Redox Pyq
Redox Pyq
On                   Oxidation
                                                                                                                                             Number7.3                (cAu    Without
                                                                                                                                                                        ) cannot                     7.2                   a)
                                                                                                                                                                                                              (d) (c) (b) (Which
                                                                                                                                                                                                                                        71
                            Ihe                   (a)
                                             (c) CH4p)       What
                                                             in (d) 2KCIO,          (b) (a) Which (c) (a) the aCr,0
                                                                              (c) displacement                                                                            (a) Pb
o=r-Br (a)                                               the                                         coefficients                                                                                                                          https//bit.ly/42OFVS
                                                                                                                                                                                                                                                         video scan Visit or
                    correct                     - +                      Fe
                                                                         Cr,0,                         1, 1, balancing                                                         Reactions
                                                                                                                                                                                TransferRedox                    In Both Oxidation
                                                                                                                                                                                                              Evaporation        Classical
                                                      4
                                                4following         2Pb(NO,),>
                                                                    is                                 3, 8,                                                                        be     atmosphereH,SO,            of                                                        CHAPTER
                                               to to t                     +                                                                                                                                                                             solutions the
                                                + +4Cl
                                                                the  2HCI +                        of 8 3bsOsaa) +
                                                                                                                                                                               keptlosing            oxidation the                                                given
              structure                         4 4 change                                      the               a,                                                                  Reactions
                                                                                                                                                                                                        with following
                                                                             2Al     reaction?                                       b          the                                in                                                                             ofQR
                                                reaction?           ->                                                    and              +                                                                   NaOH           of and ldea               questlons, Code
                                                                                                                                                                                                                                                                                7
                                             ’CCl¡h                                  ’ following          cH)’2aCrad)                       given                          contact its              O, and H,0
                                                                 FeCl,
                                                                in            2KCl   2PbO                         c           are                                 concentration,                                                                                          for
                                  of                                                                                                                                                                                is
                                                                                                                                                                                               fromreduction Reduction     of
tribromooctaoxide (d)to+4(b) 0oxidation     Al,0,        Choose       (d) (b)found                                                              redox                (dAg
                                                                                                                                                                       ) (b)Al
                                                                                                                                                                            with           in                  redox Redox
                                +       H,1
                                             +2Cr + + +
                                                   30, 4NO, reactions                                                                                                                Terms          0,
                       4HC)                                                        to                         8,  1,3
                                                                                                              3,1 8,      reaction,
                                              to0                                             the                                   be                                                              by reaction?
                                              -4       number                                                                 t                                                          lightning                Reactions
                                                                                           +               respectivelybSOag)                                                  ZnCl,       of                Reactions
                                                                                       O,T right      is                                                                                      Electron
                                                              of                        option. the                                             t
                                        is                                                                                                                                    solution
                                    (2020)              carbon (2021)                            metal (2023)                                                     (1998)                                   (1997)                               -
                                                                         9.                          8.                                                                                     7.                                         Reactions
                                                                                                                                                                                                                                           Redox
                                  10,
balanced                                         correctThe                          (c+6  ) The
                                                                                       ) (a-6        (d)        (c)   (b)            (a)
                                                                                                                                     Select (iv)disproportionation      -Br-Br=0
                                                                                                                                                                 (i) Which   0-Br(d)
                                                                                                                                                                             O=Br-Br-Br--0(c)                                         (b)
equationare TheMnO,       +For (d) (c) (b) (a) order                                                                                               (ii) (ii) reactions?
                                                                                                               (i),     (i)                                                                                                            0=
        correct             the HNO,,HNO, HNO,,
                                                     of
                                                                                       oxidation (i),                                 (i) 2KMn0,
                                                                                                                                     2MnO0, + 3Mn0}2Cu’
                             NH,CI,                                                                            (iü)  and            and the                                                                                              Br
                          redoX                          oxidation                                 (ii)
              C,0,                                                                                                                  correct                                                 of                                            -
                                                                                                    and       and     (ii)           (iv)                                                                                       BrBr=0
                        NHC),
                         N, NO, NO, order
 coefficientsreaction,                                                                       state            (iii) only        only      3Mn²*                      +Cu'*
                                                                                                                                                                                        the
                    + NO, NH,C, N,                                                                   (iv)                                4H’2MnO,
                                                                                                                                     option
                H*’                    states of                                                     of                                                                       +
                     HNO,  NO,  N-compounds
                                 NH,CI                                                               Cr                                             K,M+nO,                  following
                                                                                                                  from
                                                                                                           2H,0’5MnO,                                                         Cu
                Mn*
                of             N, N,                     ) +12(b)
                                             is(Odisha (d+4                                          in
                                                                                              CrO,
              the                                                                                                                         the                +
                           +                                              NEET                       is               following.                           MnO,    +
    reactants CO,                                                                                                                                            MnO, reactions
                                                                        in
                           +                                          its                                                                                    +
                    H,0                                     decreasing 2019,                                                                                       +
                                                                                                                                                           + O,
                                                                                                                                                              2H,0
              for                                                                                    (2019)                                          4H"                                            (2019)
                                        (2018)                            2014)                                                                                                               are
              the
21.(a)       11.       1.
