Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI

2019/758

SAFETY DATA SHEET

Penguard Midcoat Comp B

SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product identifier
Product name : Penguard Midcoat Comp B
UFI : 4P80-E092-X002-NA11
Product code : 2081
Product description : Hardener.
Product type : Liquid.
Other means of : Not available.
identification
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use in coatings - Industrial use
Use in coatings - Professional use
1.3 Details of the supplier of the safety data sheet
Jotun A/S Jotun Paints (Europe) Ltd.
P.O.Box 2021 Stather Road
3202 Sandefjord Flixborough, Scunthorpe
Norway North Lincolnshire
Tel: + 47 33 45 70 00 DN15 8RR
Fax: +47 33 45 72 42 England
E-mail: SDSJotun@jotun.no
Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
1.4 Emergency telephone number
National advisory body/Poison Centre
Telephone number : Contact NHS Direct; phone 0845 4647 or 111. Open 24/7.
Supplier
Telephone number : +47 33 45 70 00 Jotun Norway (head office)
1 2081 Industrial applications, Professional applications, Used by spraying.

^(ValidationDate)
1

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Product definition : Mixture
Classification according to UK CLP/GHS
Flam. Liq. 3, H226
Skin Corr. 1B, H314
Eye Dam. 1, H318
Skin Sens. 1, H317
The product is classified as hazardous according to UK CLP Regulation SI 2019/720 as amended.
See Section 16 for the full text of the H statements declared above.
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

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Penguard Midcoat Comp B

SECTION 2: Hazards identification

Signal word : Danger.
Hazard statements : H226 - Flammable liquid and vapour.
H314 - Causes severe skin burns and eye damage.
H317 - May cause an allergic skin reaction.
Precautionary statements
General : Not applicable.
Prevention : P280 - Wear protective gloves, protective clothing and eye or face protection.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
P261 - Avoid breathing vapour.
Response : P304 + P310 - IF INHALED: Immediately call a POISON CENTER or doctor.
P301 + P310, P330, P331 - IF SWALLOWED: Immediately call a POISON
CENTER or doctor. Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353, P310 - IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER
or doctor.
P363 - Wash contaminated clothing before reuse.
P302 + P352 - IF ON SKIN: Wash with plenty of water.
P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention.
P305 + P351 + P338, P310 - IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor.
Storage : Not applicable.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional,
national and international regulations.
Supplemental label : Not applicable.
elements
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market and
use of certain dangerous
substances, mixtures and
articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of danger : Not applicable.

2.3 Other hazards

Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a
for PBT or vPvB according vPvB.
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : None known.
not result in classification

SECTION 3: Composition/information on ingredients

3.2 Mixtures : Mixture

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Penguard Midcoat Comp B

SECTION 3: Composition/information on ingredients

Product/ingredient name Identifiers % Classification Type
benzyl alcohol REACH #: ≥10 - ≤25 Acute Tox. 4, H302 [1]
01-2119492630-38 Acute Tox. 4, H332
EC: 202-859-9 Eye Irrit. 2, H319
CAS: 100-51-6
Index: 603-057-00-5
3,6-diazaoctanethylenediamin REACH #: ≤10 Acute Tox. 4, H302 [1]
01-2119487919-13 Acute Tox. 4, H312
EC: 203-950-6 Skin Corr. 1B, H314
CAS: 112-24-3 Eye Dam. 1, H318
Skin Sens. 1, H317
Aquatic Chronic 3,
H412
xylene REACH #: ≤5 Flam. Liq. 3, H226 [1] [2]
01-2119488216-32 Acute Tox. 4, H312
EC: 215-535-7 Acute Tox. 4, H332
CAS: 1330-20-7 Skin Irrit. 2, H315
Index: 601-022-00-9 Eye Irrit. 2, H319
STOT SE 3, H335
Asp. Tox. 1, H304
Aquatic Chronic 3,
H412
2-methylpropan-1-ol REACH #: ≤5 Flam. Liq. 3, H226 [1] [2]
01-2119484609-23 Skin Irrit. 2, H315
EC: 201-148-0 Eye Dam. 1, H318
CAS: 78-83-1 STOT SE 3, H335
Index: 603-108-00-1 STOT SE 3, H336
ethylbenzene REACH #: ≤3 Flam. Liq. 2, H225 [1] [2]
01-2119489370-35 Acute Tox. 4, H332
EC: 202-849-4 STOT RE 2, H373
CAS: 100-41-4 (hearing organs)
Index: 601-023-00-4 Asp. Tox. 1, H304
Aquatic Chronic 3,
H412
3-aminopropyldimethylamine REACH #: <1 Flam. Liq. 3, H226 [1]
01-2119486842-27 Acute Tox. 4, H302
EC: 203-680-9 Skin Corr. 1B, H314
CAS: 109-55-7 Eye Dam. 1, H318
Index: 612-061-00-6 Skin Sens. 1, H317
aminoethanolamine EC: 203-867-5 <0.3 Skin Corr. 1B, H314 [1]
CAS: 111-41-1 Eye Dam. 1, H318
Index: 603-194-00-0 Skin Sens. 1, H317
Repr. 1B, H360Df
STOT SE 3, H335
See Section 16 for
the full text of the H
statements declared
above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of
equivalent concern, or have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
Occupational exposure limits, if available, are listed in Section 8.

