer to the reading, then another small
thermometer should be attached to the stem of the                 Tu = 40°C (measured on the exposed scale)
thermometer about one-third of the way up the
exposed column. This will read (approximately) the                Correction      = 0.00016 x 75 (105-40)
average temperature of the emergent length of
                                                                                  = +0.78°C
mercury (or spirit). A correction now needs to be
                                                                                  = +0.8°C rounded
applied to the thermometer reading because of the
generally lower temperature of the mercury (or
                                                           These corrections are made in addition to any scale
spirit) not immersed. This correction is given by:
                                                           corrections required by the calibration certificate.
                      kN (Tc – Tu)
                                                           9     Packing for Safe Transport
Where k = 0.00016 for mercury
                                                           Reference thermometers for calibration should be
        = 0.001 for spirit
                                                           carried by hand if at all possible, but failing that
                                                           should be packed in such a way that the whole
         N = the number of degrees of the scale
                                                           length of the thermometer is supported. This can be
         exposed
                                                           achieved by cutting slots in a solid slab of
                                                           polystyrene foam or by supporting the thermometers
         Tc = the temperature of the calibration bath
                                                           between long slabs of foam rubber in a wooden box
         during the original calibration
                                                           with a screw-on lid. Some calibrating agencies have
                                                           shipping containers which can be procured for a
         Tu = the temperature of the exposed scale
                                                           deposit which is refundable on return of the box.
         during this calibration (given by the small
         thermometer attached to the stem)
k = 0.00016
Tc = 55°C
                                                                                                            13
                                                             Working Thermometers – Calibration requirements
                                                APPENDIX 1
                     Traceability to National Standards of Measurement (SI Units)
1. New Zealand
2. Overseas
14