Safety Data Sheet

HEMPEL'S GALVOCOAT 16380

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 - Europe

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : HEMPEL'S GALVOCOAT 16380
Product identity : 1638019840
Product type : zinc cyclized rubber primer

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : metal industry, ships and shipyards.
Identified uses : Industrial applications, Used by spraying.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 19 September 2019
Date of previous issue : No previous validation.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
Aquatic Acute 1, H400 AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 1, H410 AQUATIC HAZARD (LONG-TERM) - Category 1
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Warning

Hazard statements : H226 - Flammable liquid and vapor.
H373 - May cause damage to organs through prolonged or repeated exposure.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention : Avoid breathing vapors, spray or mists. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
Response : Get medical attention if you feel unwell. In case of fire: Use alcohol-resistant foam to extinguish.
Storage : Keep cool.
Hazardous ingredients : white spirit
naphtha (petroleum), hydrodesulphurized heavy
Supplemental label elements :
Special packaging requirements
Containers to be fitted with child- Not applicable.
resistant fastenings :
Tactile warning of danger : Not applicable.

2.3 Other hazards

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

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SECTION 2: Hazards identification

Other hazards which do not result None known.
in classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
.

Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

zinc powder - zinc dust REACH #: 01-2119467174-37 ≥50 - ≤75 Aquatic Acute 1, H400 (M=1) - [1]
(stabilized) EC: 231-175-3 Aquatic Chronic 1, H410 (M=10)
CAS: 7440-66-6
white spirit REACH #: 01-2119458049-33 ≥5 - <10 Flam. Liq. 3, H226 - [1] [2]
EC: 265-191-7 STOT SE 3, H336
CAS: 64742-88-7 STOT RE 1, H372 (central nervous
Index: 649-405-00-X system (CNS)) (inhalation)
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
xylene REACH #: 01-2119488216-32 ≥5 - <10 Flam. Liq. 3, H226 C [1] [2]
EC: 215-535-7 Acute Tox. 4, H312
CAS: 1330-20-7 Acute Tox. 4, H332
Index: 601-022-00-9 Skin Irrit. 2, H315
zinc oxide REACH #: 01-2119463881-32 ≥3 - ≤5 Aquatic Acute 1, H400 (M=1) - [1]
EC: 215-222-5 Aquatic Chronic 1, H410 (M=1)
CAS: 1314-13-2
Index: 030-013-00-7
naphtha (petroleum), REACH #: 01-2119458049-33 ≥1 - ≤3 Flam. Liq. 3, H226 - [1] [2]
hydrodesulphurized heavy EC: 265-185-4 STOT SE 3, H336
CAS: 64742-82-1 STOT RE 1, H372 (central nervous
Index: 649-405-00-X system (CNS)) (inhalation)
Asp. Tox. 1, H304
Aquatic Chronic 2, H411
EUH066
ethylbenzene REACH #: 01-2119489370-35 ≥1 - ≤3 Flam. Liq. 2, H225 - [1] [2]
EC: 202-849-4 Acute Tox. 4, H332
CAS: 100-41-4 STOT RE 2, H373 (hearing organs)
Index: 601-023-00-4 Asp. Tox. 1, H304
See Section 16 for the full text of the H statements declared .
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy

SECTION 4: First aid measures

4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and
seek medical advice.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to
the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and delayed

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SECTION 4: First aid measures

Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been
ingested or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Extinguishing media : Recommended: Approved Class D extinguisher or smother with dry sand, dry clay or dry ground
limestone.
NOT TO BE USED: WATER. Risk of formation of very flammable and explosive vapours.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this
material must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides metal oxide/oxides

5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Do not use water. Violent reaction may occur. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid
breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or
without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if
released in large quantities.

6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.

6.4 Reference to other sections

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SECTION 6: Accidental release measures

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used. Open with care, danger of overpressure.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from incompatible materials and
ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids as well as of amines,
alcohols and water. No smoking. Prevent unauthorized access. Containers that are opened must be carefully resealed and kept upright to
prevent leakage.

7.3 Specific end use(s)

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Product/ingredient name Exposure limit values

white spirit EU OEL (Europe).