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Penguard Midcoat Comp B

SECTION 4: First aid measures

4.1 Description of first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately
flush eyes with plenty of water, occasionally lifting the upper and lower eyelids.
Check for and remove any contact lenses. Continue to rinse for at least 10 minutes.
Chemical burns must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove
victim to fresh air and keep at rest in a position comfortable for breathing. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
It may be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie,
belt or waistband. In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to be kept under
medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash with
plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly
by a physician. In the event of any complaints or symptoms, avoid further exposure.
Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out
mouth with water. Remove dentures if any. If material has been swallowed and the
exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Chemical burns must be treated
promptly by a physician. Never give anything by mouth to an unconscious person.
If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or
waistband.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it
is suspected that fumes are still present, the rescuer should wear an appropriate
mask or self-contained breathing apparatus. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing
thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Contains 3,6-diazaoctanethylenediamin, 3-aminopropyldimethylamine; N,N-dimethyl-1,3-diaminopropane, 2-

(2-aminoethylamino)ethanol. May produce an allergic reaction.
Over-exposure signs/symptoms

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SECTION 4: First aid measures

Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.

See toxicological information (Section 11)

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing : Recommended: alcohol-resistant foam, CO₂, powders, water spray.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture

Hazards from the : Flammable liquid and vapour. Runoff to sewer may create fire or explosion hazard.
substance or mixture In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion.
Hazardous combustion : Decomposition products may include the following materials:
products carbon dioxide
carbon monoxide
nitrogen oxides

5.3 Advice for firefighters

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilt material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapour or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

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Penguard Midcoat Comp B

SECTION 6: Accidental release measures

6.2 Environmental : Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
precautions and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

6.3 Methods and material for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble.
Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach the release from upwind. Prevent entry into
sewers, water courses, basements or confined areas. Wash spillages into an
effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilt product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.

6.4 Reference to other : See Section 1 for emergency contact information.

sections See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in
which this product is used. Do not get in eyes or on skin or clothing. Do not breathe
vapour or mist. Do not ingest. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage areas
and confined spaces unless adequately ventilated. Keep in the original container or
an approved alternative made from a compatible material, kept tightly closed when
not in use. Store and use away from heat, sparks, open flame or any other ignition
source. Use explosion-proof electrical (ventilating, lighting and material handling)
equipment. Use only non-sparking tools. Take precautionary measures against
electrostatic discharges. Empty containers retain product residue and can be
hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations. Store in a segregated and approved area. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section
10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidising materials. Keep
container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid
environmental contamination. See Section 10 for incompatible materials before handling or use.
Seveso Directive - Reporting thresholds
Danger criteria
Category Notification and MAPP Safety report threshold
threshold
P5c 5000 tonne 50000 tonne

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SECTION 7: Handling and storage

See Technical Data Sheet / packaging for further information.

