(19)

*EP002936590B1*
(11) EP 2 936 590 B1
(12) EUROPEAN PATENT SPECIFICATION

(45) Date of publication and mention (51) International Patent Classification (IPC):
of the grant of the patent: H01M 4/58 (2010.01) H01M 4/62 (2006.01)
29.06.2022 Bulletin 2022/26 H01M 10/0525 (2010.01) C01B 25/45 (2006.01)
C01G 45/12 (2006.01)
(21) Application number: 13710749.6
(52) Cooperative Patent Classification (CPC):
(22) Date of filing: 07.03.2013 C01B 25/45; C01G 45/1235; H01M 4/5825;
H01M 4/625; H01M 10/0525; C01P 2002/50;
C01P 2002/52; C01P 2002/72; C01P 2006/32;
Y02E 60/10

(86) International application number:

PCT/US2013/029597

(87) International publication number:

WO 2014/098937 (26.06.2014 Gazette 2014/26)

(54) LMFP CATHODE MATERIALS WITH IMPROVED ELECTROCHEMICAL PERFORMANCE

LMFP-KATHODENMATERIALIEN MIT VERBESSERTEN ELEKTROCHEMISCHEN
EIGENSCHAFTEN
MATÉRIAUX DE CATHODE LMFP DOTÉS D’UNE PERFORMANCE ÉLECTROCHIMIQUE
AMÉLIORÉE

(84) Designated Contracting States: • LI, Bin

AL AT BE BG CH CY CZ DE DK EE ES FI FR GB San Diego, CA 92129 (US)
GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO
PL PT RO RS SE SI SK SM TR (74) Representative: Beck Greener LLP
Fulwood House
(30) Priority: 21.12.2012 US 201261740575 P 12 Fulwood Place
London WC1V 6HR (GB)
(43) Date of publication of application:
28.10.2015 Bulletin 2015/44 (56) References cited:
EP-A1- 2 383 820 EP-A2- 1 150 367
(73) Proprietor: Dow Global Technologies LLC WO-A1-2008/018633 WO-A2-2007/064934
Midland, MI 48674 (US) JP-A- 2004 063 422 JP-A- 2012 190 568
US-A1- 2012 301 780
(72) Inventors:
• KHOT, Shrikant, N. • HAISHENG FANG ET AL:
Midland, MI 48642 (US) "LiMn0.8Fe0.19Mg0.01PO4/C as a high
• STRAND, Deidre, A. performance cathode material for lithium ion
Midland, MI 48640 (US) batteries", JOURNAL OF POWER SOURCES, vol.
• COHEN, Jamie, L. 204, 1 April 2012 (2012-04-01), pages 193-196,
Midland, MI 48642 (US) XP055076204, ISSN: 0378-7753, DOI:
• DREZEN, Thierry 10.1016/j.jpowsour.2011.12.046
EP 2 936 590 B1

Midland, MI 48674 (US)

• KAYE, Steven, S.
Midland, Michigan 48674 (US)

Note: Within nine months of the publication of the mention of the grant of the European patent in the European Patent
Bulletin, any person may give notice to the European Patent Office of opposition to that patent, in accordance with the
Implementing Regulations. Notice of opposition shall not be deemed to have been filed until the opposition fee has been
paid. (Art. 99(1) European Patent Convention).

Processed by Luminess, 75001 PARIS (FR)

 EP 2 936 590 B1

Description

[0001] The present invention relates to olivine lithium manganese iron phosphate cathode materials for lithium batteries
and to methods for making such materials.
5 [0002] Lithium batteries are widely used as primary and secondary batteries for vehicles and many types of electronic
equipment. These batteries often have high energy and power densities.
[0003] LiFePO4 is known as a low cost material that is thermally stable and has low toxicity. It can also demonstrate
very high rate capability (high power density) when made with a small particle size and a good carbon coating. For these
reasons, LiFePO4 has found use as a cathode material in lithium batteries. However, LiFePO4 has a relatively low
10 working voltage (3.4V vs. Li+/Li) and because of this has a low energy density relative to oxide cathode materials. In
principle, the working voltage and therefore the energy density can be increased by substituting manganese for some
or all of the iron to produce a lithium manganese iron phosphate (LiaMnbFe(1-b)PO4 (LMFP)) cathode, without a significant
sacrifice of power capability. However, structural stability and charge transport are adversely affected by replacing iron
with manganese, and the specific capacities obtained have fallen significantly short of theoretical levels. Energy and
15 power densities also are disappointingly low. In addition, battery cycling performance for LMFP electrodes often is less
than desirable, due to a loss of capacity with cycling.
[0004] Attempts have been made to improve the performance of olivine lithium transition metal phosphate electrode
materials by adjustments to the stoichiometry, i.e., the ratios of lithium, manganese, iron and the phosphate ions. Electrode
materials containing an excess of lithium have been described, for example, in WO 2009/144600 and USP 7,842,420.
20 Adding certain "dopants", i.e., metals other than lithium, manganese and iron, also has been suggested in LMFP electrode
materials having low manganese contents. See, e.g., WO 2011/025823, which mentions cobalt, nickel, niobium and
vanadium as the "dopant" materials in an LMFP material in which the value of b is up to 0.6. See also USP 8,168,150,
in which various other metals are suggested in an LMFP cathode material containing a large amount of iron.
[0005] US 2012/301780 relates to a positive electrode active material for a lithium ion battery including a material
25 represented by chemical formula LiMPO4 where M includes at least one of iron, manganese, cobalt, and nickel. Particles
of the positive electrode active material have a diameter d in the range of 10 nm to 200 nm, the diameter d being
determined by observation under a transmission electron microscope. A ratio d/D of the diameter d to a crystallite
diameter D is in the range of 1 to 1.35, the crystallite diameter D being determined from a half width measured by X-ray
diffraction. The positive electrode active material is coated with carbon, an amount of the carbon being in the range of
30 1 weight percent to 10 weight percent.
[0006] JP 2004 063422 relates to a positive nonaqueous electrolytic battery comprising a positive electrode including
a positive electrode active material, a negative electrode including a negative electrode active material, and a nonaqueous
electrolyte including electrolyte salt. The positive electrode includes a compound having an olivine structure represented
by a formula LiaMnbFecMdPO4(in the formula, M is one or more kinds of elements selected from Mg, Ti, V, Cr, Co, Ni,
35 Cu and Zn,
[0007] JP 2012 190568 relates to an active material containing particles of average composition represented by
LiMnFeMPO, where M represents one or more kinds of elements selected from Mg, Ti, V, Cr, Co, Ni, Cu, and Zn, 0y or
γ/(α+β+γ)>z, and (α+β+γ)/σ≥0.25, where α, β, γ, and σ represent the numbers of moles of Mn, Fe, M, and O in the
segregation phase, respectively.
40 [0008] EP 1150367 relates to a positive electrode active material and a non-aqueous electrolyte cell which uses the
positive electrode active material. The cell has a high discharge voltage without lowering the capacity and superior
charging/discharging characteristics. To this end, the positive electrode active material contains a compound represented
by the general formula LixMnyFe1-yPO4, wherein 0 < x ≤ 0.2 and 0.5 < y < 0.95, or a compound represented bythe general
formula LixMnyA1-yPO4, where 0 < x ≤ 0.2 and 0 < y < 1 and wherein A is a metal element selected from among Ti, Zn,
45 Mg and Co or plural metal elements selected from among Ti, Fe, Zn, Mg and Co,
[0009] EP 2383820 relates to how to provide a positive electrode material having a large ratio of the discharge capacity
around 4 V to the total discharge capacity including the discharge capacity at 4V or lower while making the discharge
capacity around 4 V sufficient, for the purpose of providing a lithium secondary battery using a lithium transition metal
phosphate compound excellent in thermal stability, utilizing the discharge potential around 4V (vs. Li/Li + ) that is higher
50 than the discharge potential of LiFePO4, and being advantageous with respect to the detection of the end of discharge
state, and a lithium secondary battery using the same. Used is a positive active material for a lithium secondary battery
containing a lithium transition metal phosphate compound represented by LiMn1-x-yFexCoyPO4 (0.1 ≤ x ≤ 0.2, 0 < y ≤ 0.2).
[0010] Haisheng Fang et al. in "LiMn0.8Fe1.9Mg0.01PO4/C as a high performance cathode material for lithium ion
batteries" in J. Power Sources, vol.204, 2012-04-01, pp.193-196 XP055076204 discloses a new LiMnPO4 based material,
55 LiMn0.8Fe0.19Mg0.01PO4/C, which is synthesized by a solid state method and characterized by X-ray diffraction (XRD),
scanning electron microscopy (SEM) and electrochemical test. The obtained LiMn0.8Fe0.19Mg0.01PO4 crystals with 8
wt.% carbon coating are mainly 100-500 nm in size, and aggregate into microparticles around 3-5 mm. The electrochemical
test demonstrates that the obtained LiMn0.8Fe0.19Mg0.01PO4/C has high capacity, good cycleability and quite excellent