(ACGIH) TWA: 25 ppm 8 hours.
(ACGIH) TWA: 145 mg/m³ 8 hours.
xylene EU OEL (Europe, 2/2017). Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 221 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.
naphtha (petroleum), hydrodesulphurized heavy EU OEL (Europe, 2000).
TWA: 25 ppm 8 hours.
TWA: 145 mg/m³ 8 hours.
ethylbenzene EU OEL (Europe, 2/2017). Absorbed through skin.
STEL: 884 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 442 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels

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SECTION 8: Exposure controls/personal protection

Product/ingredient name Type Exposure Value Population Effects

zinc powder - zinc dust (stabilized) DNEL Long term Dermal 83.3 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 5 mg/m³ Workers Systemic
white spirit DNEL Long term Dermal 21 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 330 mg/m³ Workers Systemic
xylene DNEL Long term Inhalation 77 mg/m³ Workers Systemic
DNEL Long term Dermal 180 mg/kg bw/day Workers Systemic
zinc oxide DNEL Long term Inhalation 5 mg/m³ Workers Systemic
DNEL Long term Dermal 83 mg/kg bw/day Workers Systemic
ethylbenzene DNEL Long term Dermal 180 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 77 mg/m³ Workers Systemic

Predicted effect concentrations

Product/ingredient name Compartment Detail Value Method Detail
zinc powder - zinc dust (stabilized) Fresh water 20.6 µg/l -
Marine 6.1 µg/l -
Sewage Treatment Plant 52 µg/l -
Fresh water sediment 118 mg/kg dwt -
Marine water sediment 56.5 mg/kg dwt -
Soil 35.6 mg/kg dwt -
xylene Fresh water 0.327 mg/l -
Marine water 0.327 mg/l -
Fresh water sediment 12.46 mg/kg -
Marine water sediment 12.46 mg/kg -
Soil 2.31 mg/kg -
Sewage Treatment Plant 6.68 mg/l -
zinc oxide Fresh water 20.6 µg/l -
Marine 6.1 µg/l -
Sewage Treatment Plant 52 µg/l -
Marine water sediment 56.5 mg/kg dwt -
Soil 35.6 mg/kg dwt -

8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: safety glasses with side-shields.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:

Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®

May be used: nitrile rubber
Short term exposure: neoprene rubber, butyl rubber, natural rubber (latex), polyvinyl chloride (PVC)

Body protection : Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Respiratory protection : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. If
working areas have insufficient ventilation: When the product is applied by means that will not generate
an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A,
when grinding use particle filter of type P. Be sure to use an approved/certified respirator or equivalent.

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SECTION 8: Exposure controls/personal protection

Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : 419.85°C This is based on data for the following ingredient: Zinc
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 25°C (77°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Lower and upper explosive 0.6 - 7.6 vol %
(flammable) limits :
Vapor pressure : Testing not relevant or not possible due to nature of the product.
Vapor density : Testing not relevant or not possible due to nature of the product.
Specific gravity : 2.557 g/cm³
Solubility(ies) : Very slightly soluble in the following materials: cold water and hot water.
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Lowest known value: >220°C (>428°F) (white spirit).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Kinematic (room temperature): >7 cm2/s
Explosive properties : Explosive in the presence of the following materials or conditions: open flames, sparks and static
discharge and heat.
Slightly explosive in the presence of the following materials or conditions: moisture.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information

Solvent(s) % by weight : Weighted average: 16 %
Water % by weight : Weighted average: 0 %
VOC content : 403.1 g/l
TOC Content : Weighted average: 354 g/l
Solvent Gas : Weighted average: 0.08 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.

10.5 Incompatible materials

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SECTION 10: Stability and reactivity

Highly reactive or incompatible with the following materials: oxidizing materials and acids.
Reactive or incompatible with the following materials: reducing materials, organic materials, alkalis and moisture.

10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides metal oxide/oxides

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
zinc powder - zinc dust (stabilized) LC50 Inhalation Dusts and mists Rat 5.41 mg/l 4 hours
LD50 Oral Rat >2000 mg/kg -
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
LD50 Dermal Rabbit >4200 mg/kg -
LD50 Oral Rat 3523 mg/kg -
zinc oxide LC50 Inhalation Dusts and mists Rat >5.7 mg/l 4 hours
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Acute toxicity estimates
Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation
mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
HEMPEL'S GALVOCOAT 16380 33178.7 150812.3 1465.6
zinc powder - zinc dust (stabilized) 5.41
xylene 3523 1100 5000
ethylbenzene 3500 11
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
zinc powder - zinc dust (stabilized) Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
zinc oxide Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
Skin - Mild irritant Rabbit - 24 hours 500 milligrams
ethylbenzene Skin - Mild irritant Rabbit - 24 hours 15 milligrams
Respiratory - Mild irritant Rabbit - -
Eyes - Mild irritant Rabbit - -
Mutagenic effects
No known significant effects or critical hazards.

Carcinogenicity
No known significant effects or critical hazards.

Reproductive toxicity
No known significant effects or critical hazards.

