Potato Starch Powder

Cambridge Commodities Chemwatch Hazard Alert Code: 1

Part Number: P16194 Issue Date: 01/03/2019
Version No: 2.2 Print Date: 18/10/2023
Safety data sheet according to REACH Regulation (EC) No 1907/2006, as amended by UK REACH Regulations SI 2019/758 S.REACH.GB.EN

SECTION 1 Identification of the substance / mixture and of the company / undertaking

1.1. Product Identifier

Product name Potato Starch Powder

Chemical Name starch

Synonyms Not Available
Chemical formula Not Applicable

Other means of
P16194
identification

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses Use according to manufacturer's directions.

Uses advised against No specific uses advised against are identified.

1.3. Details of the manufacturer or supplier of the safety data sheet

Registered company name Cambridge Commodities
Address Lancaster Way Business Park, Ely, Cambridgeshire Cambridgeshire CB6 3NX United Kingdom

Telephone +44 1353 667258

Fax Not Available

Website Not Available

Email enquiries@cambridgecommodities.com

1.4. Emergency telephone number

Association / Organisation Not Available
Emergency telephone
Not Available
numbers
Other emergency
Not Available
telephone numbers

Product code: P16194 Version No: 2.2 Page 1 of 20

S.REACH.GB.EN Lancaster Way Business Park
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) Ely, Cambridgeshire, CB6 3NX, UK.
Chemwatch: 9-637015 +44 (0) 1353 667258
Issue Date: 01/03/2019 info@c-c-l.com
Print Date: 18/10/2023 www.c-c-l.com

SECTION 2 Hazards identification

2.1. Classification of the substance or mixture

Classified according to
GB-CLP Regulation, UK SI
2019/720 and UK SI Not Applicable

2020/1567 [1]

2.2. Label elements

Hazard pictogram(s) Not Applicable

Signal word Not Applicable

Hazard statement(s)
Not Applicable

Supplementary statement(s)
Not Applicable

Precautionary statement(s) Prevention

Not Applicable

Precautionary statement(s) Response

Not Applicable

Precautionary statement(s) Storage

Not Applicable

Precautionary statement(s) Disposal

Not Applicable

2.3. Other hazards

Cumulative effects may result following exposure*.

May produce skin discomfort*.

REACH - Art.57-59: The mixture does not contain Substances of Very High Concern (SVHC) at the SDS print date.

SECTION 3 Composition / information on ingredients

3.1.Substances
See 'Composition on ingredients' in Section 3.2

3.2.Mixtures

Product code: P16194 Version No: 2.2 Page 2 of 20

S.REACH.GB.EN Lancaster Way Business Park
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) Ely, Cambridgeshire, CB6 3NX, UK.
Chemwatch: 9-637015 +44 (0) 1353 667258
Issue Date: 01/03/2019 info@c-c-l.com
Print Date: 18/10/2023 www.c-c-l.com

1. CAS No
2.EC No % Classified according to GB-CLP Regulation, UK SI SCL / M- Nanoform Particle
Name
3.Index No [weight] 2019/720 and UK SI 2020/1567 Factor Characteristics
4.REACH No
1. 9005-25-8
2.232-679-6 Not
100 starch Not Applicable Not Available
3.Not Available Available
4.Not Available

Legend: 1. Classified by Chemwatch; 2. Classification drawn from GB-CLP Regulation, UK SI 2019/720 and UK SI 2020/1567; 3.
Classification drawn from C&L; * EU IOELVs available; [e] Substance identified as having endocrine disrupting properties

SECTION 4 First aid measures

4.1. Description of first aid measures

If this product comes in contact with eyes:
Wash out immediately with water.
Eye Contact
If irritation continues, seek medical attention.
Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
If skin contact occurs:
Immediately remove all contaminated clothing, including footwear.
Skin Contact
Flush skin and hair with running water (and soap if available).
Seek medical attention in event of irritation.
If fumes, aerosols or combustion products are inhaled remove from contaminated area.
Inhalation
Other measures are usually unnecessary.
Immediately give a glass of water.
Ingestion
First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.

4.2 Most important symptoms and effects, both acute and delayed
See Section 11

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5 Firefighting measures

5.1. Extinguishing media

Water spray or fog.
Foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.

5.2. Special hazards arising from the substrate or mixture

Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may
Fire Incompatibility
result

Product code: P16194 Version No: 2.2 Page 3 of 20

S.REACH.GB.EN Lancaster Way Business Park
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) Ely, Cambridgeshire, CB6 3NX, UK.
Chemwatch: 9-637015 +44 (0) 1353 667258
Issue Date: 01/03/2019 info@c-c-l.com
Print Date: 18/10/2023 www.c-c-l.com