2
 EP 2 936 590 B1

rate capability in spite of its larger size and less carbon coating as compared to those reported in the previous works.
When discharged at a high rate of 10 C, the obtained LiMn0.8Fe0.19Mg0.01PO4/C can still deliver a capacity of 115 mAh
g-1. The results prove that the LiMn0.8Fe0.19Mg0.01PO4 is a very promising cathode material for lithium ion batteries.
[0011] WO 2007/064934 relates to provision of amorphous or partially amorphous nanoscale ion storage materials.
5 For example, lithium transition metal phosphate storage compounds are nanoscale and amorphous or partially amor-
phous in an as-prepared state, or become amorphous or partially amorphous upon electrochemical intercalation or
deintercalation by lithium. These nanoscale ion storage materials are useful for producing devices such as high energy
and high power storage batteries
[0012] WO 2008/018633 relates to a compound having an olivine structure, which makes a low-cost positive electrode
10 active material which is highly safe and excellent in battery characteristics such as energy density. Also disclosed are
a method for producing such a compound, and a nonaqueous electrolyte battery comprising a positive electrode con-
taining such a compound. Specifically disclosed is a method for producing a compound having an olivine structure,
which is characterized in that a manganese source containing manganese oxide particles, a lithium source and a phos-
phorus source are mixed and fired.
15 [0013] There remains a desire to provide an olivine LMFP cathode material that has good specific capacity, high rate
performance, and improved cycling performance.
[0014] This invention is in one aspect a cathode material comprising an electroactive material having the empirical
formula LiaMnbFecDdPO4, wherein

20 a is a number from 0.95 to 1.10;

b is from 0.70 to 0.95;
c is from 0.049 to 0.349;
d is from 0.005 to 0.10;

25 [0015] (a + 2b + 2c + dV) is 2.85 to 2.99 or 3.01 to 3.05, wherein V is the valence of D, and D is a metal ion selected
from magnesium, cobalt or a mixture of magnesium and cobalt, and further wherein at least a portion of the electroactive
material has an olivine structure.
[0016] The invention is also a nanocomposite containing at least 70% by weight of a particulate electroactive material
of the invention with up to 30% by weight of graphite, carbon black and/or other conductive carbon.
30 [0017] The LMFP cathode materials of the invention provide enhanced cycle life while retaining good specific capacity
and good high rate performance.
[0018] In another aspect, the invention is a method for making an olivine lithium manganese transition metal phosphate
cathode material, comprising

35 a) forming a mixture of at least one lithium precursor, at least one iron precursor, at least one manganese precursor,
at least one dopant metal precursor and at least one precursor of HxPO 4 ions where x is 0, 1 or 2, wherein the
dopant metal precursor includes dopant metal ions selected from magnesium, cobalt or a mixture of magnesium
and cobalt and wherein the precursors are present in amounts such that:

40 the mole ratio of lithium ions to HxPO4 ions is 0.95 to 1.1;

the mole ratio of manganese ions to HxPO4 ions is 0.70 to 0.95;
the mole ratio of iron ions to HxPO4 ions is 0.049 to 0.349;
the mole ratio of dopant metal ions to HxPO4 ions is 0.005 to 0.10; and
the mole ratio of lithium, manganese, iron and dopant metal ions combined to HxPO4 ions is such that [moles
45 Li + (2 3 Moles Mn) + (2 3 Moles Fe) + (2 3 Moles Dopant Metal)] is (2.85 to 2.99 3 Moles HxPO4) or (3.01
to 3.05 3 Moles HxPO4);

b) milling the mixture and then;

c) calcining the milled mixture to form the olivine lithium manganese iron phosphate cathode material.
50
[0019] Cathode materials made in accordance with the invention offer several important advantages over conventional
high-manganese LMFP cathode materials. One important advantage is cycle life. The cathode materials formed in
accordance with the invention have been found to exhibit excellent cycle lives. Lithium batteries containing cathodes
made from these materials tend to retain specific capacity very well over many charge/discharge cycles. Importantly,
55 this high specific capacity often is seen even at high discharge/charge rates. A second important advantage is that those
batteries often exhibit high energies, due to a combination of high capacities and high operating voltages. Another
significant advantage is that batteries containing these electrodes are capable of high charge rates.
[0020] The Figure is a graph showing the specific capacity versus number of cycles for several embodiments of the

3
 EP 2 936 590 B1

invention and for several comparative samples.

[0021] Cathode materials of the invention preferably are made in a milling process, in which the various precursor
materials described herein are milled together, followed by a calcining step. The milling step intimately mixes the pre-
cursors and in most cases reduces their particle size. Some reaction of the precursors may occur during the milling step,
5 although it is believed that the final olivine structure does not fully develop until the calcining step is performed. Dry or
wet milling methods can be used, as described more fully below.
[0022] The process of the invention is characterized in part by the ratios of the starting materials. The amounts of
starting materials are conveniently expressed in terms of mole ratios of the metal ions (lithium, manganese, iron and
dopant metal(s)) to HxPO4 ions.
10 [0023] The amount of lithium precursor provided is such that the mole ratio of lithium ions to HxPO4 ions is 0.95 to
1.10, more preferably 1.0 to 1.10, still more preferably 1.025 to 1.10 and in some embodiments may be 1.025 to 1.075.
[0024] The amount of manganese precursor provided is such that the mole ratio of manganese ions to HxPO4 ions is
0.70 to 0.95, more preferably 0.70 to 0.85, and in some embodiments may be 0.75 to 0.85.
[0025] The amount of iron precursor provided is such that the mole ratio of iron ions to H xPO4 ions is 0.049 to 0.349.
15 This ratio preferably is 0.10 to 0.30 and in some embodiments may be 0.15 to 0.25.
[0026] The amount of dopant metal precursor provided is such that the mole ratio of dopant metal ions to HxPO4 ions
is 0.005 to 0.10, more preferably 0.01 to 0.075 and in some embodiments may be 0.02 to 0.06.
[0027] In addition, the amount of lithium, manganese, iron and dopant metal precursors are chosen together. The
mole ratio of lithium, manganese, iron and dopant metal ions combined to HxPO 4 ions is such that [moles Li + (2 3
20 moles Mn) + (2 3 moles Fe) + (2 3 moles Dopant Metal)] is (2.85 to 2.99 3 Moles HxPO4) or (3.01 to 3.05 3 Moles
HxPO4). In particular embodiments, [moles Li + (2 3 moles Mn) + (2 3 moles Fe) + (2 3 moles Dopant Metal)] is (2.95
to 2.98 3 Moles HxPO 4) or (3.01 to 3.05 3 Moles HxPO4).
[0028] In specific embodiments:

25 1) the mole ratio of lithium ions to HxPO4 ions is 0.95 to 1.10, the mole ratio of manganese ions to HxPO4 ions is
0.70 to 0.95; the mole ratio of iron ions to HxPO 4 ions is 0.049 to 0.349, the mole ratio of dopant metal ions to HxPO4
ions is 0.005 to 0.10 and [moles Li + (2 3 moles Mn) + (2 3 moles Fe) + (2 3 moles Dopant Metal)] is (2.85 to 2.99
3 Moles HxPO 4) or (3.01 to 3.05 3 Moles HxPO4);
2) the mole ratio of lithium ions to HxPO4 ions is 1.00 to 1.10, the mole ratio of manganese ions to HxPO4 ions is
30 0.70 to 0.95; the mole ratio of iron ions to HxPO4 ions is 0.1 to 0.3, the mole ratio of dopant metal ions to HxPO4
ions is 0.005 to 0.10 and [moles Li + (2 3 moles Mn) + (2 3 moles Fe) + (2 3 moles Dopant Metal)] is (2.85 to 2.99
3 Moles HxPO 4) or (3.01 to 3.05 3 Moles HxPO4);
3) the mole ratio of lithium ions to HxPO4 ions is 1.025 to 1.10, the mole ratio of manganese ions to HxPO4 ions is
0.70 to 0.85; the mole ratio of iron ions to HxPO4 ions is 0.1 to 0.3, the mole ratio of dopant metal ions to HxPO4
35 ions is 0.01 to 0.075 and [moles Li + (2 3 moles Mn) + (2 3 moles Fe) + (2 3 moles Dopant Metal)] is (2.85 to 2.99
3 Moles HxPO 4) or (3.01 to 3.05 3 Moles HxPO4);
4) the mole ratio of lithium ions to HxPO4 ions is 1.025 to 1.075, the mole ratio of manganese ions to HxPO4 ions is
0.75 to 0.85; the mole ratio of iron ions to HxPO4 ions is 0.15 to 0.25, the mole ratio of dopant metal ions to HxPO4
ions is 0.02 to 0.06 and [moles Li + (2 3 moles Mn) + (2 3 moles Fe) + (2 3 moles Dopant Metal)] is (2.95 to 2.98
40 3 Moles HxPO 4) or (3.01 to 3.05 3 Moles HxPO4).

[0029] In any of the foregoing embodiments the dopant metal is selected from magnesium, cobalt or a mixture of
magnesium and cobalt. The dopant metal is most preferably magnesium.
[0030] The precursor materials are compounds other than a LMFP, and are compounds which react to form a LMFP
45 as described herein. Some or all of the precursor materials may be sources for two or more of the necessary starting
materials. Suitable lithium precursors include, for example, lithium hydroxide, lithium oxide, lithium carbonate, lithium
dihydrogen phosphate, lithium hydrogen phosphate and lithium phosphate. Lithium dihydrogen phosphate, lithium hy-
drogen phosphate and lithium phosphate all function as a source for both lithium ions and HxPO 4 ions, and can be
formed by partially neutralizing phosphoric acid with lithium hydroxide prior to being combined with the rest of the
50 precursor materials.
[0031] Suitable manganese precursors include manganese (II) compounds such as, for example, manganese (II)
phosphate, manganese (II) hydrogen phosphate, manganese (II) dihydrogen phosphate, manganese (II) carbonate,
manganese (II) hydrogen carbonate, manganese (II) formate, manganese (II) acetate, manganese (II) oxide, manganese
(II) glycolate, manganese (II) lactate, manganese (II) citrate and manganese (II) tartrate. Manganese (II) hydrogen
55 phosphate and manganese (II) phosphate will also function as all or part of the precursor for HxPO 4 ions, and can be
formed by partially neutralizing phosphoric acid with manganese metal prior to being combined with the rest of the
precursor materials.
[0032] Suitable iron precursors include iron (II) phosphate, iron (II) hydrogen phosphate, iron (II) dihydrogen phosphate,

4
 EP 2 936 590 B1

iron (II) carbonate, iron (II) hydrogen carbonate, iron (II) formate, iron (II) acetate, iron (II) oxide, iron (II) glycolate, iron
(II) lactate, iron (II) citrate, iron (II) tartrate. Iron (II) hydrogen phosphate and iron (II) phosphate will also function as all
or part of the precursor for HzPO4 ions, and can be formed by partially neutralizing phosphoric acid with iron metal prior
to being combined with the rest of the precursor materials.
5 [0033] Suitable precursors for the dopant metal include, for example, phosphate, hydrogen phosphate, dihydrogen
phosphate, carbonate, formate, acetate, glycolate, lactate, tartrate, oxalate, oxide, hydroxide, fluoride, chloride, nitrate,
sulfate, bromide and like salts of the various dopant metals. Examples include, for example, magnesium sulfate, mag-
nesium phosphate, magnesium hydrogen phosphate, magnesium dihydrogen phosphate, magnesium carbonate, mag-
nesium formate, magnesium acetate, cobalt (II) sulfate, cobalt (II) phosphate, cobalt (II) hydrogen phosphate, cobalt (II)
10 dihydrogen phosphate, cobalt (II) carbonate, cobalt (II) formate, cobalt (II) acetate. The phosphates, hydrogen phosphates
and dihydrogen phosphates in the foregoing list will in addition to serving as a source of the dopant metal ion also will
serve as some or all of the source of HxPO4 ions.
[0034] Suitable precursors for HxPO4 ions include, in addition to the hydrogen phosphate and dihydrogen phosphate
compounds listed above, phosphoric acid, tetraalkyl ammonium phosphate compounds, tetraphenyl ammonium phos-
15 phate compounds, ammonium phosphate, ammonium dihydrogen phosphate, and the like.
[0035] A carbonaceous material or precursor thereof may be included in the mixture that is taken to the milling step.
Suitable carbonaceous materials and precursors include, for example, graphite, carbon black and/or other conductive
carbon, various organic polymers, sugars such as sucrose or glucose, and the like.
[0036] In the milling process of the invention, the precursors typically are mixed in the presence of water or water/solvent
20 mixture to form a slurry or thick paste. The precursors are typically added as solids, except that phosphoric acid (if used
as the source of H xPO4 ions) is typically added as a concentrated aqueous solution. The solids content of this initial
mixture may be, for example, from 25 to 60 weight percent. If the precursors react to form gaseous reaction by-products,
it is generally preferred to permit the slurry to stand for a period to allow the gaseous by-products to liberate. Gaseous
by-products often form, for example, when carbonate and/or carboxylate precursors are used. In a preferred process,
25 the manganese, iron and dopant metal precursors are slurried with phosphoric acid, gaseous by-products are liberated,
and then lithium hydroxide is added. The lithium hydroxide addition typically results in an exothermic reaction and a
thickening of the slurry. It is believed that a mixture of intermediate reaction products such as MnHPO4, Li3PO4, Li2HPO4,
LiH2PO 4, hurealite (Mn2+5(PO3OH)2(PO4)2 · 4H2O), and Fe(C2O4) may form at this stage.
[0037] The milling step can be carried out in a wet or dry agitated media mill, such as a sand mill, ball mill, attrition
30 mill, mechanofusion mill, or colloid mill. The mill is preferably a recirculating type, necessitating a carrier liquid which is
preferably water. The milling can be performed in one or more steps to final particle size. In a two-step milling process,
larger size grinding media such as 0.8-1.0 mm ceramic beads are initially used on the raw materials to provide a finely
milled product having a particle size in the range of, for example, 0.2 to 1 microns. In the second step smaller grinding
media such as 0.05 mm ceramic beads are used to further reduce the particle size into the range of, for example, 0.01
35 to 0.1 microns. In a single-step milling process, the raw materials are reduced in size to a product on the order of 0.01
to 0.1 micron in a single step.
[0038] The amount of milling energy used to mill the particles to the aforementioned particle sizes is typically 10 to
10,000 kW-h/ton (9.09 to 9091 kW-h/1000 kg) and preferably <500 kW-h/ton (< 454.5 kW-h/1000 kg). An advantage of
this invention that is seen in cases in which [moles Li + (2 3 moles Mn) + (2 3 moles Fe) + (2 3 moles Dopant Metal)]
40 ≠ (3.0 3 Moles HxPO4) (such as from (2.95 to 2.98 3 Moles HxPO4) or (3.01 to 3.05 3 Moles HxPO4)) is that the amount
of milling energy needed to achieve a product having good electrochemical performance is significantly lower (on the
order of one-half) than that needed when [moles Li + (2 3 moles Mn) + (2 3 moles Fe) + (2 3 moles Dopant Metal)] =
(3.0 3 moles HxPO4). This allows shorter milling times, and/or less expensive larger (0.3 - 1.2 mm diameter) milling
media to be used with good results.
45 [0039] The milled product is calcined. Preferably, the milled materials are first suspended in a liquid diluent such as
water and then spray dried to form secondary agglomerates of the primary milled particles. Each droplet sprayed into
the drying chamber forms an aggregate of particles when dried. The size of this aggregate is related to the size of the
droplet formed by the spray dryer atomizer. A suitable secondary aggregate size range is, for example, 2 to 25 microns
(d50, by light scattering methods). These secondary aggregates (or the powders as received from the milling step) are
50 then calcined to form the olivine phase. A suitable calcining temperature is 350 to 750°C and preferably 500 to 700°C,
for 0.1 to 20 hours and preferably 1 to 4 hours. Conditions are selected to avoid sintering the particles.
[0040] If a carbonaceous material or precursor thereof is present during the calcining step, the calcined particles will
take the form of a nanocomposite of the olivine material and the carbonaceous material. The carbonaceous material
may form a carbonaceous coating on the powdered particles, and/or form a layered composite therewith.
55 [0041] The cathode material in certain embodiments of the invention has the empirical formula LiaMnbFecDdPO4,
based on the raw materials provided into the process. In this formula, a is a number from 0.95 to 1.10, more preferably
1.0 to 1.1, still more preferably from 1.025 to 1.10 and in some embodiments 1.025 to 1.075. b is from 0.7 to 0.95, more
preferably 0.70 to 0.85 and in some embodiments may be 0.75 to 0.85. c is from 0.049 to 0.349, preferably from 0.10