Teratogenic effects
No known significant effects or critical hazards.

Specific target organ toxicity (single exposure)

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SECTION 11: Toxicological information

Product/ingredient name Category Route of exposure Target organs

white spirit Category 3 Not applicable. Narcotic effects
naphtha (petroleum), hydrodesulphurized heavy Category 3 Not applicable. Narcotic effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
white spirit Category 1 Inhalation central nervous system (CNS)
naphtha (petroleum), hydrodesulphurized heavy Category 1 Inhalation central nervous system (CNS)
ethylbenzene Category 2 Not determined hearing organs
Aspiration hazard
Product/ingredient name Result
white spirit ASPIRATION HAZARD - Category 1
naphtha (petroleum), hydrodesulphurized heavy ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Very toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
zinc powder - zinc dust (stabilized) Acute EC50 0.3 mg/l Marine water Algae 72 hours
Acute EC50 0.354 mg/l Fresh water Daphnia 48 hours
Acute LC50 0.238 - 0.269 mg/l Fresh water Fish 96 hours
Chronic EC10 27.3 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours
- Exponential growth phase
Chronic EC10 59.2 µg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 9 mg/l Fresh water Aquatic plants - Ceratophyllum 3 days
demersum
Chronic NOEC 178 µg/l Marine water Crustaceans - Palaemon elegans 21 days
Chronic NOEC 2.6 µg/l Fresh water Fish - Cyprinus carpio 4 weeks
white spirit Acute EC50 4.6 - 10 mg/l Algae 72 hours
zinc oxide Acute EC50 0.17 mg/l Algae - Pseudokirchneriella subcapitata 72 hours
- Exponential growth phase
Acute EC50 1 mg/l Daphnia - Pseudokirchneriella 48 hours
subcapitata - Exponential growth phase
Acute LC50 24600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours
ethylbenzene Chronic NOEC <1000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours

12.2 Persistence and degradability

Product/ingredient name Test Result Dose Inoculum
xylene - >60 % - Readily - 28 days - -
ethylbenzene - >70 % - Readily - 28 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability

xylene - - Readily
zinc oxide - - Not readily
ethylbenzene - - Readily

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
white spirit 3 - 7.3 - high
xylene 3.12 8.1 - 25.9 low
zinc oxide 2.2 60960 high
naphtha (petroleum), hydrodesulphurized heavy - 10 - 2500 high
ethylbenzene 3.6 - low

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SECTION 12: Ecological information

12.4 Mobility in soil
Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.

12.5 Results of PBT and vPvB assessment

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects

No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN1263 PAINT 3 III Yes. Viscous liquid exception

Class This class 3 viscous liquid
that is also environmentally
hazardous is not subject to
regulation in packagings up
to 5 L, provided the
packagings meet the general
provisions of 4.1.1.1, 4.1.1.2
and 4.1.1.4 to 4.1.1.8
according to 2.2.3.1.5.2.
Tunnel code (D/E)

IMDG UN1263 PAINT. (zinc powder - zinc dust 3 III Yes. Emergency schedules
Class (stabilized)) F-E, S-E
Viscous liquid
exception This class 3
viscous liquid that is also
environmentally
hazardous is not subject
to regulation in
packagings up to 5 L,
provided the packagings
meet the general
provisions of 4.1.1.1,
4.1.1.2 and 4.1.1.4 to
4.1.1.8 according to
2.3.2.5.

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SECTION 14: Transport information

IATA UN1263 PAINT 3 II Yes. The environmentally
Class hazardous substance mark
may appear if required by
other transportation
regulations.
Remarks The "viscosity
exemption" provisions do not
apply to air transport.

PG* : Packing group

Env.* : Environmental hazards

14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
Not applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b
E1: Hazardous to the aquatic environment - Acute 1 or Chronic 1

Yes.

SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H336 May cause drowsiness or dizziness.
H372 (inhalation) Causes damage to organs through prolonged or repeated exposure if inhaled.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS] : Acute Tox. 4, H312 ACUTE TOXICITY (dermal) - Category 4
Acute Tox. 4, H332 ACUTE TOXICITY (inhalation) - Category 4
Aquatic Acute 1, AQUATIC HAZARD (ACUTE) - Category 1
H400
Aquatic Chronic 1, AQUATIC HAZARD (LONG-TERM) - Category 1
H410
Aquatic Chronic 2, AQUATIC HAZARD (LONG-TERM) - Category 2
H411
Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1
EUH066 Repeated exposure may cause skin dryness or cracking.

