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NUMBER ¢ AUGUST 15, 1948
On the Classical Equations of Motion of Point Charges
Peer Havas
Department of Physics, Lehigh University, Bthchem, Pennsylvania,
(Received February 9, 1948)
Recent attempts to obtain the force of radiative reaction
in the classical equations of motion of point charges have
proceeded from two diferent viewpoints. Each of these
has to introduce one basic assumption in addition to
‘Maxwell's equations, namely the conservation law for the
electromagnetic energy-momentum tensor in field theory
and the relation between the Lorentz force and the
‘momentum of the particle in action-at-a-dstance theory.
In previous fld-theoreical derivations the Lorentz-Dirac
equations including radiation damping are obtained only
‘fone takes the field produced by the particle to be the re-
‘tarded field; but equations of motion without the damping.
term are obtained if one uses half the sum of retarded and
1. INTRODUCTION
NE of the major problems of classical
electrodynamics has been to account for
the force experienced by a charge as a result of
its motion, The first attempt at a solution due
‘to Lorentz! was based on a model of an extended
charge and attributed the force of radiative
reaction to the action of one part of the particle
‘on another. It appeared as the first term in a
series in powers of the radius of the particle, and
all higher terms depended upon the charge
distribution assumed. This, and the fact that it
appears to be very difficult to fit finite-sized
elementary particles into the schemes of rela
tivity and of quantum mechanics makes it
desirable to treat these particles as mathematical
points? In Lorentz’ theory, however, infinities
appear in the equations ifthe radius goes to zero.
Recent attempts to obtain the force of radia
tive reaction have proceeded from two different
viewpoints. One is that of field theory, which
considers the otal field at all points in space to
be the fundamental physical quantity and the
point charges as singularities of the field. The
other is that of action at a distance, which
considers only the forces exerted on a charge by
other charges to be physically meaningful.
‘The field theoretical point of view was first
THEA Lorentz, Collected Papers (ML. Niof, The Hague,
1930), Va, pp. 281 and $43. Also The Theory of Electrons
(Teutiner; Leipe, 1908) pp 49 and 153.
(SE rate Zeta Biya 3,318 (1925)
advanced fields. On the other hand, the theory of action
at a distance as developed by Wheeler and Feynman was
able to obtain che radiation damping using fields sym-
‘metric in time. Ie is noted that the need for the exclusive
‘ise of retarded fields arote only in the fel-theoretieal
derivations for the one-particle problem. The considera-
tons of Wheeler and Feynman on the total fld due to all
particles of the universe are, however, applicable to eld
theory in the symmetric form as well as to actionat-a-
distance theory. The acceptance of their condition of,
“complete absorption” again leads to the radiation
damping term in the equations of motion of the many-body
problem. Some implications of this result are discussed
applied successfully to this problem by Dirac’
who showed that the equations of motion are
suggested by the conservation law for the electro-
‘magnetic energy-momentum tensor. He clearly
stated it as follows: “The usual derivation of
the stress-tensor is valid only for continuous
charge distributions and we are here using it for
point charges. This involves adopting as a
fundamental assumption the point of view that
energy and momentum are localized in the field
jin accordance with Maxwell's and Poynting’s
ideas." Using this conservation law and Max-
well’s equations he obtained Lorentz’ equations
of motion, but whereas these equations were
considered by Lorentz to be only approximate,
Dirac concluded that ‘there is good reason for
believing them exact, within the limits of the
classical theory.””
Another field theoretical derivation of these
equations was given by Infeld and Wallace,‘ who
succeeded in linking it with the general method
of obtaining equations of motion in general
relativity of Einstein, Infeld and Hoffmann.®
‘The main interest of their paper for the present.
purpose is that they showed explicitly that, for
the case of a single particle, the Lorentz-Dirac
equations including radiation damping are ob-
YP. A. M. Dirac, Prot, Roy. Soc. A167, 148 (1938). In
the flowing quoted ay D.
"Le tnfeld and P. H. Wallace, Phys. Rey. 87,797 (1940)
Inthe following quoted as IW.