                                                            17.                                16.                                       15.                                             14.                         13.
                 (d) (b)                 (a) bromineWhich moles0.(c6moles          mole
                                                                                   Number
                                                                       ) 7.(a5) wilbe                                                                                                                                                                                                         12.                                                    HotI1.
                                                                                                              (c) (a)Oxidationthat                 oxidation
                                                                                                                                                   (cCI
                                                                                                                                                      )number?     which
                                                                                                                                                            (a) Ssulphuric                    A                                                                    (C+H,sO,0,
                                 Proton                                                                                                                                                      FeCl,,
                                                                                                                                                                                              SnCl,
                                                                                                                                                                                                  (c  ) SnCl,
                                                                                                                                                                                                         FeCl(a,
                                                                                                                                                                                                               )   The          (d )   (c)       (b)
                                                                                                                                                                                                                                            respetively   ( a)        Rol       e        ()     ()          (d)             (b) reaions
                                                                                                                                                                                                                                                                                                                                     (a) stong                      () (b)
        22. 12.          2.                   H,0                                       of                   -3, +3, of                                                       mixture
                                                                is                                                                                                                                               oxidizing
                                                                                                                                                                                                                  pair   reducing        oxidizing
                                                                                                                                                                                                                                   reducing                                   H,0,+
                                                                                                                                                                                                                                                                                 ot H.0, CaF,                                S+     ut
                                                    + in                       ferrous of +6 +6 Cr                                                             element                                                                                                                                                                                                             Mn),
                                                                                                                                                                                                                                                                                                                                                                                     c0,
      (d) 13.(c) (b)          acceptor Br, the the                                                         and     and             in                                                                                    of                               hydrogen                                2H,sO,S0,                           oNizing
                                                                                       moles                               numbers                                                                                                                                                                              +
                                                   ’ best
                                             reaction                                                                   Cr,0;
                                                                                                                                                                              acid ofcompounds
                                                                                                                                                                                                                                                                                H,S0,CasO,        + M,SO,CusO,                           does entrated
       23.              3.                                                     oxalate                         +6       +5                                             potassium                                                    in    in        in Ag,0’2Ag
                                                                                                                                                                                                                                                             in      0,’H0+
                                         HOBr                                                   of                                                       undergoes is
                                                                                                                                                                                                                                                           1)                                                                              not
                                    only description                                   MnO,                                               of
                                                                                                                                                                                                                                  (1) (1) (1) (peroxide
                                                                                                                                                                                                                                      and
      (c) (c) (c)                                                                                                              are                                    heated.                                                and               and      and                                                                             showagent.
                                                                                                                                                                                                                                                                                                                                             sulphui
                                                  given
                                                   + moles.0.(dmoles4)
                                                                        completely                                                             P
                                              HBr                         (b)
                                                                           0.2                         respectively
                                                                                                          (d)       (b)                                                                                                          1) (11)reducing
      24. 14,
                                                                                                                                           in (d) C(b) H chlorate, FeCl(HgCi,
                                                                                                                                                         maximum                                  dKI
                                                                                                                                                                                                    ),SnCl,(b) that (1oxidizing                                                                                                 osidizing
                                                                                                                                                                                                                                                                                                                         + Ibehaviour?