7.3 Specific end use(s)

Recommendations : Not available.
Industrial sector specific : Not available.
solutions

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Occupational exposure limits
Product/ingredient name Exposure limit values
xylene EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 441 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.
TWA: 220 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
2-methylpropan-1-ol EH40/2005 WELs (United Kingdom (UK), 1/2020).
STEL: 231 mg/m³ 15 minutes.
STEL: 75 ppm 15 minutes.
TWA: 154 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
ethylbenzene EH40/2005 WELs (United Kingdom (UK), 1/2020). Absorbed
through skin.
STEL: 552 mg/m³ 15 minutes.
STEL: 125 ppm 15 minutes.
TWA: 100 ppm 8 hours.
TWA: 441 mg/m³ 8 hours.
Biological exposure indices
No exposure indices known.
Recommended monitoring : Reference should be made to appropriate monitoring standards. Reference to
procedures national guidance documents for methods for the determination of hazardous
substances will also be required.
DNELs/DMELs
Product/ingredient name Type Exposure Value Population Effects
benzyl alcohol DNEL Long term Oral 4 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 4 mg/kg General Systemic
bw/day population
DNEL Long term 5.4 mg/m³ General Systemic
Inhalation population
DNEL Long term Dermal 8 mg/kg Workers Systemic
bw/day
DNEL Short term Oral 20 mg/kg General Systemic
bw/day population
DNEL Short term Dermal 20 mg/kg General Systemic
bw/day population
DNEL Long term 22 mg/m³ Workers Systemic
Inhalation
DNEL Short term 27 mg/m³ General Systemic
Inhalation population
DNEL Short term Dermal 40 mg/kg Workers Systemic
bw/day
DNEL Short term 110 mg/m³ Workers Systemic
Inhalation
3,6-diazaoctanethylenediamin DNEL Short term 5380 mg/ Workers Systemic
Inhalation m³

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SECTION 8: Exposure controls/personal protection

DNEL Long term Dermal 0.57 mg/ Workers Systemic
kg bw/day
DNEL Long term 1 mg/m³ Workers Systemic
Inhalation
DNEL Long term Dermal 0.028 mg/ Workers Local
cm²
DNEL Short term Dermal 8 mg/kg General Systemic
bw/day population
[Consumers]
DNEL Short term 1600 mg/ General Systemic
Inhalation m³ population
[Consumers]
DNEL Short term Oral 20 mg/kg General Systemic
bw/day population
[Consumers]
DNEL Short term Dermal 1 mg/cm² General Local
population
[Consumers]
DNEL Long term Dermal 0.25 mg/ General Systemic
kg bw/day population
[Consumers]
DNEL Long term 0.29 mg/m³ General Systemic
Inhalation population
[Consumers]
DNEL Long term Oral 0.41 mg/ General Systemic
kg bw/day population
[Consumers]
DNEL Long term Dermal 0.43 mg/ General Local
cm² population
[Consumers]
xylene DNEL Long term 65.3 mg/m³ General Local
Inhalation population
DNEL Short term 260 mg/m³ General Local
Inhalation population
DNEL Short term 260 mg/m³ General Systemic
Inhalation population
DNEL Long term 221 mg/m³ Workers Local
Inhalation
DNEL Long term Oral 12.5 mg/ General Systemic
kg bw/day population
DNEL Long term 65.3 mg/m³ General Systemic
Inhalation population
DNEL Long term Dermal 125 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 212 mg/kg Workers Systemic
bw/day
DNEL Long term 221 mg/m³ Workers Systemic
Inhalation
DNEL Short term 442 mg/m³ Workers Local
Inhalation
DNEL Short term 442 mg/m³ Workers Systemic
Inhalation
2-methylpropan-1-ol DNEL Long term 55 mg/m³ General Systemic
Inhalation population
DNEL Long term 310 mg/m³ Workers Systemic
Inhalation
DNEL Long term 55 mg/m³ General Local
Inhalation population
DNEL Long term 310 mg/m³ Workers Local
Inhalation
ethylbenzene DNEL Long term Oral 1.6 mg/kg General Systemic
bw/day population
DNEL Long term 15 mg/m³ General Systemic
Inhalation population

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SECTION 8: Exposure controls/personal protection