VA Blasteins Es Tnfeld and B, Hoffmann, Ann, Math
39, 68 (1938).
456CLASSICAL EQUATIONS FOR POINT CHARGES
tained only if one takes the field produced by
the particle tobe the retarded feld; but equations
of motion without the damping term are obtained
if one uses half the sum of retarded and advanced
fields.
‘The first derivation of the force of radiative
reaction on the basis of action at a distance is
due to Wheeler and Feynman.® As itis necessary
in any action-ata-distance theory to introduce
an assumption on the basic equations of motion,
they had to assume that the Lorentz force acting
on a particle equals its rate of change of momen-
tum. On the other hand, they were able to obtain
the Lorentz-Dirac equations taking the forces
on the charges as determined by half the sum
of the retarded and the advanced field.
It was of considerable importance to show
that the fundamental law of fore is symmetric
with respect to past and future, and to settle
the question first raised in 1909, in which “Ritz
considers the limitation to retarded potentials
as one of the foundations of the second law of
thermodynamics, while Einstein believes that
the irreversibility of radiation depends exclu-
sively on considerations of probability."7 It
appeared that the theory of action at a distance
was preferable to the point of view of field
theory, which seemed incapable of explaining
the radiation reaction using fields symmetric in
time.
However, we shall show that this is actually
not the case. The need for the exclusive use of
retarded fields for the explanation of the radia-
tive reaction arose only in the field-theoretical
derivations for the one-particle problem. ‘The
considerations of WF on the total field de to al
particles are, however, applicable to field theory
as well as to the theory of action at a distance
‘The acceptance of their condition of “complete
absorption" does not yield any new results in
field theory if the retarded field alone is used,
tout in the case of half-advanced, half-retarded
fields it does provide the radiation damping term
in the equations of motion. Therefore, subject
to this condition, one can oain the Lorens-Dirac
fquations in both theories starting with fields
1,8, Wiel and. P. Feyaman, Rev. Mod, Phys 17,
187 (945). In the following a
Ba dada Eiotehs Pys Zets 0,323 (1909).
437
symmetric in time, in spite of the fundamentally
different underlying physical ideas.*
UL. FIELD THEORY: THE FORMULATION OF
INFELD AND WALLACE
We shall first outline the field theoretical
derivation of the equations of motion due to
Infeld and Wallace. We write down the con-
servation laws for the electromagnetic energy-
‘momentum tensor
Tn =Tnas aw 21)
Toma Tone (aw 2.22)
where
Tn =Maxwell stress tensor =FrasFss—FraoFao
H1Aige PsP $1 /28maF Pon (IW 2.3)
Poynting vector= FyaF ix (uw 24)
Energy density =1/2F.F,
+1/2F Fr, (IW 2.3)
Fu=E, and Pax=tqnoll where B, and H, are
the electric and magnetic field respectively,
Sqn is the Kronecker symbol, and eae is the
permutation symbol (Levi-Civita tensor dens-
ity). Latin letters run from 1 to 3 and repetition
‘of an index implies summation over this range.
“wn and “o” denote partial derivatives with
respect to the coordinates x* and time, respec-
tively. The velocity of light is taken as unity.
The conservation laws break down only at
points occupied by a singularity. We shall choose
a Lorentz frame of reference in which the point
charge is instantaneously at rest at the origin
at some moment f. Then if we take any surface
enclosing the singularity it can be shown that
the four surface integrals
Stortvaanris —aw2.10)
fotwtveonas awa.
Tip awn”. tay ain
ata distance and field theory, WE refer ‘only to the formal
adie raion eects
seh ataan niente here
Seeger de seach ire mies
Mas Scene rhe ene
Nerctaeteenontysncey ore
eat ealenca Sere
ipeeine ise eine? Pet Pa
ae ccgarheed eerie
ESS iS ta ote458 PETER
are independent of the shape and size of the
surface chosen, and hence can depend only on
{quantities characterizing the singularity, in par-
ticular the coordinates of the singularity and
their time derivatives, Here \" are the direction
cosines of the normal to the surface of integra-
tion
Yu Va— in
Vem e
(aw 2.14)
(aw 2.15)
where Yq, Jo are arbitrary harmonic functions
and Yq, Fe are solutions of the Poisson equation
which’do not contain in their development with
respect tor an harmonic funetion of the type 1/.