5.3. Advice for firefighters

Alert Fire Brigade and tell them location and nature of hazard.
Wear breathing apparatus plus protective gloves.
Prevent, by any means available, spillage from entering drains or water courses.
Use water delivered as a fine spray to control fire and cool adjacent area.
Fire Fighting
DO NOT approach containers suspected to be hot.
Cool fire exposed containers with water spray from a protected location.
If safe to do so, remove containers from path of fire.
Equipment should be thoroughly decontaminated after use.
Fire/Explosion Hazard For starch/ air mixtures
Starch is a class St1 dust at normal moisture level:
Minimum Ignition Temperature (MIE): >30 mJ at normal moisture level
Pmax 9.5 Bar
Kst 170 bar.m/s
Layer Ignition Temperature: >450 deg C
Autoignition Temperature: 170 deg C (above this temperature starch will self-heat)

Dust Explosion Hazard Class 1

Dusts fall into one of three Kst* classes. Class 1 dusts; Kst 1-200 m3/sec; Class 2 dusts; 201-299 m3/sec. Class 3 dusts; Kst 300
or more. Most agricultural dusts (grains, flour etc.) are Class 1; pharmaceuticals and other speciality chemicals are typically
Class 1 or 2; most unoxidised metallic dusts are Class 3. The higher the Kst, the more energetically the dust will burn and the
greater is the explosion risk and the greater is the speed of the explosion..
Standard test conditions, used to derive the Kst, are representative of industrial conditions, but do not represent and absolute
worst case. Increased levels of turbulence increase the speed of the explosion dramatically.

* Kst - a normalised expression of the burning dust pressure rise rate over time.
Dusts with Minimum Ignition Energies (MIEs) ranging between 20 and 100 mJ may be sensitive to ignition. They require that:
· plant is grounded
· personnel might also need to be grounded
· the use of high resistivity materials (such as plastics) should be restricted or avoided during handling or in
packaging
The majority of ignition accidents occur within or below this range.
The MIE of a dust/air mix depends on the particle size the water content and the temperature of the dust. The finer and the dryer
the dust the lower the MIE. Higher temperatures cause lower MIE and an increased risk of dust explosion.
Quoted values for MIE generally are only representative. Characteristics may change depending upon the process and
conditions of use or any changes made to the dust during use, including further grinding or mixing with other products. In order to
obtain more specific data for dust, as used, it is recommended that further characterisation testing.is performed.
Combustible solid which burns but propagates flame with difficulty; it is estimated that most organic dusts are combustible
(circa 70%) - according to the circumstances under which the combustion process occurs, such materials may cause fires
and / or dust explosions.
Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended
in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including
secondary explosions).
Avoid generating dust, particularly clouds of dust in a confined or unventilated space as dusts may form an explosive mixture
with air, and any source of ignition, i.e. flame or spark, will cause fire or explosion. Dust clouds generated by the fine grinding
of the solid are a particular hazard; accumulations of fine dust (420 micron or less) may burn rapidly and fiercely if ignited -
particles exceeding this limit will generally not form flammable dust clouds; once initiated, however, larger particles up to
1400 microns diameter will contribute to the propagation of an explosion.
In the same way as gases and vapours, dusts in the form of a cloud are only ignitable over a range of concentrations; in
principle, the concepts of lower explosive limit (LEL) and upper explosive limit (UEL) are applicable to dust clouds but only
the LEL is of practical use; - this is because of the inherent difficulty of achieving homogeneous dust clouds at high
temperatures (for dusts the LEL is often called the "Minimum Explosible Concentration", MEC).

Product code: P16194 Version No: 2.2 Page 4 of 20

S.REACH.GB.EN Lancaster Way Business Park
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) Ely, Cambridgeshire, CB6 3NX, UK.
Chemwatch: 9-637015 +44 (0) 1353 667258
Issue Date: 01/03/2019 info@c-c-l.com
Print Date: 18/10/2023 www.c-c-l.com

When processed with flammable liquids/vapors/mists,ignitable (hybrid) mixtures may be formed with combustible dusts.
Ignitable mixtures will increase the rate of explosion pressure rise and the Minimum Ignition Energy (the minimum amount of
energy required to ignite dust clouds - MIE) will be lower than the pure dust in air mixture. The Lower Explosive Limit (LEL) of
the vapour/dust mixture will be lower than the individual LELs for the vapors/mists or dusts.
A dust explosion may release of large quantities of gaseous products; this in turn creates a subsequent pressure rise of
explosive force capable of damaging plant and buildings and injuring people.
Usually the initial or primary explosion takes place in a confined space such as plant or machinery, and can be of sufficient
force to damage or rupture the plant. If the shock wave from the primary explosion enters the surrounding area, it will disturb
any settled dust layers, forming a second dust cloud, and often initiate a much larger secondary explosion. All large scale
explosions have resulted from chain reactions of this type.
Dry dust can be charged electrostatically by turbulence, pneumatic transport, pouring, in exhaust ducts and during transport.
Build-up of electrostatic charge may be prevented by bonding and grounding.
Powder handling equipment such as dust collectors, dryers and mills may require additional protection measures such as
explosion venting.
All movable parts coming in contact with this material should have a speed of less than 1-meter/sec.
A sudden release of statically charged materials from storage or process equipment, particularly at elevated temperatures
and/ or pressure, may result in ignition especially in the absence of an apparent ignition source.
One important effect of the particulate nature of powders is that the surface area and surface structure (and often moisture
content) can vary widely from sample to sample, depending of how the powder was manufactured and handled; this means
that it is virtually impossible to use flammability data published in the literature for dusts (in contrast to that published for
gases and vapours).
Autoignition temperatures are often quoted for dust clouds (minimum ignition temperature (MIT)) and dust layers (layer
ignition temperature (LIT)); LIT generally falls as the thickness of the layer increases.
Combustion products include:
,
carbon monoxide (CO)
,
carbon dioxide (CO2)
,
other pyrolysis products typical of burning organic material.
May emit clouds of acrid smoke
May emit corrosive fumes.