DNEL Long term 77 mg/m³ Workers Systemic
Inhalation
DNEL Long term Dermal 180 mg/kg Workers Systemic
bw/day
DNEL Short term 293 mg/m³ Workers Local
Inhalation
DMEL Long term 442 mg/m³ Workers Local
Inhalation
DMEL Short term 884 mg/m³ Workers Systemic
Inhalation
3-aminopropyldimethylamine DNEL Long term 1.2 mg/m³ Workers Systemic
Inhalation
aminoethanolamine DNEL Long term Oral 0.1 mg/kg General Systemic
bw/day population
DNEL Long term 0.174 mg/ General Systemic
Inhalation m³ population
DNEL Long term 0.704 mg/ Workers Systemic
Inhalation m³
DNEL Long term Dermal 1 mg/kg General Systemic
bw/day population
DNEL Long term Dermal 2 mg/kg Workers Systemic
bw/day
PNECs
Product/ingredient name Compartment Detail Value Method Detail
benzyl alcohol Fresh water 1 mg/l -
Marine 0.1 mg/l -
Sewage Treatment 39 mg/l -
Plant
Fresh water sediment 5.27 mg/kg dwt -
Marine water sediment 0.527 mg/kg dwt -
Soil 0.456 mg/kg dwt -
3,6-diazaoctanethylenediamin Fresh water 190 μg/l -
Marine 38 μg/l -
Sewage Treatment 4.25 mg/l -
Plant
Fresh water sediment 95.9 mg/kg dwt -
Marine water sediment 19.2 mg/kg dwt -
Soil 19.1 mg/kg dwt -
Secondary Poisoning 0.18 mg/kg -
xylene Fresh water 0.327 mg/l -
Marine 0.327 mg/l -
Sewage Treatment 6.58 mg/l -
Plant
Fresh water sediment 12.46 mg/kg dwt -
Marine water sediment 12.46 mg/kg dwt -
Soil 2.31 mg/kg dwt -
2-methylpropan-1-ol Fresh water 0.4 mg/l -
Marine 0.04 mg/l -
Sewage Treatment 10 mg/l -
Plant
Fresh water sediment 1.52 mg/kg dwt -
Marine water sediment 0.152 mg/kg dwt -
Soil 0.0699 mg/kg dwt -
ethylbenzene Fresh water 0.1 mg/l -
Marine 0.01 mg/l -
Sewage Treatment 9.6 mg/l -
Plant
Fresh water sediment 13.7 mg/kg dwt -
Soil 2.68 mg/kg dwt -
Secondary Poisoning 20 mg/kg -

8.2 Exposure controls

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SECTION 8: Exposure controls/personal protection

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust
controls ventilation or other engineering controls to keep worker exposure to airborne
contaminants below any recommended or statutory limits. The engineering
controls also need to keep gas, vapour or dust concentrations below any lower
explosive limits. Use explosion-proof ventilation equipment.
Individual protection measures
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying to ISO 16321-1:2022 should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be
required instead.
Skin protection
Hand protection
There is no one glove material or combination of materials that will give unlimited resistance to any individual or
combination of chemicals.
The breakthrough time must be greater than the end use time of the product.
The instructions and information provided by the glove manufacturer on use, storage, maintenance and
replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove material.
Always ensure that gloves are free from defects and that they are stored and used correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical damage and poor
maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be applied once exposure has
occurred.
Gloves
Wear suitable gloves tested to ISO 374-1:2016.
May be used, gloves(breakthrough time) 4 - 8 hours: polyvinyl alcohol (PVA) (> 0.3 mm), nitrile rubber (> 0.4 mm),
neoprene (> 0.35 mm), butyl rubber (> 0.4 mm)
Recommended, gloves(breakthrough time) > 8 hours: 4H/Silver Shield® (> 0.07 mm), Teflon (> 0.35 mm), Viton®
(> 0.7 mm)
Not recommended, gloves(breakthrough time) < 1 hour: PVC (> 0.5 mm)

For right choice of glove materials, with focus on chemical resistance and time of penetration, seek advice by the
supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this product is the most
appropriate and takes into account the particular conditions of use, as included in the user's risk assessment.
Body protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use a
respirator according to EN 140. Use respiratory mask with charcoal and dust filter
when spraying this product, according to EN 14387 (as filter combination A2-P2). In
confined spaces, use compressed-air or fresh-air respiratory equipment. When use
of roller or brush, consider use of charcoalfilter.
Environmental exposure : Do not allow to enter drains or watercourses.
controls