‘The motion of the singularity is determined by
the assignment of consistent values to the four
surface integrals. We ean assume that they are
equal to zero and shift the task of determining
the motion to the choice of the arbitrary har-
monic functions. Calling the coordinates of the
singularity 9"(0), and indicating derivatives with.
respect to time by dots, we have as the simplest
vial choice?
vi
and obtain then for the equations of motion
=m.li"/n)
main —1/he f Tan Ye dMER. (IW 2.16)
We note that up to this stage it did not
matter if retarded or advanced felds were used.
We are only concerned with this problem when
wwe evaluate the integral over Ty.
‘The integrals over Ye,» can be shown to be
zero. For the fells determining Tn we have t0
take the total fekds
aw La),
aw 12)
the electromagnetic scalar potential,
Fan tne omtentPan
Far tne Yam tent ae
where eis
Ti has been shown in IW that this choice corresponds
to the choice of an energy-momentim tepor for matter
snd that the arbitrariness can be removed by an appeal
the eneal rity theory. The same argument bole
of the derivation nD Equations of marion based on the
Sesion of B, but using a diferent choice of the abe
trary functions, have ben sugested by C. J. Elica,
Brog. Camb, Phi, Soc: 42,218 (1516) Teappeae rom the
hve iat ne se euton ate pte enue
ith the general theory
HAVAS
and 7 the vector potential of the field of the
point charge itself, and wiFy» is the external
field (including the fields of other point charges).
If we take for 7, half the sum of the retarded
and advanced potentials, we obtain for the
equations of motion
mei =e elm (aw 2.17)
where uw, is the external electric field (the
fields of the other point charges also being taken
as 1/2 (retarded +advanced) field) evaluated at
the position of the singularity at the moment #.
These ate just the usual equations of motion
without radiation reaction, except for the special
‘form of the felds of the other charges.
If we choose for 7, retarded potentials only
wwe obtain
main —e alin + 2/309" (IW 2.18)
where we have to take in wy the contribution
due to other charges as retarded fields only
‘These equations do contain the radiation rea
tion.
The above equations held in a special coordi-
nate system only. We consider a four-space with
coordinates 2 and signature + — — —, Greek
letters taking the values 0,1, 2, 3 where x* is the
time coordinate and x','x, x are the space
coordinates. The vector ois defined as the
four-dimensional velocity vector of the point
charge. Accents indicate differentiation with
respect to arc length in space-time. Then it may
be shown that in the first case (from now on
referred to as the symmetric case) the equations
of motion become
For (IW 2.19)
and in the second case (from now on referred to
as the retarded case)
mf? oF +2/300"*
+2/3e%* (IW 2.20)
where ae? is evaluated at the world point of
the singularity and contains symmetric contri-
butions from the other charges in the symmetric
case and retarded contributions only in the
retarded case." Equations (IW 2.20) are just
the Lorentz-Dirac equations.
‘This distinction in the meaning of may" i the two sets
‘of equations has not been made explicit in IW, ae that
was not concerned with aryapplication of thowe
‘abalone, but it obvious from their Gerivaton.
maCLASSICAL EQUATIONS FOR POINT
For future reference we shall make the dis-
tinction between the meaning of waF,* in Eqs.
(IW 2.19) and (IW 2.20) explicit by writing it as
waPP= E 1/2 FH” + aah AO) + FY (1)
in the symmetric case and
oF Z vel
Ey @
in the retarded case. Here ya FiM and yay”
are the retarded and advanced fields of the k-th
charge, and .F,* is a solution of Maxwell's
‘equations for empty space, which of course is not,
necessarily the same in the retarded and in the
symmetric case.