SECTION 6 Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

See section 8

6.2. Environmental precautions

See section 12

6.3. Methods and material for containment and cleaning up

Clean up all spills immediately.
Avoid breathing dust and contact with skin and eyes.
Wear protective clothing, gloves, safety glasses and dust respirator.
Use dry clean up procedures and avoid generating dust.
Minor Spills Sweep up, shovel up or
Vacuum up (consider explosion-proof machines designed to be grounded during storage and use).
Place spilled material in clean, dry, sealable, labelled container.

Major Spills Moderate hazard.

Product code: P16194 Version No: 2.2 Page 5 of 20

S.REACH.GB.EN Lancaster Way Business Park
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) Ely, Cambridgeshire, CB6 3NX, UK.
Chemwatch: 9-637015 +44 (0) 1353 667258
Issue Date: 01/03/2019 info@c-c-l.com
Print Date: 18/10/2023 www.c-c-l.com

CAUTION: Advise personnel in area.

Alert Emergency Services and tell them location and nature of hazard.
Control personal contact by wearing protective clothing.
Prevent, by any means available, spillage from entering drains or water courses.
Recover product wherever possible.
IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and place in sealed plastic bags or other
containers for disposal. IF WET: Vacuum/shovel up and place in labelled containers for disposal.
ALWAYS: Wash area down with large amounts of water and prevent runoff into drains.
If contamination of drains or waterways occurs, advise Emergency Services.

6.4. Reference to other sections

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 Handling and storage

7.1. Precautions for safe handling

Safe handling Avoid all personal contact, including inhalation.
Wear protective clothing when risk of exposure occurs.
Use in a well-ventilated area.
Prevent concentration in hollows and sumps.
DO NOT enter confined spaces until atmosphere has been checked.
DO NOT allow material to contact humans, exposed food or food utensils.
Avoid contact with incompatible materials.
When handling, DO NOT eat, drink or smoke.
Keep containers securely sealed when not in use.
Avoid physical damage to containers.
Always wash hands with soap and water after handling.
Work clothes should be laundered separately. Launder contaminated clothing before re-use.
Use good occupational work practice.
Observe manufacturer's storage and handling recommendations contained within this SDS.
Atmosphere should be regularly checked against established exposure standards to ensure safe working conditions are
maintained.
Organic powders when finely divided over a range of concentrations regardless of particulate size or shape and suspended
in air or some other oxidizing medium may form explosive dust-air mixtures and result in a fire or dust explosion (including
secondary explosions)
Minimise airborne dust and eliminate all ignition sources. Keep away from heat, hot surfaces, sparks, and flame.
Establish good housekeeping practices.
Remove dust accumulations on a regular basis by vacuuming or gentle sweeping to avoid creating dust clouds.
Use continuous suction at points of dust generation to capture and minimise the accumulation of dusts. Particular attention
should be given to overhead and hidden horizontal surfaces to minimise the probability of a "secondary" explosion. According
to NFPA Standard 654, dust layers 1/32 in.(0.8 mm) thick can be sufficient to warrant immediate cleaning of the area.
Do not use air hoses for cleaning.
Minimise dry sweeping to avoid generation of dust clouds. Vacuum dust-accumulating surfaces and remove to a chemical
disposal area. Vacuums with explosion-proof motors should be used.
Control sources of static electricity. Dusts or their packages may accumulate static charges, and static discharge can be a
source of ignition.
Solids handling systems must be designed in accordance with applicable standards (e.g. NFPA including 654 and 77) and
other national guidance.
Do not empty directly into flammable solvents or in the presence of flammable vapors.
The operator, the packaging container and all equipment must be grounded with electrical bonding and grounding systems.
Plastic bags and plastics cannot be grounded, and antistatic bags do not completely protect against development of static
charges.

Product code: P16194 Version No: 2.2 Page 6 of 20

S.REACH.GB.EN Lancaster Way Business Park
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) Ely, Cambridgeshire, CB6 3NX, UK.
Chemwatch: 9-637015 +44 (0) 1353 667258
Issue Date: 01/03/2019 info@c-c-l.com
Print Date: 18/10/2023 www.c-c-l.com

Empty containers may contain residual dust which has the potential to accumulate following settling. Such dusts may explode in
the presence of an appropriate ignition source.
Do NOT cut, drill, grind or weld such containers.
In addition ensure such activity is not performed near full, partially empty or empty containers without appropriate workplace
safety authorisation or permit.
Fire and explosion
See section 5
protection

Store in original containers.

