Safety data sheet number D047
Version 1
Revision date 21/Jan/2014
Supercedes date
Safety Data Sheet
ANTIFOAM AGENT D47
1. Identification of the substance/preparation and of the Company/undertaking
1.1 Product identifier
Product name ANTIFOAM AGENT D47
Product code D047
1.2 Relevant identified uses of the substance or mixture and uses advised against
Recommended use Antifoam in oilfield applications
Uses advised against None known.
1.3 Details of the supplier of the safety data sheet
Supplier identification
Schlumberger Oilfield UK PLC
Victory House, Churchill Court
Manor Royal, Crawley
West Sussex RH10 9LU
SDS@slb.com
1.4 Emergency Telephone Number
Emergency telephone - (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44
(0) 1235 239 670, MiddleEastand Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600
2. Hazards Identification
2.1 Classification of the substance or mixture
Regulation (EC) No. 1272/2008
Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC
Health hazards Not classified
Environmental hazards Not classified
Physical Hazards Not classified
2.2 Label Elements
Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC
Contains
Classification according to EU Directives 67/548/EEC or 1999/45/EC
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ANTIFOAM AGENT D47
Safety data sheet number D047
Revision date 21/Jan/2014
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For the full text of the R-phrases and H-Statements mentioned in this Section, see Section 16.
2.3 Other data
Not classified as PBT/vPvB by current EU criteria
3. Composition/information on Ingredients
3.1 Substances
3.2 Mixtures
Comment
No classified ingredients, or those having occupational exposure limits, present above the level of disclosure.
4. First aid measures
4.1 Description of first-aid measures
Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation
develops or if breathing becomes difficult.
Ingestion Rinse mouth. Do not induce vomiting without medical advice. Never give anything by mouth
to an unconscious person. Get medical attention if symptoms occur.
Skin contact Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes. Get medical attention immediately if symptoms occur.
Eye contact Remove contact lenses. Promptly wash eyes with lots of water while lifting eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2 Most important symptoms and effects, both acute and delayed
General advice The severity of the symptoms described will vary dependant of the concentration and the
length of exposure. If adverse symptoms develops described the casualty should be
transferred to hospital as soon as possible.
Main symptoms
Inhalation Please see Section 11. Toxicological Information for further information.
Ingestion Please see Section 11. Toxicological Information for further information.
Skin contact Please see Section 11. Toxicological Information for further information.
Eye contact Please see Section 11. Toxicological Information for further information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician Treat symptomatically.
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ANTIFOAM AGENT D47
Safety data sheet number D047
Revision date 21/Jan/2014
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5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media
Water spray mist or foam, Alcohol Foam, CO2, Dry Chemical.
Extinguishing media which shall not be used for safety reasons
Do not use water jet.
5.2 Special hazards arising from the substance or mixture
Precautions against fire and explosion
None known.
Hazardous combustion products
When heated strongly or burned, oxides of carbon and harmful organic chemical fumes are released.
5.3 Advice for firefighters
Special protective equipment for fire-fighters
As in any fire, wear self-contained breathing apparatus and full protective gear.
Special Fire-Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. See also section 8.
6.2 Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
Environmental exposure controls
Avoid release to the environment.
6.3 Methods and materials for containment and cleaning up
Methods for Containment
Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal.
Methods for cleaning up
Absorb with earth, sand or other non-combustable material and transfer to containers for later disposal. After cleaning, flush away
traces with water.
6.4 Reference to other sections
See section 13 for more information.
7. Handling and Storage
7.1 Precautions for safe handling
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ANTIFOAM AGENT D47
Safety data sheet number D047
Revision date 21/Jan/2014
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Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Do not breathe vapors or
spray mist. Avoid spills and splashing during use.
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. When using do not smoke, eat or drink. Wash hands and
face before breaks and immediately after handling the product.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures/precautions Provide sufficient air exchange and/or exhaust in work rooms. Keep away from heat,
sparks, and flame.
Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Store away from
incompatibles. See also Section 10.5
Storage class Chemical storage.
Packaging material Use specially constructed containers only
7.3 Specific end uses
See also Section 1.2.
8. Exposure Controls/Personal Protection
8.1 Control parameters
Exposure limits The product does not contain any hazardous materials with occupational exposure limits
established.
Component Information
8.2 Exposure controls
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard
present and the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical
hazards associated with this product. Where this product is used in a mixture with other products or fluids, additional hazards may
be created and as such further assessment of risk may be required. The risk of exposure and need of respiratory protection will
vary from workplace to workplace and should be assessed by the user in each situation.
Engineering measures to
reduce exposure
Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into work environment.
Personal protective equipment
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ANTIFOAM AGENT D47
Safety data sheet number D047
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Eye protection It is good practice to wear goggles when handling any chemical. Safety glasses with
side-shields.
Hand protection Wear chemical resistant gloves such as nitrile or neoprene, Be aware that liquid may
penetrate the gloves. Frequent change is advisable.
Respiratory protection No personal respiratory protective equipment normally required, In case of insufficient
ventilation wear suitable respiratory equipment, Suitable mask with particle filter P3
(European Norm 143).
Skin and body protection Wear appropriate personal protective clothing to prevent skin contact, Eye wash and
emergency shower must be available at the work place.
Hygiene measures Wash hands before eating, drinking or smoking, Remove and wash contaminated clothing
before re-use.