We obtain, therefore, for the equations of
motion
mapa = 06 EAA FA + aay EAP)
teas eet (3)
for the symmetric case, and
acaba EPPO Hee Erte
OY papsecee$2/Sececrae
for the retarded case. All #'s are evaluated at
the world point of the a-th singularity, whose
rest mass we have denoted by m, now instead of
‘ma its velocity vector by 144, and its charge by e,.
Dirac’s results are entirely equivalent to those
of Infeld and Wallace. As Dirac states, however,
of Eq. (4) that it has been “obtained in a theory
which is fundamentally symmetrical between
retarded and advanced potentials”, we shall show
in the Appendix that actually he did not use any
symmetry relations in his derivation of the above
‘equations, but retarded fields only.
MIL ACTION AT A DISTANCE: THE WHEELER-
FEYNMAN THEORY
In the theory of action at a distance as
developed by Fokker" and Wheeler and Feyn-
man’ the equations of motion of the a-th charge
are assumed to be!
mata eaP 04" ©)
WA. D. Fokker, ets, Physik $8, 86 (1929), We are
got entre herewith cer formulations actin a
**Hlere and inthe following we shall change the notation
‘of WE ightly to conform tothe one employed above.
CHARGES 459
where the right-hand side is the Lorentz force
acting on the particle, and F is the field
LUA P+ say),
(WF 38)
‘Therefore, we have
malt ee EAA FO + ao PM}!
O)
‘The expression (WF 38) can be broken down into
three parts
Em FO 1/2 wa —1/2 wae)
~ E12 Fay FO),
(WF 39)
‘The second term of this will contribute to the
force an expression
Cal /2raFoM© —1/2uae PM)"
‘This reduces, according to Dirac, to the form
2/3eaate! —04"ty)04? (WE 41)
which can also be written
2/Seoa"*-+04!099),
‘The third term has no singularities anywhere and
is, therefore, a solution of Maxwell's equations
for empty space, which we shall call /F to
distinguish it from the empty-space solutions
introduced in (1) and (2), or
E 1/2 mF
a sar P) o
‘Then we obtain for the final equations of motion
rmesE mbes
$2/eaMoa! +
for the case which WF call “
tion”. The case which they call “complete
absorption" is characterized by
E (oF — sav F®) =O (everywhere).
Using t
“7 While (WF 37) was obtained in WF from the relation
3 (12 iF 41/2 sayF)=0 (outside the absorber)
(WE 37)
relation, * we obtain for the equations
{is only (WWF 37) which i used inthe equations of motion
A GWE 3) te a division of the universe into,
Dart inside” the absorber and’a part “outside” it it
Sopears irreconcilable. with any” current comologial460 PETER
of motion
mand ta E oh!
+2/3e2(ou"+2%00). (WE 42)
IV, FIELD THEORY AND THE CONSIDERATIONS
‘OF WHEELER AND FEYNMAN
Following Infeld and Wallace we obtained two
different sets of equations of motion for the
retarded and the symmetric case (Eqs. (3) and
(4) respectively. If we considered the equations
significant for the case of a single particle, we
would obtain a force of radiative reaction in the
retarded case only. However, itis clear that we
can only compare those equations with experi-
‘ment which take account of the existence of a
large number of particles in the universe (which
may or may not lead to the same conclusions
as the simpler equations for the one-particle
case). We shall show that we can take over the
considerations of Wheeler and Feynman on the
field of all particles in the universe into field
theory and we shall then obtain the radiative
reaction also én the symmetric case just as in the
theory of action at a distance.
Except for its last term, Eq. (3) of feld theory
is of the same form as Eq. (6), the starting point
of the theory of action at a’ distance. Its first
term on the right-hand side is just the expression
(WF 38) and we can break it down into three
different fields exactly as WF have done, for
none of their arguments (once Eq. WF 38 is
accepted) involves any distinction between field
theory and action at a distance. Therefore, we
we obtain finally, corresponding to (WF 44),
ca mF PV + 2/3004 040)
telFet Feet (8)
where the sum in the last term is due to two
fields each of which is a solution of Maxwell's
equations for empty space and, therefore, still a
solution for empty space.
