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CBSE Class-12 Physics Quick Revision Notes
Chapter-12: Atoms
Thomson's Model of an Atom:
An atom consists of positively charged matter in which the negatively charged electrons
are uniformly embedded like plums in a pudding, This model could not éxplain
scattering of alpha-particles through thin foils and hence discarded
Rutherford’s Model of an Atom: (1411)
Ge
and Marsden in their experiment on scattering of alpha-particles found that mos
of the alpha-particles passed undeviated through thin foils but some of them were
scattered through very large angles
he following model of ar
From the results of these experiments, Rutherford proposed
atom, ae
ay a
tom Consists of a small and massive central cc ye which the entire positive
charge and almost the whole mass of the atom are coucentrated. This Gore is caller
the nucle <14m) %
10 : ,
pe fosedeits tatupies avery sali Spoce asCompared to the size of the stung 10. ™
¢) The atom is surrounded by a suitable number of clectros so that their total negative
charge is equal to the total positive charge on the nucleus and the atom as a whole
electrically neutral
a) The electrons
volve around the nucleus in various orbits jist as planets revolv«
around the sun
¢) The centripetal force required for their revolution is provided by the elvetrostatio
attraction between the electrons and the nucleus
Draw-back of Rutherford Modi
This model could not expiain
lability of the atom because according to classical
electromagnetic theory the electron revolving around the nucleus must continuo oly
radiate energy revolving around the nucleus must continuously radiate energy in the
form of electromagnetic radiate energy in the form of ¢lectromagnetic radiation ane
hence it should f.
Distance of Closest Approach:
When an alpha-particle of mass m and velocily Vmoves directly towards a nuch
atomic number Z, its initial energy E, which is just the kinctic energy K gets complete!
converted into potential energy U at stopping point. This stopping point happens te be ab
a distance of closest approach from the nucleus.
Lip | Ze I 97e
2 Aly do Afétly Alegk
i into the nucleus.
Hence,
It.
Impact Parameter: yor
a) Itis defined as the perpendicular distance of the velocity’of the alpha-particle from
the central of the nucleus, when it is far away from the atom
b)_ The shape of the trajectory of the scattered alpha-particle depends on the impact
parameter b and the nature of the potential field. ,
c) Rutherford deduced the following relationship between the impact parameter band
the scatte
4% np 20 D Geb 275 Cal
Quantisation or Discretisatior
The quantization or discretisation of a physical quantity means hat it cannot Vary
conunuously to have any arbitrary valu€but can change only discontinaously to take
certain specitic values.
Bohr’s Model for the Hane Atom: (/9/2)
Basic postulates (Quontum iene es Ruthescfirdt abornte model)
4) Nuclear concepts
An atom consists of a small ynassive central called nucleus around which Fe=Fe
planetary clectrons revolve. The centripetal force required fot their rotationie tut. p Se
provided by the electrostatic attraction between the electrons and the queleug
b) Quantum condition: ,
Of all the possible girewlar orbits allowed by the classical theory the electrons are.
permitted to circ ly in such orbits in which the angular momentur
electron is an integral multipleof h/2ar, hleeing Planck’s constant -
tre b-62%I0 eters
eDr
ye
led principal quantum number,
tionary orbits:
While revolving in the per
‘These non-radiating orbits a
d) Frequency, conditions
An atom Can emit or absorb radiation in the form of discrete
when an electron jumps from 4
orbit Es and ts are the energies axsoctated with these pert
issibie orbits, an clectron does not
called stationary orbits.
frequency Y of the emitted absorbed radiation is,
hw = Ej - &f
©) Radius of the orbit of an cleetron in hydrogen atom is,ww ewe eee ree ere ee ee
7 TF Fy FF
[i
s —_ Larch. hagpem of Hal
Eo=
€s
€
«6 | a (x)
2 13% 2 0. 85eU ;
eat 23 . = Coen
th ponradttd
Be CBSE de rar Cxoddl of 1 FO rs teh 5
A abem
e _ berth Qadivs of 3 op BE (n=) Of
amin ~ prnert ' 44 cableol Bob radtus (Aa) again
‘Aol Kinetic energy K ony tic potential energy U of the electron in hydrogen
atom E= K+U
BP Total enemy E of the electron it hydrogen atom
- 2 _ -2' ne mer _ En |. ks
Boksve-ge, = Gane (eatwe) 9|-greemt "PS
aye on
h) Speed of an eletyon in th rast
murs hse OF tind A
Where a
1s (ine structure constont ot
y
ch
i) Energy ofan electron in ath orbit tf €
En = EE for BEA Ey Rye - Be
+ Failure of Bohr’s Model: (heowe Ry = AO called Ting Cette
8) This mode! is applicahiconly tolyerager-tke Sams and folaincaee other = 10% F a
‘atoms.
b) Itcould not explain the tine structure of the spectral Fines in the spectrum of
hydrogen atom
he ehergies of the different stationary’states of an atem are
izontal lines drawn according to Some suita ble energy seals.
Atom:
epresented by paralle! |
+ Spectral Series of Hydrog
Whenever an cle in hydrogen atom makes a transition from a higher ene piled
ni to lower « vel vy. the difference of energy appears iti the form of a phoror ot
frequency Visgwenby— Ej Eg=hO > yr EI-Ef whee ee
va deneel als +: CeVA gy ca gh Ee
ae % ae
Different Spectral Series of Hydrogen a $ ehh ae
These are 2s follows:
a) Lymon Series. Herem=2.3.4....andryed This series ies inthe suite on
5) Bolmer Series, Here} 45 ond ¥y=2 This Senes lies inthe visible region
| Paschen Series. Herenj= 45.6 andmy =3 This series lies inthe infrared regien
Brockett Series Here mg= 5,67... ty =4-This sores hes in the infrored region
136 - 3.400 “i exiled flabes
ee t- nee
5 ABE = ST
«)te) Pfund Series. Here nye 6.7.8 ong? 8 ‘This series lies in the infrared region.
Excitation Energy:
Its defined as the energy required by an electron ofan atom to jump from its ground
state to any one of its existed state.
lonisation Energy
Wis defined as the energy required to remove an electron from an atom, ie, the energy
required Lo Lake an electron from its ground state to the outermost orbit (n= ©)
Excitation Potential:
Tis the accelerating potential which gives sullicient energy to a bombarding electron se
to excite the target atom by raising one of its electrons from an inner to and outer oF
Jonisation Potential;
{tis the accelerating potential which gives to bombardjng elect: on the sufficient energ:
to an outer orbit
De Broglie’s Hypothesis:
The electrons having a wavelength 2 =h/mv gave an explan:
orbits by bringing in the wa
ton for Boli's quantised
ve particle duality. The arbits correspond to circular
standing waves in which the circumference of the orbit equals a whole number of
MASER:
a) Maser stands for Microwaves Amplification by Stimulated Emission of Radiation
b)_Itis simply a device for producing
collimated beam of microwaves
LASER:
a) Itstand for Light Amplification by Stimulated Emission of Radiation.
b) tis a device used to produce highly intense strong monochromatic coherent anct
epllimated beam of hi
y intense, monochromatic coherent and
ESS
n=6
st
Leonel m4
NeB