Keep containers securely sealed.
Store in a cool, dry area protected from environmental extremes.
Store away from incompatible materials and foodstuff containers.
Protect containers against physical damage and check regularly for leaks.
Other information Observe manufacturer's storage and handling recommendations contained within this SDS.
For major quantities:
Consider storage in bunded areas - ensure storage areas are isolated from sources of community water (including
stormwater, ground water, lakes and streams}.
Ensure that accidental discharge to air or water is the subject of a contingency disaster management plan; this may require
consultation with local authorities.

7.2. Conditions for safe storage, including any incompatibilities

Lined metal can, lined metal pail/ can.
Plastic pail.
Suitable container Polyliner drum.
Packing as recommended by manufacturer.
Check all containers are clearly labelled and free from leaks.
Dilute solutions of all sugars are subject to fermentation, either by yeast or by other microorganisms or enzymes derived from
these, producing gases which can pressurise and burst sealed containers.
Some microorganisms will produce hydrogen or methane, adding a fire and explosion hazard.
Reducing sugar-based material.
Autooxidation of reducing sugars may produce up to 3000 ppm carbon monoxide under moderately alkaline conditions. High pH
aqueous solutions of saccharides (aldoses, ketoses) or polysaccharides based on these sugars may generate hazardous
atmospheres in confined spaces.
Reducing sugars contain an aldehyde or free hemiacetal in the open-chain form. Sugars with ketone groups in their open chain
form are capable of isomerising via a series of tautomeric shifts to produce an aldehyde group in solution. Therefore, ketone-
Storage incompatibility
bearing sugars like fructose are considered reducing sugars but it is the isomer containing an aldehyde group which is reducing
since ketones cannot be oxidized without decomposition of the sugar.
Many disaccharides, like lactose and maltose, also have a reducing form, as one of the two units may have an open-chain form
with an aldehyde group. However, sucrose and trehalose, in which the anomeric carbons of the two units are linked together, are
non-reducing disaccharides since neither of the rings is capable of opening.
In glucose polymers such as starch and starch-derivatives like glucose syrup, maltodextrin and dextrin the macromolecule begins
with a reducing sugar, a free aldehyde. More hydrolysed starch contains more reducing sugars. The percentage of reducing
sugars present in these starch derivatives is called dextrose equivalent (DE).
Avoid reaction with oxidising agents
Hazard categories in
accordance with
Not Available
Regulation (EC) No
1272/2008
Qualifying quantity Not Available
(tonnes) of dangerous
substances as referred to
in Article 3(10) for the
application of

Product code: P16194 Version No: 2.2 Page 7 of 20

S.REACH.GB.EN Lancaster Way Business Park
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) Ely, Cambridgeshire, CB6 3NX, UK.
Chemwatch: 9-637015 +44 (0) 1353 667258
Issue Date: 01/03/2019 info@c-c-l.com
Print Date: 18/10/2023 www.c-c-l.com

7.3. Specific end use(s)

See section 1.2

SECTION 8 Exposure controls / personal protection

8.1. Control parameters

DNELs PNECs
Ingredient
Exposure Pattern Worker Compartment

Not Available Not Available Not Available

* Values for General Population

Occupational Exposure Limits (OEL)

INGREDIENT DATA

Source Ingredient Material name TWA STEL Peak Notes

UK Workplace Exposure
starch Starch: respirable 4 mg/m3 Not Available Not Available Not Available
Limits (WELs).
UK Workplace Exposure
starch Starch: total inhalable 10 mg/m3 Not Available Not Available Not Available
Limits (WELs).

Emergency Limits

Ingredient TEEL-1 TEEL-2 TEEL-3

starch 30 mg/m3 330 mg/m3 2,000 mg/m3

Ingredient Original IDLH Revised IDLH

starch Not Available Not Available

8.2. Exposure controls

8.2.1. Appropriate Assess operations based upon available dust explosion information to determine the suitability of preventative or protective
engineering controls systems as precautionary measures against possible dust explosions. If prevention is not possible, consider protection by use of
containment, venting or suppression of dust handling equipment. Where explosion venting is considered to be the most
appropriate method of protection, vent areas should preferably be calculated based on Kst rather than an St value. If nitrogen
purging is considered as the protective system, it must operate with an oxygen level below the limiting oxygen concentration. The
system should include an oxygen monitoring and shut-down facility in the event of excessive oxygen being detected.

The maximum surface temperature of enclosures potentially exposed to this material should be based on values obtained by
taking 2/3 of the minimum ignition temperature (MIE) of the dust cloud. The effect of dust layers should be reviewed.

An isolated (insulated) human body can readily produce electrostatic discharges in excess of 50 mJ, but have been recorded up
to 100 mJ.
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.