If we accept (WF 37), we obtain corresponding
theory, while (WF. 37) holds everywhere and ia therefore
secon wd ana maghe even bea consequence eons:
‘geal considerations, Alaa (WF 33) does not have fo hold
EGHESH o be tre, Tae makes ore platable at
sreentainpytotaks OVE 31) asan additonal aesmption
BRC Ros:
HAVAS
to (WF 42)
tata! 60 Esa A
i
$2/eao"-+ 0.0) tee Fee. (9)
Equation (4) (the retarded case) is already of
the form of Eq. (8) (except that the term
involving F if absent), and nothing new is
obtained if one takes into account all particles
the universe
We have considered in outline the derivation
of the equations of motion from the point of
view of field theory first in order to show that,
starting from the total field, one may obtain the
Eqs. (3) or (4) which apparently do not involve
the total field, but only the “external” one, and
are therefore of the same form as in action at a
distance. This, then, enabled us to show that the
application of the WF considerations to the
symmetric case yields the radiation damping
term which appears in the retarded case already
without these considerations.
However, we could have seen without any
calculation ‘that under the so-called “complete
absorption” conditions any results of field theory
‘must be the same in the symmetric and in the
retarded (and also the advanced) case. For the
condition (WF 37) can also be written
Eh = Tae
=F 1/2 PO +1/2 sae), (10)
and these are the fields (due to sources) which
have to be inserted into the energy-momentum
tensor at the start of any field-theoretical calcu-
lation in the retarded, advanced and symmetric
cases, respectively. As these are equal, it is
obvious that the equations of motion must also
be the same in all cases.¥¢
While this demonstrates the equality of the
equations of motion arrived at in the various
cases, the explicit form of the equations must be
obtained by a calculation such as those of Dirac
or Infeld and Wallace.
It should be noted that in the theory of action
‘at a distance, contrary to field theory, Eqs. (10)
or (WF 37) do not lead to the same equations of
“he ton (10) was sgzested by A. insti, Phys
Zit 0,18 C00), Cl aaa seleneCLASSICAL EQUATIONS FOR POINT CHARGES
461
TAME I
Basic assumptions
Fields used Retarded
Equations obtained ®
Additional assumption None
Final equations ©
‘Terms common to all fal equations
Additional terms (to be multiplied by eat)
*
Field theory Action ata distance
“Maxwells equations
Conservation laws forthe electro-
smametic energy-momentusn tensor
Lorente Eq. (5)
awa)
Symmetric Symmetric
® ©
None (WF 37) None. (WE 37)
° OWE 44) WF 42)
eBing $2) eae)
a ae None
motion in all cases. As it is not the total field
which enters the starting equations (8), the final
equations (WF 42) ean be obtained in the sym-
metric case only.
If one does not assume condition (WF 37), we
have from (7)
E ea FE (/2 FED aay) 4 F
=D seP+2,F.
(a)
Therefore, the total fields in the three cases
differ only by solutions of Maxwell's equ
for empty space, and the equations of motion
will only. differ in the terms involving such
solutions (ef. Eqs. 4 and 8).
In short, the mathematical reason for the
similarity of (4) and (8) is simply that two
solutions of the inhomogeneous wave equation
can at most differ by a solution of the homo-
sgencous one.
DISCUSSION
We shall now inquire into the relationship
between the five different sets of equations of
motion: Eqs. (4), (8) and (9) from field theory
and (WF 42) and (WF 44) from action at a
distance.
‘To facilitate the comparison we summarize
the assumptions and results in Table I. ‘The
last row shows that these equations differ
mathematically only in fields which represent
‘empty-space solutions. However, physically the
fields .F and ,F do not have the same significance.
JF is a solution of the homogeneous wave equa-
tion, which arises only in field theory and may be
due wholly, partly, or not at all to sources; but
at present field theory is unable to analyze it
any further. ;F on the other hand is uniquely
determined by the sources according to relation
(@, which states that it is half the difference of
the retarded and advanced fields of all particles.