                         4                                                       required +5, +5, PO,,
                                                                                                                                                                                                                   can                                                           in         20,                   280,   21,0   + Whih
                                               below? of                                                                                                              During                                                                                                 the          +                     +                       +
     (d) (c) (c)                                          the                          in                    +6 +3                                                                                      together existis                                                            1,0                  2HF                       S(),             Acid
                                                                                                         and      and                      of                                    oxalic                                                            in        in    above                                                 +
                                              behaviour                         acidic to                                                                                                                                                      (II) (11)                                                        211,0 thetollowing      + of is
             15. 5.                                                                oxidize                                                inS                   change the                                                                                                             0,+ (NEET                                 21,0
                                                                                                             +6 +6
                                                                              medium                                                 SO,                                              acid                                                               reactions                                                                      oderately A
                                                              (2008)                               (2009)                                 (2012)                    reaction
             (d) ANSWER
                     (c) KEY                                                                                                                                               in                (2014)                     (2014)
                                                            of                             one                                        and                              the             and                                                                                                             2016) 1                                              (2018)
               16.      6.                                                                                                                                                                                                                                                       is
                                                                                                           24.                                                 23.                                                  22.
              (d) (b)                                                                                                                                                                                                                              21.                               20.                           19,
                                     (c)Br
                                        BrO;(a) Then                     corresponding theConsider                        7.4                                                                                                                                                                                                                                        18.                       moG
                                                                                                                                             (+7
                                                                                                                                              c) (a) +The H,0(c) (aH*                  ) 14H"following
                                                                                                                                                                                             reaction?thWhich
                                                                                                                                                                                                            e                                    The                        (a)
                                                                                                                                                                                                                           NO,(c) CO,(a) sulphateio(cn) Reaction                                    (a)
                                                                                                                                                                                                                                                                                                  Oxidation                                                                         () (b)
            17. 7.                                  the                            given                         Redox                          oxidation
                                                                                                                                                                                                                                                                                                                          () (c) (b) (a) S,0, lReduced              he onlOxidised
                                                                                                                                                                                                                                                                                                                                                                           (yd) onlyNEET-AIPMT
                                                                                                                                                           1                                      +                                        oxide,
                                                                                                                                                                                                                                              tetrathionate               io  n                     4         5
                                                                          BrO,                                                                                                                                                                                                                                          S,0, S,0; S0; S,0 oxidation                                    Both
           (b) (b)8.                         species              Br diagram                             the                                                                               Cr,0, substance                                                                                                                                                a nd
                                                                                                      Reactions                                                                                                                            which                                       of                                                                                       oxidised
                                                              1.0652 V          L change                                                                                                                                                                             sodium
           18.                                                                                     to                                                     state                    +3Ni-’                                                                                                           (b) state<S,0; <s,0, <S,0,                      <S,0,
                                  undergoing                                       diferent                                                                                                                                                                                                           5 4 of
                                                                                                                                                                                                                                                                                                                                  soS,0                         states               Chapterwine
                                                                                           :                                                                    of                                                     is              cannot
           (a) (c)                                      Bro;15V
                                                        -Bry                                                in                                                                                          serVing                                        thiosulphate                                                 Fe             $,0,            follow                                and
                                     (d)BrO,(b)                                         oxidation                      and                 (d)  5
                                                                                                                                                +   (b )  1
                                                                                                                                                          -
                                                                                                                                                                inI TH,0+2Cr*
                                                                                                                                                                          (d)Ni
                                                                                                                                                                                                                                                                                                                    in soso; <                                          of reduced
           19. 9.                                                                            emf                                                      HI0,                    Cr,(0b)                                                            act sulphide
                                                                                                                                                                                                                           SO,(d) ClO,(b) sulphite          io(n.d) i(b)on                          (c) Fe,0,                                            sulphur
                                                                                                                                                                                                                                                                                                                                                            the
                                 HBrO
                         disproportionation                  1.595 V                                  Electrode                                                                                                                                                                                                                                                                           Toplcwse
                                                                                                                                                                                                                     as                             as                                               2         3
           (d) (a)                                                                     values                                                                                                                           a                              a                                                              is                              order
                                                                                                     state                                                      is                                 reducing                        reducing                                      with
                                                                       HBrO                                                                                                                                                                                                                                                                                         thein
           20. 10.                                                                                                                                                                                +                                                                                                                                                                                    Solutions
                                                                                                   as of
                                                                                                        Processes                                                                             3N?                                                                        iodine                   (d)                                               anions
                                                                                         shown     in
                                                                                             bromine