Product code: P16194 Version No: 2.2 Page 8 of 20

S.REACH.GB.EN Lancaster Way Business Park
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) Ely, Cambridgeshire, CB6 3NX, UK.
Chemwatch: 9-637015 +44 (0) 1353 667258
Issue Date: 01/03/2019 info@c-c-l.com
Print Date: 18/10/2023 www.c-c-l.com

Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if
designed properly. The design of a ventilation system must match the particular process and chemical or contaminant in use.
Employers may need to use multiple types of controls to prevent employee overexposure.
Local exhaust ventilation is required where solids are handled as powders or crystals; even when particulates are relatively
large, a certain proportion will be powdered by mutual friction.
Exhaust ventilation should be designed to prevent accumulation and recirculation of particulates in the workplace.
If in spite of local exhaust an adverse concentration of the substance in air could occur, respiratory protection should be
considered. Such protection might consist of:
(a): particle dust respirators, if necessary, combined with an absorption cartridge;
(b): filter respirators with absorption cartridge or canister of the right type;
(c): fresh-air hoods or masks
Build-up of electrostatic charge on the dust particle, may be prevented by bonding and grounding.
Powder handling equipment such as dust collectors, dryers and mills may require additional protection measures such as
explosion venting.
Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture
velocities" of fresh circulating air required to efficiently remove the contaminant.

Type of Contaminant: Air Speed:

direct spray, spray painting in shallow booths, drum filling, conveyer loading, crusher dusts, gas 1-2.5 m/s (200-
discharge (active generation into zone of rapid air motion) 500 ft/min)
grinding, abrasive blasting, tumbling, high speed wheel generated dusts (released at high initial 2.5-10 m/s (500-
velocity into zone of very high rapid air motion). 2000 ft/min)

Within each range the appropriate value depends on:

Lower end of the range Upper end of the range

1: Room air currents minimal or favourable to capture 1: Disturbing room air currents
2: Contaminants of low toxicity or of nuisance value only 2: Contaminants of high toxicity
3: Intermittent, low production. 3: High production, heavy use
4: Large hood or large air mass in motion 4: Small hood-local control only

Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity
generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the
extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the
extraction fan, for example, should be a minimum of 4-10 m/s (800-2000 ft/min) for extraction of crusher dusts generated 2
metres distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction
apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are
installed or used.

8.2.2. Individual protection

measures, such as
personal protective
equipment

Safety glasses with side shields.

Chemical goggles. [AS/NZS 1337.1, EN166 or national equivalent]
Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy
document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. This should
Eye and face protection include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience.
Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the
event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should
be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers
have washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].

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S.REACH.GB.EN Lancaster Way Business Park
Safety Data Sheet (Conforms to Annex II of REACH (1907/2006) - Regulation 2020/878) Ely, Cambridgeshire, CB6 3NX, UK.
Chemwatch: 9-637015 +44 (0) 1353 667258
Issue Date: 01/03/2019 info@c-c-l.com
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Skin protection See Hand protection below

The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from
manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material
can not be calculated in advance and has therefore to be checked prior to the application.
The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and has to be
observed when making a final choice.
Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands
should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.
Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:
· frequency and duration of contact,
· chemical resistance of glove material,
· glove thickness and
· dexterity
Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national equivalent).
· When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time
greater than 240 minutes according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
· When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes
according to EN 374, AS/NZS 2161.10.1 or national equivalent) is recommended.
· Some glove polymer types are less affected by movement and this should be taken into account when considering gloves for
long-term use.
· Contaminated gloves should be replaced.
As defined in ASTM F-739-96 in any application, gloves are rated as:
· Excellent when breakthrough time > 480 min
· Good when breakthrough time > 20 min
Hands/feet protection
· Fair when breakthrough time < 20 min
· Poor when glove material degrades
For general applications, gloves with a thickness typically greater than 0.35 mm, are recommended.
It should be emphasised that glove thickness is not necessarily a good predictor of glove resistance to a specific chemical, as the
permeation efficiency of the glove will be dependent on the exact composition of the glove material. Therefore, glove selection
should also be based on consideration of the task requirements and knowledge of breakthrough times.
Glove thickness may also vary depending on the glove manufacturer, the glove type and the glove model. Therefore, the
manufacturers technical data should always be taken into account to ensure selection of the most appropriate glove for the task.
Note: Depending on the activity being conducted, gloves of varying thickness may be required for specific tasks. For example:
· Thinner gloves (down to 0.1 mm or less) may be required where a high degree of manual dexterity is needed. However, these
gloves are only likely to give short duration protection and would normally be just for single use applications, then disposed of.
· Thicker gloves (up to 3 mm or more) may be required where there is a mechanical (as well as a chemical) risk i.e. where there
is abrasion or puncture potential
Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a
non-perfumed moisturiser is recommended.
Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids,
where abrasive particles are not present.
polychloroprene.
nitrile rubber.
butyl rubber.
fluorocaoutchouc.
polyvinyl chloride.
Gloves should be examined for wear and/ or degradation constantly.
Body protection See Other protection below
Overalls.
P.V.C apron.
Other protection Barrier cream.
Skin cleansing cream.
Eye wash unit.

