Name                                                     Class     Date
Assessment
  Chapter Test A
Chapter: Chemical Bonding
In the space provided, write the letter of the term or phrase that best completes each
statement or best answers each question.
______ 1. The charge on an ion is
          a. always positive.
          b. always negative.
          c. either positive or negative.
          d. zero.
______ 2. According to the octet rule, a calcium atom has a tendency to
          a. lose one electron.
          b. lose two electrons.
          c. gain one electron.
          d. gain two electrons.
______ 3. If a compound forms by ionic bonding, which is not true?
          a. A positively charged atom or group of atoms attracts a negatively
              charged atom or group of atoms.
          b. The net charge of the compound is zero.
          c. The compound contains just two atoms, each of opposite charge.
          d. Several ions group together in a tightly packed structure.
______ 4. The only property listed that is not characteristic of ionic compounds is
          a. high melting point.
          b. hardness.
          c. lack of crystal structure.
          d. brittleness.
______ 5. Which formula listed below represents a polyatomic ion?
          a. HCO3
          b. H2SO4
          c. Cl
          d. Na
______ 6. The crystal structure of an ionic compound depends on the
          a. sizes of the cations and anions.
          b. ratio of cations to anions.
          c. masses of the cation and anion.
          d. Both (a) and (b)
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Modern Chemistry                                        46                   Chapter Test
Name                                                                 Class            Date
  Chapter Test A, continued
______ 7. The melting points of ionic compounds are higher than the melting
          points of molecular compounds because
          a. ionic substances tend to vaporize at room temperature.
          b. ionic substances are brittle.
          c. attractive forces between ions are greater than the attractive forces
             between molecules.
          d. the numbers of positive and negative charges are equal in an ionic
             compound.
______ 8. A covalent bond is formed when two atoms
          a. share an electron with each other.
          b. share one or more pairs of electrons with each other.
          c. gain electrons.
          d. gain and lose electrons.
                                              0
                Potential Energy (kJ/mol)
                                            50
                                        100
                                        150
                                        200
                                        250
                                        300
                                        350
                                                  100    200   300        400   500
                                                        Bond length (pm)
______ 9. The molecule described by the figure above has an average bond
          length of
          a. 70 kJ/mol.
          b. 347 kJ/mol.
          c. 154 pm.
          d. 290 pm.
______10. The bond energy for the molecule described by the figure above is
          a. 70 kJ/mol.
          b. 347 kJ/mol.
          c. 154 pm.
          d. 290 pm.
Copyright © by Holt, Rinehart and Winston. All rights reserved.
Modern Chemistry                                                     47                      Chapter Test
Name                                                     Class    Date
  Chapter Test A, continued
______11. Two atoms will likely form a polar covalent bond if the
          electronegativity difference is
          a. 0.1.
          b. 1.0.
          c. 2.5.
          d. 4.0.
______12. In which of these compounds is the bond between the atoms not a
          nonpolar covalent bond?
          a. Cl2
          b. H2
          c. HCl
          d. O2
______13. Bonding in molecules or ions that cannot be represented adequately by
          a single Lewis structure is represented by
          a. resonance structures.
          b. covalent bonding.
          c. overlapping orbitals.
          d. double bonding.
______14. As the electronegativity difference between bonded atoms decreases,
          the bond becomes more
          a. covalent.
          b. ionic.
          c. metallic.
          d. Both (b) and (c)
______15. The boiling point of water, H2O, is higher than the boiling point of
          hydrogen sulfide, H2S, because water molecules are
          a. less polar and form hydrogen bonds.
          b. more covalent and form hydrogen bonds.
          c. ionic and form hydrogen bonds.
          d. more polar and form hydrogen bonds.
______16. Even though the following molecules contain polar bonds, the only
          polar molecule is
          a. CCl4.
          b. CO2.
          c. NH3.
          d. CH4.
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Modern Chemistry                                        48               Chapter Test
Name                                                       Class                                   Date
  Chapter Test A, continued
______ 17. As atoms bond with each other, they
           a. increase their potential energy, thus creating less stable
              arrangements of matter.
           b. decrease their potential energy, thus creating less stable
              arrangements of matter.
           c. increase their potential energy, thus creating more stable
              arrangements of matter.
           d. decrease their potential energy, thus creating more stable
              arrangements of matter.
______18. In which of the following compounds has the central atom not formed
          sp3 hybrid orbitals?
          a. CCl4
          b. CO2
          c. PCl3
          d. NH3
______19. When a carbon atom’s 2s and 2p orbitals hybridize, which orbitals do
          they form?
          a. four sp3
          b. two sp3
          c. four sp
          d. two sp
______20. Which is the correct Lewis structure for SiF4?
                          ••
                                                  ••
                                                                                    ••
                              F                       F                             F
                         ••
                              ••
                                                 ••
                                                      ••
                          —
                    ••             ••       ••                                                                ••
                                                                                                                ••
                                                                                                                 — F —F — Si
                                                                                                                     ••
               a. •• F  — Si — F ••     b. •• F  — F — Si          c. •• F — Si — F ••                  d. •• F
                                                                                                              ••
                     ••        ••             ••
                          —
                          F                       F                                 F
                         ••
                              ••
                                                 ••
                                                      ••
                          ••
                                                  ••
                                                                                 ••
______21. Which is the correct Lewis structure for C2H4?
                                                                                ••
                                                                                 C
                                                                               ••
                                                                                    ••
                        ••          ••
                                                                                —
                                                                           —H
                    •• H—           H  ••
               a.
                        ••
                            C — C — ••
                                                                   b. H— H—
                        ••
                     •• H —
                                  — •• •
                                                                            H
                                                                               —
                        ••
                                    H
                                    ••
                                        •
                                                                         C
                                                                            ••
                                                                                    ••
                                                                               ••
                                                                                              ••
                                                                       ••
                    H—                                                 H—                          ••
                          —H                                                  —C
                                                                     ••
                                                                          ••
                                                                                ••
               c.    C — C—                                        d. •• H — H—
                  H—        H                                        •• C —     H
                                                                                         ••
                                                                                                   ••
                                                                        ••
                                                                                          ••
Copyright © by Holt, Rinehart and Winston. All rights reserved.
Modern Chemistry                                           49                                                    Chapter Test
Name                                                     Class    Date
  Chapter Test A, continued
______22. Which type of hybrid orbitals do oxygen atoms form in water
          molecules?
          a. sp4
          b. sp3
          c. sp2
          d. sp
______23. Which type of bonding is characterized by overlapping orbitals that
          allow outer electrons of atoms to move about freely throughout the
          entire lattice?
          a. ionic
          b. covalent
          c. metallic
          d. multiple
______24. According to VSEPR theory, what is the shape of a molecule of CS2?
          a. linear
          b. bent
          c. trigonal-planar
          d. tetrahedral
______25. According to VSEPR theory, what is the shape of a molecule of NBr3?
          a. bent
          b. trigonal-planar
          c. tetrahedral
          d. trigonal-pyramidal
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Modern Chemistry                                        50               Chapter Test