9. Physical and Chemical Properties
9.1 Information on basic physical and chemical properties
Physical state Liquid
Appearance Viscous
Odour No information available
Colour Colourless
Odor threshold Not applicable
Property Values Remarks
pH
pH regulating agent No information available
Melting/freezing point
Boiling point/range
Flash Point 229 °C PMCC ASTM D-93
Evaporation rate
Flammability (solid, gas) Not Applicable
Flammability Limits in Air Not applicable
Upper flammability Limit No information available
Lower flammability limit No information available
Vapor pressure No information available
Vapor density No information available
Specific gravity No information available
bulk density No information available
Relative density 1 (@ 21.1°C).
Water solubility No data available
Solubility in other solvents No information available
Autoignition temperature No information available
Decomposition temperature No information available
Kinematic viscosity 414-496 cst
Viscosity, dynamic No information available
Log Pow Not determined
Explosive properties Not Applicable
Oxidizing properties None known.
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ANTIFOAM AGENT D47
Safety data sheet number D047
Revision date 21/Jan/2014
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9.2 Other information
Pour point < 0 °C
Molecular weight No information available
VOC content(%) None
Density VALUE No information available
10. Stability and Reactivity
10.1 Reactivity
No specific reactivity hazards associated with this product.
10.2 Chemical stability
Stable under normal temperature conditions and recommended use.
10.3 Possibility of Hazardous Reactions
Hazardous polymerization
Hazardous polymerisation does not occur.
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Strong oxidising agents.
10.6 Hazardous decomposition products
When heated strongly or burned, oxides of carbon and harmful organic chemical fumes are released.
11. Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
Product information Product does not present an acute toxicity hazard based on known or supplied information.
Inhalation Inhalation of vapours in high concentration may cause irritation of respiratory system.
Eye contact May cause slight irritation.
Skin contact Prolonged contact may cause redness and irritation.
Ingestion Ingestion may cause stomach discomfort.
Acute toxicity .
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ANTIFOAM AGENT D47
Safety data sheet number D047
Revision date 21/Jan/2014
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Sensitisation This product does not contain any components suspected to be sensitizing.
Mutagenic effects This substance has no evidence of mutagenic properties.
carcinogenicity This substance has no evidence of carcinogenic properties.
Reproductive toxicity None known.
Routes of exposure None known.
Routes of entry No route of entry noted.
Specific target organ toxicity (single Not classified.
exposure)
Specific target organ toxicity No information available.
(repeated exposure)
Aspiration hazard No hazard from product as supplied.
12. Ecological Information
12.1 Toxicity
Ecotoxicity effects
Contains no substances known to be hazardous to the environment or not degradable in waste water treatment plants.
Toxicity to algae
This product is not considered toxic to algae.
Toxicity to fish
Not considered toxic to fish.
Toxicity to daphnia and other aquatic invertebrates
Not considered toxic.
12.2 Persistence and degradability
READILY BIODEGRADABLE.
12.3 Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating.
12.4 Mobility in soil
Mobility
The product is insoluble and floats on water.
12.5 Results of PBT and vPvB assessment
Not classified as PBT/vPvB by current EU criteria.
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ANTIFOAM AGENT D47
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Revision date 21/Jan/2014
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12.6 Other adverse effects.
None known.
13. Disposal Considerations
13.1 Waste treatment methods
Waste from residues / unused Dispose of in accordance with local regulations.
products
Contaminated packaging Empty containers should be transported/delivered using a registered waste carrier for local
recycling or waste disposal.
EWC waste disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, but
application specific. Waste codes should be assigned by the user based on the application
for which the product was used. The following Waste Codes are only suggestions: EWC
waste disposal No: 16 03 06 - organic wastes other than those mentioned in 16 03 05
14. Transport Information
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,ADR/RID/ADG).
14.1 UN number
Not regulated
14.2 Proper shipping name
Not regulated
14.3. Hazard class(es)
Hazard class Not regulated
14.4 Packing group
Packing group Not regulated
14.5 Environmental hazard
Marine pollutant No
14.6 Special precautions
Not Applicable
14.7 Transport in bulk according to MARPOL 73/78 and IBC Code
Not Applicable Please contact SDS@slb.com for info regarding transport in Bulk.
15. Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Germany, Water Endangering Hazardous to water/Class 1
Classes (VwVwS)
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ANTIFOAM AGENT D47
Safety data sheet number D047
Revision date 21/Jan/2014
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Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals
Agency, amending Directive 1999/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC)
No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and
2000/21/EC, including amendments.
This safety data sheet complies with the requirements of Regulation (EC) No. 1272/2008.
International inventories
USA, Toxic Substances Control Act inventory (TSCA) Complies
European Union - EINECS and ELINCS Complies
Canada, Domestic Substance List (DSL) Complies
Philippines (PICCS) Complies
Inventory - Japan - Existing and New Chemicals list Complies
China (IECSC) Complies
Australia (AICS) Complies
Korea (KECL) Complies
Inventory - New Zealand - Inventory of Chemicals (NZIoC) Complies
15.2 Chemical Safety Report
No information available
16. Other Information
Prepared by Global Chemical Regulatory Compliance (GCRC)
Supercedes date
Revision date 21/Jan/2014
Version 1
HMIS classification
Health 1
Flammability 1
Physical 0
Text of R phrases mentioned in Section 3
none
Full text of H-Statements referred to under sections 2 and 3
No hazard from product as supplied
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ANTIFOAM AGENT D47
Safety data sheet number D047
Revision date 21/Jan/2014
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N/A - Not Applicable, N/D - Not Determined.
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guide for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
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