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S.REACH.GB.EN Lancaster Way Business Park
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Chemwatch: 9-637015 +44 (0) 1353 667258
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Respiratory protection
Type -P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

Required Minimum Protection Factor Half-Face Respirator Full-Face Respirator Powered Air Respirator
P1 - PAPR-P1
up to 10 x ES
Air-line* - -
up to 50 x ES Air-line** P2 PAPR-P2
up to 100 x ES - P3 -

Air-line* -
100+ x ES - Air-line** PAPR-P3

* - Negative pressure demand ** - Continuous flow

A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid gas or hydrogen cyanide(HCN), B3 = Acid gas or hydrogen cyanide(HCN), E = Sulfur
dioxide(SO2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic
compounds(below 65 degC)

· Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures.
· The decision to use respiratory protection should be based on professional judgment that takes into account toxicity information, exposure measurement data,
and frequency and likelihood of the worker's exposure - ensure users are not subject to high thermal loads which may result in heat stress or distress due to
personal protective equipment (powered, positive flow, full face apparatus may be an option).
· Published occupational exposure limits, where they exist, will assist in determining the adequacy of the selected respiratory protection. These may be
government mandated or vendor recommended.
· Certified respirators will be useful for protecting workers from inhalation of particulates when properly selected and fit tested as part of a complete respiratory
protection program.
· Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN143) dust masks. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU)
· Use approved positive flow mask if significant quantities of dust becomes airborne.
· Try to avoid creating dust conditions.

8.2.3. Environmental exposure controls

See section 12

SECTION 9 Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Not Available

Relative density (Water =

Physical state Divided Solid|Powder Not Available
1)
Partition coefficient n-
Odour Not Available Not Available
octanol / water
Auto-ignition temperature
Odour threshold Not Available Not Available
(°C)
Decomposition
pH (as supplied) Not Available Not Available
temperature (°C)
Melting point / freezing Not Available Viscosity (cSt) Not Available
point (°C)

Product code: P16194 Version No: 2.2 Page 11 of 20

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Initial boiling point and

Not Available Molecular weight (g/mol) Not Available
boiling range (°C)
Flash point (°C) Not Available Taste Not Available
Evaporation rate Not Available Explosive properties Not Available
Flammability Not Available Oxidising properties Not Available
Surface Tension (dyn/cm
Upper Explosive Limit (%) Not Available Not Applicable
or mN/m)
Lower Explosive Limit (%) Not Available Volatile Component (%vol) Not Available
Vapour pressure (kPa) Not Available Gas group Not Available
Solubility in water Miscible pH as a solution (1%) Not Available

Vapour density (Air = 1) Not Available VOC g/L Not Available

Nanoform Particle
Nanoform Solubility Not Available Not Available
Characteristics
Particle Size Not Available

9.2. Other information

Not Available

SECTION 10 Stability and reactivity

10.1.Reactivity See section 7.2

10.2. Chemical stability Product is considered stable and hazardous polymerisation will not occur.
10.3. Possibility of
See section 7.2
hazardous reactions
10.4. Conditions to avoid See section 7.2
10.5. Incompatible
See section 7.2
materials
10.6. Hazardous
See section 5.3
decomposition products

SECTION 11 Toxicological information

11.1. Information on toxicological effects

The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by EC Directives
using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable
control measures be used in an occupational setting.
Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur
Inhaled
further disability if excessive concentrations of particulate are inhaled.
If prior damage to the circulatory or nervous systems has occurred or if kidney damage has been sustained, proper screenings
should be conducted on individuals who may be exposed to further risk if handling and use of the material result in excessive
exposures.

Ingestion Starch is generally of low toxicity. An abnormal craving for starch (amylophagia) during pregnancy has been recognized in certain
areas.

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The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because
of the lack of corroborating animal or human evidence.
Polysaccharides are not easily absorbed from the digestive tract, but may produce a laxative effect. Larger doses may produce
intestinal or stomach blockage.
<
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce
health damage following entry through wounds, lesions or abrasions.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
Skin Contact
Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
There is some evidence to suggest that the material may cause mild but significant inflammation of the skin either following direct
contact or after a delay of some time. Repeated exposure can cause contact dermatitis which is characterised by redness,
swelling and blistering.
Although the material is not thought to be an irritant (as classified by EC Directives), direct contact with the eye may cause
Eye
transient discomfort characterised by tearing or conjunctival redness (as with windburn). Slight abrasive damage may also result.
Long-term exposure to the product is not thought to produce chronic effects adverse to the health (as classified by EC Directives
using animal models); nevertheless exposure by all routes should be minimised as a matter of course.
Some workers may develop chronic occupational dermatitis (generally mild) through the handling of starch products.
When starch is used as a lubricant in surgical gloves, small amounts, released into the patient during the course of surgery, have
Chronic resulted in granulomas and peritonitis.
Long term exposure to high dust concentrations may cause changes in lung function i.e. pneumoconiosis, caused by particles
less than 0.5 micron penetrating and remaining in the lung.
Studies indicate that diets containing large amounts of non-absorbable polysaccharides, such as cellulose, might decrease
absorption of calcium, magnesium, zinc and phosphorus.