             (a) (b              (2018)                                                                                                                                                                       agent                         agent                                                 3 8
                                                                                                                                    (1994)                         (1994)                                             (1995)                       (1996)                         give (199,                     (2009,                                           (2044%
                                                      is                                                                                                                                                            in                               is                                                                                                             s
  numbers.                                                                                        12.    So,Here,    2MnO,  10. 9.                                 +6
                                                                                                                                                                    +Cuo
                                                                                                                                                                     Cuz
                                                                                                                                       LetPeroxobonds. simultaneously.                           oidation
                                                                                                                                                                                                        the
                                                                                                                                                                                                   (b) 6. 5(c):                            is
                                                                                                                                                                                                                                        Sedes,
   Oxidation evolved. isH,O,                                                                                          11. CrO,:x+4(-1)                  3MnO+4H* 2Cut-’                                            cCL             known              ired 4.                 32Al ZnCl,whichaenZn lies(b) 2              AeacHons
                                                                                                                                                                                                                                                                                                                              Rodor
                                                                                                            it                        oxidation                                   samne
                                                                                                                                                                                                                                                                                                        involvbote ahnd
                                                                                               (c):         is the(d) (b): (a)                                  (c)                      (b): oxidation                                                    (c):Cr,Oe)               +
              Both reducing
                   © actsas                                                                             not                                   oxygen                                                                                        then with ic)                    3ZnCl      wil
                                                                                                                                                                    :                             number                   In              as When :
                                      H,0,+                               H,O,+         OIncreaseoxidation            : +The : +5
                                                                                                                                HNO,                       CrO,
                                                                                                                                                            element/compound
                                                                                                                                                                    Disproportionation metadisplacement.                                   more the
                                                                                                                                                                                                                                                                                                              : Redox
                                                                                                    redox
                                                                                                           a CaF, 5C,0,
                                                                                                                        correct                                                                                        CHp Cr0,2AI + ionsofa                                           displaconc.ce.
                                                                                                                                                                                                                                                                              decrease Oxidation  Only
             FeCl,
             SnCl,and                                     Increase                                                    +                     state has                                                    number
                                                              Decrease                               in H,S0,                           +2 +                 has                                               of                       active                     a 2AlCI,                                Al
                                                                                                                                                                                                                                                                                                      'reactions
                            Decrease        Ag,0          +1                             oxidation                         + NO, 1(-2) of -1                                                        carbonOXidation                                       metal
                         agent in                                                             reaction. state                                                            >                                                                                                    +      when
                                                                     in                                        16H*>  balanced             oxidation  butterfly2MnO,                                                                 metallower
                                                         oxidation           in                                                      N,          Cr                       +7                                          of                  metal
                                                                                                                      ’
                                                                                                                                                                                                                                                             3SOso+ + fromaboveZn'
                                        in                   oxidation                                         of                         =0 be                                                                in
                                                                                                                                                                                                           carbon                                          from                  3Zn keptZnCl,reduction are
                            oxidation                                                   ’ state everyCaS0,                    NH,CI -3                                                                      the number              displaces
                           both                                                                                        equation is                x structure            + reactions                                                ’                                                 'Al'in                    those
                   are                                           state           H,0      (reducing                  2Mn²*                   ’ state.               MnO,   +4        gets               given                      Hence,                     the
                                                     ’                   state              -2                                                                                                                                                      down               8H,         solution.
        reducing reactionsthe in              2Ag                                                         atom +                                                                                                       is Al,0, electrochemical                          aq)                                in
                                                                                                                                                                                                                                                                                                           chemical
                                    state                (reducing                                                                        x=                                                                       +4.                                                     container.
                                                                                        +                        2HF                                                          oxidised            reaction                   of                 the                              simultaneously.
                                                                                  202                                       +              +6                                                                                           the               in                 electrochemical
                                                     +                                        0agent)
                                                                                                      remains 10C0,                                      having 2H,0 +                       are               Thus,carbon           +                                         ’Therefore,
            agents
                                               H,0           agent)                                                                                                                      those
                                                                                                                                                                                                                                2Crcorrect less the                  2Crta
                                                                                                                                                                                                                                                                                      Explanations
                                                                                                                                                                                                                                                                                               Hints & reactions
                                                                                                                                                                                                                is            electrochenmical
                                                                                                                                                                                                                                          active
                                              +O2            0                                                                                                                        and                from the is
                                                                                                                            +                                 two                                                           -4 reaction
                with     which                                                                               the                                                                                 in change                                                                    +
                                                                                                                      8H,0                                                     reduced                         -4      while                  one, +4H,Ouseries3SOtag)
                                                                                                          same                                           peroxo                         which                   to                                                                           series, which
                   low           O,                                                                                                                                                                          +4. in in                         this
                                                                                                                                                                                                                                             is                   is
                                 HBrO positive 24. (4get                                                                                                or          or
         Egl            HBrOBr,;
                      2HBrO                                                     23. to 22.agent. +4, 21.                           19.