As shown in section III, the term ¢.0."/F,* con-
tains a part which just cancels the radiation
damping term 2/3ez(o4"*+04"4). ‘Therefore,
the similarity of Eqs. (8) and (WF 44) to (4), (9)
and (WF 42) is purely formal and (8) and
(WF 44) actually do not describe radiating
icles (ef. the discussion of “‘incomplete ab-
"in WF).
If we adopt the assumption frequently used in
field theory that .F=0, Eqs. (4) and (9) reduce
to (WF 42). However, it should be kept in mind
‘that while the solutions of the equations of the
symmetric case (9) and (WF 42) are subject to
the restriction (WF 37), those of the retarded
case (4) are not. Therefore, we (and also WF)
have not shown the complete equivalence of the
retarded and symmetric cases.
Keeping the assumption .'=0, we have, on
the other hand, complete equivalence of Eq. (9)
and (WF 42) of field theory and action-at-a-
distance theory, respectively, describing the mo-
tion of radiating charges. These identical equa-
tions have been obtained from two basically
different starting points, while using in common
Maxwell's equations, fields symmetric in time,
and the condition (WF 37).462 PETER
In both theories we have to introduce one
additional assumption, namely, either the con-
servation law for the electromagnetic energy=
momentum tensor, or the relation between
Lorentz force and momentum. The advantage
of action at a distance is the plausibility of the
physical idea of reducing everything to the
interaction of particles. But this is balanced by
the difficulties connected with the conservation"
and transmission of energy and momentum.
Therefore, none of the viewpoints appears to be
preferable to the other from considerations of
simp!
Clearly a direct verification of the fundamental
assumptions of the two viewpoints is impossible,
as one cannot observe a field without a test
charge, the effect of which, however, would have
to be included in the total field. ‘The only
experimentally verifiable conclusions are pre-
cisely the equations of motion.
Comparing these equations, we see that there
is mo effect which would require the point of view
of action at a distance. On the other hand, the
demonstration of a non-vanishing .F would show
an effect which can only be explained by field
theory
Such a demonstration, while possible in princi
ple, appears to be impossible in practice, a
would amount to finding whether the observed
field is “only” due to the retarded fields of all
the charges in the universe, or whether there is
still another part.
‘Therefore, as far as the symmetric case is
concerned, there do not seem to be any com-
pelling reasons at present to prefer either of the
‘two points of view. It appears possible, however,
that the application of these viewpoints to
general relativity or to quantum mechanics will
provide such reasons.
‘The author wishes to thank Professors J. A.
Wheeler and R, P. Feynman for a stimulating
discussion, and Professor R. J. Emrich for his
valuable criticism of the manuscript.
APPENDIX
‘We want to show that Dirac’s formulation of
the field theory for the one-particle problem
leads to the same conclusions as that of Infeld
and Wallace, namely that one does obtain the
term of radiative reaction only in the retarded,
HAVAS
but not in the symmetric case,
‘tual field as"®
saP ra tial
where iF is the incident field, a solution of the
homogeneous wave equation, as is ue, which is
defined by
(D8)
wePal oul (D9)
‘The difference
bP = oy, PF = in (D10)
a = a —aaeP wm
is called the field of radiation in D. The equations
‘of motion are obtained by substituting the actual
field (D 8) into the energy-momentum tensor.
After a rather long calculation, which, however,
wolves only the use of Maxwell's equations,
his stress-tensor and (D 8), Dirac obtains the
result
ot (D2)
where
wP-1/UvaF+uivF), — (D 13)
J=1/Moa Pav) inF
from which we get (see (WF 41) above)
mo! —2/38(0"*-+ 00H) =00" Fi? (D 24)
If we had used the field of what we called above
symmetric case, we would have had
sesF 1/2 + uaF) +inP.