5
 EP 2 936 590 B1

to 0.30 and more preferably 0.10 to 0.25. d is from 0.005 to 0.1, more preferably 0.01 to 0.075 and in some embodiments
may be 0.02 to 0.06. The values of a, b, c and d are such that (a + 2b + 2c + dV) is 2.85 to 2.99 or 3.01 to 3.05. In
particular embodiments, (a + 2b + 2c + dV) is 2.95 to 2.98 or 3.01 to 3.05.
[0042] At least a portion of the cathode material has an olivine structure. The olivine structure is revealed using X-ray
5 diffraction methods. It is preferred that at least 50%, more preferably at least 80% and still more preferably at least 95%
of the weight of the electroactive material is a LiaMnbFecDdPO4 having an olivine structure.
[0043] The cathode material preferably is formed during the milling and calcining processes into particles that may
have flake-like, rod-like, spherical, or other morphologies and preferably have primary particle sizes of 200 nm or below.
Primary particles sizes are conveniently measured by scanning electron microscopy. Aggregate sizes are conveniently
10 measured by light scattering methods.
[0044] The lithium transition metal olivine produced in the process is useful as an electrode material, particularly as
a cathode material, in various types of lithium batteries, especially secondary (rechargeable) batteries. It can be formulated
into electrodes in any convenient manner, typically by blending it with a binder, forming a slurry and casting it onto a
current collector. The electrode may contain particles and/or fibers of an electroconductive material such as graphite,
15 carbon black, carbon fibers, carbon nanotubes, metals and the like. The lithium transition metal olivine particles may be
formed into a nanocomposite with graphite, carbon black and/or other conductive carbon using, for example, dry ball
milling processes as described in WO 2009/127901 and/or a wet milling process. Such a nanocomposite preferably
contains at least 70% by weight of the lithium transition metal olivine particles, more preferably at least 75% by weight
thereof, and up to 30%, more preferably 10 to 25%, by weight of carbon.
20 [0045] Secondary batteries containing a cathode which includes electroactive material of the invention exhibit unex-
pectedly good capacity retention upon battery cycling (i.e., subjecting the battery to repeated charge/discharge cycles),
while retaining specific capacity and rate performance. In a secondary (rechargeable) battery, the good capacity retention
correlates to long battery life and more consistent performance of the battery as it is repeatedly charged and discharged.
This good capacity retention is seen at ambient temperature (20-25°C) and at somewhat elevated temperatures (40-50°C)
25 as are often produced during the operation of an electrical device that contains the battery (and to which energy is
supplied by the battery).
[0046] Cycle life testing for purposes of this invention is done using full cells with graphite anodes in pouches. The
anodes, cathodes and separators are cut. Current tabs are welded onto the electrode sheet, the separator is sandwiched
between the electrode sheets, and the sandwiched layers are sealed under vacuum in an aluminum laminated film bag
30 filled with electrolyte (1.15 M LiPF6 in ethylene carbonate/ethylmethylcarbonate (1:3 volume ratio) + 2% vinylidene
carbonate). The anode/cathode capacity ratio is kept between 1.1 - 1.2 to prevent lithium plating on to the anode and
for good cycling performance. After sealing and assembly, the cells undergo the following formation cycle: 1st cycle:
C/20 to 4.2 V, C/100 cutoff (charge); rest 15 minutes at RT; C/20 to 2.7 V (discharge), 2nd cycle: C/20-4.2 V, C/100 cutoff
(charge); rest at 50°C for 24 hours, and then degas at room temperature; C/20 to 2.7 V (discharge). After the formation
35 cycle, the cells are cycled on a Maccor electrochemical tester at 50°C under the following protocol: 1C to 4.2 C, C/20
cutoff (charge), rest 15 minutes; C/10 to 2.7 V (discharge).
[0047] Lithium batteries containing cathodes containing the electroactive material of the invention also exhibit good
specific capacity, which is often close to theoretical. Specific capacity is measured using half-cells at 25°C on electro-
chemical testing using a Maccor 4000 electrochemical tester or equivalent electrochemical tester, using in order discharge
40 rates of C/10, 1C, 5C, 10C and finally C/10. The lithium transition metal olivine produced in accordance with the invention
may have a specific capacity of at least 80%, at least 90% or even at least 93% of the theoretical capacity at 5C testing
in coin cells. For example, a lithium transition metal olivine made in accordance with the invention may exhibit, for
example, a specific capacity of at least 140 mAh/g, at least 150 mAh/g, at least 155 mAh/g or even at least 160 mAh/g
at a C/10 discharge rate, which values are close to the theoretical value of approximately 170 mAh/g.
45 [0048] A lithium battery containing such a cathode can have any suitable design. Such a battery typically comprises,
in addition to the cathode, an anode, a separator disposed between the anode and cathode, and an electrolyte solution
in contact with the anode and cathode. The electrolyte solution includes a solvent and a lithium salt.
[0049] Suitable anode materials include, for example, carbonaceous materials such as natural or artificial graphite,
carbonized pitch, carbon fibers, graphitized mesophase microspheres, furnace black, acetylene black, and various other
50 graphitized materials. Suitable carbonaceous anodes and methods for constructing same are described, for example,
in U. S. Patent No. 7,169,511. Other suitable anode materials include lithium metal, lithium alloys, other lithium compounds
such as lithium titanate and metal oxides such as TiO 2, SnO 2 and SiO 2, as well as materials such as Si, Sn, or Sb.
[0050] The separator is conveniently a non-conductive material. It should not be reactive with or soluble in the electrolyte
solution or any of the components of the electrolyte solution under operating conditions. Polymeric separators are
55 generally suitable. Examples of suitable polymers for forming the separator include polyethylene, polypropylene, poly-
butene-1, poly-3-methylpentene, ethylene-propylene copolymers, polytetrafluoroethylene, polystyrene, polymethylmeth-
acrylate, polydimethylsiloxane, polyethersulfones and the like.
[0051] The battery electrolyte solution has a lithium salt concentration of at least 0.1 moles/liter (0.1 M), preferably at