                                                                                                                         20. Oxidation                                                                      On 16.              oxidation
                                                                                                                                                                                                                                Let numberLet chlorine,
                                                                                                                                                                                                                                                      15.Maximum
                         E                                H=+land
                                                                x                          2,                                                            S,0 S,0: 18. 17.(b) mole l moles2MnO,2(C,0’                                                                                14.
                    cell                                                                      therefore,                                                                                           addition,
         >0        =     =                          (d): 1)               therefore
                                                                                 (c)          (d)                (a)
         1.595- SRP
                                                                                                                          (a) (d):                      2x          2x (a):         Number                           (oxidation
                                                                                                                                                                                                                      d) 2z y+ x+(d)                                                (c)
                                                    as +x
                                                                                                                       :                                 - :2x     -82x+                   of of
                                                                                                                                                                                                          +                    +
                                         > AG° For                                   :
                                                                               Let Since          :         Since             :                     12=                           oxalate                               :          4(-2)       4(-2) Let  :   i.e.,
         (cathode)
          AG                     BrO,;                          +                                                2Na,S,O, Fe,O,: states                                                       MnO, 16H*           2e(5e 7(-2)                                change             KCIÓ, :
                             Br,                           (6xoxidation           x=
                                                                                                                                                                + -2= (- SO{
                                                                                                                                                               (-                                           we                                             fronm
               1.5                                    = a                                  it carbon                                                   -2              2)4
          <0                     +           E= reaction                               acts the          carbon                                         2)6=        or
                                                                                                                                                                  :x+(-2)3                   =
                                                                                                                                                                                               of+5C,0 get + +number
                                                                                                                                                                                                             2C0,              =          =oxidation =
                   =                     E    -nFEO             -Oxidation                                                             follow
                                                                                                                                      3x                                                   required               MnO,                   -2         -3
ontaneous) 0.095          BrO;                                 2)                          as                                                           or 2x= =-2                        5
                                                                                                                                                                                        2/moles                               -2                                  +5 in                 +
                         -               =
                                         1.595 cell                              oxidation                               +1,                                                                                                                                               (COOH),
                                                                                                                                                                                                                                                                                H,SO,   +
                                                                = state                     a      dioxide                             +                       -2                            =                                                                     to
                   SRP              -15                         -          reducing                                   is        4(-2)        the        2x                                                                                                      -l.
                                                                                                                                                                                        0.4
                                                                                                                                                                                                          ...ii)] ’z=+ of ’ number oxidation
                   V                                     to 1                                                                                                       +6
                                                                                                                     in       ’          order            =                     =                                      8H Cry= of x=
             (anode)                                                        of
                                                                            state                     tetrathionate)
                                                                                                               (Sodium                                    +          ..
                                                                                                                                                                                                of to ’                                         S +5
                                        V,SRP V, be
                                                                                      number         (CO,)         its =0’x=+                           10                     -2            oxidise2Mn'           x                           in
                            (anode) SOP spontaneous,                         O                                                                                                                                           ’
                                                                                                                                                                                                                   5 +6 in +6SO,
                                                          N=+ 7 -2, = agent.                        maximum Na,S,O,                                : . x= or MnO,                                                   Mn*                                   of
                                  (cathode)                                          of                                                      S, 0                                                                               Cr,O
                                                                                     I.             cannot                                                          +3          x                      5  +                                                PnumberK,SO,
                                                              therefore Since                                                                     X=+5                     -6=                                                                            in
                                                                                                  of                                                                                                                      +               bey.
                                                                                                  Ni                                                                                requiredmoles10CO,                                                    PO
                                                                                                     oxidation
                                                                                                                               + 3 sO; <                                       -2                         4H,0..(i)]                 be                          occurs +
                                                                  oxidationincreases                      act                  2                                                                     of                              z.
                                                          E                                                               Nal                                                  or                          +                                              be                KCI
                                                                        for                                  as                                    <                                                 8H,
                                                                                                                                                                                              oxalate.  0                                                  x.
                                                                                                               a                                                                 x               to
                                                  Should                                                                                    S,0;                                 =                                                                                        inCO, +
                                                                  H1O;,                         reducing      state                                                              +                                         x
                                                                             state from                                                                                                                                                                              case
                                                                                                                                                                                 4 oxidise                                 2
                                                                         be
                                                                                                                                                                                                                                                                                                    +H,0
                                                                                              weof                   0          of                                                                                                                                                                  ot                                69