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Penguard Midcoat Comp B

SECTION 9: Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

9.1 Information on basic physical and chemical properties

Appearance
Physical state : Liquid.
Colour : Colourless.
Odour : Characteristic.
Odour threshold : Not applicable.
Melting point/freezing point : Not applicable.
Initial boiling point and : Lowest known value: 108°C (226.4°F) (2-methylpropan-1-ol). Weighted average:
boiling range 189.69°C (373.4°F)
Flammability : Not applicable.
Upper/lower flammability or : 0.8 - 13%
explosive limits
Flash point : Closed cup: 25°C (77°F)
Auto-ignition temperature : Lowest known value: 337.78°C (640°F) (3,6-diazaoctanethylenediamin).
Decomposition temperature : Not available.
pH : Not applicable.
Viscosity : Kinematic (40°C): >20.5 mm2/s
Solubility(ies) :
Media Result
cold water Not soluble
hot water Not soluble
Partition coefficient: n-octanol/ : Not available.
water
Vapour pressure : Highest known value: <1.6 kPa (<12 mm Hg) (at 20°C) (2-methylpropan-1-ol).
Weighted average: 0.37 kPa (2.78 mm Hg) (at 20°C)
Evaporation rate : Highest known value: 0.84 (ethylbenzene) Weighted average: 0.27compared
with butyl acetate
Density : 0.97 g/cm³
Vapour density : Highest known value: 6 (Air = 1) (polyamide). Weighted average: 4.45 (Air = 1)
Explosive properties : Not available.
Oxidising properties : Not available.
Particle characteristics
Median particle size : Not applicable.

9.2 Other information

No additional information.

SECTION 10: Stability and reactivity

10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : Stable under recommended storage and handling conditions (see Section 7).
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition
products.
10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions:
oxidising agents, strong alkalis, strong acids.
10.6 Hazardous : Decomposition products may include the following materials: carbon monoxide,
decomposition products carbon dioxide, smoke, oxides of nitrogen.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Penguard Midcoat Comp B

SECTION 11: Toxicological information

11.1 Information on toxicological effects
There are no data available on the mixture itself. The mixture has been assessed following the conventional method
of the CLP Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2
and 3 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result
in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the
kidneys, liver and central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular
weakness, drowsiness and, in extreme cases, loss of consciousness.
Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with
the mixture may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption
through the skin.
If splashed in the eyes, the liquid may cause irritation and reversible damage.
Ingestion may cause nausea, diarrhea and vomiting.
This takes into account, where known, delayed and immediate effects and also chronic effects of components from
short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.

Contains 3,6-diazaoctanethylenediamin, 3-aminopropyldimethylamine; N,N-dimethyl-1,3-diaminopropane, 2-

(2-aminoethylamino)ethanol. May produce an allergic reaction.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
benzyl alcohol LD50 Oral Rat 1230 mg/kg -
3,6-diazaoctanethylenediamin LD50 Oral Mouse 1600 mg/kg -
LD50 Oral Mouse 38.5 mg/kg -
xylene LC50 Inhalation Vapour Rat 20 mg/l 4 hours
LD50 Oral Rat 4300 mg/kg -
TDLo Dermal Rabbit 4300 mg/kg -
2-methylpropan-1-ol LC50 Inhalation Vapour Rat 19200 mg/m³ 4 hours
LD50 Dermal Rabbit 3400 mg/kg -
LD50 Oral Rat 2460 mg/kg -
ethylbenzene LC50 Inhalation Vapour Rat - Male 17.8 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
3-aminopropyldimethylamine; LD50 Oral Rat 1870 mg/kg -
N,N-dimethyl-
1,3-diaminopropane
2-(2-aminoethylamino) LD50 Dermal Rat 2250 mg/kg -
ethanol
LD50 Oral Rat 3 g/kg -
Acute toxicity estimates
Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapours) (dusts
(ppm) (mg/l) and mists)
(mg/l)
Penguard Midcoat Comp B 3916.6 10989.6 N/A 51.2 N/A
benzyl alcohol 1230 N/A N/A 11 N/A
3,6-diazaoctanethylenediamin 500 1100 N/A N/A N/A
xylene 4300 1100 N/A 20 N/A
2-methylpropan-1-ol 2460 3400 N/A N/A N/A
ethylbenzene 3500 N/A N/A 17.8 N/A
3-aminopropyldimethylamine 1870 N/A N/A N/A N/A
aminoethanolamine 3000 2250 N/A N/A N/A
Irritation/Corrosion