6
 EP 2 936 590 B1

least 0.5 moles/liter (0.5 M), more preferably at least 0.75 moles/liter (0.75 M), preferably up to 3 moles/liter (3.0 M),
and more preferably up to 1.5 moles/liter (1.5 M). The lithium salt may be any that is suitable for battery use, including
lithium salts such as LiAsF6, LiPF6, LiPF4(C2O4), LiPF2(C2O4)2, LiBF4, LiB(C2O4)2, LiBF2(C2O4), LiClO4, LiBrO4, LiIO4,
LiB(C6H5)4, LiCH3SO3, LiN(SO2C2F5)2, and LiCF3SO3. The solvent in the battery electrolyte solution may be or include,
5 for example, a cyclic alkylene carbonate like ethyl carbonate; a dialkyl carbonate such as diethyl carbonate, dimethyl
carbonate or methylethyl carbonate, various alkyl ethers; various cyclic esters; various mononitriles; dinitriles such as
glutaronitrile; symmetric or asymmetric sulfones, as well as derivatives thereof; various sulfolanes, various organic esters
and ether esters having up to 12 carbon atoms, and the like.
[0052] The battery is preferably a secondary (rechargeable) battery, more preferably a secondary lithium battery. In
10 such a battery, the charge reaction includes a dissolution or delithiation of lithium ions from the cathode into the electrolyte
solution and concurrent incorporation of lithium ions into the anode. The discharging reaction, conversely, includes an
incorporation of lithium ions into the cathode from the anode via the electrolyte solution.
[0053] The battery containing a cathode which includes lithium transition metal olivine particles made in accordance
with the invention can be used in industrial applications such as electric vehicles, hybrid electric vehicles, plug-in hybrid
15 electric vehicles, aerospace vehicles and equipment, e-bikes, etc. The battery of the invention is also useful for operating
a large number of electrical and electronic devices, such as computers, cameras, video cameras, cell phones, PDAs,
MP3 and other music players, tools, televisions, toys, video game players, household appliances, medical devices such
as pacemakers and defibrillators, among many others.
[0054] The following examples are provided to illustrate the invention, but are not intended to limit the scope thereof.
20 All parts and percentages are by weight unless otherwise indicated.

Examples 1-3 and Comparative Samples A-D

[0055] Examples 1-3 and Comparative Samples A-D are prepared using a solid state process as described in WO
25 2009/144600.

Table 1
Designation Formula a + 2b + 2c + dV

30 Comp. Sample A LiMn0.8Fe0.2PO4 3.0

Comp. Sample B Li1.025Mn0.8Fe0.2PO4 3.025
Comp. Sample C Li1.1Mn0.71Fe0.24PO4 3.0
Comp. Sample D Li1.1Mn0.76Fe0.19PO4 3.0
35
*Example 1 Li1.1Mn0.8Fe0.1Mg0.05PO 4 3.0
*Example 2 Li1.1Mn0.8Fe0.08Mg0.07PO 4 3.0
Example 3 LiMn0.7Fe0.2Mg0.05PO4 2.90

40 *Reference Examples, not according to the invention

[0056] The resulting particles are mixed with vapor-grown carbon fibers and binder at a 93:2:5 weight ratio to form
electrodes. The electrodes are given the same designations as the respective electroactive materials they contain (as
indicated in Table 1 above).
45
[0057] Half cell specific capacities are measured at 20 °C at C/10 discharge rate. Newly made cells are cycled using
a CC/CV charge protocol with 2 cycles at C/10 charge/discharge, followed by subsequent cycles at varying C-rates. Full
cell cycle life is measured at elevated temperature (50°C) at 1C/1C charge/discharge with CC/CV charging from 2.7 to
4.2V. Two formation cycles are done at room temperature (20°C) at C/10 charge/discharge over the same voltage range
prior to placing the cells at elevated temperature. Full cell cycle life results are indicated graphically in the Figure.
50
[0058] In the Figure, reference symbols A, B, C, D, 1, 2 and 3 represent the results obtained with the corresponding
sample designation. The top portion of the Figure shows measured capacity (in mAh/g) plotted against the number of
charge/discharge cycles. The bottom portion of the Figure shows the capacity retention, i.e., the percentage of the
original capacity of each of the tested electrodes.
[0059] As can be seen from the Figure, Examples 1-3 are far superior to any of the Comparative Samples in retaining
55
capacity over many charge/discharge cycles. Although these electrodes show a lower specific capacity initially, they
retain much more of their capacity as the cell is cycled. *Example 1 retains about 83% of its initial specific capacity,
*Example 2 retains 90% of its initial capacity and Example 3 retains only about 78% of its initial capacity. After 168

7
 EP 2 936 590 B1

cycles, Examples 1-3 are equivalent even in absolute terms to the best of the Comparative Samples. Due to the superior
capacity retention exhibited through the first 168 cycles Examples 1-3 are expected upon additional cycling to exhibit
higher specific capacities in absolute terms than any of the Comparative Samples.
[0060] The electroactive material of *Examples 1 and 2 both contain more than 1 atom of lithium per phosphate group
5 (a>1) and are doped. Comparative Sample A is not doped and contains only 1 atom of lithium per phosphate group
(a=1). The electrode made from that material retains little more than 60% of its initial capacity after only 140 cycles, and
has a lower specific capacity at that point than either of *Examples 1 or 2.
[0061] Comparative Samples B, C and D each has an excess of lithium (a>1) but are not doped. The electrode made
using these material loses capacity quite rapidly upon charge/discharge cycling, and demonstrates that increasing the
10 amount of lithium by itself provides little benefit.
[0062] Example 3 is doped with magnesium but contains only one atom of lithium per phosphate group (a=1). The
data in Table 1 shows that doping by itself provides improved specific capacity retention in this test, but not as much as
*Examples 1 and 2 (*Reference Examples).

15 Examples 4-8 and Comparative Sample E

[0063] Olivine LMFP particles having the formulae indicated in Table 2 below are made using the following process.
In a mix tank with a high shear agitator (or rotor stator mixer), iron oxalate dihydrate (solid) and manganese carbonate
(solid) are slurried with water to a concentration of 35-45 wt-% solids. In cases in which a dopant metal is included, the
20 dopant metal precursor is magnesium acetate and/or cobalt acetate. 85% Phosphoric acid is slowly metered by a pump
into the mix tank. Carbon dioxide becomes liberated as the phosphoric acid reacts with the manganese carbonate. After
the acid addition is finished, the slurry is given about 30 minutes to mix to allow the carbon dioxide to continue to off
gas. Then, lithium hydroxide monohydrate (solid) is added to the mix tank. The slurry goes through a viscous phase as
the lithium hydroxide mixes with the solids. The LiOH addition is exothermic and the temperature rises to 55-60°C.
25 [0064] Once well mixed, the slurries are milled with a series of two mills. The materials are first loaded into a Centex
disk style mill. The milling media size is approximately 0.7-0.9 mm in diameter. Once the mill is running at steady
conditions, cellulose acetate powder is loaded. Aminopropanol and citric acid are added to control viscosity. The milling
is continued until the particles are reduced to less than 40 microns. The material is then transferred into a Buhler
Micromedia mill with milling media having a size of 0.1-0.3 mm in diameter. The milling is continued until the particles
30 are reduced to approximately 50 nm in diameter.
[0065] The milled samples are spray dried at 170°C to agglomerate the small particles into micron sized balls having
diameters of up to about 20 microns. The spray dried particles contain approximately 5% water. The spray dried particles
are calcined under an atmosphere containing < 100 ppm oxygen. The particles are heated from room temperature to
400°C over three hours and held at 400°C for one hour. The temperature is then increased to 650°C over two hours
35 and held at 650°C for three hours. CO, CO2, H2O, acetic acid and tars are given off throughout the calcination process.
The particles are then cooled to below 60°C and sieved through a 44 micron sieve.