TOXICITY IRRITATION
Potato Starch Powder
Not Available Not Available

TOXICITY IRRITATION
starch
Not Available Skin (human): 0.3 mg/3d-I mild

Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2. Value obtained from manufacturer's SDS.
Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances

The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling,
STARCH
the production of vesicles, scaling and thickening of the skin.

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity
Serious Eye
STOT - Single Exposure
Damage/Irritation
Respiratory or Skin
STOT - Repeated Exposure
sensitisation
Mutagenicity Aspiration Hazard

Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification

11.2 Information on other hazards

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11.2.1. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

11.2.2. Other information

See Section 11.1

SECTION 12 Ecological information

12.1. Toxicity

Endpoint Test Duration (hr) Species Value Source

Potato Starch Powder Not Not Not
Not Available Not Available
Available Available Available

Endpoint Test Duration (hr) Species Value Source

starch Not Not Not
Not Available Not Available
Available Available Available

Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity
4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) -
Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Sugar-based compounds (saccharides), including polysaccharides are generally easily decomposed by biodegradation. Not all polysaccharides decompose with
equal rapidity, and polysaccharides are also synthesised by microorganisms during, for example, the compost maturation phases. Water-insoluble species such as
cellulose take longer to decompose and those with a significant degree of branching also take longer.

12.2. Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air
No Data available for all ingredients No Data available for all ingredients

12.3. Bioaccumulative potential

Ingredient Bioaccumulation
No Data available for all ingredients

12.4. Mobility in soil

Ingredient Mobility
No Data available for all ingredients

12.5. Results of PBT and vPvB assessment

P B T
P B T
Relevant available data Not Available Not Available Not Available
PBT
vPvB

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PBT Criteria fulfilled? No

vPvB No

12.6. Endocrine disrupting properties

No evidence of endocrine disrupting properties were found in the current literature.

12.7. Other adverse effects

No evidence of ozone depleting properties were found in the current literature.

SECTION 13 Disposal considerations

13.1. Waste treatment methods

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws
operating in their area. In some areas, certain wastes must be tracked.
A Hierarchy of Controls seems to be common - the user should investigate:
Reduction
Reuse
Recycling
Product / Packaging Disposal (if all else fails)
disposal This material may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. Shelf
life considerations should also be applied in making decisions of this type. Note that properties of a material may change in use,
and recycling or reuse may not always be appropriate. In most instances the supplier of the material should be consulted.
DO NOT allow wash water from cleaning or process equipment to enter drains.
It may be necessary to collect all wash water for treatment before disposal.
In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
Where in doubt contact the responsible authority.
Waste treatment options Not Available
Sewage disposal options Not Available

SECTION 14 Transport information

Labels Required
Marine Pollutant NO
HAZCHEM Not Applicable

Land transport (ADR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS

14.1. UN number or ID
Not Applicable
number
14.2. UN proper shipping
Not Applicable
name

14.3. Transport hazard Class Not Applicable

class(es) Subsidiary Hazard Not Applicable

14.4. Packing group Not Applicable

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14.5. Environmental Not Applicable

hazard

Hazard identification (Kemler) Not Applicable

Classification code Not Applicable

14.6. Special precautions Hazard Label Not Applicable

for user Special provisions Not Applicable
Limited quantity Not Applicable
Tunnel Restriction Code Not Applicable

Air transport (ICAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name

ICAO/IATA Class Not Applicable

14.3. Transport hazard
ICAO / IATA Subsidiary Hazard Not Applicable
class(es)
ERG Code Not Applicable

14.4. Packing group Not Applicable

14.5. Environmental
Not Applicable
hazard

Special provisions Not Applicable

Cargo Only Packing Instructions Not Applicable
Cargo Only Maximum Qty / Pack Not Applicable
14.6. Special precautions
Passenger and Cargo Packing Instructions Not Applicable
for user
Passenger and Cargo Maximum Qty / Pack Not Applicable
Passenger and Cargo Limited Quantity Packing Instructions Not Applicable
Passenger and Cargo Limited Maximum Qty / Pack Not Applicable

Sea transport (IMDG-Code / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name

14.3. Transport hazard IMDG Class Not Applicable

class(es) IMDG Subsidiary Hazard Not Applicable

14.4. Packing group Not Applicable

14.5 Environmental hazard Not Applicable

14.6. Special precautions
EMS Number Not Applicable
for user
Special provisions Not Applicable

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Limited Quantities Not Applicable