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Penguard Midcoat Comp B

SECTION 11: Toxicological information

Product/ingredient name Result Species Score Exposure Observation
benzyl alcohol Eyes - Mild irritant Mammal - - - -
species
unspecified
3,6-diazaoctanethylenediamin Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Eyes - Severe irritant Rabbit - 49 milligrams -
Skin - Severe irritant Rabbit - 490 -
milligrams
Skin - Severe irritant Rabbit - 24 hours 5 -
milligrams
xylene Eyes - Mild irritant Rabbit - 87 milligrams -
Skin - Mild irritant Rat - 8 hours 60 -
microliters
2-methylpropan-1-ol Eyes - Irritant Mammal - - - -
species
unspecified
Skin - Mild irritant Mammal - - - -
species
unspecified
3-aminopropyldimethylamine; Eyes - Moderate irritant Rabbit - 5 milligrams -
N,N-dimethyl-
1,3-diaminopropane
2-(2-aminoethylamino)ethanol Eyes - Severe irritant Rabbit - 50 milligrams -
Skin - Mild irritant Rabbit - 445 -
milligrams
Sensitisation
Product/ingredient name Route of Species Result
exposure
3,6-diazaoctanethylenediamin skin Mammal - species Sensitising
unspecified
3-aminopropyldimethylamine; skin Mammal - species Sensitising
N,N-dimethyl- unspecified
1,3-diaminopropane
2-(2-aminoethylamino)ethanol skin Mammal - species Sensitising
unspecified
Mutagenicity
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Reproductive toxicity
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Teratogenicity
No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
xylene Category 3 - Respiratory tract
irritation
2-methylpropan-1-ol Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
2-(2-aminoethylamino)ethanol Category 3 - Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)

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Penguard Midcoat Comp B

SECTION 11: Toxicological information

Product/ingredient name Category Route of Target organs
exposure
ethylbenzene Category 2 - hearing organs
Aspiration hazard
Product/ingredient name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes severe burns. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Eye contact : Adverse symptoms may include the following:
pain
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Ingestion : Adverse symptoms may include the following:
stomach pains
General : Once sensitized, a severe allergic reaction may occur when subsequently exposed
to very low levels.
Other information : None identified.

SECTION 12: Ecological information

12.1 Toxicity
There are no data available on the mixture itself.
Do not allow to enter drains or watercourses.

The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is
not classified as hazardous to the environment, but contains substance(s) hazardous to the environment. See section
3 for details.
Product/ingredient name Result Species Exposure
3,6-diazaoctanethylenediamin Acute LC50 33900 μg/l Fresh water Daphnia - Water flea - Daphnia 48 hours
magna
xylene Acute LC50 8500 μg/l Marine water Crustaceans - Daggerblade 48 hours
grass shrimp - Palaemonetes
pugio
Acute LC50 13400 μg/l Fresh water Fish - Fathead minnow - 96 hours
Pimephales promelas
2-methylpropan-1-ol Chronic NOEC 4000 μg/l Fresh water Daphnia - Water flea - Daphnia 21 days
magna
ethylbenzene Acute EC50 7700 μg/l Marine water Algae - Diatom - Skeletonema 96 hours
costatum
Acute EC50 2.93 mg/l Daphnia 48 hours
Acute LC50 4.2 mg/l Fish 96 hours
Conclusion/Summary : No known significant effects or critical hazards.
12.2 Persistence and degradability
Conclusion/Summary : Not available.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Penguard Midcoat Comp B

SECTION 12: Ecological information

Product/ingredient name Aquatic half-life Photolysis Biodegradability
benzyl alcohol - - Readily
3,6-diazaoctanethylenediamin - - Not readily
xylene - - Readily
ethylbenzene - - Readily