Table 2
Designation Formula a + 2b + 2c + dV
40
Ex. 4 Li1.05Mn0.75Fe0.01Mg0.07CO 0.01PO4 2.87
Ex. 5 Li1.05Mn0.75Fe0.24CO0.01PO4 3.05
Ex. 6 Li1.05Mn0.7Fe0.23Mg0.03CO0.01PO4 2.99
45 Ex. 7 Li1.05Mn0.75Fe0.15Mg0.04CO 0.01PO4 2.95
Ex. 8 Li1.05Mn0.71Fe0.19Mg0.04CO 0.01PO4 2.95
Comp. Sample E Li1.05Mn0.71Fe0.24PO 4 2.95

50
[0066] Half-cell specific capacity at 25°C is measured on each of electrode Examples 4-8 and for Comparative Sample
A (Table 1) using a Maccor 4000 electrochemical tester. Testing is performed using half-cells using a charge/discharge
rates 0.1C, 5C and 10 C. Results are as indicated in Table 3.

55

8
 EP 2 936 590 B1

Table 3
Specific Capacity
Sample Designation (mAh/g)
5 0.1C 5C 10C
Ex. 4 145 128 117
Ex. 5 155 135 108
Ex. 6 146 128 113
10
Ex. 7 148 120 100
Ex. 8 147 123 105
Comp. Sample E 154 135 118
15
[0067] Half and full cell battery for Examples 4-8 and Comparative Battery E are assembled. The anode in each case
is lithium (in the case of a half cell) and a commercially available graphite (in the case of a full cell), the anode/cathode
capacity ratio is 1.1 to 1.2 for the full cells, and the total cathode density is 1.4-1.6 g/cm3. A commercially available
separator is used with an electrolyte of a 1.15 molar LiPF6 solution in a 1:3 by weight mixture of ethylene carbonate and
20 ethylmethylcarbonate that also contains 2% by weight vinylidene carbonate.
[0068] Discharge energies at 1/10C, 1C and 5C discharge rates are measured at 25°C on each of half cell (lithium
anode) using 2025 coin cell configurations. The cells were charged using a constant current (1/10 C-rate) to 4.25V, and
then held at constant voltage of 4.25 until the current decays to C/100. The discharge is done at constant current (varying
with different c-rates) with a voltage cutoff of 2.7V. The discharge energy is calculated as the product of the integrated
25 capacity vs. voltage. Results are as indicated in Table 4.

Table 4
Discharge Energy (W-
Sample Designation h/kg)
30
0.1C 1C 5C
Ex. 4 577 535 470
Ex. 5 587 540 450
35 Ex. 6 570 530 450
Ex. 7 577 525 430
Ex. 8 570 525 440
Comp. Sample E 585 555 495
40

[0069] Full cell 50°C cycling is performed on each of Battery Examples 4 through 8. Pouch cell configurations are
used consisting of a single-side coated cathode and anode with a separator encased in a sealed pouch with electrolyte.
Two formation cycles are done at room temperature, consisting of a constant current charge at 1/10 C-rate to 4.2V, with
45 a constant voltage hold at 4.2V until the current decays to C/100. After a 5 minute rest, the cell is discharged at constant
current (C/10) to a voltage cutoff of 2.7V. After the two initial cycles, the cell is moved to a 50°C oven for cycling. The
cycle test is done using a 1C constant current charge to 4.2V, with a constant voltage hold at 4.2V until the current
decays to C/100. The discharge is done at 1C constant current with a 2.7V cutoff. Degassing of the pouch cell is done
after 5 cycles at elevated temperature, by removal of the gases in the pouch and resealing of the pouch. Examples 4,
50 6, 7 and 8 all retain at least 80% of their initial capacity for 325 to 350 cycles at 50°C, 1C/1C cycling. Example 5 retains
about 92.5% of its initial capacity only up to 250 cycles. These results, together with the results reported in Table 4,
demonstrate the advantage of selecting the value of a + 2b + 2c + dV slightly below 3.00. Example 5, which has both
excess lithium (a>1.0) and is Co doped but has an a + 2b + 2c + dV of 3.05, shows a greater loss of capacity at higher
discharge rates and a faster loss of capacity on cycling than do the other examples, in which a + 2b + 2c + dV < 3 and
55 has both Mg and Co doping. Comparative Example E, which does not have any doping, exhibits poor cycle life, and can
retain 80% of its capacity for fewer than 250 cycles.

9
 EP 2 936 590 B1

Examples 9 and 10 and Comparative Samples E and F

[0070] Olivine LMFP particles having the formulae indicated in Table 5 below are made using the process described
for Examples 1-3.
5
Table 5
Designation Formula a + 2b + 2c + dV
Ex. 9 Li1.05Mn0.75Fe0.2Mg0.02CO0.01PO4 3.01
10 Ex. 10 Li1.05Mn0.75Fe0.15Mg0.05CO 0.01PO4 2.97
Comp. Sample E Li1.05Mn0.71Fe0.24PO4 2.95
Comp. Sample F Li1.0Mn0.75Fe0.25PO4 3.00

15
[0071] Half-cell specific capacity at 25°C and discharge energy are measured for each of electrode Examples 9 and
10 and for Comparative Samples E and F as described before Results are as indicated in Tables 6 and 7.

Table 6
20 Specific Capacity (mAh/g)
Sample Designation
C/10 1C 5C 10C
Ex. 9 148 140 124 112
Ex. 10 150 144 132 116
25
Comp. Sample E 147 139 118 93
Comp. Sample F 146 127 88 47

30 [0072] As can be seen from the data in Table 6, specific capacities are much higher for Examples 9 and 10 at higher
discharge rates.

Table 7
Sample
35 Designation
CC/(CC+CV) Vave (discharge), C/ C/10 discharge energy Vave (discharge),
10 (Wh/kg) 5C
Ex. 9 0.68 3.83 564 3.61
Ex. 10 0.71 3.86 579 3.54
40
Comp. Sample E 0.70 3.85 565 3.45
Comp. Sample F 0.38 3.80 553 3.29

45 [0073] As seen from the data in Table 7, all four of the tested electrode materials provide similar average voltage and
discharge energy at a low (C/10) discharge rate. However, at a high (5C) discharge rate, average operating voltage is
significantly higher for Examples 9 and 10 than for the Comparatives.

50 Claims

1. A particulate cathode material comprising an electroactive material having the empirical formula LiaMnbFecDdPO4,
wherein

55 a is a number from 0.95 to 1.10;

b is from 0.70 to 0.95;
c is from 0.049 to 0.349;
d is from 0.005 to 0.10;

10
 EP 2 936 590 B1

(a + 2b + 2c + dV) is 2.85 to 2.99 or 3.01 to 3.05, wherein V is the valence of D, and D is a metal ion selected from
magnesium, cobalt or a mixture of magnesium and cobalt; and further wherein at least a portion of the electroactive
material has an olivine structure.

5 2. The cathode material of claims 1, wherein a is 1.00 to 1.10, b is 0.70 to 0.95; c is 0.1 to 0.3 and d is 0.005 to 0.10.

3. The cathode material of claim 1 or claim 2, wherein a is 1.025 to 1.10, b is 0.70 to 0.85; c is 0.1 to 0.3 and d is 0.01
to 0.075.

10 4. The cathode material of any of claims 1-3, wherein a is 1.025 to 1.075, b is 0.70 to 0.85; c is 0.15 to 0.25, d is 0.02
to 0.06 and (a + 2b + 2c + dV) is 2.95 to 2.98 or 3.01 to 3.05.