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Safety Data Sheet
HEMPEL'S GALVOCOAT 16380

SECTION 16: Other information

Flam. Liq. 2, H225 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2
STOT RE 1, H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (inhalation) -
(inhalation) Category 1
STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) -
Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
AQUATIC HAZARD (ACUTE) - Category 1 Calculation method
AQUATIC HAZARD (LONG-TERM) - Category 1 Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

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Safe Use of Mixture Information
HEMPEL'S GALVOCOAT 16380

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor spray painting by professionals with efficient ventilation such as spray booth or local exhaust ventilation
This safe use information is : Professional spray painting, near-industrial setting - Level I
linked to HMP I/PW 01a
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
application hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Loading of application PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
equipment and handling hours (mechanical) room according to EN 166. tested to EN374.
of coated parts before ventilation
curing

Industrial application of PROC07 More than 4 Local exhaust Refer to Wear a respirator Use eye protection Wear suitable gloves
coatings by spraying hours ventilation relevant conforming to EN140 with according to EN 166. tested to EN374.
technical an assigned protection
standards factor of at least 10.

Film formation - force PROC04 More than 4 Enhanced 5 - 10 None None None
drying, stoving and other hours (mechanical) room
technologies ventilation

Cleaning PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Waste management PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 12/15
Safe Use of Mixture Information
HEMPEL'S GALVOCOAT 16380

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor painting by professionals by dipping or with brush, roller, putty knife etc. with enhanced ventilation or local exhaust ventilation (LEV)
This safe use information is : Professional low-energy painting, near-industrial setting - Level I
linked to HMP I/PW 02a
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
application hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Loading of application PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
equipment and handling hours (mechanical) room according to EN 166. tested to EN374.
of coated parts before ventilation
curing

Industrial application of PROC10 More than 4 Local exhaust Refer to Wear a respirator Use eye protection Wear suitable gloves
coatings by other than hours ventilation relevant conforming to EN140 with according to EN 166. tested to EN374.
spraying technical an assigned protection
standards factor of at least 10.

Film formation - force PROC04 More than 4 Enhanced 5 - 10 None None None
drying, stoving and other hours (mechanical) room
technologies ventilation

Cleaning PROC05 More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation

Waste management PROC08b More than 4 Enhanced 5 - 10 None Use eye protection Wear suitable gloves
hours (mechanical) room according to EN 166. tested to EN374.
ventilation
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 13/15
Safe Use of Mixture Information
HEMPEL'S GALVOCOAT 16380

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor spray painting by professionals for specialist applications, with respiratory protection
Wear suitable coveralls to prevent exposure to the skin. Wear chemical-resistant gloves in combination with 'basic' employee training.
This safe use information is : Professional spray painting, near-industrial setting - Level IV
linked to HMP I/PW 05d
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use
Range of application/Process : Assumes a good standard of occupational hygiene and safety management has been implemented.
conditions Avoid contact with contaminated tools and objects.

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemical-resistant
application hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Loading of application PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear chemical-resistant
equipment and handling hours according to EN 166. gloves (tested to EN374)
of coated parts before in combination with 'basic'
curing employee training.

Industrial application of PROC07 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemical-resistant
coatings by spraying hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Film formation - force PROC04 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
drying, stoving and other hours according to EN 166. tested to EN374.
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemical-resistant
hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Waste management PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear chemical-resistant
hours according to EN 166. gloves (tested to EN374)
in combination with 'basic'
employee training.
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 14/15
Safe Use of Mixture Information
HEMPEL'S GALVOCOAT 16380

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Outdoor painting by professionals by dipping or with brush, roller, putty knife etc.
This safe use information is : Professional low-energy painting, near-industrial setting - Level IV
linked to HMP I/PW 05d
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Outdoor use

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemical-resistant
application hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Loading of application PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear chemical-resistant
equipment and handling hours according to EN 166. gloves (tested to EN374)
of coated parts before in combination with 'basic'
curing employee training.

Professional application of PROC10 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemical-resistant
coatings by brush or roller hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Film formation - force PROC04 More than 4 Outdoors 3-5 None Use eye protection Wear suitable gloves
drying, stoving and other hours according to EN 166. tested to EN374.
technologies

Cleaning PROC05 More than 4 Outdoors 3-5 Wear a respirator Use eye protection Wear chemical-resistant
hours conforming to EN140 with according to EN 166. gloves (tested to EN374)
an assigned protection in combination with 'basic'
factor of at least 10. employee training.

Waste management PROC08b More than 4 Outdoors 3-5 None Use eye protection Wear chemical-resistant
hours according to EN 166. gloves (tested to EN374)
in combination with 'basic'
employee training.
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
Page: 15/15