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
benzyl alcohol 0.87 <100 low
3,6-diazaoctanethylenediamin -1.66 to -1.4 - low
xylene 3.12 8.1 to 25.9 low
2-methylpropan-1-ol 1 - low
ethylbenzene 3.6 - low
3-aminopropyldimethylamine; -0.352 - low
N,N-dimethyl-
1,3-diaminopropane
2-(2-aminoethylamino) -1.46 <0.2 low
ethanol

12.4 Mobility in soil

Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations

The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be
consulted for any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
Hazardous waste : Yes.
Waste catalogue
Waste code Waste designation
08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Type of packaging Waste catalogue
CEPE Guidelines 15 01 10* packaging containing residues of or contaminated by
hazardous substances

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Penguard Midcoat Comp B

SECTION 13: Disposal considerations

Special precautions : This material and its container must be disposed of in a safe way. Care should be
taken when handling emptied containers that have not been cleaned or rinsed out.
Empty containers or liners may retain some product residues. Vapour from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR/RID ADN IMDG IATA
14.1 UN number UN3469 UN3469 UN3469 UN3469

14.2 UN proper Paint related material, Paint related material, Paint related material, Paint related material,
shipping name flammable, corrosive flammable, corrosive flammable, corrosive flammable, corrosive
14.3 Transport 3 (8) 3 (8) 3 (8) 3 (8)
hazard class(es)

14.4 Packing III III III III

group
14.5 No. No. No. No.
Environmental
hazards
Additional information
ADR/RID : Hazard identification number 38
Tunnel code (D/E)
IMDG : Emergency schedules F-E, S-C
Segregation Group: 18 - Alkalis

14.6 Special precautions for : Transport within user’s premises: always transport in closed containers that are
user upright and secure. Ensure that persons transporting the product know what to do in
the event of an accident or spillage.

14.7 Transport in bulk : Not available.

according to IMO
instruments

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
UK (GB)/REACH
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.

Ozone depleting substances

Not listed.

Prior Informed Consent (PIC)

Not listed.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Penguard Midcoat Comp B

SECTION 15: Regulatory information

Persistent Organic Pollutants
Not listed.
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Seveso Directive
This product is controlled under the Seveso Directive.
Danger criteria
Category
P5c
EU regulations
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Air
Industrial emissions : Not listed
(integrated pollution
prevention and control) -
Water
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
15.2 Chemical safety : This product contains substances for which Chemical Safety Assessments are still
assessment required.

SECTION 16: Other information

Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms GB CLP = UK CLP (EC No 1272/2008) on the Classification, Labelling and
Packaging of Substances and Mixtures as amended by (EU Exit) Regulations 2019
No. 720 and amendments
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
EUH statement = GB CLP-specific Hazard statement
N/A = Not available
PBT = Persistent, Bioaccumulative and Toxic
PNEC = Predicted No Effect Concentration
RRN = REACH Registration Number
SGG = Segregation Group
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by UK REACH Regulation SI 2019/758
Penguard Midcoat Comp B

SECTION 16: Other information

Classification Justification
Flam. Liq. 3, H226 On basis of test data
Skin Corr. 1B, H314 Calculation method
Eye Dam. 1, H318 Calculation method
Skin Sens. 1, H317 Calculation method
Full text of abbreviated H statements
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H360Df May damage the unborn child. Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications
Acute Tox. 4 ACUTE TOXICITY - Category 4
Aquatic Chronic 3 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Eye Dam. 1 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Repr. 1B REPRODUCTIVE TOXICITY - Category 1B
Skin Corr. 1B SKIN CORROSION/IRRITATION - Category 1B
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1 SKIN SENSITISATION - Category 1
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE - Category 2
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE - Category 3
Date of printing : 21.04.2023
Date of issue/ Date of : 21.04.2023
revision
Date of previous issue : 30.03.2023
Version : 1.02
Notice to reader
The information in this document is given to the best of Jotun's knowledge, based on laboratory testing and
practical experience. Jotun's products are considered as semi-finished goods and as such, products are often
used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of the product
itself. Minor product variations may be implemented in order to comply with local requirements. Jotun
reserves the right to change the given data without further notice.

Date of issue/Date of revision : 21.04.2023 Date of previous issue : 30.03.2023 Version : 1.02 18/18