5. A nanocomposite containing at least 70% by weight of a particulate cathode material of any of claims 1-4 with up
to 30% by weight of a graphite, carbon black and/or other conductive carbon.
15
6. A battery cathode comprising the cathode material of any of claims 1-4, or the nanocomposite of claim 5.

7. A lithium battery comprising an anode, a cathode of claim 6, a separator disposed between the anode and cathode,
and an electrolyte solution containing at least one lithium salt.
20
8. A method for making an olivine lithium manganese transition metal phosphate cathode material, comprising

a) forming a mixture of at least one lithium precursor, at least one iron precursor, at least one manganese
precursor, at least one dopant metal precursor and at least one precursor of HxPO4 ions where x is 0, 1 or 2,
25 wherein the dopant metal precursor includes dopant metal ions selected from magnesium, cobalt or a mixture
of magnesium and cobalt and the precursors are present in amounts such that:

the mole ratio of lithium ions to HxPO 4 ions is 0.95 to 1.1;

the mole ratio of manganese ions to HxPO4 ions is 0.70 to 0.95;
30 the mole ratio of iron ions to HxPO4 ions is 0.049 to 0.349;
the mole ratio of dopant metal ions to HxPO4 ions is 0.005 to 0.10; and
the mole ratio of lithium, manganese, iron and dopant metal ions combined to HxPO4 ions is such that
[moles Li + (2 3 moles Mn) + (2 3 moles Fe) + (2 3 moles Dopant Metal)] is (2.85 to 2.99 3 Moles HxPO4)
or (3.01 to 3.05 3 Moles HxPO4);
35
b) milling the mixture and then;
c) calcining the milled mixture to form the olivine lithium manganese iron phosphate cathode material.

9. The method of claim 8 wherein the mole ratio of lithium ions to HxPO4 ions is 1.00 to 1.10, the mole ratio of manganese
40 ions to HxPO4 ions is 0.70 to 0.95; the mole ratio of iron ions to HxPO4 ions is 0.1 to 0.3 and the mole ratio of dopant
metal ions to HxPO4 ions is 0.005 to 0.10.

10. The method of claim 8 or 9 wherein the mole ratio of lithium ions to HxPO4 ions is 1.025 to 1.10, the mole ratio of
manganese ions to HxPO4 ions is 0.70 to 0.85; the mole ratio of iron ions to HxPO4 ions is 0.1 to 0.3 and the mole
45 ratio of dopant metal ions to H xPO4 ions is 0.01 to 0.075.

11. The method of claim 8 or 9 wherein the mole ratio of lithium ions to HxPO4 ions is 1.025 to 1.075, the mole ratio of
manganese ions to HxPO4 ions is 0.75 to 0.85; the mole ratio of iron ions to HxPO4 ions is 0.15 to 0.25, the mole
ratio of dopant metal ions to HxPO4 ions is 0.02 to 0.06 and [moles Li + (2 3 moles Mn) + (2 3 moles Fe) + (2 3
50 moles Dopant Metal)] is (2.95 to 2.98 3 Moles HxPO4) or (3.01 to 3.05 3 Moles HxPO4).

Patentansprüche

55 1. Teilchenförmiges Kathodenmaterial, das ein elektroaktives Material umfasst, das die Summenformel
LiaMnbFecDdPO4 aufweist, wobei

a eine Zahl von 0,95 bis 1,10 ist;

11
 EP 2 936 590 B1

b von 0,70 bis 0,95 beträgt;

c von 0,049 bis 0,349 beträgt;
d von 0,005 bis 0,10 beträgt;

5 (a + 2b + 2c + dV) 2,85 bis 2,99 oder 3,01 bis 3,05 beträgt, wobei V die Valenz von D ist und D ein Metallion ist,
das aus Magnesium, Kobalt oder einer Mischung aus Magnesium und Kobalt ausgewählt ist; und ferner wobei
wenigstens ein Abschnitt des elektroaktiven Materials eine Olivinstruktur aufweist.

2. Kathodenmaterial nach Anspruch 1, wobei a 1,00 bis 1,10 beträgt, b 0,70 bis 0,95 beträgt; c 0,1 bis 0,3 beträgt und
10 d 0,005 bis 0,10 beträgt.

3. Kathodenmaterial nach Anspruch 1 oder 2, wobei a 1,025 bis 1,10 beträgt, b 0,70 bis 0,85 beträgt; c 0,1 bis 0,3
beträgt und d 0,01 bis 0,075 beträgt.

15 4. Kathodenmaterial nach einem der Ansprüche 1-3, wobei a 1,025 bis 1,075 beträgt, b 0,70 bis 0,85 beträgt; c 0,15
bis 0,25 beträgt, d 0,02 bis 0,06 beträgt und (a + 2b + 2c + dV) 2,95 bis 2,98 oder 3,01 bis 3,05 beträgt.

5. Nanokomposit, der wenigstens 70 Gew.-% eines teilchenförmigen Kathodenmaterials nach einem der Ansprüche
1-4 mit bis zu 30 Gew.-% eines Graphits, Industrierußes und/oder anderen leitfähigen Kohlenstoffs enthält.
20
6. Batteriekathode, die das Kathodenmaterial nach einem der Ansprüche 1-4 oder den Nanokomposit nach Anspruch
5 umfasst.

7. Lithiumbatterie, die eine Anode, eine Kathode nach Anspruch 6, einen zwischen der Anode und der Kathode an-
25 geordneten Separator und eine Elektrolytlösung umfasst, die wenigstens ein Lithiumsalz enthält.

8. Verfahren zum Herstellen eines Olivin-Lithium-Mangan-Übergangsmetallphosphat-Kathodenmaterials, das Folgen-

des umfasst

30 a) Ausbilden einer Mischung aus wenigstens einem Lithiumvorläufer, wenigstens einem Eisenvorläufer, we-
nigstens einem Manganvorläufer, wenigstens einem Dotierungsmetallvorläufer und wenigstens einem Vorläufer
von HxPC4-Ionen, wobei x 0, 1 oder 2 ist, wobei der Dotierungsmetallvorläufer Dotierungsmetallionen beinhaltet,
die aus Magnesium, Kobalt oder einer Mischung aus Magnesium und Kobalt ausgewählt sind, und wobei die
Vorläufer in derartigen Mengen vorhanden sind, dass:
35
das Molverhältnis von Lithiumionen zu HxPC 4-Ionen 0,95 bis 1,1 beträgt;
das Molverhältnis von Manganionen zu H xPC4-Ionen 0,70 bis 0,95 beträgt;
das Molverhältnis von Eisenionen zu HxPC4-Ionen 0,049 bis 0,349 beträgt;
das Molverhältnis von Dotierungsmetallionen zu HxPC4-Ionen 0,005 bis 0,10 beträgt; und
40 das Molverhältnis von Lithium-, Mangan-, Eisen- und Dotierungsmetallionen kombiniert zu HxPC4-Ionen
derart ist, dass [Mol Li + (2 x Mol Mn) + (2 x Mol Fe) + (2 x Mol Dotierungsmetall)] (2,85 bis 2,99 x Mol
HxPO4) oder (3,01 bis 3,05 x Mol HxPO4) beträgt;

b) Mahlen der Mischung und dann;

45 c) Kalzinieren der gemahlenen Mischung, um das Olivin-Lithium-Mangan-Eisen-Phosphat-Kathodenmaterial
auszubilden.

9. Verfahren nach Anspruch 8, wobei das Molverhältnis von Lithiumionen zu HxPC4-Ionen 1,00 bis 1,10 beträgt, das
Molverhältnis von Manganionen zu H xPC4-Ionen 0,70 bis 0,95 beträgt; das Molverhältnis von Eisenionen zu
50 HxPC 4-Ionen 0,1 bis 0,3 beträgt und das Molverhältnis von Dotierungsmetallionen zu HxPO4-Ionen 0,005 bis 0,10
beträgt.