Inland waterways transport (ADN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS
14.1. UN number Not Applicable
14.2. UN proper shipping
Not Applicable
name
14.3. Transport hazard
Not Applicable Not Applicable
class(es)
14.4. Packing group Not Applicable
14.5. Environmental
Not Applicable
hazard

Classification code Not Applicable

Special provisions Not Applicable
14.6. Special precautions
Limited quantity Not Applicable
for user
Equipment required Not Applicable
Fire cones number Not Applicable

14.7.1. Transport in bulk according to Annex II of MARPOL and the IBC code
Not Applicable

14.7.2. Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
starch Not Available

14.7.3. Transport in bulk in accordance with the IGC Code

Product name Ship Type
starch Not Available

SECTION 15 Regulatory information

15.1. Safety, health and environmental regulations / legislation specific for the substance or mixture

starch is found on the following regulatory lists

UK Workplace Exposure Limits (WELs).

This safety data sheet is in compliance with the following EU legislation and its adaptations - as far as applicable - : Directives 98/24/EC, - 92/85/EEC, - 94/33/EC,
- 2008/98/EC, - 2010/75/EU; Commission Regulation (EU) 2020/878; Regulation (EC) No 1272/2008 as updated through ATPs.

Information according to 2012/18/EU (Seveso III):

Seveso Category Not Available

15.2. Chemical safety assessment

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No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

ECHA SUMMARY
Ingredient CAS number Index No ECHA Dossier
starch 9005-25-8 Not Available Not Available

Harmonisation (C&L
Hazard Class and Category Code(s) Pictograms Signal Word Code(s) Hazard Statement Code(s)
Inventory)
1 Not Classified Not Available Not Available
2 Not Classified Not Available Not Available
1 Not Classified Not Available Not Available
2 Acute Tox. 4; STOT SE 3; Aquatic Chronic 2; Eye Irrit. 2 GHS07; Wng; GHS09 H332; H335; H411; H319
1 Not Classified Not Available Not Available
2 Not Classified Not Available Not Available
Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.

National Inventory Status

National Inventory Status
Australia - AIIC / Australia
Yes
Non-Industrial Use
Canada - DSL Yes
Canada - NDSL Yes
China - IECSC Yes

Europe - EINEC / ELINCS /

Yes
NLP
Japan - ENCS Yes
Korea - KECI Yes
New Zealand - NZIoC Yes
Philippines - PICCS Yes
USA - TSCA Yes
Taiwan - TCSI Yes
Mexico - INSQ Yes
Vietnam - NCI Yes
Russia - FBEPH Yes

National Inventory Yes = All CAS declared ingredients are on the inventory
Status
Legend: No = One or more of the CAS listed ingredients are not on the inventory. These ingredients may be exempt or will require
registration.

SECTION 16 Other information

Revision Date 01/03/2019

Initial Date 01/03/2019

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Full text Risk and Hazard codes

H319 Causes serious eye irritation.
H332 Harmful if inhaled.

H335 May cause respiratory irritation.

H411 Toxic to aquatic life with long lasting effects.

Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch
Classification committee using available literature references.

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks
in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available
engineering controls must be considered.

For detailed advice on Personal Protective Equipment, refer to the following EU CEN Standards:
EN 166 Personal eye-protection
EN 340 Protective clothing
EN 374 Protective gloves against chemicals and micro-organisms
EN 13832 Footwear protecting against chemicals
EN 133 Respiratory protective devices

Definitions and abbreviations

PC－TWA: Permissible Concentration-Time Weighted Average
PC－STEL: Permissible Concentration-Short Term Exposure Limit
IARC: International Agency for Research on Cancer
ACGIH: American Conference of Governmental Industrial Hygienists
STEL: Short Term Exposure Limit
TEEL: Temporary Emergency Exposure Limit。
IDLH: Immediately Dangerous to Life or Health Concentrations
ES: Exposure Standard
OSF: Odour Safety Factor
NOAEL :No Observed Adverse Effect Level
LOAEL: Lowest Observed Adverse Effect Level
TLV: Threshold Limit Value
LOD: Limit Of Detection
OTV: Odour Threshold Value
BCF: BioConcentration Factors
BEI: Biological Exposure Index
DNEL: Derived No-Effect Level
PNEC: Predicted no-effect concentration
AIIC: Australian Inventory of Industrial Chemicals
DSL: Domestic Substances List
NDSL: Non-Domestic Substances List
IECSC: Inventory of Existing Chemical Substance in China
EINECS: European INventory of Existing Commercial chemical Substances
ELINCS: European List of Notified Chemical Substances
NLP: No-Longer Polymers
ENCS: Existing and New Chemical Substances Inventory
KECI: Korea Existing Chemicals Inventory

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NZIoC: New Zealand Inventory of Chemicals

PICCS: Philippine Inventory of Chemicals and Chemical Substances
TSCA: Toxic Substances Control Act
TCSI: Taiwan Chemical Substance Inventory
INSQ: Inventario Nacional de Sustancias Químicas
NCI: National Chemical Inventory
FBEPH: Russian Register of Potentially Hazardous Chemical and Biological Substances

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