It can be easily seen, following Dirac’s caleula-
tions, that the introduction of this expression
‘would still have led to (D 22) with the definition
(13) or with
Sauk
and, therefore, we would have obtained as our
equations of motion
mle meo? WF,
do not include the term of radiative
Here, and in the following, we shall change the nota-
tion of B slightly to-conform to the one employed above
‘Alo, as we shall only have to follow the argument of D
‘without any detailed caleutatons, we shailomie sub and
ereipa for conveience wietever there w no dager
S97 reaule has alzo been obtained b ieee,
Rev, Mods Piya oy 147 GBH) fae b= Syn waPHOTO-VoLTS
For the case of several particles, analogous
considerations would lead to our Eqs. (4) and
(3) respectively.
‘Therefore Dirac’s derivation is in accord wit
the one of Infeld and Wallace outlined previ-
ously. However, we noted that Dirac himself
calls his theory fundamentally symmetrical be-
tween retarded and advanced potentials. The
contradiction seems to come from the fact that
Dirac considers his theory symmetrical due to
the apparent symmetry of the use of retarded
and advanced fields in definitions (D 8) and
(D9) (and the analogous definitions (D 38) and
(D 39) for the many-body problem).
Ic EFFECT 463
However, it should be noted that in the
derivation by Dirac outlined above, he is only
using (D 8) (respectively D 38). ‘The definition
(D9) never enters into any of
which lead to his equations of mi
used in a purely formal manner to introduce
the notion of aM (see (D 10)) into some of the
‘equations; but the results themselves are inde-
pendent of it
"The purely formal character of any definition of the
radiation Bild can be sce hwo Trom the fact that in WE
{he term “radiation field” i teed for just 1/2 mF of D,
stain Sy a dingo otros 4 he ony
ROESa of cifpon chartbe “mations
VOLUME 74, NUMBER ¢ august 1s,
The Photo-Voltaic Effect
K, Lanovee
‘Signal Corps Engineering Laboratories, Fort Monmouth, New Jersey
(Received March 19, 148)
‘The Schothy-Mott theory of the barrier layer rectification is extended with respect to the
action of light absorbed in the barrier layer. The essential physical assumptions to be used
are as follows: (a) The barrier layer is a boundary layer of a semiconductor with a reduced
‘density of mobile charges (cther electrons or holes"); (b) both positive and negative mobile
‘charges are released by light; (€) the recombination within the barrier layer is negligible;
‘and, (€) the electrons and "holes" have the same properties whether released by light or by
thermal agitation. Thus an “equation of state” connecting. photowoltage, photo-currea,
Tight intensity, wave-length, external resistance, etc, i derived. Among others the regularities
of short circuit exerent, open circuit voltage, photo-characteristc, dark characteristic (barrier
layer rectification), power output, and spectral distribution of the quantum yield are involved.
1 INTRODUCTION
HE, most successful theory in the explana-
tion of the barrier rectification is the theory
of W. Schottky? and N. F. Mott.! In his discus-
sion of the action of light in a barrier layer of the
nature described by the above theory, N. F.
Mott has already succeeded in explaining the
sign of the photo-voltage* In this paper we
generalize the fundamental assumptions of
W. Schottky and N. F. Mott and derive a
comprehensive formula for the barrier layer
photo-effect.‘ The establishment of one formula
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oy. Soe London AUT, 27 (1950)
tN’ Fi Mot’ Pros Roy Soe: London
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note by the author in Optik 1, tse 3 (1946)
for the manifold of barrier layer photo-cells
varying in peculiarities is possible since the
peculiarities of minor importance enter only into
the parameters of the formula, which remain
‘open to a further discussion in special cases.
We shall treat explicitly the photo-effect in
semiconductors only for the case where the
mobile carriers of charge are electrons (n-type
semiconductors) and shall state the corre-
sponding results for semiconductors with “hole”
conductance (p-type semiconductors).*
TL BASIC CONCEPTS ABOUT THE BARRIER LAYER
In principle both barrier layer rectifiers and
barrier layer photo-cells consists of a semicon-
K, Lehover, Zeit. f. Naturforsch. 2,398 (1947).