10. Verfahren nach Anspruch 8 oder 9, wobei das Molverhältnis von Lithiumionen zu HxPO4-Ionen 1,025 bis 1,10
beträgt, das Molverhältnis von Manganionen zu HxPC4-Ionen 0,70 bis 0,85 beträgt; das Molverhältnis von Eisenionen
55 zu HxPC4-Ionen 0,1 bis 0,3 beträgt und das Molverhältnis von Dotierungsmetallionen zu HxPC4-Ionen 0,01 bis 0,075
beträgt.

11. Verfahren nach Anspruch 8 oder 9, wobei das Molverhältnis von Lithiumionen zu HxPO4-Ionen 1,025 bis 1,075

12
 EP 2 936 590 B1

beträgt, das Molverhältnis von Manganionen zu HxPC4-Ionen 0,75 bis 0,85 beträgt; das Molverhältnis von Eisenionen
zu HxPC4-Ionen 0,15 bis 0,25 beträgt, das Molverhältnis von Dotierungsmetallionen zu HxPC4-Ionen 0,02 bis 0,06
beträgt und [Mol Li + (2 x Mol Mn) + (2 x Mol Fe) + (2 x Mol Dotierungsmetall)] (2,95 bis 2,98 x Mol HxPO4) oder
(3,01 bis 3,05 3 Mol HxPO4) beträgt.
5

Revendications

1. Matériau de cathode particulaire comprenant un matériau électroactif ayant la formule empirique LiaMnbFecDdPO4,
10 dans laquelle

a est un nombre allant de 0,95 à 1,10 ;

b va de 0,70 à 0,95 ;
c va de 0,049 à 0,349 ;
15 d va de 0,005 à 0,10;

(a + 2b + 2c + dV) vaut de 2,85 à 2,99 ou de 3,01 à 3,05, dans lequel V est la valence de D, et D est un ion métallique
choisi parmi le magnésium, le cobalt ou un mélange de magnésium et de cobalt ; et en outre dans lequel au moins
une partie du matériau électroactif a une structure d’olivine.
20
2. Matériau de cathode selon la revendication 1, dans lequel a vaut de 1,00 à 1,10, b vaut de 0,70 à 0,95 ; c vaut de
0,1 à 0,3 et d vaut de 0,005 à 0,10.

3. Matériau de cathode selon la revendication 1 ou la revendication 2, dans lequel a vaut de 1,025 à 1,10, b vaut de
25 0,70 à 0,85 ; c vaut de 0,1 à 0,3 et d vaut de 0,01 à 0,075.

4. Matériau de cathode selon l’une quelconque des revendications 1 à 3, dans lequel a vaut de 1,025 à 1,075, b vaut
de 0,70 à 0,85 ; c vaut de 0,15 à 0,25, d vaut de 0,02 à 0,06 et (a + 2b + 2c + dV) vaut de 2,95 à 2,98 ou de 3,01 à 3,05.

30 5. Nanocomposite contenant au moins 70 % en poids d’un matériau de cathode particulaire selon l’une quelconque
des revendications 1 à 4 avec jusqu’à 30 % en poids d’un graphite, de noir de carbone et/ou d’un autre carbone
conducteur.

6. Cathode de batterie comprenant le matériau de cathode selon l’une quelconque des revendications 1 à 4, ou le
35 nanocomposite selon la revendication 5.

7. Batterie au lithium comprenant une anode, une cathode selon la revendication 6, un séparateur disposé entre
l’anode et la cathode, et une solution d’électrolyte contenant au moins un sel de lithium.

40 8. Procédé de fabrication d’un matériau de cathode olivine-lithium-manganèse-métal de transition-phosphate com-

prenant

a) la formation d’un mélange d’au moins un précurseur de lithium, d’au moins un précurseur de fer, d’au moins
un précurseur de manganèse, d’au moins un précurseur de métal dopant et d’au moins un précurseur d’ions
45 HxPO 4 où x vaut 0, 1 ou 2, dans lequel le précurseur de métal dopant comporte des ions de métal dopant
choisis parmi le magnésium, le cobalt ou un mélange de magnésium et de cobalt et les précurseurs sont présents
en des quantités telles que :

le rapport molaire des ions lithium aux ions HxPO 4 vaut de 0,95 à 1,1 ;
50 le rapport molaire des ions manganèse aux ions HxPO4 vaut de 0,70 à 0,95 ;
le rapport molaire des ions fer aux ions HxPO4 vaut de 0,049 à 0,349 ;
le rapport molaire des ions de métal dopant aux ions HxPO4 vaut de 0,005 à 0,10 ; et
le rapport molaire des ions combinés de lithium, de manganèse, de fer et de métal dopant aux ions HxPO4
est tel que [moles de Li + (2 x moles de Mn) + (2 x moles de Fe) + (2 x moles de métal dopant)] vaut (2,85
55 à 2,99 x moles de HxPO4) ou (3,01 à 3,05 x moles de HxPO4) ;

b) le broyage du mélange puis ;

c) la calcination du mélange broyé pour former le matériau de cathode olivine-lithium-manganèse-fer-phosphate.

13
 EP 2 936 590 B1

9. Procédé selon la revendication 8, dans lequel le rapport molaire des ions lithium aux ions H xPO4 vaut de 1,00 à
1,10, le rapport molaire des ions manganèse aux ions H xPO4 vaut de 0,70 à 0,95 ; le rapport molaire des ions fer
aux ions HxPO4 vaut de 0,1 à 0,3 et le rapport molaire des ions de métal dopant aux ions HxPO4 vaut de 0,005 à 0,10.

5 10. Procédé selon la revendication 8 ou 9, dans lequel le rapport molaire des ions lithium aux ions HxPO 4 vaut de 1,025
à 1,10, le rapport molaire des ions manganèse aux ions HxPO4 vaut de 0,70 à 0,85 ; le rapport molaire des ions fer
aux ions HxPO4 vaut de 0,1 à 0,3 et le rapport molaire des ions de métal dopant aux ions HxPO4 vaut de 0,01 à 0,075.

11. Procédé selon la revendication 8 ou 9, dans lequel le rapport molaire des ions lithium aux ions HxPO 4 vaut de 1,025
10 à 1,075, le rapport molaire des ions manganèse aux ions HxPO4 vaut de 0,75 à 0,85 ; le rapport molaire des ions
fer aux ions HxPO4 vaut de 0,15 à 0,25, le rapport molaire des ions de métal dopant aux ions HxPO4 vaut de 0,02
à 0,06 et [moles de Li + (2 x moles de Mn) + (2 x moles de Fe) + (2 x moles de métal dopant)] vaut (2,95 à 2,98 x
moles de HxPO4) ou (3,01 à 3,05 x moles de HxPO 4).

15

20

25

30

35

40

45

50

55

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EP 2 936 590 B1

15
 EP 2 936 590 B1

REFERENCES CITED IN THE DESCRIPTION

This list of references cited by the applicant is for the reader’s convenience only. It does not form part of the European
patent document. Even though great care has been taken in compiling the references, errors or omissions cannot be
excluded and the EPO disclaims all liability in this regard.

Patent documents cited in the description

• WO 2009144600 A [0004] [0055] • EP 1150367 A [0008]

• US 7842420 B [0004] • EP 2383820 A [0009]
• WO 2011025823 A [0004] • WO 2007064934 A [0011]
• US 8168150 B [0004] • WO 2008018633 A [0012]
• US 2012301780 A [0005] • WO 2009127901 A [0044]
• JP 2004063422 A [0006] • US 7169511 B [0049]
• JP 2012190568 A [0007]

Non-patent literature cited in the description

• HAISHENG FANG et al.

LiMn0.8Fe1.9Mg0.01PO4/C as a high performance
cathode material for lithium ion batteries. J. Power
Sources, 01 April 2012, vol. 204, 193-196 [0010]

16